CN104711685B - Multifunctional electrostatic spinning equipment - Google Patents

Abstract

The invention discloses multifunctional electrostatic spinning equipment. The multifunctional electrostatic spinning equipment comprises electrostatic spinning chambers, a preprocessing chamber, a sampling chamber, a disk feeding chamber and a sample receiving chamber and can achieve the functions of self-cleaning of electrostatic spinning nozzles, automatic sampling and sample replacing, in-situ modifying, continuous preparing of multi-layer nanofiber thin films and the like. The multifunctional electrostatic spinning equipment is characterized in that the three electrostatic spinning chambers are each provided with a nozzle fixator which can fix and clean the corresponding nozzle so that electrostatic spinning can be conducted smoothly; the sample receiving chamber comprises a sample disk fixator which is used for controlling rotation of sampling disks so that the sample disks can be switched between different units, and the functions of preprocessing, automatic sampling, automatic disk loading, preparing of the multi-layer nanofiber thin films and the like can be achieved. The preprocessing chamber and the sampling chamber can achieve preprocessing, acquisition and modification of electrostatic spinning products. The disk feeding chamber can automatically supplement the sample receiving chamber with the sample disks. The multifunctional electrostatic spinning equipment has the advantages of being simple in structure, convenient to operate and capable of improving the electrostatic spinning efficiency, having multiple functions and the like.

Description

A kind of Multifunctional static electricity spinning equipment

Technical field

The invention belongs to electrostatic spinning field, more particularly, to one kind have shower nozzle self-cleaning, automatically sampling vary, (in situ) Electrostatic spinning apparatus that are modified, continuously preparing the functions such as multi-layer nano fiber membrane.

Background technology

With the development of national economy and science and technology, people are increasing to the demand of nano-fiber material, electrostatic Spining technology prepares 1-dimention nano fibrous material or nano-fiber film has the advantage of uniqueness as a kind of, thus extensive Research and application.Particularly after last century the eighties, with the proposition of this concept of nano material, it is right that research finds The optimization of the parameter of electrostatic spinning, can easily prepare diameter and reach the nanofiber of nanometer scale and even more evoke science Family is to the research interest of electrostatic spinning and enthusiasm.Electrostatic spinning is gradually in catalysis material, photoelectric material and device, bio-medical group Knit, play a great role in the field such as aerospace.

During electrostatic spinning, apply certain voltage in shower nozzle (anode), formed between shower nozzle and receiver board with one Individual electrostatic field, is in the electric charge of droplet in electric field or melt droplet table enriched, if the charge repulsion of droplet surface During more than or equal to its surface tension, droplet surface produces small " jet ", and " jet " is drawn in the presence of electric field force Stretch, solvent volatilizees rapidly, solidifies, be deposited on receiver board, that is, define nanofiber.Since formalas is first in 1934 Since the secondary experimental provision having applied for being prepared polymer fiber with electrostatic force, the spring after the patent such as rain related to electrostatic spinning apparatus Bamboo shoot, electrostatic spinning apparatus have obtained a lot of improvement, and form is also varied, solve a lot of problems, such as Chinese patent: Zl201210245532.2, zl 201210024657.2 etc.；United States Patent (USP) us6616435, us6656394 etc.；World patent: Wo06043968, wo2005099308 etc..

However, in electrostatic spinning, if the viscosity of precursor solution is too big, sweetening agent solution volatile (as ethanol does During solvent), it is easily caused solution in the solidification of shower nozzle end, grow one section of silk (see accompanying drawing 1) so that shower nozzle is plugged；And such as Fruit precursor solution polymer solubility is low, shower nozzle solution can be made to form drop, drip, these phenomenons all make Static Spinning Silk is difficult to, and reduces the efficiency of electrostatic spinning.Secondly, traditional electrostatic spinning apparatus typically adopt negative electrode (earthing pole) straight Connect as receiver board, receive Electrospun product, flexibility is not high, has certain limitation, such as: sampling is inconvenient, be difficult to into There is impact on electric field and then have influence on the pattern of Electrospun product: this laboratory in row modification, the thickness of receiver board sample Research find, when preparing nanofiber using common electrostatic spinning process, the sampling time of Electrospun product affects nanometer The appearance of fiber: the sampling time is long, that is, the time of spinning is oversize, and main nanofiber is thicker, much thin along with occurring Little fiber, the diameter of fiber is uneven (see accompanying drawing 2), and when the sampling time is shorter, the nanofiber of electrostatic spinning preparation is thick Thin ratio more uniform (see accompanying drawing 3), therefore, the control controlling sampling time of electrostatic spinning product pattern to nanofiber is very It is necessary.Finally, with the development of nano material, there is the research of novel nano-material of property with demand increasingly Many, the such as preparation of nano-fiber film and research, the study on the modification to nanofiber, even in-situ modified research, therefore, Exploitation one kind can (in situ) modified, continuously prepare what the electrostatic spinning apparatus of multi-layer nano fiber membrane were a need for, this has Experimental study beneficial to electrostatic spinning and practical application, have considerable application prospect.

Content of the invention

It is an object of the invention to provide a kind of Multifunctional static electricity spinning equipment.With realize electrostatic spinning nozzle self-cleaning, Automatically sampling is varied, (in situ) is modified, continuously prepare the functions such as multi-layer nano fiber membrane.

The present invention also aims to designing the electrostatic spinning apparatus of multiple electrostatic spinning chambers, phase between each electrostatic spinning chamber Mutually independent, it does not interfere with each other, to lift the efficiency of electrostatic spinning and to realize being carried out continuously the preparation of multi-layer nano fiber membrane.

The present invention also aims to designing a kind of shower nozzle fixator, to realize shower nozzle self-cleaning during electrostatic spinning, Eliminate dropping liquid during electrostatic spinning and clogging it is ensured that being smoothed out of electrostatic spinning.

The present invention also aims to design a kind of metal ring as electrostatic spinning negative electrode (earth terminal), make negative electrode with Sample receiver separate, thus sample receiver both can with general sample disc, directly receive electrostatic spinning product it is also possible to Realize receiving Electrospun product with special reception device (as beaker, culture dish etc.), to realize the in-situ modified of electrostatic spinning.

The present invention also aims to designing a kind of sample disc fixator, sample disc fixator is moulding of hollow positive six prismsby Material thin slice, the outside hub of each side is provided with the sample cell of circle, for placing sample disc；In addition to the sample cell of bottom surface, It is respectively and fixedly provided with a magnetic stirring apparatus immediately below remaining each sample cell, by magnetic force, the sample disc having built-in magnetic stripe is fixed on On sample cell, and so that sample disc can be rotated in sample cell；The control that positive six prismsby connects rotary electric machine outside can timing edge The central shaft rotation of positive six prismsby, realize sample disc switching between different units takes place, to reach in different electrostatic spinnings Receive Electrospun product between room, prepare multi-layer nano fiber membrane, the sampling of Electrospun product and the purpose loading sample disc.

The present invention also aims to designing a sample pretreatment unit in electrostatic spinning apparatus, pretreatment unit is permissible Electrospun product is dried it is also possible to create specific in pretreatment unit by heating or putting into the modes such as drier Gas atmosphere (as ammonia) etc. realizes the direct pretreatment of Electrospun product.

The present invention also aims to designing a sampling unit in electrostatic spinning apparatus, electricity is realized in the effect using gravity Spinning is sampled automatically, can put into some reagent in sampling unit, receive Electrospun product, realize changing of Electrospun product Property.

The present invention also aims to providing one kind to enter disk device, after completing automatically to sample for electrostatic spinning, supplement sample Disk, enables electrostatic spinning persistently to go on.

The present invention also aims to designing a kind of sample disc, material is the erosion-resisting material such as polytetrafluoroethylene (PTFE) or pottery Material, rounded thin slice；The receiving plane of sample disc has a lot of kicks, makes Electrospun product be readily removed or to sample It is ensured that Electrospun product can be fully contacted with modifying agent when Electrospun product on disk is directly modified；Sample disc centre is embedding Enter a bar magnet so that sample disc can rotate in the presence of magnetic stirring apparatus it is ensured that Electrospun product equably falls On sample disc, form homogeneous film.

Adopt technical scheme as follows for realizing the purpose of the present invention:

A kind of Multifunctional static electricity spinning equipment of the present invention, including the electrostatic spinning being provided with housing and housing Room, pretreatment chamber, sampler chamber, enter disk room and sample receiving chamber, electrostatic spinning chamber in housing, pretreatment chamber, sampler chamber, enter disk Room and sample receiving chamber cover sealing it is characterised in that sample receiving chamber is arranged at casing center, sample receiving chamber by cloche By cylinder dividing plate and electrostatic spinning chamber, pretreatment chamber, sampler chamber with enter disk room and separate；Pass through horizontal baffle outside cylinder dividing plate Be separated into upper and lower two-layer, be distributed with above horizontal baffle be divided into by dividing plate between left, center, right three and its separate Electrostatic spinning chamber, its middle electrostatic spinning chamber is located at vertical direction, and left side electrostatic spinning chamber and right side electrostatic spinning chamber divide Wei Yu not middle electrostatic spinning chamber both sides；It is being provided with pretreatment chamber, sampler chamber and entering disk room below horizontal baffle, adjacent Between separated by dividing plate.

It is equipped with a shower nozzle fixator in the electrostatic spinning chamber of left, center, right, shower nozzle fixator is used for stationary nozzle；Described The top of shower nozzle is connected with silica gel catheter, and Electrospun solution can be transported to shower nozzle by silica gel catheter, and shower nozzle connects outside High voltage power supply anode；Metal ring is located at the lower section of shower nozzle and is fixed on cylinder bulkhead sides, by wire and height The negative electrode of voltage source connects；Heating rod is located at metal ring dead astern and is fixed on cylinder dividing plate；Described shower nozzle fixator includes Height regulating rod, cleaning motor, fixed plate, fixing pipe, connecting plate, sprayer channel, metal knob, rotating bars and rotary shaft；High Degree adjusting rod passes through cloche and top to be located at electrostatic spinning outdoor, bottom in electrostatic spinning chamber interior, by pulling and solid Determine height regulating rod and can control the distance between shower nozzle and metal ring；The bottom of height regulating rod is fixed with cleaning motor, clearly Wash motor bottom and be fixed with fixing pipe；Fixed connecting plate on the left of fixing pipe, connecting plate end is fixed with and shower nozzle can be allowed to pass through Sprayer channel, be provided with metal knob with stationary nozzle in sprayer channel opposite side center position；Fixing on the right side of fixing pipe Fixed plate, a breach that rotating bars can be allowed to pass through is provided with fixed plate, breach can retain rotating bars from syringe needle upper band mistake The drop coming or the silk of condensation；One rotary shaft being connected with rotating bars is provided with the center line of fixing pipe, rotary shaft is even Then clean motor, cleaning motor control rotary shaft rotates, drive the rotating bars that rotation shaft end is provided with to rotate, rotating bars are in rotation The silk of the drop of shower nozzle end or condensation can be scraped during turning and play cleaning sprayer, prevent the effect blocking.

Sample receiving chamber is in integrally cylinder, has three-decker from outside to inside, is sequentially: cylinder dividing plate, sample disc are fixed Device and magnetic stirring apparatus；The side of cylinder dividing plate be provided with respectively with sampler chamber, enter disk room, left, center, right electrostatic spinning chamber and pre- Sampling channel that process chamber is connected, enter disk passage, fiber channel and pre-processing channel；In the fiber channel positioned at cylinder dividing plate Fix a heating rod with pre-processing channel dead astern respectively, for controlling the temperature of electrostatic spinning chamber and pretreatment chamber；In place A fixed metal ring on cylinder dividing plate above the fiber channel, sample disc fixator is the plastics of hollow positive six prismsby Thin slice, is located at cylinder diaphragm internal；The center of each side of six sides of sample disc fixator is provided with a circular sample Product groove, uppermost circular sample cell is located at the underface of fiber channel, and each sample cell is used for placing sample receiver, sample Product receiver adopts sample disc, beaker or culture dish, and sample disc is used for receiving Electrospun product, and beaker or culture dish are used for containing Put reagent, to realize the in-situ modified of electrostatic spinning；Sealing strip is fixed with every seamed edge of sample disc fixator, every close Strip of paper used for sealing is contacted with the corresponding position of cylinder dividing plate.

Pretreatment chamber is located at immediately below the electrostatic spinning chamber of left side, and the lower left corner of sample receiving chamber, by pretreatment chamber's passage The fixed heating rod in side, for controlling the temperature of pretreatment chamber, pretreatment chamber is mainly used in the interim storage of Electrospun product Deposit and preliminary treatment, pass through heating in pretreatment chamber or put into drier or create specific gas atmosphere to electrospinning Silk product carries out some pretreatments.

Sampler chamber in pretreatment chamber and the centre entering disk room, in the underface of left side electrostatic spinning chamber and sample receiving chamber, It is connected by the sample receiving chamber of sampling channel and center, sampler chamber is mainly used in automatically collecting Electrospun product and straight Connect modified Electrospun product；When sample disc enters sampler chamber, the disappearance due to magnetic force the effect in gravity, Electrospun product Sampler chamber will be fallen into together with sample disc and be collected, realize the process of sampling automatically；In sampler chamber bottom, sampling is logical The container equipped with special modified liquid is put into, for receiving sample disc and the Electrospun collected in sample disc being produced immediately below road Product are modified.

Enter disk room and be located at immediately below the electrostatic spinning chamber of right side, the lower right corner of sample receiving chamber, it is close to sampler chamber；Enter disk room Comprise one and enter disk device, be connected with sample receiving chamber by entering disk passage, for the sample disc new toward sample cell conveying, with complete Become electrostatic spinning varies process it is ensured that electrostatic spinning can persistently be carried out.

It is internally located at five samples being symmetrically distributed with above the bottom surface of sample disc fixator in sample disc fixator It is respectively and fixedly provided with a magnetic stirring apparatus, each is located at the magnetic stirring apparatus at the sample cell back side at the back side of each sample cell of groove The interior sample disc being provided with magnetic stripe is inhaled on corresponding sample cell by magnetic force energy, and magnetic stirring apparatus rotates and respective sample disk can be driven to exist Rotation in sample cell；The sample disc fixator of positive six prismsby connects the control lower energy timing of rotary electric machine outside along positive six prismsby Central shaft rotates, and drives switching between different chamber for the sample disc, receives electricity to reach between different electrostatic spinning chambers Spinning, prepare multi-layer nano fiber membrane, the sampling of Electrospun product and load sample disc.

Described enter disk device include sample disc, sabot cylinder, push-plate device, pushing cylinder device and correcting wedge；Correcting wedge passes through draw-in groove It is fixed on on the bottom surface of disk room, towards entering disk passage, correcting wedge plays the effect of fixing pushing cylinder device on the inclined-plane of correcting wedge； Pushing cylinder device is located between correcting wedge and sabot cylinder, plays promotion, connection and the effect supporting sabot cylinder；Pushing cylinder device includes bottom Plate, outer spring and base plate, outer spring two ends fixed upper plate and base plate respectively, upper plate is fixed on fixed plate by draw-in groove On, and base plate is fixed on the inclined-plane of correcting wedge by draw-in groove；When sample disc fixator is in non-sampled or varies state During without rotating, under the Action of Gravity Field of the push-plate device above upper plate, outer spring is in the state compressed all the time, is pressed The outer spring of contracting produces a thrust, sabot cylinder can be pushed sample receiving chamber, so that sabot cylinder is abutted against on sample disc fixator； Push-plate device includes movable plate, inner spring and fixed plate, and sabot cylinder external diameter is more smaller than the internal diameter entering disk passage, makes sabot cylinder upper end firm It is enclosed within well on disk passage, can move between disk room in sample receiving chamber and entering, and not fall out；One end of inner spring is fixed Movable plate, the other end is fixed in fixed plate, inner spring and movable plate are contained in sabot cylinder, and fixed plate is fixed on sabot cylinder bottom End；When sample disc fixator is in non-sampled or varies state without rotating, in the sample disc positioned at movable plate top Action of Gravity Field under, inner spring is in the state compressed all the time, and the inner spring that compressed produces a thrust and promotes movable plate, Sample disc is pushed sample cell, so that sample disc is withstood on sample cell, the sample disc withstanding on sample cell held by magnetic stirring apparatus and Inhale in sample cell；When sample disc fixator is in sampling or when varying state and starting to rotate counterclockwise 60 °, by located at Sampler chamber and the sealing strip extruding entering Pan Shichu, and promote the upper end of sabot cylinder, make outer spring be compressed, sabot cylinder and sample disc Pushed back together into disk room, and the sample disc being in the top of movable plate is inhaled, by magnetic force, the sample being rotated in sample cell It is indoor that right side electrostatic spinning brought into by product disk fixator；When sample disc fixator rotate terminate after, the top of movable plate change one Individual new sample disc, in the presence of outer spring force, pushing cylinder device is pushed back sample receiving chamber again, and the promotion in inner spring Under, new sample disc is pushed into sample cell again, and the new sample disc on the top of movable plate is held by magnetic stirring apparatus again, and fixing In sample cell；So, complete being automatically replenished of sample disc after the once rotation of sample disc fixator, make Static Spinning Silk can persistently be carried out.

Described middle electrostatic spinning chamber is located at vertical direction, and left side electrostatic spinning chamber and right side electrostatic spinning chamber and centre The angle of electrostatic spinning chamber is 60 °, and sample disc fixator is the plastic tab of hollow positive six prismsby, and sample disc fixator is outside Connect and periodically rotate counterclockwise so that sample disc can switch between different chamber, sample can be worked as under the control of rotary electric machine Disk fixator first time turns over 60 °, sample disc from enter disk room enter right side electrostatic spinning chamber start receive Electrospun product；Work as sample Product disk fixator turns over 60 ° for the second time, and sample disc electrostatic spinning chamber in the middle of right side electrostatic spinning chamber enters, to receive Static Spinning Silk product；When sample disc fixator third time turns over 60 °, sample disc enters left side electrostatic spinning chamber from middle electrostatic spinning chamber, To receive electrostatic spinning product；Turn over 60 ° when sample disc fixator 4th time, sample disc is from left side electrostatic spinning chamber enters in advance Reason room, to realize the pretreatment to electrostatic spinning product；Turn over 60 ° when sample disc fixator 5th time, sample disc is from pretreatment Room enters sampler chamber, now because the sample cell at sampler chamber is no installed magnetic stirring apparatus and so that the magnetic force of sample disc is disappeared, sample Product disk under gravity, falls into sampler chamber automatically, to realize the automatic data collection of sample；Turn for 6th time when sample disc fixator Cross 60 °, empty sample cell enters into disk room from sampler chamber, in entering disk room enter disk device in the presence of, sample cell is reinstalled Sample disc.

Described sample disc is thin rounded flakes, and material is pottery or polytetrafluoroethylene (PTFE), has much tiny in receiving plane Projection, projection can allow Electrospun product contact with sample disc will not be too tight, on the one hand conveniently take off Electrospun product, another Aspect can make the Electrospun product on sample disc surface when pretreatment chamber or sampler chamber carry out some process, so that Electrospun is produced Product are processed more abundant；Embed a magnetic stripe in the back side centre of sample disc, magnetic stripe is comprised in inside sample disc, embedding The magnetic stripe entering can make sample disc rotate in the presence of magnetic stirring apparatus, allows the Electrospun product receiving to be uniformly dispersed In sample disc.

Preferably, three electrostatic spinning chambers in above-mentioned electrostatic spinning apparatus are mainly used in electrostatic spinning, each electrostatic The design of spinning chamber is consistent, all comprises a shower nozzle fixator, a heating rod and a metal ring；Shower nozzle fixator is located at The top of electrostatic spinning chamber, for stationary nozzle；Shower nozzle is the syringe needle of metal material, by a metal knob and high voltage power supply Anode be connected, the top of shower nozzle is connected with silica gel catheter, in the presence of outside plug-flow pump, Electrospun solution pass through silica gel Conduit is transported to shower nozzle；Metal ring, in the underface of shower nozzle, is fixed on cylinder bulkhead sides, by wire and high pressure The negative electrode of power supply connects (ground connection)；Heating rod is fixed on cylinder dividing plate, in metal ring dead astern, for controlling Static Spinning The temperature of cabinet.Each electrostatic spinning chamber, is controlled by single high voltage power supply and heater, it is possible to achieve synchronization phase respectively Electrostatic spinning under the conditions of same, or the electrostatic spinning under synchronization each different condition.

Preferably, the shower nozzle fixator in above-mentioned electrostatic spinning apparatus includes a height regulating rod and a cleaning motor. Height regulating rod passes through cloche, top in outer electrostatic spinning outdoor, bottom in electrostatic spinning chamber interior, by pulling and solid Determine height regulating rod, the distance of shower nozzle and metal ring can be controlled；The fixed small electrical in bottom of height regulating rod Machine cleans motor, and under the control of motor, the rotating bars of its end of rotary shaft band rotate, and rotating bars are during rotation The silk of the drop of shower nozzle end or condensation can be scraped, and take on the fixed plate on side, to play cleaning sprayer, prevent The only effect of blocking.

Preferably, the sample receiving chamber in above-mentioned electrostatic spinning apparatus is located at the center of electrostatic spinning apparatus, point Become three layers, be respectively as follows: a cylinder dividing plate, a sample disc fixator and five magnetic stirring apparatus from outside to inside.Cylinder dividing plate It is fixed on the outermost layer of sample receiving chamber；Fix respectively in the fiber channel (three) of cylinder dividing plate and pre-processing channel dead astern One heating rod, for the temperature of electrostatic spinning chamber and pretreatment chamber；Fixing above the fiber channel (three) of cylinder dividing plate A metal ring, as the negative electrode of electrostatic spinning.

Preferably, the sample disc fixator in above-mentioned electrostatic spinning apparatus is the plastic tab of hollow positive six prismsby, peace It is contained in cylinder diaphragm internal；Six center side of sample disc fixator, are respectively equipped with a circular sample cell, for placing Sample receiver (as sample disc, beaker or culture dish etc.), receives Electrospun product；Six seamed edges in sample disc fixator Fixing a sealing strip respectively, playing the effect of isolation it is ensured that there is certain seal between unit, it is to avoid be different Interfere between unit；Inside sample disc fixator, in addition to the sample cell of bottom, remaining each sample cell just under Side's fixed magnetic stirring apparatus (totally five) respectively, magnetic stirring apparatus plays the work(holding sample disc and being sample disc rotation Energy；Under the control of motor, sample disc fixator can periodically the certain angle of rotate counterclockwise so that sample disc is in electrostatic Switch between different units in device for spinning, to reach specific purpose, taking one of circulation as a example: when sample disc is solid Determining device first time turns over 60 °, and sample disc is from entering disk room and enter electrostatic spinning chamber to start to receive Electrospun product；When sample disc is fixed Device turns over 60 ° for the second time, and sample disc enters electrostatic spinning chamber from electrostatic spinning chamber, to receive electrostatic spinning product；Work as sample disc Fixator third time turns over 60 °, and sample disc enters electrostatic spinning chamber from electrostatic spinning chamber, to receive electrostatic spinning product；Work as sample Product disk fixator turns over 60 ° the 4th time, and sample disc enters pretreatment chamber from electrostatic spinning chamber, to realize to electrostatic spinning product Pretreatment；Turn over 60 ° when sample disc fixator 5th time, sample disc enters sampler chamber from pretreatment chamber, now due to magnetic force Disappear, sample disc under gravity, calls in sampler chamber automatically, to realize the automatic data collection of sample；When sample disc fixator Turn over 60 ° 6th time, empty sample cell enters into disk room from sampler chamber, and in the presence of entering disk device, sample cell is reinstalled sample Product disk.

Preferably, above-mentioned electrostatic spinning apparatus pretreatment chamber immediately below electrostatic spinning chamber, sample receiving chamber The lower left corner, in the fixed heating rod in pretreatment chamber's passage side, for controlling the temperature of pretreatment chamber.Pretreatment chamber is main Interim storage for Electrospun product and preliminary treatment, by heating or can put into drier to electrospinning in pretreatment chamber Silk product is dried process and it is also possible to create specific gas atmosphere (as ammonia atmosphere) in pretreatment chamber, Electrospun is produced Product carry out some pretreatments.

Preferably, above-mentioned electrostatic spinning apparatus sampler chamber in pretreatment chamber and the centre entering disk room, quiet in left side Electrospinning cabinet and the underface of sample receiving chamber, are connected by the sample receiving chamber of sampling channel and center, sampler chamber It is mainly used in automatically collecting Electrospun product and direct modified Electrospun product；When sample disc enters sampler chamber, due to magnetic force Disappearance and the effect in gravity, Electrospun product will fall into sampler chamber together with sample disc and be collected, realize from The process of dynamic sampling；In sampler chamber bottom, the container equipped with special liquid (modified solution etc.) immediately below sampling channel, can be put into, As beaker or culture dish, can be used to receive sample disc, the Electrospun product that sample disc is collected above is modified, In the presence of the magnetic stirring apparatus that container bottom is placed, the sample being collected into can rotate, and make Electrospun product and change Property solution is fully contacted.

Preferably, above-mentioned electrostatic spinning apparatus enter disk room electrostatic spinning chamber just under, the bottom right of sample receiving chamber Angle, is close to sampler chamber；Enter disk room mainly to include, into disk device, being connected with sample receiving chamber by entering disk passage, for toward sample The product groove new sample disc of conveying, varies process it is ensured that electrostatic spinning can persistently be carried out with complete electrostatic spinning.

Preferably, the disk device that enters in above-mentioned electrostatic spinning apparatus includes sabot cylinder, push-plate device, pushing cylinder device and a wedge shape Cushion block；Correcting wedge is fixed on on the bottom surface of disk room by draw-in groove, and inclined-plane, towards entering disk passage, plays the work of fixing pushing cylinder device With；Pushing cylinder device, between correcting wedge and sabot cylinder, plays promotion, connection and the effect supporting sabot cylinder；Pushing cylinder device includes Base plate, outer spring and lower shoe, outer spring two ends fixed upper plate and lower shoe respectively, upper plate is fixed on by draw-in groove In fixed board, and lower shoe is fixed on the inclined-plane of correcting wedge by draw-in groove；When sample disc fixator is in static not rotation When, that is, non-sampled or non-vary state in the case of, under the Action of Gravity Field of the push-plate device at upper plate top, outer spring is all the time It is in the state compressed, the outer spring being compressed produces a thrust, sabot cylinder can be pushed sample receiving chamber, make sabot cylinder Abut against on sample disc fixator；Push-plate device includes a movable plate, an inner spring and a fixed plate, and sabot cylinder external diameter ratio enters disk The internal diameter of passage is smaller, so that sabot cylinder upper end is just enclosed within disk passage, can move between disk room in sample receiving chamber and entering, And do not fall out；The fixed movable plate in one end of inner spring, the other end is fixed in fixed plate, and inner spring and movable plate are contained in In sabot cylinder, fixed plate is fixed on sabot cylinder bottom；When sample disc fixator be in static do not rotate when, that is, non-sampled or Non- vary state in the case of, under the Action of Gravity Field positioned at the sample disc on movable plate top, inner spring is in all the time and is compressed State, the inner spring that compressed produces a thrust and promotes movable plate, and sample disc is pushed sample cell；Sample disc is made to withstand on sample On product groove, the sample disc withstanding on sample cell is held and inhaled in sample cell by magnetic stirring apparatus；When sample disc fixator start inverse When hour hands rotate 60 °, that is, in the case of being in sampling or varying state, the upper end of sabot cylinder is in sampler chamber and is entered disk The sealing strip extruding of room, outer spring compressed, sabot cylinder and sample disc by together with push back into disk room, and be in movable plate top Sample disc the sample disc fixture belt that has been rotated in sample cell is inhaled by magnetic force to enter electrostatic spinning indoor；Work as sample disc Fixator rotate terminate after, movable plate top change a new sample disc, in the presence of outer spring force, pushing cylinder device Pushed back sample receiving chamber again, and under the promotion of inner spring, new sample disc is pushed into sample cell, movable plate top again New sample disc held by magnetic stirring apparatus again, and be fixed in sample cell；So, once turning through sample disc fixator Complete being automatically replenished of sample disc after dynamic, so that electrostatic spinning is persistently carried out.

Preferably, the sample disc in above-mentioned electrostatic spinning apparatus is thin rounded flakes, and material is ceramic or poly- four PVF, is provided with much tiny projection in receiving plane, and these projections can allow Electrospun product contact with sample disc will not be too Closely, on the one hand conveniently take off Electrospun product, the Electrospun product that on the other hand can make sample disc surface is in pretreatment chamber Or when sampler chamber carries out some process, Electrospun product can be processed more abundant；Embedding in the back side centre of sample disc Enter a magnetic stripe, magnetic stripe is comprised in inside sample disc, embedded magnetic stripe can make sample disc in the presence of magnetic stirring apparatus Rotate, allow the Electrospun product receiving to be evenly dispersed in sample disc.

It can be seen from above-mentioned technical scheme that, the present invention has the advantage that

The present invention has multiple independent electrostatic spinning chambers, it is possible to achieve multiple electrostatic spinning chambers under the same conditions or Carry out electrostatic spinning, to prepare a kind of nanofiber simultaneously, preparation multiple fiber or preparation multilayer are received under different condition simultaneously The functions such as rice film, improve the efficiency of electrostatic spinning；Obtain the product shown in Fig. 3, it is observed from fig. 1 that what 1h sampling obtained The no obvious difference of nanofiber diameter size, distribution is relatively uniform.

This electrostatic spinning apparatus has shower nozzle fixator, it is possible to achieve the automatic cleaning (removing dropping liquid and filament) of shower nozzle, Overcome shower nozzle clogging, allow electrostatic spinning to be smoothed out.

This electrostatic spinning apparatus adopts metal ring negative electrode the most, so that negative electrode is separated with sample disc, improves sample disc Flexibility, under the cooperation of sample disc fixator, it is possible to achieve the automatic sampling of Electrospun product, the function such as (in situ) modification.

This electrostatic spinning apparatus has sample disc fixator, by the rotation of sample disc fixator, makes sample disc in difference Unit between switch over, the automatic of multi-layer nano fiber, the pretreatment of Electrospun product and Electrospun product is prepared in realization The functions such as sampling.

This electrostatic spinning apparatus has pretreatment chamber, and Electrospun product can be carried out with some pretreatments.

This electrostatic spinning apparatus has sampler chamber, it is possible to achieve the automatic sampling of Electrospun product or modification.

Electrostatic spinning apparatus have into disk room, automatically can supplement sample disc toward sample receiving chamber, so that electrostatic spinning is continued Carry out.

Brief description

Fig. 1 is that in polymer solution electro-spinning process, shower nozzle long filament causes stifled phenomenon.From the figure, it can be seen that in electrostatic spinning During it may be possible to because solvent volatilizees too fast, the reason polymer concentration is too high, lead to the drop of shower nozzle to have little time to be formed Jet and condense, with the prolongation of electrostatic spinning time, the drop of condensation is slowly elongated, finally be in strip, cause shower nozzle block up Live, hamper carrying out further of electrostatic spinning.

Sem after Fig. 2 is polymer solution electrostatic spinning 10h schemes.The polymerization that electrostatic spinning obtains as we can see from the figure Substantially, the polymer fiber obtaining is not bery uniform for fiber diameter difference in size.

Sem figure after Fig. 3 certain polymer solution electrostatic spinning 1h.Compared with Fig. 2, it is observed from fig. 1 that 1h sampling obtains The no obvious difference of the nanofiber diameter size obtaining, distribution is relatively uniform.Electrostatic spinning obtained by Fig. 2 and Fig. 3 produces The same polymer solution of product obtains under identical electrospinning conditions, and the sample time in Fig. 2 is 10h, The sample time in Fig. 3 is 1h, the pattern of fiber have than larger difference it may be possible to because the electrostatic spinning time long, The Electrospun product of sample disc (is negative electrode) itself is thicker, have impact on electric-field intensity so that polymer fiber pattern occurs The change compared.

Fig. 4 is the front view of the present invention.

Fig. 5 is the shower nozzle fixator schematic diagram of the present invention.

Fig. 6 is the cylinder dividing plate schematic diagram of the present invention.

Fig. 7 is the sample disc fixator schematic diagram of the present invention.

Fig. 8 enters disk device schematic diagram for the present invention's.

Fig. 9 is the sample disc schematic diagram of the present invention.

Specific embodiment

In order to more clearly explain the present invention, will be briefly described by some accompanying drawings below it should be apparent that, below Listed accompanying drawing is only some embodiments of the present invention, for those of ordinary skill in the art, is not paying creativeness On the premise of work, other accompanying drawings can also be obtained according to these accompanying drawings.

Below in conjunction with accompanying drawing 4- Fig. 9, the present invention is described in more detail, so that those skilled in the art can reference And implement.

As shown in Figure 4, a kind of Multifunctional static electricity of present invention spinning equipment, including seven units: electrostatic spinning chamber (e1, e2 and e3), pretreatment chamber p, sampler chamber s, enter disk room c and sample receiving chamber r, and unit is sealed in cloche 36 Interior；As shown in figure 4, adjacent unit is separated by dividing plate, on the upper strata of device, that is, on horizontal baffle 37, be three side by side and Separate electrostatic spinning chamber (e1, e2 and e3), wherein middle electrostatic spinning chamber e2 is in vertical direction, and left side electrostatic spinning Room e1 and right side electrostatic spinning chamber e3 is 60 ° with the angle of middle electrostatic spinning chamber e2, side by side, abuts against middle electrostatic spinning Room e2 both sides, are separated by dividing plate；The lower floor of device, that is, under horizontal baffle 37, is from left to right followed successively by pretreatment chamber p, sampling Room s, enters disk room c, and adjacent cells are separated by dividing plate；The mid portion of electrostatic spinning apparatus is sample receiving chamber r, sample receiving chamber R is separated with other units by cylinder dividing plate 13；By six circular channels (see Fig. 6) of cylinder dividing plate 13 side: sampling is logical Road 14, enter disk passage 15, fiber channel 16 (three) and pre-processing channel 18 respectively with sampler chamber s, enter disk room c, electrostatic spinning Room (e1, e2, and e3) and pretreatment chamber p are connected.

Three electrostatic spinning chambers (e1, e2 and e3) are mainly used in electrostatic spinning, as shown in Figure 4, Figure 5 and Figure 6, electrostatic spinning Room includes shower nozzle fixator (see Fig. 5), heating rod 19 and metal ring 17；Shower nozzle fixator is located at the top of electrostatic spinning chamber, For stationary nozzle 10；Shower nozzle 10 is the syringe needle of metal material, and top is connected with silica gel catheter 6, in outside plug-flow pump Under promotion, Electrospun solution is delivered to shower nozzle, the anode of outside high voltage power supply is connected to shower nozzle 10, be that shower nozzle applies an electricity Pressure；Metal ring 17, in the underface of shower nozzle 10, is fixed on cylinder dividing plate 13 side, by the moon of wire and high voltage power supply Pole connects (ground connection)；Forming high voltage electric field between shower nozzle 10 and metal ring 17, the Electrospun solution of shower nozzle 10 end is being produced A raw effect, to carry out electrostatic spinning；Heating rod 19 is located at metal ring 17 dead astern, is fixed on cylinder dividing plate 13 (this figure In grid, be the information representation for the ease of drawing, the actual product of cylinder dividing plate 13 is except six circular channels are (see figure 6): sampling channel 14, enter outside disk passage 15, fiber channel 16 (three) and pre-processing channel 18, other parts are airtight There is no hole or grid) on, heating rod 19 is used for controlling the temperature of electrostatic spinning chamber.Three electrostatic spinning chambers (e1, e2 and E3 design) is consistent, is controlled by single high voltage power supply and heater respectively, it is possible to achieve spinning while under the same terms, Or the spinning under different condition.

Shower nozzle fixator includes height regulating rod 1, cleaning motor 2, fixed plate 3, fixing pipe 4, connecting plate 5, silica gel catheter 6th, sprayer channel 8, metal knob 9, shower nozzle 10, rotating bars 11 and rotary shaft 12.Height regulating rod 1 passes through cloche 36, its top End is located at electrostatic spinning outdoor, and bottom, in electrostatic spinning chamber interior, by pulling and level altitude adjusting rod 1, can control Shower nozzle 10 and the distance of metal ring 17；The fixed micro-machine in bottom of height regulating rod 1 cleans motor 2, clearly Wash the fixed plastic tube fixing pipe 4 in motor 2 bottom；In the fixed connecting plate 5 in fixing pipe 4 left side, connecting plate 5 end Fixed sprayer channel 8, can allow shower nozzle 10 pass through, and by be located at the metal knob 9 of sprayer channel 8 opposite side center with Stationary nozzle 10；Metal knob 9 passes through wire, connects the anode of high voltage power supply, applies a voltage on shower nozzle 10；Fixing The fixed fixed plate 3 in pipe 4 right side, is provided with a breach 7 in fixed plate 3, rotating bars 11 just can be allowed to pass through, play retention Drop or the silk of condensation that rotating bars 11 come from syringe needle upper band；One and rotating bars are provided with the center line of fixing pipe 4 The rotary shaft 12 of 11 connections, rotary shaft 12 is connected to clean motor 2, and under the control of cleaning motor, rotary shaft 12 drives and rotates The rotating bars 11 that axle 12 end is provided with rotate, and rotating bars 11 by the drop of shower nozzle 10 end or can coagulate during rotation The silk of knot scrapes, and takes on fixed plate 3, to play cleaning sprayer, prevents the effect blocking.

Sample receiving chamber r is located at the center of electrostatic spinning apparatus, as shown in Fig. 4, Fig. 6 and Fig. 7, sample receiving chamber r Overall is in cylinder, is divided into three layers, is respectively as follows: cylinder dividing plate 13, sample disc fixator 20 and magnetic stirring apparatus 23 from outside to inside. Cylinder dividing plate 13 is fixed on the outermost layer of sample receiving chamber r, and the side of cylinder dividing plate 13 is provided with six circular channels: sampling Passage 14, enter disk passage 15, fiber channel 16 (three) and pre-processing channel 18 respectively with sampler chamber s, enter disk room c, Static Spinning Cabinet (e1, e2, e3) and pretreatment chamber p are connected；Fiber channel 16 (three) and pre-processing channel 18 in cylinder dividing plate 13 A heating rod 19 is fixed in dead astern respectively, for controlling the temperature of electrostatic spinning chamber (e1, e2, e3) and pretreatment chamber p；Justifying The fixed metal ring 17 in fiber channel 16 top of cylinder dividing plate 13.Sample disc fixator 20 is moulding of hollow positive six prismsby Material thin slice, is located inside cylinder dividing plate 13；Six center side of sample disc fixator 20, i.e. the underface of fiber channel 16, It is respectively equipped with the sample cell 22 of circle, for placing sample receiver (as sample disc, beaker or culture dish etc.), receive electrospinning Silk product；Fix a sealing strip 21 respectively in six seamed edges of sample disc fixator 20, play the effect of isolation it is ensured that each Between unit, there is certain seal, it is to avoid interfere；Sample disc fixator 20 is the plastic housing in six prisms, each The outside hub of side is provided with the sample cell 22 of circle, for placing sample disc；Except the sample cell of bottom is not provided with a magnetic Power agitator 23, the fixed magnetic stirring apparatus 23 of difference immediately below remaining each sample cell 22, it is provided with interior by magnetic force The sample disc of magnetic stripe is fixed on sample cell 22, and magnetic stirring apparatus rotates and drives sample disc can rotate in sample cell；Just The control that the sample disc fixator 20 of six prisms connects rotary electric machine outside can regularly rotate along the central shaft of positive six prismsby, and The sample disc spins in sample cell 22 are driven to realize switching between different units room for the sample disc, to reach different quiet Receive Electrospun product between electrospinning cabinet, prepare multi-layer nano fiber membrane, the sampling of Electrospun product and load sample disc Purpose；Inside sample disc fixator 20, a fixed magnetic stirring apparatus 23 is (common respectively for the underface of each sample cell 22 Five)；Sample disc fixator 20, connects under the control of rotary electric machine, sample disc fixator 20 can periodically revolve counterclockwise outside Turn certain angle so that sample disc switches between different units in electrostatic spinning apparatus, to reach specific purpose, Taking one of circulation as a example: turn over 60 ° when sample disc fixator 20 first time, sample disc enters right side electrostatic from entering disk room c Spinning chamber e3 starts to receive Electrospun product；When sample disc fixator 20 turns over 60 ° for second, drive sample disc from right side electrostatic Spinning chamber e3 enters middle electrostatic spinning chamber e2, to receive electrostatic spinning product；When sample disc fixator 20 third time turns over 60 °, sample disc is driven to enter left side electrostatic spinning chamber e1 from middle electrostatic spinning chamber e2, to receive electrostatic spinning product；Work as sample Product disk fixator 20 turns over 60 ° the 4th time, drives sample disc to enter pretreatment chamber p from left side electrostatic spinning chamber e1, right to realize The pretreatment of electrostatic spinning product；Turn over 60 ° 5th time when sample disc fixator 20, drive sample disc to enter from pretreatment chamber p Sampler chamber s, now because sample disc fixator 20 bottom surface is fitted without magnetic stirring apparatus 23 and makes the disappearance of magnetic force, sample disc exists In the presence of gravity, automatically fall into sampler chamber s, to realize the automatic data collection of sample；Turn over for 6th time when sample disc fixator 20 60 °, drive empty sample cell 22 to enter into disk room c from sampler chamber s, enter disk room c enter disk device in the presence of, sample cell 22 weight Sample disc on new clothes.

As shown in Figure 4 and Figure 6, pretreatment chamber p is immediately below the electrostatic spinning chamber e1 of left side, the lower left corner of sample receiving chamber r, In the fixed heating rod 19 in pretreatment chamber's passage side, for controlling the temperature of pretreatment chamber p.Pretreatment is mainly used in electricity The interim storage of spinning and preliminary treatment, by heating or can put into drier drying Electrospun product in pretreatment chamber Product；Or create specific gas atmosphere (as ammonia atmosphere) and some pretreatments are carried out to Electrospun product.

As Fig. 4, sampler chamber s in pretreatment chamber p and the centre entering disk room c, in middle electrostatic spinning chamber and sample receiving chamber r Underface, be connected by the sample receiving chamber r of sampling channel 14 and center, sampler chamber s is mainly used in automatically collecting Electrospun product and directly modified Electrospun product；When sample disc enter sampler chamber s when, due to magnetic force disappearance and in gravity Effect, Electrospun product will be fallen into sampler chamber s together with sample disc and be collected, and realize the process of sampling automatically；? Sampler chamber s bottom, puts into the container equipped with special modified liquid immediately below sampling channel 14, such as beaker or culture dish, permissible It is used for receiving sample disc, the Electrospun product that sample disc is collected above is modified, the magnetic force placed in container bottom stirs In the presence of mixing device, the sample being collected into can rotate, and so that Electrospun product and modified solution is fully contacted.

As shown in Figure 4 and Figure 8, enter disk room c right side electrostatic spinning chamber e3 just under, the lower right corner of sample receiving chamber r, adjacent Sampler chamber s；Enter disk room c mainly to include, into disk device, being connected with sample receiving chamber r by entering disk passage 15, for toward sample Groove 22 conveys new sample disc, varies process it is ensured that electrostatic spinning can persistently be carried out with complete electrostatic spinning.

As shown in figure 8, entering disk device to include sample disc 24, sabot cylinder 26, push-plate device, pushing cylinder device and correcting wedge 30；Wedge shape Cushion block 30 is fixed on on the bottom surface of disk room c by draw-in groove, and towards entering disk passage 15, correcting wedge 30 plays fixing pushing cylinder on inclined-plane The effect of device；Pushing cylinder device, between correcting wedge 30 and sabot cylinder 26, plays promotion, connection and the effect supporting sabot cylinder 26； Pushing cylinder device includes upper plate 28, outer spring 31 and base plate 29, outer spring 31 two ends fixed upper plate 28 and base plate 29 respectively, on Base plate 28 is fixed in fixed plate 27 by draw-in groove, and base plate 29 is fixed on the inclined-plane of correcting wedge 30 by draw-in groove；Work as sample Product disk fixator 20 be in static when not rotating, that is, non-sampled or non-vary state in the case of, on upper plate 28 The Action of Gravity Field of push-plate device under, outer spring 31 is in the state compressed all the time, and the outer spring 31 being compressed produces one and pushes away Sabot cylinder 26 can be pushed sample receiving chamber r by power, so that sabot cylinder 26 is abutted against on sample disc fixator 20；Push-plate device includes Movable plate 25, inner spring 32 and fixed plate 27, sabot cylinder 26 external diameter is more smaller than the internal diameter entering disk passage 15, makes sabot cylinder 26 upper end Just it is enclosed within disk passage 15, can move between the c of disk room in sample receiving chamber r and entering, and not fall out；Inner spring 32 The fixed movable plate in one end 25, the other end is fixed in fixed plate 27, and inner spring 32 and movable plate 25 are contained in sabot cylinder 26, Gu Fixed board is fixed on sabot cylinder 26 bottom；When sample disc fixator 20 be in static do not rotate when, i.e. non-sampled or non-vary In the case of state, under the Action of Gravity Field positioned at the sample disc 24 on movable plate 25 top, inner spring 32 is in all the time and is compressed State, the inner spring 32 being compressed produces thrust and promotes movable plate 25, and sample disc is pushed sample cell 22；Make sample disc 24 withstand on sample cell 22, and the sample disc withstanding on sample cell 22 is held and inhaled in sample cell by magnetic stirring apparatus；Work as sample disc When fixator 20 starts to rotate counterclockwise 60 °, that is, in the case of being in sampling or varying state, the upper end of sabot cylinder 26 is subject to Be in sampler chamber s and enter the sealing strip 21 of disk room c and extrude, outer spring 31 is compressed, sabot cylinder 26 and sample disc 24 by together with push away Back into disk room c, and the sample disc being in movable plate 25 top is inhaled, by magnetic force, the sample disc being rotated in sample cell Fixator 20 is brought in electrostatic spinning chamber e3；When sample disc fixator 20 rotate terminate after, movable plate 25 top change one Individual new sample disc, in the presence of outer spring 31 elastic force, sabot cylinder 26 is pushed back sample receiving chamber r again, and in inner spring Under 32 promotion, new sample disc 24 is pushed into sample cell 22 again, and the new sample disc of movable plate 25 top is stirred by magnetic force again Mix device to hold, and be fixed in sample cell；So, complete sample disc after the once rotation of sample disc fixator 20 It is automatically replenished, so that electrostatic spinning is persistently carried out.

As shown in figure 9, sample disc is thin rounded flakes, material is pottery or polytetrafluoroethylene (PTFE), has very in receiving plane How tiny projection 34, projection 34 can allow Electrospun product contact with sample disc will not be too tight, on the one hand conveniently take off electricity Spinning, on the other hand can make the Electrospun product on sample disc surface carry out some places in pretreatment chamber p or sampler chamber s During reason, Electrospun product is made to be processed more abundant；Embed a magnetic stripe 35, magnetic stripe 35 in the back side 33 centre of sample disc It is comprised in inside sample disc, embedded magnetic stripe 35 can make sample disc rotate in the presence of magnetic stirring apparatus, allow and connect The Electrospun product receiving is evenly dispersed in sample disc.

Although embodiment of the present invention is disclosed as above, it is not restricted to listed in specification and embodiment With, it can be applied to various suitable the field of the invention completely, for those skilled in the art, can be easily Realize other modification, therefore under the universal being limited without departing substantially from claim and equivalency range, the present invention does not limit In specific details with shown here as the legend with description.

Claims (9)

1. a kind of Multifunctional static electricity spinning equipment, including the electrostatic spinning chamber being provided with housing and housing, pretreatment chamber (p), Sampler chamber (s), enter disk room (c) and sample receiving chamber (r), electrostatic spinning chamber in housing, pretreatment chamber (p), sampler chamber (s), Enter disk room (c) and sample receiving chamber (r) and sealing is covered it is characterised in that sample receiving chamber (r) is arranged at shell by cloche (36) Body center, sample receiving chamber (r) passes through cylinder dividing plate (13) and electrostatic spinning chamber, pretreatment chamber (p), sampler chamber (s) and enters disk Room (c) separates；Outward upper and lower two-layer is separated into by horizontal baffle (37) in cylinder dividing plate (13), on horizontal baffle (37) Side is distributed with left, center, right three and is divided into separate electrostatic spinning chamber by dividing plate between it, its middle electrostatic spinning chamber (e2) it is located at vertical direction, and left side electrostatic spinning chamber (e1) and right side electrostatic spinning chamber (e3) are located at middle electrostatic spinning respectively Room (e2) both sides；It is being provided with pretreatment chamber (p), sampler chamber (s) below horizontal baffle (37) and entering disk room (c), adjacent Between separated by dividing plate；Described sampler chamber (s) is located at pretreatment chamber (p) and enters the centre of disk room (c), in left side electrostatic spinning chamber (e1) and sample receiving chamber (r) underface, be connected by the sample receiving chamber (r) of sampling channel (14) and center, Sampler chamber (s) is mainly used in automatically collecting Electrospun product and direct modified Electrospun product；When sample disc enters sampler chamber (s) When, the disappearance due to magnetic force the effect in gravity, Electrospun product will be fallen into sampler chamber (s) together with sample disc and be received Collection gets up, and realizes the process of sampling automatically；In sampler chamber (s) bottom, sampling channel is put into equipped with special modification immediately below (14) The container of liquid, for receiving sample disc and the Electrospun product collected in sample disc being modified.

2. as claimed in claim 1 a kind of Multifunctional static electricity spinning equipment it is characterised in that in the electrostatic spinning chamber of left, center, right It is equipped with a shower nozzle fixator, shower nozzle fixator is used for stationary nozzle (10)；The top of described shower nozzle (10) and silica gel catheter It is connected, Electrospun solution can be transported to shower nozzle, the sun of the high voltage power supply outside shower nozzle (10) connection by silica gel catheter (6) Pole；Metal ring (17) is located at the lower section of shower nozzle (10) and is fixed on cylinder dividing plate (13) side, by wire and high pressure The negative electrode of power supply connects；Heating rod (19) is located at metal ring (17) dead astern and is fixed on cylinder dividing plate；Described shower nozzle is fixed Device includes height regulating rod (1), cleaning motor (2), fixed plate (3), fixing pipe (4), connecting plate (5), sprayer channel (8), gold Belong to knob (9), rotating bars (11) and rotary shaft (12)；Height regulating rod (1) passes through cloche and top is located at electrostatic spinning chamber Outside, bottom, in electrostatic spinning chamber interior, can control shower nozzle (10) and metal ring by pulling and level altitude adjusting rod (1) The distance between (17)；The bottom of height regulating rod (1) is fixed with cleaning motor, and cleaning motor (2) bottom is fixed with fixing pipe (4)；Fixed connecting plate (5) on the left of fixing pipe (4), connecting plate end is fixed with the sprayer channel that shower nozzle (10) can be allowed to pass through (8), it is provided with metal knob (9) with stationary nozzle (10) in sprayer channel (8) opposite side center position；Right in fixing pipe (4) The fixed fixed plate in side (3), is provided with a breach (7) that rotating bars (11) can be allowed to pass through, breach (7) energy in fixed plate (3) Drop or the silk of condensation that retention rotating bars (11) comes from syringe needle upper band；The center line of fixing pipe (4) is provided with one The rotary shaft being connected with rotating bars (11), rotary shaft (12) is connected to clean motor (2), and cleaning motor control rotary shaft (12) turns Dynamic, drive the rotating bars (11) that rotary shaft (12) end is provided with to rotate, rotating bars (11) can be by shower nozzle during rotation (10) drop of end or the silk of condensation scrape and play cleaning sprayer, prevent the effect blocking.

3. as claimed in claim 1 or 2 a kind of Multifunctional static electricity spinning equipment it is characterised in that described sample receiving chamber (r) Overall is in cylinder, has three-decker from outside to inside, is sequentially: cylinder dividing plate (13), sample disc fixator (20) and magnetic force stir Mix device (23)；The side of cylinder dividing plate (13) be provided with respectively with sampler chamber (s), enter disk room (c), left, center, right electrostatic spinning chamber The sampling channel (14) that is connected with pretreatment chamber (p), enter disk passage (15), fiber channel (16) and pre-processing channel；In place Fix a heating rod (19) respectively in the fiber channel (16) of cylinder dividing plate (13) and pre-processing channel (18) dead astern, be used for Control the temperature of electrostatic spinning chamber and pretreatment chamber (p)；In the upper fixation of the cylinder dividing plate (13) above fiber channel (16) A metal ring (17), sample disc fixator (20) is the plastic tab of hollow positive six prismsby, is located at cylinder dividing plate (13) Internal；The center of each side of six sides of sample disc fixator (20) is provided with a circular sample cell (22), goes up most The sample cell (22) of the circle in face is located at the underface of fiber channel (16), and each sample cell is used for placing sample receiver, sample Product receiver adopts sample disc, beaker or culture dish, and sample disc is used for receiving Electrospun product, and beaker or culture dish are used for containing Put reagent, to realize the in-situ modified of electrostatic spinning；Every seamed edge of sample disc fixator (20) is fixed with sealing strip (21), every sealing strip (21) is contacted with the corresponding position of cylinder dividing plate (13).

4. as claimed in claim 1 or 2 a kind of Multifunctional static electricity spinning equipment it is characterised in that described pretreatment chamber (p) position Immediately below left side electrostatic spinning chamber (e1), the lower left corner of sample receiving chamber (r), fixed one on pretreatment chamber's passage side Heating rod, for controlling the temperature of pretreatment chamber (p), pretreatment chamber (p) is mainly used in the interim storage of Electrospun product with just Step is processed, and passes through heating or put into drier or create specific gas atmosphere to Electrospun product in pretreatment chamber Carry out some pretreatments.

5. as claimed in claim 1 or 2 a kind of Multifunctional static electricity spinning equipment it is characterised in that described enter disk room (c) be located at Immediately below right side electrostatic spinning chamber (e3), the lower right corner of sample receiving chamber (r), it is close to sampler chamber (s)；Enter disk room (c) to comprise One is entered disk device, is connected with sample receiving chamber (r) by entering disk passage (15), for the sample new toward sample cell (22) conveying Disk, varies process it is ensured that electrostatic spinning can persistently be carried out with complete electrostatic spinning.

6. as claimed in claim 3 a kind of Multifunctional static electricity spinning equipment it is characterised in that in sample disc fixator (20) Each sample cell of five sample cells (22) being symmetrically distributed with above bottom surface that is internal, being located at sample disc fixator (20) It is respectively and fixedly provided with a magnetic stirring apparatus (23), each is located at the magnetic force of the magnetic stirring apparatus (23) at sample cell (22) back side at the back side The interior sample disc being provided with magnetic stripe can be inhaled on corresponding sample cell (22), magnetic stirring apparatus (23) rotates and can drive respective sample Disk rotates in sample cell；The sample disc fixator (20) of positive six prismsby connect outside under the control of rotary electric machine can timing along just The central shaft rotation of six prisms, and drives switching between different chamber for the sample disc, with reach different electrostatic spinning chambers it Between receive Electrospun product, prepare multi-layer nano fiber membrane, the sampling of Electrospun product and load sample disc.

7. as claimed in claim 5 a kind of Multifunctional static electricity spinning equipment it is characterised in that described enter disk device include sample disc, Sabot cylinder (26), push-plate device, pushing cylinder device and correcting wedge (30)；Correcting wedge (30) is fixed on into disk room (c) by draw-in groove On bottom surface, towards entering disk passage (15), correcting wedge (30) plays the effect of fixing pushing cylinder device on the inclined-plane of correcting wedge (30)；Push away Cylinder device is located between correcting wedge (30) and sabot cylinder (26), plays promotion, connection and the effect supporting sabot cylinder；Pushing cylinder device bag Include upper plate (28), outer spring (31) and base plate (29), outer spring (31) two ends fixed upper plate (28) and base plate respectively (29), upper plate (28) is fixed in fixed plate (27) by draw-in groove, and base plate (29) is fixed on correcting wedge by draw-in groove (30) on inclined-plane；When sample disc fixator (20) is in non-sampled or varies state without rotating, in upper plate (28), under the Action of Gravity Field of push-plate device above, outer spring (31) is in the state compressed all the time, the outer spring being compressed (31) produce a thrust, sabot cylinder (26) can be pushed sample receiving chamber (r), make sabot cylinder (26) abut against sample disc and fix On device (20)；Push-plate device includes movable plate (25), inner spring (32) and fixed plate (27), and sabot cylinder (26) external diameter ratio enters disk passage (15) internal diameter is smaller, so that sabot cylinder (26) upper end is just enclosed within disk passage (15), can sample receiving chamber (r) with enter disk Move between room (c), and do not fall out；The fixed movable plate in one end (25) of inner spring, the other end is fixed on fixed plate (27), on, inner spring (32) and movable plate (25) are contained in sabot cylinder (26), and fixed plate is fixed on sabot cylinder (26) bottom；Work as sample When product disk fixator (20) are in non-sampled or vary state without rotating, in the sample disc positioned at movable plate (25) top (24) under Action of Gravity Field, inner spring is in the state compressed all the time, and the inner spring (32) being compressed produces a thrust and pushes away Dynamic movable plate (25), sample disc is pushed sample cell (22), so that sample disc (24) is withstood on sample cell (22), withstands on sample cell (22) sample disc is held and inhaled in sample cell by magnetic stirring apparatus；When sample disc fixator (20) is in sampling or varies State and when starting to rotate counterclockwise 60 °, by located at sampler chamber (s) with sealing strip (21) extruding of entering disk room (c) place, and Promote the upper end of sabot cylinder, so that outer spring (31) is compressed, sabot cylinder (26) and sample disc (24) by together with push back into disk room (c), and the sample disc being in the top of movable plate (25) is inhaled, by magnetic force, the sample disc being rotated in sample cell and is fixed Device (20) is brought in right side electrostatic spinning chamber (e3)；After sample disc fixator (20) rotation terminates, the top of movable plate (25) Change a new sample disc, in the presence of outer spring (31) elastic force, sabot cylinder (26) is pushed back sample receiving chamber again, And under the promotion of inner spring (32), new sample disc (24) is pushed into sample cell (22) again, the top of movable plate (25) new Sample disc held by magnetic stirring apparatus again, and be fixed in sample cell；So, once turning through sample disc fixator (20) Complete being automatically replenished of sample disc after dynamic, so that electrostatic spinning is persistently carried out.

8. as claimed in claim 6 a kind of Multifunctional static electricity spinning equipment it is characterised in that described middle electrostatic spinning chamber (e2) it is located at vertical direction, and left side electrostatic spinning chamber (e1) and right side electrostatic spinning chamber (e3) and middle electrostatic spinning chamber (e2) Angle be 60 °, sample disc fixator (20) is the plastic tab of hollow positive six prismsby, and sample disc fixator (20) is outside Connect and periodically rotate counterclockwise so that sample disc can switch between different chamber, sample can be worked as under the control of rotary electric machine Disk fixator first time turns over 60 °, sample disc from enter disk room (c) enter right side electrostatic spinning chamber (e3) start receive Electrospun Product；When sample disc fixator (20) turns over 60 ° for the second time, sample disc electrostatic in the middle of right side electrostatic spinning chamber (e3) enters Spinning chamber, to receive electrostatic spinning product；When sample disc fixator (20) turns over 60 ° for the third time, sample disc is from middle Static Spinning Cabinet enters left side electrostatic spinning chamber (e1), to receive electrostatic spinning product；Turn over 60 when sample disc fixator (20) 4th time °, sample disc enters pretreatment chamber (p) from left side electrostatic spinning chamber (e1), to realize the pretreatment to electrostatic spinning product；Work as sample Product disk fixator (20) turns over 60 ° the 5th time, and sample disc enters sampler chamber (s) from pretreatment chamber (p), now due to sampler chamber S the sample cell at () place is no installed magnetic stirring apparatus and so that the magnetic force of sample disc is disappeared, sample disc under gravity, is fallen automatically Enter sampler chamber (s), to realize the automatic data collection of sample；Turn over 60 ° when sample disc fixator (20) 6th time, the sample cell of sky (22) enter into disk room (c) from sampler chamber (s), in entering disk room (c) enter disk device in the presence of, sample cell (22) is reinstalled Sample disc.

9. as claimed in claim 6 a kind of Multifunctional static electricity spinning equipment it is characterised in that described sample disc be a circle Thin slice, material is pottery or polytetrafluoroethylene (PTFE), has much tiny projection (34) in receiving plane, and projection (34) can allow Electrospun Product is contacted with sample disc will not be too tight, on the one hand conveniently takes off Electrospun product, on the other hand can make sample disc surface Electrospun product when pretreatment chamber (p) or sampler chamber (s) carry out some process, make Electrospun product be processed more fill Point；Embed a magnetic stripe (35) in the back side (33) centre of sample disc, magnetic stripe (35) is comprised in inside sample disc, embed Magnetic stripe (35) sample disc can be made in the presence of magnetic stirring apparatus to rotate, allow the Electrospun product receiving equably to divide It is dispersed in sample disc.