CN104738805A - Method for manufacturing reconstituted tobacco paper base with apocynum venetum and obtained reconstituted tobacco paper base - Google Patents
Method for manufacturing reconstituted tobacco paper base with apocynum venetum and obtained reconstituted tobacco paper base Download PDFInfo
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- CN104738805A CN104738805A CN201510047844.6A CN201510047844A CN104738805A CN 104738805 A CN104738805 A CN 104738805A CN 201510047844 A CN201510047844 A CN 201510047844A CN 104738805 A CN104738805 A CN 104738805A
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- reconstituted tobacco
- tobacco paper
- paper substrate
- apocynum fibre
- paper base
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B3/00—Preparing tobacco in the factory
- A24B3/14—Forming reconstituted tobacco products, e.g. wrapper materials, sheets, imitation leaves, rods, cakes; Forms of such products
Abstract
The invention discloses a method for manufacturing a reconstituted tobacco paper base with apocynum venetum and the obtained reconstituted tobacco paper base. The method for manufacturing the reconstituted tobacco paper base with the apocynum venetum comprises the steps of cut tobacco rolling, digestion, pulp grinding and sheet making. A key process for manufacturing the reconstituted tobacco paper base is accurately determined according to apocynum venetum fiber raw materials, the obtained reconstituted tobacco paper base is applied to cigarettes obtained through production manufacturing, and the advantages of being high in smoke concentration, fine and smooth in smoke, good in note expression, good in comfort degree of the oral cavity and the like are achieved. The tar release amount, the total particle matter and the carbon monoxide release amount of the reconstituted tobacco paper base are lowered, the advantages are achieved in reducing tar and harmful components, and a novel simple easily-obtained excellent raw material is provided for production of reconstituted tobacco.
Description
Technical field
The present invention relates to technical field of tobacco, more specifically, relate to preparation method and the gained reconstituted tobacco paper substrate of apocynum fibre reconstituted tobacco paper substrate.
Background technology
In recent years, people are devoted to the research of reconstituted tobacco production technology always, and obtain certain effect.Reconstituted tobacco (Reconstituted Tobacco), also known as reconstituted tobacoo, homogeneous tobacco leaf or recombination tobacco leaf, have Filling power high, have good burning performance, the characteristic such as releasing content of coke tar decreases, substitute with reconstituted tobacco or pipe tobacco that Some substitute is traditional to prepare cigarette be one of effective means of Tar.
For saving tobacco leaf resource, research adopts discarded cheap fibre resources, prepare colory reconstituted tobacco to substitute or Some substitute tobacco leaf, this can not only reducing tar and reducing harm, society can also be promoted to economize on resources and all there is considerable meaning the aspect such as sustainable development that maintains environment.
Bluish dogbane is Apocynaceae herbaceos perennial, and formal name used at school Apocynuml, relieves inflammation or internal heat, step-down, cardiac stimulant, and the effects such as heart disease are controlled in diuresis.Folium Apocyni Veneti, not containing nicotine, is harmful to human health, so can not produce the health problem that caused by nicotine and the dependence to nicotine.But way current is at present plucked by Folium Apocyni Veneti to dry rear direct use, although processing technology is simple, but also there is mouthfeel bitterness, the blue foreign smell technical problem such as heavily when sucking in rough machined bluish dogbane leaf, the performances such as burning are also difficult to be guaranteed and are not easy to realize volume production, make it can not get popularizing within a very long time.
Bluish dogbane is as wild string resource, main product in Xinjiang, Qinghai, Gansu, the province such as Ningxia, due to the particularity of its growth region, be separated pulp making operations more difficult, to bluish dogbane string carry out the research in pulping and paper-making report less, be applied to by apocynum fibre and prepare reconstituted tobacco, referential correlation technique is less, for apocynum fibre technology and determine the governing factor research of sense organ interior quality have no correlation technique report.
Summary of the invention
The technical problem to be solved in the present invention is preparing the technical deficiency in reconstituted tobacco paper substrate for bluish dogbane, provides a kind of preparation method of bluish dogbane reconstituted tobacco paper substrate.
A present invention also technical problem that will solve is to provide bluish dogbane reconstituted tobacco paper substrate.
Object of the present invention is achieved by the following technical programs:
Bluish dogbane is provided to prepare the application in reconstituted tobacco paper substrate, be applied to improve reconstituted tobacco paper substrate flammability, improve note and/or reducing tar and reducing harm aspect, specifically the waste of flax thread rolling of spreading out of drying is obtained apocynum fibre, the filter residue defibrination of acquisition will be filtered after the lixiviate of apocynum fibre science, gained apocynum fibre slurry handsheet is obtained reconstituted tobacco paper substrate.
Particularly, the preparation method of described bluish dogbane reconstituted tobacco paper substrate comprises the following steps:
S1. thread rolling: the waste of flax thread rolling of spreading out of drying is obtained apocynum fibre;
S2. lixiviate apocynum fibre: be that 1:12 ~ 20 add water by liquor ratio in described apocynum fibre, be placed in the isoperibol soak extraction 30 ~ 120min of 70 DEG C, filters, gets apocynum fibre slag;
S3. defibrination: by the apocynum fibre sizing slurry after lixiviate;
S4. handsheet, obtains reconstituted tobacco paper substrate after drying.
Preferably, described in S1, the concentration of thread rolling is about 5%.
Preferably, lixiviate apocynum fibre described in S2 step is that 1:20 adds water by liquor ratio in described apocynum fibre, is placed in the isoperibol soak extraction 60min of 70 DEG C, filters, get apocynum fibre slag.
Preferably, defibrination described in S3 step adopts two sections of defibrinations, and the grinding clearance of first paragraph and second segment defibrination is respectively 0.4mm and 0.2mm, and the mill of defibrination is K dish.
Preferably, the apocynum fibre after defibrination is quantitatively 60g/m according to copying
2the scraps of paper are also dry.Baking temperature 105 DEG C, drying time 10min, vacuum 0.08MPa.Paper substrate processes 24h at relative humidity 50 ± 2% and temperature 23 ± 1 DEG C.
The present invention provides the bluish dogbane reconstituted tobacco prepared paper substrate simultaneously, and the bluish dogbane reconstituted tobacco paper substrate of gained is the reconstituted tobacco that raw material prepares.
Beneficial effect of the present invention:
The present invention is directed to bluish dogbane summary and obtain accurate extracting technology, under described extracting technology operation, the constituents extraction of the unfavorable cigarette in bluish dogbane is out separately dealt with filtrate, the apocynum fibre obtained is through science defibrination, the reconstituted tobacco paper substrate that handsheet technique prepares, combustibility is good, be applied to production of cigarettes, produce the cigarette smoke concentration obtained higher, flue gas is finer and smoother, note performance better, comfort level is better, time sweet sense in oral cavity is more obvious, and its releasing content of coke tar, TPM, puff number and carbon monoxide release amount lower, there is certain advantage in reducing tar and reducing harm.
The present invention is that the production of reconstituted tobacco provides a kind of quality raw materials simple and easy to get newly.
Detailed description of the invention
Further describe the present invention below in conjunction with specific embodiment, the equipment that in the embodiment of the present invention, thread rolling adopts is east, Dandong light industry and machinery company DFB φ 150 kneading or grinding leaser; Equipment during defibrination is KRK-2500 II refining system, and the mill of defibrination is K dish; Handsheet adopts Austria to produce the quick handshcet former of PTI; But therefore do not limit the scope of the equipment such as thread rolling, defibrination that the present invention uses.Unless stated otherwise, the reagent that adopts of the present invention and raw material are the conventional commercial reagent in this area and raw material.
Embodiment 1
S1 thread rolling: drying spreaded out waste of flax thread rolling; The concentration of thread rolling is about 5%.
S2. lixiviate: by the apocynum fibre after thread rolling and water in mass ratio 1:12 be placed in the isoperibol soak extraction 30min of 70 DEG C, filter, get apocynum fibre slag;
S3 defibrination: the apocynum fibre sizing slurry after lixiviate; Adopt two sections of defibrinations, grinding clearance is respectively 0.4mm and 0.2mm;
S4 handsheet, obtains reconstituted tobacco paper substrate after drying.
After slurry in proportion after defibrination prepares, be quantitatively 60g/m according to copying
2the scraps of paper are also dry.Baking temperature 105 DEG C, drying time 10min, vacuum 0.08MPa.Paper substrate processes 24h at relative humidity 50 ± 2% and temperature 23 ± 1 DEG C, then measures the different paper substrate performance indications prepared.
Embodiment 2
S1 thread rolling: drying spreaded out waste of flax thread rolling; The concentration of thread rolling is about 5%.
S2 lixiviate: by the apocynum fibre after thread rolling and water in mass ratio 1:20 be placed in the isoperibol soak extraction 30min of 70 DEG C, filter, get apocynum fibre slag;
S3 defibrination: the apocynum fibre sizing slurry after lixiviate; Adopt two sections of defibrinations, grinding clearance is respectively 0.4mm and 0.2mm;
S4 handsheet: obtain reconstituted tobacco paper substrate after drying.
After slurry in proportion after defibrination prepares, be quantitatively 60g/m according to copying
2the scraps of paper are also dry.Baking temperature 105 DEG C, drying time 10min, vacuum 0.08MPa.Process 24h at paper substrate relative humidity 50 ± 2% and temperature 23 ± 1 DEG C, then measure the different paper substrate performance indications prepared.
Embodiment 3
S1 thread rolling: drying spreaded out waste of flax thread rolling, with embodiment 1;
S2 lixiviate: by the apocynum fibre after thread rolling and water in mass ratio 1:20 be placed in the isoperibol soak extraction 60min of 70 DEG C, filter, get apocynum fibre slag;
S3 defibrination: the apocynum fibre sizing slurry after lixiviate; Adopt two sections of defibrinations, grinding clearance is respectively 0.4mm and 0.2mm;
S4 handsheet, obtains reconstituted tobacco paper substrate after drying.After slurry in proportion after defibrination prepares, be quantitatively 60g/m according to copying
2the scraps of paper are also dry.Baking temperature 105 DEG C, drying time 10min, vacuum 0.08MPa.Process 24h at paper substrate relative humidity 50 ± 2% and temperature 23 ± 1 DEG C, then measure the different paper substrate performance indications prepared.
The present embodiment bluish dogbane reconstituted tobacco paper substrate physical property testing result is as shown in table 1:
Table 1 physical property testing result
Project | Numerical value |
Quantitatively (g/m 2) | 63.60 |
Thickness (mm) | 0.39 |
Tightness (g/cm 3) | 0.16 |
Tensile strength (N/m) | 368.56 |
Tearability (mN) | 69.70 |
Tear index (mN.m 2/g) | 1.10 |
From table 1 testing result, bluish dogbane reconstituted tobacco paper substrate physical property detected parameters meets the demand of daily production.
Embodiment 4
S1 thread rolling: drying spreaded out waste of flax thread rolling, by the offal thread rolling of drying, thread rolling concentration is with embodiment 1;
S2 spreads out waste of flax lixiviate: by the apocynum fibre after thread rolling and water in mass ratio 1:20 be placed in the isoperibol soak extraction 60min of 70 DEG C, filter, get apocynum fibre slag;
Offal lixiviate: offal is added water according to liquor ratio 1:6, soak extraction 100min in the isoperibol of 60 DEG C, filters, gets offal slag;
S3 defibrination: respectively by apocynum fibre slag and offal sizing slurry, technique is employing two sections of defibrinations, and grinding clearance is respectively 0.4mm and 0.2mm;
The rear handsheet of mass ratio mixing of 1:1 pressed by apocynum fibre slurry and offal slurry by S4, obtains reconstituted tobacco paper substrate, with embodiment 1 after drying.
The reconstituted tobacco paper substrate physical property testing result of the present embodiment bluish dogbane and offal mixture is as shown in table 2:
Table 2 physical property testing result
Project | Numerical value |
Quantitatively (g/m 2) | 61.80 |
Thickness (mm) | 0.35 |
Tightness (g/cm 3) | 0.19 |
Tensile strength (N/m) | 354.89 |
Tearability (mN) | 65.60 |
Tear index (mN.m 2/g) | 1.06 |
From table 2 testing result, the reconstituted tobacco paper substrate physical property detected parameters of bluish dogbane and offal mixture meets the demand of daily production.
Embodiment 5
S1 thread rolling: drying spreaded out waste of flax thread rolling, by the offal thread rolling of drying;
S2 spreads out waste of flax lixiviate: by the apocynum fibre after thread rolling and water in mass ratio 1:20 be placed in the isoperibol soak extraction 60min of 70 DEG C, filter, get apocynum fibre slag;
Offal lixiviate: offal is added water according to liquor ratio 1:6, soak extraction 100min in the isoperibol of 60 DEG C, filters, gets offal slag;
S3 defibrination: respectively by apocynum fibre slag and offal sizing slurry, defibrination condition is with embodiment 4;
The rear handsheet of mass ratio mixing of 1:1 pressed by apocynum fibre slurry and offal slurry by S4, and obtain reconstituted tobacco paper substrate after drying, handsheet and drying process condition are with embodiment 1.
Embodiment 6
S1 thread rolling: drying spreaded out waste of flax thread rolling, by the offal thread rolling of drying;
S2 spreads out waste of flax lixiviate: by the apocynum fibre after thread rolling and water in mass ratio 1:20 be placed in the isoperibol soak extraction 120min of 70 DEG C, filter, get apocynum fibre slag;
Offal lixiviate: offal is added water according to liquor ratio 1:6, soak extraction 100min in the isoperibol of 60 DEG C, filters, gets offal slag;
S3 defibrination: respectively by apocynum fibre slag and offal sizing slurry;
The rear handsheet of mass ratio mixing of 1:1 pressed by apocynum fibre slurry and offal slurry by S4, obtains reconstituted tobacco paper substrate after drying.
Embodiment 7 bluish dogbane reconstituted tobacco paper substrate sample is smoked panel test test
In Example 1 ~ 6, each 50g of gained reconstituted tobacco paper substrate sample, is numbered 1
#~ 6
#, chopping respectively, carries out craft with k-A chimney and rolls, often prop up in cigarette and add reconstituted tobacco paper substrate silk 0.6g, roll, obtain often kind of sample cigarette each ten; Set up and be numbered 7
#contrast sample, described 7
#contrast sample pipe tobacco is expanded cut stem.Rolled cigarette is smoked panel test through row by ten professional members of smoking.Smoking result is as follows:
1
#: flue gas concentration is higher, note still can, wooden breath is slightly revealed, and oral cavity is micro-to be had stimulates and residual, and comfort level can.
2
#: flue gas concentration is slightly low, compared with 1
#decline to some extent, note still can, oral cavity is micro-to be had stimulates and residual, comfort level can, oral cavity is micro-Hui Tian.
3
#: flue gas concentration is high, and texture is good, and the stimulation in oral cavity is compared with 1
#, 2
#little, comfort level is compared with 1
#, 2
#promote, time sweet sense in oral cavity is obvious.
4
#: flue gas concentration is slightly low, and the stimulation in oral cavity is less, but lingual surface is residual slightly large, and oral cavity is micro-Hui Tian, and comfort level can.
5
#: flue gas concentration is moderate, and note is some muddiness a little, and the stimulation in oral cavity is less, has residual a little, and oral cavity comfort level can.
6
#: flue gas concentration is moderate, and note is more clear, and the stimulation in oral cavity is less, has residual a little, and oral cavity comfort level can.
7
#: flue gas concentration is moderate, and flue gas is more coarse, and wooden breath is comparatively obvious, assorted gas and dried-up breath heavier, oral cavity residual comparatively large, comfort level is poor.
Smoking result shows:
Pure apocynum fiber reconstituted tobacco paper substrate (1
#, 2
#, 3
#, 4
#), after carrying out sensory evaluating smoking by manual sample preparation, entirety is felt as: flue gas concentration is higher, and flue gas is finer and smoother, and better, comfort level is better in note performance, and time sweet sense in oral cavity is comparatively obvious, and 3
#it is relatively good sample; The burning velocity of pure apocynum fiber reconstituted tobacco paper substrate is very fast, and flammability is better.
Apocynum fibre and tobacco stalk fibre mixing reconstituted tobacco paper substrate (5 processed
#, 6
#), after carrying out sensory evaluating smoking by manual sample preparation, entirety is felt as: flue gas concentration is moderate, and flue gas is finer and smoother, and oral cavity comfort level still can; Burning velocity when aspirating after apocynum fibre and tobacco stalk fibre mixing is slightly slower than pure apocynum fiber, but more desirable than the combustibility of offal reconstituted tobacco.
Pure apocynum fiber reconstituted tobacco paper substrate (1
#, 2
#, 3
#, 4
#) and apocynum fibre and tobacco stalk fibre mixing reconstituted tobacco paper substrate (5 processed
#, 6
#) at smoke behavior, reduce in assorted gas, raising oral cavity comfort level all than expanded cut stem (7
#) be significantly improved.
Embodiment 8 bluish dogbane reconstituted tobacco paper substrate is mixed and is joined " double happiness is classical " cigarette leaf group laboratory sample sensory evaluating smoking test
The present embodiment is described for following 4 samples:
8
#: " double happiness is classical " perfuming frontal lobe group (taking from Guangzhou cigar mill production line 2014.05.12 day);
9
#: 10%3
#bluish dogbane reconstituted tobacco paper substrate handsheet is mixed join through chopping and 90% " double happiness is classical " perfuming frontal lobe group;
10
#: " double happiness is classical " perfuming posterior lobe group (taking from Guangzhou cigar mill production line 2014.05.12 day);
11
#: 10%3
#bluish dogbane reconstituted tobacco paper substrate handsheet is mixed join through chopping and 90% " double happiness is classical " perfuming posterior lobe group;
Wherein, 3
#bluish dogbane reconstituted tobacco paper substrate handsheet to adopt described in embodiment 33
#the paper substrate that sample preparation methods is obtained;
8
#with 9
#be one group of sample, carry out contrast and smoke panel test; 10
#with 11
#be one group of sample, adopt that k-A chimney is manual to be rolled, then carry out contrast and smoke panel test.
Smoking result:
9
#with 8
#relatively: flue gas concentration remains unchanged, and note is harmony comparatively, and micro-have apocynum fibre breath, and perfume quantity is slightly low, thoroughly send out slightly weak, but definition slightly improves, the sweet sense in oral cavity is relatively better.
11
#with 10
#relatively: flue gas concentration remains unchanged, and note is harmony comparatively, and micro-have apocynum fibre breath, and perfume quantity is slightly low, thoroughly send out slightly weak, the sweet sense in oral cavity is relatively better.
Add 10%3
#apocynum fibre reconstituted tobacco paper substrate is in " double happiness is classical " forward and backward leaf group of perfuming, the flue gas concentration of leaf group remains unchanged, note is harmony comparatively, and without obvious change in comfort level, apocynum fibre reconstituted tobacco paper substrate is better with the compatibility of " double happiness is classical " perfuming forward and backward leaf group.Wherein, " double happiness classical " perfuming frontal lobe group and perfuming posterior lobe group only based on the citing of leaf group.Adopt leaf group based on other leaf groups, after adding apocynum fibre reconstituted tobacco paper substrate, sum up and find that compatibility is better.
The detection analysis of embodiment 9 bluish dogbane reconstituted tobacco paper substrate
With bluish dogbane reconstituted tobacco paper substrate in embodiment 3, (described paper substrate is numbered 3 to the present embodiment in embodiment 7
#) carried out flue gas conventional analysis detection and physical property for example and detect explanation.
3
#bluish dogbane reconstituted tobacco paper substrate and allocate flue gas conventional index testing result of " double happiness classical " Ye Zuzhong and other reconstituted tobacco paper substrates into flue gas conventional analysis result respectively as shown in Table 3 and Table 4.
Table 3 bluish dogbane paper substrate flue gas conventional index testing result
* (1) 10%3
#mix in apocynum fibre paper substrate: 10%3
#apocynum fibre paper substrate and 90% " double happiness is classical " perfuming posterior lobe group is mixed and is joined; (2) chimney is K-A chimney.
Random selecting Guangzhou cigar mill produces paper substrate A, the paper substrate B of existing use, paper substrate C testing result is as follows:
Table 4 reconstituted tobacco paper substrate flue gas conventional index testing result
Note: table 4 data are 2013.06.05 sample presentation.
From the result that table 3 and table 4 contrast, in releasing content of coke tar, TPM, puff number and carbon monoxide release amount, 3
#bluish dogbane reconstituted tobacco paper substrate and 10%3
#the numerical value of the indices of apocynum fibre paper substrate is all lower, therefore in reducing tar and reducing harm, has advantage.
Embodiment 10 paper substrate is applied to the Indexs measure preparing reconstituted tobacco gained reconstituted tobacco
The reconstituted tobacco physical index that the bluish dogbane prepare random a collection of employing the inventive method and offal mixture prepare detects, and average result is as shown in table 5:
Table 5 physical property testing result
Project | Numerical value |
Quantitatively (g/m 2) | 63.60 |
Thickness (mm) | 0.39 |
Tightness (g/cm 3) | 0.16 |
Bulk (cm 3/g) | 6.13 |
Tensile strength (N/m) | 368.56 |
Radius (cm) | 10 |
Experiment finds, the bulk of the reconstituted tobacco that the inventive method prepares is desirable, has good absorbability, be conducive to the production of cigarette product to feed liquid.Carry out sensory evaluation, the general perfume quantity of the reconstituted tobacco that the inventive method prepares is comparatively sufficient, and cigarette perfume is coordinated, and assorted gas is less, returns sweet obvious.
Claims (7)
1. the preparation method of bluish dogbane reconstituted tobacco paper substrate, is characterized in that, comprises the following steps:
S1. thread rolling: the waste of flax thread rolling of spreading out of drying is obtained apocynum fibre;
The process conditions of described thread rolling are:
S2. lixiviate apocynum fibre: be that 1:12 ~ 20 add water by liquor ratio in described apocynum fibre, be placed in the isoperibol soak extraction 30 ~ 120min of 70 DEG C, filters, gets apocynum fibre slag;
S3. defibrination: by the apocynum fibre sizing slurry after lixiviate;
S4. handsheet, obtains reconstituted tobacco paper substrate after drying.
2. the preparation method of bluish dogbane reconstituted tobacco paper substrate according to claim 1, it is characterized in that, the concentration of thread rolling described in S1 is 5%.
3. the preparation method of bluish dogbane reconstituted tobacco paper substrate according to claim 1, it is characterized in that, the described process conditions by apocynum fibre lixiviate are: be that 1:20 adds water by liquor ratio in described apocynum fibre, be placed in the isoperibol soak extraction 60min of 70 DEG C.
4. the preparation method of bluish dogbane reconstituted tobacco paper substrate according to claim 1, it is characterized in that, copying of handsheet described in S4 is quantitatively 60 g/m
2.
5. the preparation method of bluish dogbane reconstituted tobacco paper substrate according to claim 1, is characterized in that, temperature 105 DEG C dry described in S4, dry time 10 min, dry vacuum 0.08MPa.
6. the bluish dogbane reconstituted tobacco paper substrate of the application gained described in any one of claim 1 to 5.
7. described in claim 6, bluish dogbane reconstituted tobacco paper substrate is the reconstituted tobacco that raw material prepares.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110771944A (en) * | 2019-11-07 | 2020-02-11 | 南百慧 | Apocynum venetum health-care cigarette and preparation method thereof |
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CN85101482A (en) * | 1985-04-01 | 1986-08-20 | 北京卷烟厂 | Tobacco composition and preparation method thereof |
CN102217783A (en) * | 2010-04-15 | 2011-10-19 | 厦门中海钓台生物工程有限公司 | Thin sheet for cigarette, preparation method thereof and cigarette |
CN103211288A (en) * | 2013-02-07 | 2013-07-24 | 赵鸿 | Tobacco slice and cigarette |
CN103371431A (en) * | 2012-04-28 | 2013-10-30 | 南百慧 | Apocynum venetum health-care cigarettes |
CN104068463A (en) * | 2014-07-15 | 2014-10-01 | 安徽中烟再造烟叶科技有限责任公司 | Method for preparing tobacco sheet with cane shoot leaves |
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US4270552A (en) * | 1977-10-04 | 1981-06-02 | Brown & Williamson Tobacco Corporation | Process and apparatus for producing paper reconstituted tobacco |
CN85101482A (en) * | 1985-04-01 | 1986-08-20 | 北京卷烟厂 | Tobacco composition and preparation method thereof |
CN102217783A (en) * | 2010-04-15 | 2011-10-19 | 厦门中海钓台生物工程有限公司 | Thin sheet for cigarette, preparation method thereof and cigarette |
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CN110771944A (en) * | 2019-11-07 | 2020-02-11 | 南百慧 | Apocynum venetum health-care cigarette and preparation method thereof |
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Application publication date: 20150701 |