CN104725060A - High-strength refractory castable taking secondary guimo brick as aggregate - Google Patents

High-strength refractory castable taking secondary guimo brick as aggregate Download PDF

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Publication number
CN104725060A
CN104725060A CN201510114449.5A CN201510114449A CN104725060A CN 104725060 A CN104725060 A CN 104725060A CN 201510114449 A CN201510114449 A CN 201510114449A CN 104725060 A CN104725060 A CN 104725060A
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Prior art keywords
brick
refractory castable
aggregate
content
strength refractory
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CN201510114449.5A
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CN104725060B (en
Inventor
王国飞
夏银凤
罗华明
赵燕
姚维东
王江龙
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Beijing Jinyu Tongda refractory Technology Co.,Ltd.
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TONGDA REFRACTORY TECHNOLOGIES Co Ltd
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Abstract

The invention discloses a high-strength refractory castable taking a secondary guimo brick as an aggregate, which belongs to the technical field of refractory castable for cement kilns. The refractory castable comprises the following raw materials in percentage by mass: 50-60% of a secondary guimo brick with a particle size of less than or equal to 8mm, 10-20% of a scrap porcelain block material with a particle size of less than or equal to 8mm, 2-6% of silicon micropowder, 3-7% of aluminate cement, 5-10% of high aluminum powder and 3-8% of 180-mesh quartz powder, as well as 0.02-0.23wt % of an admixture. The refractory castable disclosed by the invention has the advantages that the regeneration and utilization of refractory materials are realized, so that resources are recycled and the usability of products is improved.

Description

A kind of secondary siliceous mullite brick is the high-strength refractory mould material of aggregate
Technical field
The invention belongs to refractory castable for cement kiln technical field, specifically provide the high-strength refractory mould material that a kind of secondary siliceous mullite brick is aggregate.
Background technology
Refractory materials is the important subsidiary material of ferrous metallurgy, cement, electric power, petrochemical industry, has a wide range of applications in every profession and trade.China consumes refractory materials about 1,000 ten thousand t in current year, waste and old refractory materials reaches 4,000,000 t, if waste and old refractory materials recycle can be made, also significantly can reduce the preparation cost of refractory materials, and drive the decline of the cost of industry Industrial products will bring significant economic and social profit with development.
The regeneration of domestic waste refractory materials is also in the stage at the early-stage, and the exploitation of developed countries to waste refractory materials are more Zao than China.The regeneration rate of China's refractory materials is also not high, only reaches 20%, and the waste and old refractory materials recovery utilization rate of metallurgy industry is about 40%.At present, the waste and old resistance to material of most enterprise adopts substantially buries process, relevant experimental study display: adopt a high proportion of waste and old refractory materials can make the very value product such as the refractory brick of high-quality, mould material, ramming mass, repair material, slag splashing furnace protecting material, tap hole filler, stuffing sand and slag former, and product performance can close to or reach the level of original product, some can also exceed the level of original product.Therefore, constantly appreciate in fireproof raw material market, today that fire-resistant finished product market value constantly reduces by user's cost needs, give full play to the surrogate of waste and old resistance to material as fire-resistant finished product, by technique means, promote its utility value further, have great importance.
Summary of the invention
The object of the present invention is to provide a kind of secondary siliceous mullite brick to be the high-strength refractory mould material of aggregate, solve product cost high, the problem of strength property difference.Make the again utilization of waste refractory materials in mould material.
A kind of secondary siliceous mullite brick is the high-strength refractory mould material of aggregate, be formulated as with mass percent: the secondary siliceous mullite brick 50 ~ 60% of granularity≤8mm, the useless porcelain block material 10 ~ 20% of granularity≤8mm, silicon powder 2 ~ 6%, aluminate cement 3 ~ 7%, high-alumina fly 5 ~ 10%, 180 object silica powders 3 ~ 8%; The admixture of another interpolation said ratio 0.02 ~ 0.23wt%.
Al in secondary siliceous mullite brick 2o 3content 60-65wt%, SiC content 5-10wt%, SiO 2content 15-25wt%.
Al in useless porcelain block material 2o 3content 45-55wt%, SiO 2content 30-45wt%.
Admixture is one or more in tripoly phosphate sodium STPP, Sodium hexametaphosphate 99, sodium lignosulfonate and lithium hydroxide.
The invention has the advantages that: the regeneration realizing waste refractory materials, make resource obtain recycle, improve the use properties of product simultaneously.First apply secondary siliceous mullite brick as aggregate, make used refractory obtain regeneration in mould material, the high-strength refractory mould material simultaneously prepared can apply to the industries such as electric power, environmental protection, smelting and heating, improves the operation factor of equipment, enhances productivity; Secondly this product application secondary siliceous mullite brick effectively reduces costs, and product performance are also improved, and production technique is simple, use properties is good, reduces environmental pollution, resources circulation is recycled.
Embodiment
The proportioning raw materials of high-strength refractory mould material of the present invention presses following weight percents preparation:
Admixture content is the 0.02wt% of said ratio.
Production method is: first by aluminate cement, admixture premix in mixer, premix is evenly for subsequent use, again secondary siliceous mullite brick, useless electroceramics block material, silica powder, silicon ash, high-alumina fly are jointly mixed with the cement mixed, admixture Preblend in mixer, the mould material bag distribution packaging will mixed after mixing.
By the properties of the high-strength refractory mould material of examples produce of the present invention as following table

Claims (4)

1. a secondary siliceous mullite brick is the high-strength refractory mould material of aggregate, it is characterized in that: be formulated as with mass percent: the secondary siliceous mullite brick 50 ~ 60% of granularity≤8mm, the useless porcelain block material 10 ~ 20% of granularity≤8mm, silicon powder 2 ~ 6%, aluminate cement 3 ~ 7%, high-alumina fly 5 ~ 10%, 180 object silica powders 3 ~ 8%; The admixture of another interpolation said ratio 0.02 ~ 0.23wt%.
2. high-strength refractory mould material according to claim 1, is characterized in that: Al in secondary siliceous mullite brick 2o 3content 60-65wt%, SiC content 5-10wt%, SiO 2content 15-25wt%.
3. high-strength refractory mould material according to claim 1, is characterized in that: Al in useless porcelain block material 2o 3content 45-55wt%, SiO 2content 30-45wt%.
4. high-strength refractory mould material according to claim 1, is characterized in that: admixture is one or more in tripoly phosphate sodium STPP, Sodium hexametaphosphate 99, sodium lignosulfonate and lithium hydroxide.
CN201510114449.5A 2015-03-16 2015-03-16 A kind of secondary siliceous mullite brick is the high-strength refractory castable of aggregate Active CN104725060B (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106045536A (en) * 2016-06-08 2016-10-26 郑州市豫茂工贸有限公司 Novel refractory block for flue wall of roasting furnace and preparation method of novel refractory block
CN106747493A (en) * 2016-11-24 2017-05-31 通达耐火技术股份有限公司 A kind of secondary siliceous mullite brick coating
CN111718143A (en) * 2020-06-10 2020-09-29 西安建筑科技大学 High-wear-resistance anti-skid pavement aggregate, pavement and preparation method
CN111848192A (en) * 2020-07-31 2020-10-30 北京金隅通达耐火技术有限公司 Refractory material prepared from waste high-alumina ceramic balls and waste shed plate
CN113045322A (en) * 2021-03-17 2021-06-29 北京金隅通达耐火技术有限公司 High-thermal-conductivity wear-resistant castable prepared from secondary silicon mullite bricks
CN113354402A (en) * 2021-06-25 2021-09-07 西安建筑科技大学 Surface modification method of used cement kiln silicon mullite brick and iron runner castable
CN115536407A (en) * 2022-09-30 2022-12-30 安徽芜湖海螺建筑安装工程有限责任公司 Castable special for cement kiln and preparation method thereof

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CN102515792A (en) * 2011-11-30 2012-06-27 浙江锦诚耐火材料有限公司 High-strength, wear-resistant and quick-change preform
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CN103739299A (en) * 2013-12-16 2014-04-23 洛阳利尔耐火材料有限公司 Fire-resistant self-flow castable
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CN102515792A (en) * 2011-11-30 2012-06-27 浙江锦诚耐火材料有限公司 High-strength, wear-resistant and quick-change preform
CN102515793A (en) * 2011-11-30 2012-06-27 浙江锦诚耐火材料有限公司 Prefabricated part used for grate cooler sunk fence
CN102757249A (en) * 2012-08-01 2012-10-31 山国强 Refractory castable for molten iron tank
CN103819204A (en) * 2013-11-12 2014-05-28 长兴兴鹰新型耐火建材有限公司 Silicon carbide mullite wear-resisting casting material
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106045536A (en) * 2016-06-08 2016-10-26 郑州市豫茂工贸有限公司 Novel refractory block for flue wall of roasting furnace and preparation method of novel refractory block
CN106747493A (en) * 2016-11-24 2017-05-31 通达耐火技术股份有限公司 A kind of secondary siliceous mullite brick coating
CN111718143A (en) * 2020-06-10 2020-09-29 西安建筑科技大学 High-wear-resistance anti-skid pavement aggregate, pavement and preparation method
CN111848192A (en) * 2020-07-31 2020-10-30 北京金隅通达耐火技术有限公司 Refractory material prepared from waste high-alumina ceramic balls and waste shed plate
CN113045322A (en) * 2021-03-17 2021-06-29 北京金隅通达耐火技术有限公司 High-thermal-conductivity wear-resistant castable prepared from secondary silicon mullite bricks
CN113045322B (en) * 2021-03-17 2022-09-06 北京金隅通达耐火技术有限公司 High-thermal-conductivity wear-resistant castable prepared from secondary silicon mullite bricks
CN113354402A (en) * 2021-06-25 2021-09-07 西安建筑科技大学 Surface modification method of used cement kiln silicon mullite brick and iron runner castable
CN113354402B (en) * 2021-06-25 2023-02-28 西安建筑科技大学 Surface modification method of used cement kiln silicon mullite brick and iron runner castable
CN115536407A (en) * 2022-09-30 2022-12-30 安徽芜湖海螺建筑安装工程有限责任公司 Castable special for cement kiln and preparation method thereof

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Address after: 100085, Beijing, Haidian District Qinghe Anning East Road No. 1 hospital

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Address before: 100035, Qinghe Road, Qinghe, Beijing, Haidian District, No. 1

Patentee before: TONGDA REFRACTORY TECHNOLOGIES Co.,Ltd.

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