CN104743600A - Equipment for producing calcium chloride by using waste liquor - Google Patents

Equipment for producing calcium chloride by using waste liquor Download PDF

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Publication number
CN104743600A
CN104743600A CN201310747861.1A CN201310747861A CN104743600A CN 104743600 A CN104743600 A CN 104743600A CN 201310747861 A CN201310747861 A CN 201310747861A CN 104743600 A CN104743600 A CN 104743600A
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CN
China
Prior art keywords
pipe
waste liquid
motorized valve
waste liquor
waste
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310747861.1A
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Chinese (zh)
Inventor
陈鑫
刘勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TIANJIN CITY XINZE FINE CHEMICAL CO Ltd
Original Assignee
TIANJIN CITY XINZE FINE CHEMICAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TIANJIN CITY XINZE FINE CHEMICAL CO Ltd filed Critical TIANJIN CITY XINZE FINE CHEMICAL CO Ltd
Priority to CN201310747861.1A priority Critical patent/CN104743600A/en
Publication of CN104743600A publication Critical patent/CN104743600A/en
Pending legal-status Critical Current

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Abstract

The invention belongs to the technical field of waste liquor treatment equipment, and in particular relates to equipment for producing calcium chloride by using waste liquor. The equipment comprises a waste liquor reaction kettle, a waste gas recycling kettle, a pH detector, a controller, a gas inlet pipe, an exhaust pipe, a liquid level sensor, a feed pipe electrically operated valve and an ejector, wherein the side of the waste liquor reaction kettle is provided with a waste liquor feed pipe, the top of the waste liquor reaction kettle is provided with an acid liquor pipe and an alkali liquor pipe, and the bottom of the waste liquor reaction kettle is provided with a discharge pipe; the liquid level sensor is arranged in the waste liquor reaction kettle and connected with an input end of the controller; the exhaust pipe is arranged to communicate the waste liquor reaction kettle and the waste gas recycling kettle, chlorine produced in the waste liquor kettle in the reaction process is absorbed by using the calcium hydroxide slurry in the waste gas reaction kettle, chlorine is recycled, the production cost is greatly reduced, and the environment pollution is reduced; a circulating pump is arranged between the waste gas recycling kettle and ejector, the slurry is circulated to absorb chlorine.

Description

A kind of equipment utilizing waste liquid to produce calcium chloride
Technical field
The invention belongs to technical field of waste liquid treatment equipment, particularly relate to a kind of equipment utilizing waste liquid to produce calcium chloride.
Background technology
Losantin also claims chlorinated lime, is often applied to the bleaching process in Chemical Manufacture, due to its fast can onset and bleaching remarkably productive and occupy vital role in the industrial production.To be that calcium hydroxide and chlorine are counter generate Losantin to the reaction principle of Losantin, and with the generation of calcium chloride, react after follow-up separation of coming, a large amount of waste liquid can be produced, usually often produce 1 ton of Losantin and can produce 6 tons of waste liquids, the waste liquid main component produced is Losantin, calcium chloride is calcareous with other, and be dissolved with a certain amount of chlorine wherein, because Losantin and chlorine all have corrodibility, direct discharge can cause serious environmental pollution, by process Losantin waste liquid, Losantin can be converted into calcium chloride, 6 tons of waste liquids can reclaim the calcium chloride of preparation 2 ton 96%, there is huge economic benefit, and reduce the discharge fee of waste water, but at present not about the relevant device processed Losantin waste liquid.
Summary of the invention
For solving the problem, the invention provides a kind of equipment utilizing waste liquid to produce calcium chloride, comprise waste liquid reactor, the crown center of described waste liquid reactor is provided with stir shaft, the lower end of described stir shaft is connected with paddle, characterized by further comprising waste gas recovery still, pH detector, controller and injector, described waste gas recovery still is connected by pipeline with between injector, and described pipeline is provided with recycle pump; The probe of described pH detector is arranged in described waste liquid reactor; Described waste liquid reactor is provided with inlet pipe and vapor pipe; Described vapor pipe is connected with described waste gas recovery still; The side of described waste liquid reactor is provided with waste liquid feed-pipe, and top is provided with acid solution pipe, alkali liquor pipe, and bottom is provided with discharge nozzle; Described acid solution pipe, alkali liquor pipe and discharge nozzle are respectively equipped with acid solution motorized valve, alkali lye motorized valve and discharging motorized valve; Described alkali lye motorized valve, acid solution motorized valve are all connected with the output terminal of described controller with discharging motorized valve.
Also comprise liquid level sensor and feed-pipe motorized valve, described liquid level sensor is arranged in described waste liquid reactor, and is connected with the input terminus of described controller; Described feed-pipe motorized valve is arranged on described waste liquid feed-pipe, and described feed-pipe motorized valve is connected with described controller output end.
Beneficial effect of the present invention is: due to the chlorine produced in reaction process, by arranging vapor pipe by waste liquid reactor and waste gas recovery still UNICOM, the chlorine produced in waste liquid still is absorbed by the calcium hydroxide slip in waste gas recovery still, the recovery achieving chlorine uses, greatly reduce production cost, decrease environmental pollution; Adopt and arrange recycle pump between waste gas recovery still and injector, in the working cycle of slurries, make the top of waste gas recovery still form negative pressure, chlorine is inhaled into waste gas recovery still, and the slurries be recycled absorb; By arranging the motorized valve in pH detector, controller and each pipeline, realizing Mechanical course, making endpoint determination accurate, easy to operate; By arranging liquid level sensor in waste liquid reactor, control the liquid level in waste liquid reactor; The disposable Losantin that completes of the present invention is converted into calcium chloride, the absorption of chlorine and the adjustment of solution ph, directly generates the liquid calcium chloride of 33%, makes the contaminative of the liquid of discharge to environment less.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention.
Embodiment
Below in conjunction with accompanying drawing, explanation is further explained to the present invention.
In figure, 1, waste liquid reactor, 2, stir shaft, 3, paddle, 4, waste gas recovery still, 5, pH detector, 6, controller, 7, inlet pipe, 8, vapor pipe, 9, recycle pump, 10, waste liquid feed-pipe, 11, acid solution pipe, 12, alkali liquor pipe, 13, discharge nozzle, 14, acid solution motorized valve, 15, alkali lye motorized valve, 16, discharging motorized valve, 17, liquid level sensor, 18, feed-pipe motorized valve, 19, injector.
As shown in Figure 1, a kind of equipment utilizing waste liquid to produce calcium chloride provided by the present invention, comprise waste liquid reactor 1, waste gas recovery still 4, pH detector 5, controller 6, inlet pipe 7, vapor pipe 8, liquid level sensor 17, feed-pipe motorized valve 18 and injector 19, the crown center of waste liquid reactor 1 is provided with stir shaft 2, the lower end of stir shaft 2 is connected with paddle 3, connected by pipeline between waste gas recovery still 4 and injector 19, and on pipeline, be provided with recycle pump 9; The probe of pH detector 5 is arranged in waste liquid reactor 1; Inlet pipe 7 and vapor pipe 8 are arranged on the top of waste liquid reactor 1; Vapor pipe 8 is connected with waste gas recovery still 4; The side of waste liquid reactor 1 is provided with waste liquid feed-pipe 10, and top is provided with acid solution pipe 11, alkali liquor pipe 12, and bottom is provided with discharge nozzle 13; Acid solution pipe 11, alkali liquor pipe 12 and discharge nozzle 13 are respectively equipped with acid solution motorized valve 14, alkali lye motorized valve 15 and discharging motorized valve 16; Alkali lye motorized valve 15, acid solution motorized valve 14 are all connected with the output terminal of controller 6 with discharging motorized valve 16, and liquid level sensor 17 is arranged in waste liquid reactor 1, and are connected with the input terminus of controller 6; Feed-pipe motorized valve 16 is arranged on waste liquid feed-pipe 10, and feed-pipe motorized valve 18 is connected with controller 6 output terminal.
Above one embodiment of the present of invention have been described in detail, but described content being only preferred embodiment of the present invention, can not being considered to for limiting practical range of the present invention.All equalizations done according to the present patent application scope change and improve, and all should belong within patent covering scope of the present invention.

Claims (2)

1. the equipment utilizing waste liquid to produce calcium chloride, comprise waste liquid reactor, the crown center of described waste liquid reactor is provided with stir shaft, the lower end of described stir shaft is connected with paddle, characterized by further comprising waste gas recovery still, pH detector, controller and injector, described waste gas recovery still is connected by pipeline with between injector, and described pipeline is provided with recycle pump; The probe of described pH detector is arranged in described waste liquid reactor; Described waste liquid reactor is provided with inlet pipe and vapor pipe; Described vapor pipe is connected with described waste gas recovery still; The side of described waste liquid reactor is provided with waste liquid feed-pipe, and top is provided with acid solution pipe, alkali liquor pipe, and bottom is provided with discharge nozzle; Described acid solution pipe, alkali liquor pipe and discharge nozzle are respectively equipped with acid solution motorized valve, alkali lye motorized valve and discharging motorized valve; Described alkali lye motorized valve, acid solution motorized valve are all connected with the output terminal of described controller with discharging motorized valve.
2. a kind of equipment utilizing waste liquid to produce calcium chloride according to claim 1, characterized by further comprising liquid level sensor and feed-pipe motorized valve, described liquid level sensor is arranged in described waste liquid reactor, and is connected with the input terminus of described controller; Described feed-pipe motorized valve is arranged on described waste liquid feed-pipe, and described feed-pipe motorized valve is connected with described controller output end.
CN201310747861.1A 2013-12-31 2013-12-31 Equipment for producing calcium chloride by using waste liquor Pending CN104743600A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310747861.1A CN104743600A (en) 2013-12-31 2013-12-31 Equipment for producing calcium chloride by using waste liquor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310747861.1A CN104743600A (en) 2013-12-31 2013-12-31 Equipment for producing calcium chloride by using waste liquor

Publications (1)

Publication Number Publication Date
CN104743600A true CN104743600A (en) 2015-07-01

Family

ID=53583974

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310747861.1A Pending CN104743600A (en) 2013-12-31 2013-12-31 Equipment for producing calcium chloride by using waste liquor

Country Status (1)

Country Link
CN (1) CN104743600A (en)

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C06 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150701

WD01 Invention patent application deemed withdrawn after publication