CN104718311B - The method that the surface of the parts of automobile-use is carried out plating - Google Patents
The method that the surface of the parts of automobile-use is carried out plating Download PDFInfo
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- CN104718311B CN104718311B CN201380041682.4A CN201380041682A CN104718311B CN 104718311 B CN104718311 B CN 104718311B CN 201380041682 A CN201380041682 A CN 201380041682A CN 104718311 B CN104718311 B CN 104718311B
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- solution
- cabin
- ejector
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- type
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1617—Purification and regeneration of coating baths
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1619—Apparatus for electroless plating
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1619—Apparatus for electroless plating
- C23C18/1628—Specific elements or parts of the apparatus
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1619—Apparatus for electroless plating
- C23C18/1628—Specific elements or parts of the apparatus
- C23C18/163—Supporting devices for articles to be coated
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1655—Process features
- C23C18/166—Process features with two steps starting with addition of reducing agent followed by metal deposition
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B13/00—Machines or plants for applying liquids or other fluent materials to surfaces of objects or other work by spraying, not covered by groups B05B1/00 - B05B11/00
- B05B13/02—Means for supporting work; Arrangement or mounting of spray heads; Adaptation or arrangement of means for feeding work
- B05B13/0221—Means for supporting work; Arrangement or mounting of spray heads; Adaptation or arrangement of means for feeding work characterised by the means for moving or conveying the objects or other work, e.g. conveyor belts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B14/00—Arrangements for collecting, re-using or eliminating excess spraying material
- B05B14/40—Arrangements for collecting, re-using or eliminating excess spraying material for use in spray booths
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Chemically Coating (AREA)
- Details Or Accessories Of Spraying Plant Or Apparatus (AREA)
Abstract
The plating meeting the present invention is non-electrolytic.The present invention relates to a kind of method, the method is comprising at least one activator ejector (18, 20, 22) and slaine ejector (18, 20, 22) cabin (10) is implemented, each ejector (18, 20, 22) it is fixedly mounted in described cabin (10), parts (28) are operated by operation robot (24), said method comprising the steps of: first parts are placed in activator ejector (18 by robot (24), 20, 22) opposite, and make it move so that whole surface is activated agent and covers relative to this ejector；And, then parts are placed in slaine ejector (18,20,22) opposite by robot (24), and make it move so that whole surface is covered by slaine relative to this ejector.
Description
Technical field
The present invention relates to Vehicle component, especially include the method that the parts of plastic material carry out plating.
Background technology
Known being included the method that the solution of slaine carries out plating to parts by injection, the method need not use
Electric current.Especially, the method for the type is referred to as non-electrolytic formula metallization.The method is thus different from by using electric current
The metallization implemented, such as, electroplate chromium plating, realize the electrochemical deposition of chromium during this plating chromium plating.
Especially interesting is that the metallization using metal injection salt is to give outside the parts metals including plastic material
Seeing, this is the chromium bath allowing to be avoided use cost high due to this and having contaminative.
But, the parts of plating to be carried out by metal injection salt and must be subjected to a number of different process and walk
Suddenly.Generally, parts are arranged on a conveyor, and move on to another work station from a work station.The body of the facility of the type
Long-pending can be the biggest, and occupies a lot of space.
Summary of the invention
Especially, it is an object of the invention to by providing a kind of method needing less space to make up these defects.
To this end, the present invention theme is the method that the surface of a kind of parts to automobile-use carries out plating,
This plating is non-electrolytic, and the method is real in including the cabin of at least one activator ejector and slaine ejector
Executing, each ejector is fixedly mounted in cabin, and described parts are operated by operating robot, and the method includes following step
Rapid:
First parts are placed in activator ejector opposite by-robot so that it is move so that whole relative to this ejector
Individual surface is activated agent and covers；And,
Then parts are placed in slaine ejector opposite by-robot, and make it move so that relative to this ejector
Whole surface is covered by slaine.
Have benefited from the method to implement in the cabin including activator ejector and slaine ejector especially, Ke Yi
The space that volume is relatively small realizes multiple step, especially moves to another from a work station on a conveyor with parts
Realize space necessary to these same steps when work station is to implement different step to compare.Due to this greater compactness of space and
Use uniform machinery people to complete the applying of activator and the applying of slaine especially, therefore decrease and implement the method phase
The investment closed.
Further, each ejector is fixedly mounted in room, and makes parts in each injection by means of operation robot
Move before device.Therefore, the translational speed being different from ejector can be restricted, and the translational speed of parts is unrestricted.It practice, work as
During movable spray device, it is necessary to consider that spray-cone angle deformation during movement, this deformation limits translational speed.Therefore obtain
Metallization faster, it is possible to process more parts in given time interval.
Robot can be arranged in cabin.However, it is possible to only parts are placed in the part in ejector front in cabin
In, the remainder of robot is then positioned at outside cabin.
It should be noted that parts can stand other steps in addition to applying activator solution and metal salt solution.
Especially, before injection activator and slaine, non-electrolytic formula method for plating metal generally comprises the preliminary step of deposition varnish,
It is possible to any kind of parts, especially include that the parts of plastic material carry out plating, wherein said varnish also by
It is referred to as " priming coat " (English is " basecoat ") or priming paint.It addition, before the step of metal injection salt, spray activated solution
Step after can be rinsing step.Further, after the injection of slaine, preferably deposition protects the step of varnish, wherein
Described protection varnish is also referred to as " finish paint " (English is " topcoat ").
Generally, " activator " or " activated solution " refers to change parts surface state with beneficially oxidation-reduction
The beginning of reaction the solution of the attachment of the metallic particles in the metal salt solution that sprayed after being conducive to.Thus, by work
Change the deposition of the product deposition of slaine of injection after coming from (this activation product can be conducive to), react, be grafted, this
Activated solution can make the surface active of parts.
Generally, " slaine " refers to include the solution of oxidative cations and reducing solution.Such as, metal cation
With reducing solution by two nozzle ejections of same ejector, this produces two panels mist, and this two panels mist is joined mutually so that at parts
Metal level is deposited on surface.
It being understood that activator and slaine are liquid form, this liquid form has enough mobility with in carefully
The form injection of droplet.It is achieved in effectively and rapidly spraying activator and salt on the parts of plating to be carried out.
Automotive component can be the vehicle part of any desired its metal appearance of imparting, such as air-inlet grille, snap ring
(jonc), lamp decoration peripheral element, handle, wheelhouse portions, rocker panel (bas de caisse), chafing strip (bandeau de
Protection) etc..These parts can be made up of thermoplastic or thermosets or composite.
The present invention can also include the one or more of following characteristics alone or in combination:
-during the method, in cabin, on parts, spray at least one first kind solution and Second Type is molten
Liquid, the solution of each type includes that at least one selects from the set being made up of varnish, cleanout fluid, slaine and activator
Solution, the method is included in cabin and reclaims the step of first kind solution after injection, and reclaims after injection the in cabin
The step of two type solutions, cabin include respectively, for reclaiming the retracting device of each type solution.Thus, it is possible to easily
Ground separately and reclaims two kinds of solution respectively.Accordingly, because the solution of the first and second types is not mixed, reclaim
Process (removal of such as these solution or recirculation) to these solution becomes easier to afterwards.It should be noted that first and/
Or the solution every kind of Second Type can be made up of the single solution being ejected in cabin, or by simultaneously or successively spraying
The mixture of the multiple solution in cabin is constituted.In this case, it is to be understood that the class reclaimed by retracting device
The solution of type can stand after the process being exclusively used in every kind of solution mixture.It addition, the solution of a type can be corresponding
In the solution of one group of same nature, but necessarily.Such as, the solution of the first kind corresponds to the molten of one or more organic natures
Liquid, Second Type is then corresponding to the solution of one or more water-soluble character.But, according to the classification side of another kind of solution type
Method, the solution of the first kind is corresponding to one or more for by the most treated and that directly spray solution, and Second Type is then
Corresponding to one or more for solution through being subject to processing before ejecting or before being recovered.However, it is possible to arrange other
The method of solution of these types of classifying, such as, a type of solution corresponds to a kind of special solution to be isolated, especially
Being the solution for being specially treated, Second Type then corresponds to the mixture of the solution of every other injection.It is appreciated that
It is that " respectively, for reclaiming the retracting device of each type solution ", referring to can subsequently by the solution of each type each other
The retracting device of isolation.
The solution of-the first kind includes organic solution, and the retracting device of this first kind solution includes organic material absorbing
Base plate.In the case of vertically injection and being reclaimed by vertical system, absorbing base plate can be disposed on sidewall, or can be by
It is arranged in the bottom in cabin.Preferably, first kind solution is organic solution, is the most only made up of organic solution.At the bottom of this absorption
Plate is such as used for the organic solution reclaiming viscosity more than 0.01Pa.s (pascal second), such as varnish.These solution are injected
On parts so that only spray-cone angle the part not touching parts just by absorb base plate reclaim.It should be noted that it is permissible
The retracting device arranging first kind solution includes multiple absorption base plate, such as, include the second absorption base plate, and it is installed to be phase
It is movable (particularly rotate or translate) for the first base plate.Thus can absorb when base plate is saturated with solution at one and have
Standby absorption base plate.
The retracting device of-Second Type solution includes collecting board, and this collecting board is installed to be can be in non-work in cabin
Making position and collect activity between position, on this collection position, collecting board is configured to reclaim Second Type solution, and by it
Guide to discharge-channel.Generally, this retracting device is for reclaiming the solution that can easily flow and/or injected with at parts
The solution of upper trickling.The viscosity of these solution is generally less than 0.01Pa.s, and preferably its viscosity is close to the viscosity of water, is about
0.001Pa.s.In general manner, the volume of the volume ratio first kind solution of Second Type solution to be reclaimed is bigger.Collecting board
The most movable or translatable ground can be installed to be movable.
-when collecting board is positioned at the collection position of Second Type solution, before collecting board is inserted into organic substance absorption base plate
Side so that absorb base plate and do not contact with Second Type solution.Therefore, organic substance absorption base plate does not comes with for the type base plate
Say sufficiently bulky Second Type solution contact to be recycled.Thus, it is possible to change absorption base plate less frequently, this causes saving
The cost relevant to the exchonge step absorbing base plate being avoided by and time.When absorption base plate is positioned at the bottom in cabin, permissible
Understand that collecting board is positioned at the top bottom this.
-Second Type solution includes slaine and/or activator and/or cleanout fluid.Cleanout fluid for example, water, it is therefore preferable to
Distilled water.
-Second Type solution is aqueous solution.
-first kind solution includes varnish and/or cleanout fluid.In this case, cleanout fluid is preferably organically.
-reuse the Second Type solution that is recovered be injected into another Vehicle component at least partially
Surface on.Owing to different types of solution is reclaimed respectively, it can be considered to use the solution being recovered and it is heavy
Newly it is ejected on current part or is ejected in another Vehicle component.Thus, owing to the molten of same volume can be utilized
Liquid processes greater number of parts, reduces production cost.This is special in the case of the solution of Second Type includes activator
The most favourable.It practice, in general manner, the whole activators sprayed differ to establish a capital and react with parts surface, therefore live
Agent can re-use, and therefore can implement to reclaim.It addition, differently (in technical process, pass with traditional coating solution
System coating solution can be more or less dry), physical characteristic (the such as viscosity or evaporation speed of activator in whole procedure
Degree) keep substantially constant so that facilitate it to reclaim.
-cabin also includes flushing liquid ejector, and parts are placed in flushing liquid ejector opposite by robot, and makes
It moves relative to this ejector, to rinse whole surface.When this injection is implemented on activator injecting step and slaine injection
Time between step, this injection is especially interesting.
-in cabin, on parts, spray the 3rd type solution, the method be included in cabin reclaim spray after the 3rd
The step of type solution, the retracting device of the 3rd type solution and other retracting devices are devices respectively.3rd type is molten
Liquid includes in solution maybe this combination selected from the combination being made up of varnish, cleanout fluid, slaine and activator possibly
Multiple solution.
The retracting device of the-the three type solution includes collecting board, and this collecting board is installed to be can be in non-work in cabin
Making position and collect activity between position, on this collection position, this collecting board is configured to reclaim the solution of the 3rd type, and
It is conducted to discharge-channel.Thus, it is possible to separate the 3rd type solution (such as slaine), by avoiding at other solution
Dilution metal ion in (such as cleaning distilled water), and the metal ion that cost recovery is the highest.According to another example, can
To separate activator, the most again sprayed.Possibly, this collecting board can be the most movable around rotary shaft, Qi Zhongsuo
State rotary shaft and be disposed in the side relative with the rotary shaft of the collecting board for reclaiming another type solvent.Alternatively, collect
Plate can be translationally movable.
-collecting board is made up of plastic material or metal.
Subject of the present invention also resides in for carrying out gold-plated according to method as above to the surface of Vehicle component
The cabin belonged to, it is characterised in that this cabin include being configured for reclaiming the organic substance of first kind solution absorb base plate and
Being installed to be can be at off-position with collect collecting board movable between position in cabin, on described collection position,
Collecting board is configured to reclaim Second Type solution, and is conducted to discharge-channel.
Alternatively, when collecting board is on the collection position of Second Type solution, this collecting board is positioned at organic substance and inhales
Receive above base plate so that absorb base plate and do not contact with Second Type solution.
This cabin can also include one or more other collecting boaries stacked on top of each other, to reclaim the solution of Second Type,
Or the even the 3rd type or the solution of the n-th type.
It should be noted that can consider to realize being separately recovered of polytype solution, and do not implement above-mentioned by means of operation
The method for plating metal of robot.
Thus, therefore subject of the present invention also resides in a kind of method that surface to Vehicle component carries out plating,
This plating is non-electrolytic, and described method includes step and the step of metal injection salt spraying activator, in the method
During, in cabin, on parts, spray at least one first kind solution and Second Type solution, the solution of each type
All including at least one solution selected from the combination being made up of varnish, cleanout fluid, slaine and activator, the method includes
The step of first kind solution and reclaim the step of Second Type solution after injection, cabin in cabin after reclaiming injection in cabin
Room includes difference, the retracting device of each type solution.
It being understood that and described above or below be also suitably for the method to preceding method or the feature relevant with cabin
Implement.
Accompanying drawing explanation
With the reading following exemplary explanation that is given referring to the drawings, the present invention will be easier to understand.At these accompanying drawings
In:
Fig. 1 is the perspective diagram in the plating cabin of the parts of automobile-use；
Fig. 2 is the cross-sectional schematic in plating cabin, and this cabin includes absorbing base plate and be installed to be can be in cabin
Movable collecting board.
Detailed description of the invention
Figure 1 illustrates a plating cabin 10, this cabin includes floor 12, sidewall 14 and upper wall 16.Show at this
In example, cabin 10 includes three ejectors 18,20,22, and these ejectors are fixedly mounted in cabin 10.
Cabin is additionally included in this example the operation robot 24 being arranged in cabin 10.This robot 24 carries support member
26, clamper in other words, three Vehicle component 28 of plating to be carried out are fixed on this support member or clamper.Parts
28 for example, air-inlet grille, snap ring, lamp decoration peripheral element, wheelhouse portions, rocker panel, chafing strips.
Figure 2 illustrates the sectional view in cabin 10, to illustrate in greater detail the floor 12 in cabin 10.Clear in order to show
Chu, is shown without robot 24.The element that the two accompanying drawing has is indicated by same number designation.
Thus, floor 12 includes organic material absorbing base plate 30 and be installed as can be movable rotatably around rotary shaft 34
Collecting board 32.This collecting board 32 may be at off-position in cabin 10 and collects on position, at described off-position
On, collecting board extends along the plane of general vertical, and on described collection position, collecting board be configured to reclaim solution and
It is conducted to discharge-channel 36, therefore, as in figure 2 it is shown, collecting board such as extends along approximate horizontal plane and the lightest
Tilt, liquid to be drawn guide channel 36 micro-ly.
Collecting on position, collecting board 32 is positioned at the top absorbing base plate 30；On off-position, collecting board 32 is erected
Directly arrange, absorbed so that the material being injected on parts 28 can absorb base plate 30.
Presently describe the working method in cabin 10.
Robot 24 takes support member 26 from display rack away.This display rack can be arranged in cabin 10, or is arranged in
Outside cabin 10, in the face of the opening in cabin 10.
Robot 24 makes first component 28 be positioned at the front of the first ejector 18.In this example, the first ejector 18 sprays
Penetrating the first solution (the first solution here constitutes first kind solution as above), this first solution includes that viscosity is about
The organic coatings of 0.15Pa.s.In the step of injection varnish, collecting board 32 is in off-position, therefore absorbs base plate 30 and does not has
It is collected plate 32 to cover.Thus, the varnish ejected and be not deposited on first component 28 is absorbed base plate 30 and is absorbed.
Once layer of varnish is deposited on parts 28, and this layer is just thermally processed to form network structure or is dried.
Then, robot 24 makes first component 28 be in the front of the second ejector 20.Second ejector 20 is injected in this
In include the second solution of activator, such as viscosity is close to the aqueous solution of the viscosity of water.In this example, the second solution is second
The one of type solution.When this second injecting step, collecting board 32 is positioned at collection position, so that not being deposited on first
The activator on part 28 and trickled thereon is guided to discharge-channel 36.
It will consequently be understood that, including absorb base plate 30 first kind solution retracting device with include collecting board 32
The retracting device of Second Type solution be device respectively.Therefore, it can residual solution is carried out separate process, such as, make
For waste liquid and/or the separately process of solution to be recycled.
It is contemplated that reclaiming after Second Type solution, reuse this Second Type solution and be injected in the
On two parts 28.
Then, making first component 28 be in the front of the 3rd ejector 22, the 3rd ejector is injected in and includes gold here
Belong to the 3rd solution of salt.In this example, the form of slaine is also aqueous solution, and is considered to be the one of Second Type solution
Kind, therefore when metal injection salt, collecting board 32 is also at collecting position.
Slaine can be collected plate 32 and guide to same discharge-channel 36.It is contemplated that cabin includes such as valve
Device, this device can separate the solution reclaimed from collecting board 32.In this case, cabin includes the recovery of three difference
Device, is separately recovered first, second, and third solution.
It being understood that the quantity of the ejector being arranged in cabin 10 can be according to the step of the method implemented in cabin
Suddenly change.Thus, it is possible to consider to arrange additional eductor, this additional eductor can be in the step of injection activator and injection
First component 28 is rinsed between the step of slaine.
Cabin 10 can also include can on the parts 28 of plated metal before plating deposit bottom varnish and/or
The additional eductor of the protection varnish of deposition metal cladding on the components.
Modification as the method, it is also contemplated that simultaneously process multiple parts 28.Thus, it is possible on first component 28
Injection activator, and simultaneously passing through activator or spraying gold-plated on second component 28 that flushing liquid injection processed
Belong to salt.
The solution reclaimed from collecting board 32 will be then activator and the mixture of slaine constituting Second Type solution.
Advantageously, reclaim plate 30 and be provided for reclaiming organic solution or the mixture of organic solution (such as: varnish), and
(such as: cleaning liquid, or be slaine or the activation of aqueous solution collecting board is then provided for recycle-water solution or aqueous solution
Agent) mixture.
It being understood that the present invention is not restricted to the embodiment being described in the drawings, and described in description preamble
Feature can be mutually combined.Especially, retracting device is primarily described as the device being flatly arrange, however, it is possible to consider
Withdrawal liquid on the vertical wall in cabin, especially in the case of horizontal spray products.Especially, it may be considered that be arranged in perpendicular
Absorption base plate on wall, and the little product of other viscosity flows in the groove being conducted bottom cabin.
Claims (10)
1. the method surface of the parts (28) of automobile-use being carried out plating, described plating is non-electrolytic,
Described method is implemented in the cabin (10) including at least one activator ejector and slaine ejector, each described injection
Device is fixedly mounted in described cabin (10), and described parts (28) are operated by operation robot (24), described method bag
Include following steps:
First described parts are placed in described activator ejector opposite by-described operation robot (24), and make described parts phase
This ejector is moved so that whole surface is activated agent and covers；And,
Then described parts are placed in described slaine ejector opposite by-described operation robot (24), and make described parts phase
This ejector is moved so that whole surface is covered by slaine.
The most the method for claim 1, wherein in described procedure, at described cabin (10) introversive described parts
At least one first kind solution of upper injection and Second Type solution, the solution of described each type include at least one from by
The solution selected in the set that varnish, cleanout fluid, slaine and activator are constituted, described method is included in described cabin (10)
Reclaim the step of described first kind solution after spraying, and in described cabin (10), reclaim described Second Type solution after injection
Step, described cabin (10) include respectively, for reclaiming the retracting device of described each type solution.
3. method as claimed in claim 2, wherein, described first kind solution includes organic solution, and the described first kind
The retracting device of type solution includes organic material absorbing base plate (30).
4. method as claimed in claim 2 or claim 3, wherein, the retracting device of described Second Type solution includes collecting board (32),
Described collecting board is installed to be can be movable, in described receipts between described cabin (10) inherent off-position and collection position
On collection position, described collecting board is configured to reclaim described Second Type solution, and guides described Second Type solution to row
Put passage (36).
5. method as claimed in claim 4, in described procedure, when described collecting board (32) is positioned at described Second Type
During the collection position of solution, described collecting board is inserted into described organic substance and absorbs base plate (30) front so that described Organic substance
Matter absorbs base plate (30) and does not contacts with described Second Type solution.
6. as claimed in claim 2 or claim 3 method, wherein, described Second Type solution include slaine and/or activator and/
Or cleanout fluid.
7. method as claimed in claim 2 or claim 3, wherein, described first kind solution includes varnish and/or cleanout fluid.
8. method as claimed in claim 2 or claim 3, in described procedure, on described cabin (10) introversive described parts
Spraying the 3rd type solution, described method reclaims the step of described 3rd type solution after spraying in being included in described cabin (10)
Suddenly, the retracting device of described 3rd type solution and other retracting devices are devices respectively.
9. a cabin (10), this cabin is for coming automobile-use according to the method as according to any one of claim 1 to 8
The surface of parts (28) carry out plating, it is characterised in that described cabin includes:
-operation robot；
-activator ejector；
-slaine ejector, described each ejector is fixedly mounted in described cabin；
-it is configured for reclaiming organic substance absorption base plate (30) of first kind solution；And,
-collecting board (32), described collecting board is installed to be can be in described cabin (10) inherent off-position and collection position
Between movable, on described collection position, described collecting board is configured to reclaim described Second Type solution, and by described second
Type solution guides to discharge-channel (36).
10. cabin (10) as claimed in claim 9, in described cabin, when described collecting board (32) is positioned at described Equations of The Second Kind
During the collection position of type solution, described collecting board is positioned at described organic substance and absorbs the top of base plate (30) so that described organic
Material absorbing base plate (30) does not contacts with described Second Type solution.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1257641A FR2994197B1 (en) | 2012-08-06 | 2012-08-06 | METHOD FOR METALLIZING A SURFACE OF A PIECE FOR A MOTOR VEHICLE |
| FR1257641 | 2012-08-06 | ||
| PCT/FR2013/051869 WO2014023898A1 (en) | 2012-08-06 | 2013-08-01 | Method for metallizing a surface of a part for a motor vehicle |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104718311A CN104718311A (en) | 2015-06-17 |
| CN104718311B true CN104718311B (en) | 2016-12-21 |
Family
ID=47191914
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380041682.4A Expired - Fee Related CN104718311B (en) | 2012-08-06 | 2013-08-01 | The method that the surface of the parts of automobile-use is carried out plating |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP2880197B1 (en) |
| CN (1) | CN104718311B (en) |
| ES (1) | ES2610455T3 (en) |
| FR (1) | FR2994197B1 (en) |
| WO (1) | WO2014023898A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107930938A (en) * | 2017-12-18 | 2018-04-20 | 宁波斯凯勒智能科技有限公司 | A kind of uniform spray-painting plant of machinery production |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1946486A (en) * | 2004-04-28 | 2007-04-11 | 株式会社荏原制作所 | Substrate processing unit and substrate processing apparatus |
| CN101605924A (en) * | 2006-11-24 | 2009-12-16 | 喷射金属技术公司 | Make the improved non-electrolysis process of base metalization by reducing metal salt and spraying aerosol |
| FR2954716A1 (en) * | 2009-12-29 | 2011-07-01 | Plastic Omnium Cie | PROCESS FOR THE SURFACE TREATMENT OF LARGE-SIZED PARTS, PRE-HEATER FOR PARTS SUITABLE FOR THE IMPLEMENTATION OF SUCH A PROCESS, THE USE OF THIS PRE-HEATER AND THE PROCESSING CABIN |
| CN102144045A (en) * | 2008-07-30 | 2011-08-03 | 喷射金属技术公司 | Electoless method for in-line metallization of substrates by spraying them, with prior surface treatment and device for implementing the method |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1009633A (en) * | 1950-02-02 | 1952-06-03 | Pour Le Perfectionnement Des A | Silver metallization process |
| DE102005033972A1 (en) * | 2005-07-20 | 2007-01-25 | Dürr Systems GmbH | Coating method and associated coating device |
-
2012
- 2012-08-06 FR FR1257641A patent/FR2994197B1/en not_active Expired - Fee Related
-
2013
- 2013-08-01 CN CN201380041682.4A patent/CN104718311B/en not_active Expired - Fee Related
- 2013-08-01 EP EP13756652.7A patent/EP2880197B1/en not_active Not-in-force
- 2013-08-01 ES ES13756652.7T patent/ES2610455T3/en active Active
- 2013-08-01 WO PCT/FR2013/051869 patent/WO2014023898A1/en active Application Filing
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1946486A (en) * | 2004-04-28 | 2007-04-11 | 株式会社荏原制作所 | Substrate processing unit and substrate processing apparatus |
| CN101605924A (en) * | 2006-11-24 | 2009-12-16 | 喷射金属技术公司 | Make the improved non-electrolysis process of base metalization by reducing metal salt and spraying aerosol |
| CN102144045A (en) * | 2008-07-30 | 2011-08-03 | 喷射金属技术公司 | Electoless method for in-line metallization of substrates by spraying them, with prior surface treatment and device for implementing the method |
| FR2954716A1 (en) * | 2009-12-29 | 2011-07-01 | Plastic Omnium Cie | PROCESS FOR THE SURFACE TREATMENT OF LARGE-SIZED PARTS, PRE-HEATER FOR PARTS SUITABLE FOR THE IMPLEMENTATION OF SUCH A PROCESS, THE USE OF THIS PRE-HEATER AND THE PROCESSING CABIN |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104718311A (en) | 2015-06-17 |
| ES2610455T3 (en) | 2017-04-27 |
| FR2994197B1 (en) | 2014-08-22 |
| FR2994197A1 (en) | 2014-02-07 |
| EP2880197A1 (en) | 2015-06-10 |
| WO2014023898A1 (en) | 2014-02-13 |
| EP2880197B1 (en) | 2016-10-12 |
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