CN104711896A - Surface sizing agent and preparation method thereof and sizing paper - Google Patents
Surface sizing agent and preparation method thereof and sizing paper Download PDFInfo
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- CN104711896A CN104711896A CN201310689112.8A CN201310689112A CN104711896A CN 104711896 A CN104711896 A CN 104711896A CN 201310689112 A CN201310689112 A CN 201310689112A CN 104711896 A CN104711896 A CN 104711896A
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- cypres
- lcfa
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- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 238000004513 sizing Methods 0.000 title abstract description 13
- 150000004668 long chain fatty acids Chemical class 0.000 claims abstract description 48
- 229920002472 Starch Polymers 0.000 claims abstract description 44
- 235000019698 starch Nutrition 0.000 claims abstract description 44
- 239000008107 starch Substances 0.000 claims abstract description 44
- 244000085692 Cordia alliodora Species 0.000 claims description 45
- 235000004258 Cordia alliodora Nutrition 0.000 claims description 45
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 42
- 238000009835 boiling Methods 0.000 claims description 27
- 235000021314 Palmitic acid Nutrition 0.000 claims description 21
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 21
- 210000002966 serum Anatomy 0.000 claims description 17
- 240000003183 Manihot esculenta Species 0.000 claims description 15
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 15
- 229920002261 Corn starch Polymers 0.000 claims description 6
- 239000008120 corn starch Substances 0.000 claims description 6
- 229940099112 cornstarch Drugs 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 3
- 239000008117 stearic acid Substances 0.000 claims description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005642 Oleic acid Substances 0.000 claims description 2
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- 229940070765 laurate Drugs 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- 235000021313 oleic acid Nutrition 0.000 claims description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 29
- 239000002002 slurry Substances 0.000 abstract description 15
- 239000003795 chemical substances by application Substances 0.000 abstract description 8
- 239000011268 mixed slurry Substances 0.000 abstract 3
- 238000010411 cooking Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000003292 glue Substances 0.000 description 30
- 230000001846 repelling effect Effects 0.000 description 13
- 239000000243 solution Substances 0.000 description 12
- 239000011347 resin Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 238000003756 stirring Methods 0.000 description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 description 6
- -1 alkyl ketene dimer Chemical compound 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
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- Paper (AREA)
Abstract
A preparation method of a surface sizing agent comprises the following steps: providing a starch slurry, heating the starch slurry to a starch gelatinization temperature, and cooking; adding a long-chain fatty acid into the cooked starch slurry to prepare a mixed slurry, wherein the addition amount of the long-chain fatty acid is 0.1%-10% of the weight of starch; adjusting the pH of the mixed slurry to an alkaline environment, after the long-chain fatty acid is fully dissolved, again adjusting the pH value of the mixed slurry to be in the range of 2-11, and thus obtaining the surface sizing agent. The invention also provides the surface sizing agent prepared by the preparation method of the surface sizing agent and sizing paper prepared by applying the surface sizing agent. The surface sizing agent provided by the invention can improve the water-resistant performance and surface strength of paper simultaneously, and the preparation method has the advantages of simple operation, low cost and the like.
Description
Technical field
The present invention relates to a kind of Cypres, this Cypres preparation method and apply above-mentioned Cypres and carry out the obtained sized paper of applying glue.
Background technology
What surface sizing agent for paper making adopted is AKD (alkyl ketene dimer), gum rosin, PVA(polyvinyl alcohol) etc., but these Cypres often can only improve paper water repelling property or can only improve the intensity of paper surface, can not take into account paper WATER RESISTANCE and surface strength of paper two indices simultaneously.
At present, if desired improve paper WATER RESISTANCE and surface strength of paper in prior art, general needs adds at least two kinds of medicines, complex manufacturing, and cost increases simultaneously.
Summary of the invention
In view of this, be necessary the preparation method providing a kind of Cypres, the Cypres that the method obtains can take into account paper WATER RESISTANCE and surface strength of paper simultaneously.
In addition, there is a need to the Cypres providing a kind of preparation method applying above-mentioned Cypres to obtain.
In addition, there is a need to provide a kind of apply above-mentioned Cypres and carry out the obtained sized paper of applying glue.
A preparation method for Cypres, it comprises the steps:
Farinaceous size is provided, this farinaceous size is heated to starch gelatinization temperature and carries out boiling;
In the farinaceous size after above-mentioned boiling, add LCFA make mixed serum, the addition of this LCFA is the 0.1%-10% of starch weight;
Above-mentioned mixed serum is adjusted to alkaline environment, after described LCFA fully dissolves, then adjusts above-mentioned mixed serum pH value in the scope of 2-11, obtained described Cypres.
The Cypres that the preparation method applying above-mentioned Cypres obtains, this Cypres contains starch and LCFA, and the addition of this LCFA is the 0.1%-10% of starch weight.
A kind of sized paper applied above-mentioned Cypres and obtain.
Cypres preparation method provided by the invention, by to add in LCFA to farinaceous size and to regulate the pH value of these slurries, utilize LCFA under pH value, have the Cypres drawn prepared by different forms and two characteristics of good water repelling property of itself having, be applied to surface strength and water repelling property that paper surface can improve paper simultaneously.In addition, the method that the present invention prepares top sizing has simple to operate, medicine addition and reduces and low cost and other advantages.
Detailed description of the invention
A preparation method for Cypres, it comprises the steps:
(1) provide farinaceous size, this farinaceous size is heated to starch gelatinization temperature and carries out boiling.
This step makes amidin for be added water by starch, then this amidin is warming up to starch gelatinization temperature (as 95 DEG C and more than) carry out boiling until the obtained required farinaceous size of starch gelatinization.
This starch is selected from least one in tapioca, cornstarch and wheaten starch.
(2) in the farinaceous size after above-mentioned boiling, add LCFA and make mixed serum, the addition of this LCFA is the 0.1%-10% of starch weight.
Described LCFA refers to the aliphatic acid of carbon atom more than 12 in fatty acid molecule structure in carbochain.Carbon atom number in the carbochain of this LCFA is within the scope of 12-20.Preferably, described long-chain fat includes but not limited to sour laurate, myristic acid, palmitic acid, oleic acid and stearic acid.
Preferably, the addition of described LCFA is the 0.5%-3% of starch weight.
(3) above-mentioned mixed serum is adjusted to alkaline environment, after described LCFA fully dissolves, then adjusts obtained described Cypres in above-mentioned mixed serum pH value to the scope of 2-11.
After described LCFA is added into above-mentioned farinaceous size, fully to stir and the pH adjusting mixed serum fully dissolves to alkaline environment to enable this LCFA.Preferably, the pH referring to this mixed serum of the mixed serum of this alkaline environment is 11.
Preferably, after described LCFA fully dissolves, then regulate the pH value of this mixed serum in the scope of 5-11.
The LCFA that the present invention adds has following two performances: the first, the chain alkyl of LCFA has splendid water repelling property; The second, LCFA presents different shape under the environment of different pH, concrete, when LCFA is in the basic conditions in threadiness, when LCFA then shrinks under acidic or neutral conditions in cotton-shaped.
The present invention makes full use of two characteristics of above-mentioned LCFA, to be added in farinaceous size and to be prepared into Cypres, enabling paper have outstanding water repelling property and surface strength after this Cypres is applied to paper simultaneously.Concrete principle is as follows:
LCFA is utilized to present fibrous characteristic under alkaline environment, be added in farinaceous size at it and regulate this mixed serum to alkaline environment afterwards and make it abundant dissolving, part LCFA can enter into the inside of starch helical structure, and remaining LCFA relies on the filamentary structure of self to be distributed between starch molecule with the wrapped of network skeleton;
After LCFA fully dissolves, regulate the pH value of mixed serum to shrink at the LCFA of the inside of starch helical structure and the outside that is wrapped in starch molecule to make injection again, and it is more tight to make starch be combined with LCFA, there is the surface strength that sizing agent that this starch of combining closely and LCFA make significantly improves paper to paper surface.
So, obtained Cypres applying glue, to paper surface, can make paper have outstanding surface strength, in addition, because this LCFA has outstanding water repelling property, therefore Cypres applying glue this paper to paper surface containing LCFA also has outstanding water repelling property.Therefore, compared to prior art, surface strength and the water repelling property of paper after Cypres provided by the invention is applied to paper surface, can be improved simultaneously.
The present invention also provides the preparation method in a kind of Cypres described above the Cypres obtained, and this Cypres comprises starch and LCFA, and the addition of this LCFA is the 0.1%-10% of starch weight.
The present invention also provides a kind of and applies the obtained sized paper of above-mentioned Cypres.
Below by embodiment, the present invention is specifically described.
Blank example
Get 40g over dry tapioca, add water and be made into the slurries that mass percentage concentration is 10%, be heated to 95 DEG C of boiling half an hour, give paper applying glue after boiling completes, resin added is 2g/m
2.
Comparative example 1
Get 40g over dry cassava ative starch, add water and be made into the slurries that mass percentage concentration is 10%, be heated to 95 DEG C of boiling half an hour, after boiling completes, add the AKD(alkyl ketene dimer that emulsification is good) 0.8g, then by this glue application solution to paper applying glue, resin added is 2g/m
2.
Comparative example 2
Get 40g over dry cassava ative starch, add water and be made into the slurries that mass percentage concentration is 10%, be heated to 95 DEG C of boiling half an hour, after boiling completes, add PVA(polyvinyl alcohol) 0.8g, then by this glue application solution to paper applying glue, resin added is 2g/m
2.
Embodiment 1
Get 40g over dry cassava ative starch, add water and be made into the slurries that mass percentage concentration is 10%, be heated to 95 DEG C of boiling half an hour, 0.04g palmitic acid (namely the addition of palmitic acid is 0.1% of cassava ative starch weight) is added after boiling completes, adjustment pH is 11, after palmitic acid dissolves completely again by this glue application solution to paper applying glue, resin added is 2g/m
2.
Embodiment 2
Get 40g over dry cassava ative starch, add water and be made into the slurries that mass percentage concentration is 10%, be heated to 95 DEG C of boiling half an hour, 0.04g palmitic acid (namely the addition of palmitic acid is 0.1% of cassava ative starch weight) is added after boiling completes, adjustment pH is 11, stirs 10 minutes, adjusts pH to 7 after palmitic acid dissolves completely again, again by this glue application solution to paper applying glue, resin added is 2g/m
2.
Embodiment 3
Get 40g over dry cassava ative starch, add water and be made into the slurries that mass percentage concentration is 10%, be heated to 95 DEG C of boiling half an hour, 0.04g palmitic acid (namely the addition of palmitic acid is 0.1% of cassava ative starch weight) is added after boiling completes, adjustment pH is 11, stirs 10 minutes, adjusts pH to 5 after palmitic acid dissolves completely again, again by this glue application solution to paper applying glue, resin added is 2g/m
2.
Embodiment 4
Get 40g over dry cassava ative starch, add water and be made into the slurries that mass percentage concentration is 10%, be heated to 95 DEG C of boiling half an hour, 0.04g palmitic acid (namely the addition of palmitic acid is 0.1% of cassava ative starch weight) is added after boiling completes, adjustment pH is 11, stirs 10 minutes, adjusts pH to 2 after palmitic acid dissolves completely again, again by this glue application solution to paper applying glue, resin added is 2g/m
2.
Embodiment 5
Get 40g over dry native cornstarch, add water and be made into the slurries that mass percentage concentration is 10%, be heated to 95 DEG C of boiling half an hour, 2g palmitic acid (namely the addition of palmitic acid is 5% of native cornstarch weight) is added after boiling completes, adjustment pH is 11, stirs 10 minutes, adjusts pH to 7 after palmitic acid dissolves completely again, again by this glue application solution to paper applying glue, resin added is 2g/m
2.
Embodiment 6
Get 40g over dry cassava ative starch, add water and be made into the slurries that mass percentage concentration is 10%, be heated to 95 DEG C of boiling half an hour, 4g palmitic acid (namely the addition of palmitic acid is 10% of cassava ative starch weight) is added after boiling completes, adjustment pH is 11, stirs 10 minutes, adjusts pH to 5 after palmitic acid dissolves completely again, again by this glue application solution to paper applying glue, resin added is 2g/m
2.
Embodiment 7
Get 40g over dry native cornstarch, add water and be made into the slurries that mass percentage concentration is 10%, be heated to 95 DEG C of boiling half an hour, 2g stearic acid (namely stearic addition is 5% of native cornstarch weight) is added after boiling completes, adjustment pH is 11, stirs 10 minutes, adjusts pH to 7 after palmitic acid dissolves completely again, again by this glue application solution to paper applying glue, resin added is 2g/m
2.
The performance test results of the paper of above-mentioned obtained 10 groups of Cypres applying glues is as shown in following table one.
Table one
| Sample | RI surface strength | Contact angle 0.5s |
| Blank example | 5 | 43.8° |
| Comparative example 1 | 5 | 71.2° |
| Comparative example 2 | 7 | 44.6° |
| Embodiment 1 | 6 | 63.5° |
| Embodiment 2 | 6 | 65.5° |
| Embodiment 3 | 5 | 68.2° |
| Embodiment 4 | 5 | 68.5° |
| Embodiment 5 | 7 | 78.2° |
| Embodiment 6 | 7 | 82.5° |
| Embodiment 7 | 7 | 78.8° |
Note: 1.RI surface strength: surface strength of paper detection method, is given a mark by the stripping situation of paper fiber after RI printing, and numerical value is larger, and to represent surface strength higher.
2. contact angle: express liquid drips on paper, when official hour, the angle that drop and paper are formed.Angle is larger, and to represent paper water resistant ability stronger.
As shown in Table 1:
1. being drawn by comparative example 1 and blank example: in farinaceous size, add AKD(alkyl ketene dimer) obtained glue application solution only improves paper water repelling property to after paper applying glue, and Strength Changes is little.
2. being drawn by comparative example 2 and blank example: in farinaceous size, add PVA(polyvinyl alcohol) obtained glue application solution only improves paper strength to after paper applying glue, and water repelling property change is little.
3. drawn by above-described embodiment: in farinaceous size, add the obtained glue application solution of LCFA to after paper applying glue, water repelling property and the surface strength of paper of paper strengthen all to some extent.
Cypres preparation method provided by the invention, by to add in LCFA to farinaceous size and to regulate the pH value of these slurries, utilize LCFA under pH value, have different forms and two characteristics of good water repelling property of itself having prepare Cypres, this Cypres is applied to surface strength and the water repelling property that paper surface can improve paper simultaneously.In addition, the method that the present invention prepares top sizing has simple to operate, medicine addition and reduces and low cost and other advantages.
Those skilled in the art also can make various amendments in other form and details, interpolation and replacement in the claims in the present invention scope of disclosure and spirit.Certainly, the changes such as these various amendments made according to the present invention's spirit, interpolation and replacement, all should be included within the present invention's scope required for protection.
Claims (9)
1. a preparation method for Cypres, it comprises the steps:
Farinaceous size is provided, this farinaceous size is heated to starch gelatinization temperature and carries out boiling;
In the farinaceous size after above-mentioned boiling, add LCFA make mixed serum, the addition of this LCFA is the 0.1%-10% of starch weight;
Above-mentioned mixed serum is adjusted to alkaline environment, after described LCFA fully dissolves, then adjusts above-mentioned mixed serum pH value in the scope of 2-11, obtained described Cypres.
2. the preparation method of Cypres as claimed in claim 1, is characterized in that: this starch is selected from least one in tapioca, cornstarch and wheaten starch.
3. the preparation method of Cypres as claimed in claim 1, is characterized in that: the carbon atom number in the carbochain of described LCFA is within the scope of 12-20.
4. the preparation method of Cypres as claimed in claim 3, is characterized in that: described LCFA is selected from least one in laurate, myristic acid, palmitic acid, oleic acid and stearic acid.
5. the preparation method of Cypres as claimed in claim 1, is characterized in that: the addition of described LCFA is the 0.5%-3% of starch weight.
6. the preparation method of Cypres as claimed in claim 1, is characterized in that: the pH value of the mixed serum of alkaline environment is 11.
7. the preparation method of Cypres as claimed in claim 1, is characterized in that: after described LCFA fully dissolves, then adjusts above-mentioned mixed serum pH value in the scope of 5-11.
8. the Cypres that the preparation method of the Cypres as described in claim 1-7 item any one obtains, it is characterized in that: this Cypres contains starch and LCFA, the addition of this LCFA is the 0.1%-10% of starch weight.
9. the sized paper that an application Cypres as claimed in claim 8 is obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310689112.8A CN104711896B (en) | 2013-12-13 | 2013-12-13 | Cypres and preparation method thereof, sized paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310689112.8A CN104711896B (en) | 2013-12-13 | 2013-12-13 | Cypres and preparation method thereof, sized paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104711896A true CN104711896A (en) | 2015-06-17 |
| CN104711896B CN104711896B (en) | 2017-10-24 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310689112.8A Expired - Fee Related CN104711896B (en) | 2013-12-13 | 2013-12-13 | Cypres and preparation method thereof, sized paper |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114702924A (en) * | 2022-03-29 | 2022-07-05 | 深圳深汕特别合作区昌茂粘胶新材料有限公司 | Environment-friendly degradable adhesive, preparation method and preparation method of prepared sticker |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101050611A (en) * | 2007-05-14 | 2007-10-10 | 南京林业大学 | Surface sizing agent for improving paper deflection and paperboard circular press stength |
| CN101240517A (en) * | 2008-03-14 | 2008-08-13 | 广东轻工职业技术学院 | Method for complexing composite starch sizing agent |
| CN103362031A (en) * | 2013-08-05 | 2013-10-23 | 金华盛纸业（苏州工业园区）有限公司 | Surface sizing agent for printing paper and application thereof |
| CN103410052A (en) * | 2013-07-09 | 2013-11-27 | 上海东升新材料有限公司 | Preparation method for surface sizing agent emulsion |
-
2013
- 2013-12-13 CN CN201310689112.8A patent/CN104711896B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101050611A (en) * | 2007-05-14 | 2007-10-10 | 南京林业大学 | Surface sizing agent for improving paper deflection and paperboard circular press stength |
| CN101240517A (en) * | 2008-03-14 | 2008-08-13 | 广东轻工职业技术学院 | Method for complexing composite starch sizing agent |
| CN103410052A (en) * | 2013-07-09 | 2013-11-27 | 上海东升新材料有限公司 | Preparation method for surface sizing agent emulsion |
| CN103362031A (en) * | 2013-08-05 | 2013-10-23 | 金华盛纸业（苏州工业园区）有限公司 | Surface sizing agent for printing paper and application thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114702924A (en) * | 2022-03-29 | 2022-07-05 | 深圳深汕特别合作区昌茂粘胶新材料有限公司 | Environment-friendly degradable adhesive, preparation method and preparation method of prepared sticker |
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