CN104711663B - It is a kind of to use seven grades of middle-high voltage electrode foil manufacture methods of different hair engaging aperture conditions - Google Patents
It is a kind of to use seven grades of middle-high voltage electrode foil manufacture methods of different hair engaging aperture conditions Download PDFInfo
- Publication number
- CN104711663B CN104711663B CN201310727798.5A CN201310727798A CN104711663B CN 104711663 B CN104711663 B CN 104711663B CN 201310727798 A CN201310727798 A CN 201310727798A CN 104711663 B CN104711663 B CN 104711663B
- Authority
- CN
- China
- Prior art keywords
- direct current
- paper tinsel
- seconds
- engaging aperture
- hair engaging
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims abstract description 41
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 26
- 239000011888 foil Substances 0.000 title claims abstract description 19
- 239000007788 liquid Substances 0.000 claims abstract description 43
- 238000004140 cleaning Methods 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000002203 pretreatment Methods 0.000 claims abstract description 9
- 239000000126 substance Substances 0.000 claims abstract description 8
- 238000005406 washing Methods 0.000 claims abstract description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 112
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 58
- 230000005611 electricity Effects 0.000 claims description 31
- 239000011259 mixed solution Substances 0.000 claims description 18
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 15
- 239000005864 Sulphur Substances 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 10
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 9
- 229910017604 nitric acid Inorganic materials 0.000 claims description 9
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 claims description 4
- 239000012530 fluid Substances 0.000 claims description 4
- 230000002000 scavenging effect Effects 0.000 claims description 4
- 238000005516 engineering process Methods 0.000 abstract description 9
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 16
- 239000005030 aluminium foil Substances 0.000 description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 229940067597 azelate Drugs 0.000 description 4
- 239000003990 capacitor Substances 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- FZUJWWOKDIGOKH-UHFFFAOYSA-N sulfuric acid hydrochloride Chemical compound Cl.OS(O)(=O)=O FZUJWWOKDIGOKH-UHFFFAOYSA-N 0.000 description 1
Abstract
It is a kind of using seven grades of middle-high voltage electrode foil manufacture methods of different hair engaging aperture conditions, mainly comprise the following steps pre-treatment and once wash the secondary washing Chemical cleanings four times of the washing paper tinsel surface expanding treatment three times washing pure water of the direct current hair engaging aperture treatment paper tinsel surface second direct current hair engaging aperture treatment paper tinsel surface three times in the paper tinsel surface direct current hair engaging aperture treatment paper tinsel surface five times of direct current hair engaging aperture treatment paper tinsel surface four times direct current hair engaging aperture treatment paper tinsel surface six direct current hair engaging aperture treatment paper tinsel surfaces, seven direct current hair engaging aperture treatment and be cleaned and dried.Patent of the present invention by changing the concentration of reaming corrosive liquid and the height of temperature, can effective controlling paper tinsel hole generation and production, the increase of accurate control hole area reaches production Technology requirement, obtains high-quality middle-high voltage electrode foil, improves production efficiency.
Description
Technical field
It is particularly a kind of using seven grades of mesohigh electrodes of different hair engaging aperture conditions the present invention relates to the manufacture method of electrode foil
Foil making method.
Background technology
Since reform and opening-up, national economy rapid growth, " scientific and technical innovation, autonomous innovation " has turned into current domestic industry hair
The main flow of exhibition, China's electronic industry is developed rapidly, especially the urgency in the machine product such as communication products, computer, household electrical appliances market
Play expands, and the development to aluminum electric pole foil industry has play a part of to add fuel to the flames.Simultaneously because the miniaturization of aluminium electrolutic capacitor, height
Performance-based, chip type requirement it is more and more urgent, the manufacturing industry to electrode foil it is also proposed technology and quality requirement higher.Electricity
Pole paper tinsel is the key raw material of aluminium electrolutic capacitor manufacture, and the quality of electrode foil will directly influence aluminium electrolutic capacitor
Functionality, quality and appealing design is poor.The conventional corrosion technology flow of currently manufactured electrode foil is pre-treatment-washing-Chemical cleaning-washing-pure water
Cleaning-dry, is main corrosive liquid with hydrochloric acid sulfuric acid or nitric acid, using direct current hair engaging aperture for several times, each corrosive liquid and electricity
Stream, temperature all same.Such as existing five-stage manufacturing method：Aluminium foil that first learn from else's experience excessive erosion, that purity is 99.99%, 90~
Impregnated 5~10 minutes in 100 DEG C of pure water, the water-soluble of 0.1~8% citric acid and 0.1~5% citrate is placed in after taking-up
It is then that one-level is melted into 8~15 points under conditions of 20mA/ (cm) 2, voltage is 140V in 70~95 DEG C, current density in liquid
Clock；Aluminium foil after one-level is melted into again is rinsed after taking out with water, then is placed in 0.1~5% azelaic acid and 0.1~5% nonyl two
It is two grades of changes under conditions of 20rriA/ (CIII) 2, voltage is 280V in 70~95 DEG C, current density in the aqueous solution of hydrochlorate
Into 8~15 minutes；Aluminium foil after two grades are melted into is placed in the water of 0.1~5% azelaic acid and 0.1~50/ azelate again
It is that three-level is melted into 8~15 minutes under conditions of 20mA/ (cm) 2, voltage is 450V in 70~95 DEG C, current density in solution；
Aluminium foil after the chemical conversion of special three-level is placed in the aqueous solution of 0.1~5% azelaic acid and 0.1~5% azelate again, 70~
95 DEG C, current density be 20mA/ (cm) 2, voltage be 580V under conditions of, level Four be melted into 8~15 minutes；After level Four is melted into
Aluminium foil is placed in the aqueous solution of 0.1~3% azelaic acid and 0.1~3% azelate again, in 70~95 DEG C, current density
Be 20mA/ (cm) 2, voltage be 620V under conditions of, Pyatyi be melted into 8~15 minutes；Aluminium foil after Pyatyi is melted into is from electrolyte
Taken out in groove, carry out 500 DEG C of high-temperature heat treatment 3~4 minutes；0.1~3% azelaic acid and 0.1~3% nonyl two are placed in again
It is under conditions of 20mA/ (cm) 2, voltage is 620V, to be melted into 8~15 points in 70~95 DEG C, current density in the aqueous solution of hydrochlorate
Clock；Then processed with temperature as 50~80 DEG C in 1~8% phosphoric acid solution；Be placed in again 0.1~3% azelaic acid and
It is then that 20mA/ (cm) 2, voltage is 620V's in 70~95 DEG C, current density in the aqueous solution of 0.1~3% azelate
Under the conditions of, it is melted into 8~15 minutes；Finally take out, dry.The manufacturing process of electrode foil for aluminum electrolytic capacitors is also aluminium foil surface
The process that hole produces and grows, in generation and production process, the length change in aperture and hole can be because of the structure shape in hole itself in hole
State and it is different, and in existing manufacturing technology, hair engaging aperture condition is single, it is impossible to fully meet hole different phase pair in growth course
Required in the difference of etching condition, cause pore size distribution uneven or the problem that hole merges and reduces effective hole number occurs.In order to
This problem is solved, R＆D institution and the technical staff of enterprise are explored constantly, research, it is desirable to find out a kind of more advanced
Method manufacture meets the electrode foil of market demands, although makes some progress, but is remained still in practice
The technical barrier not overcome.
The content of the invention
It is an object of the invention to overcome the above not enough, there is provided a kind of using seven grades of mesohigh electrodes of different hair engaging aperture conditions
Foil making method.By changing the concentration of reaming corrosive liquid and the height of temperature, can effective controlling paper tinsel hole generation and production, it is accurate
The really increase of control hole area, reaches production Technology requirement, obtains high-quality middle-high voltage electrode foil, improves production efficiency.
The present invention solves the technical step that is used of its technical problem：Washing-paper tinsel the surface of pre-treatment-once is once straight
Stream hair engaging aperture treatment-paper tinsel surface second direct current hair engaging aperture treatment-paper tinsel surface three times direct current hair engaging aperture treatment-paper tinsel surface four times direct current hair
At the direct current hair engaging aperture treatment-paper tinsel surface seven times direct current hair engaging aperture of the direct current hair engaging aperture treatment-paper tinsel surface six times of hole treatment-paper tinsel surface five times
Reason-secondary washing-paper tinsel surface expanding treatment-tri- time washing-Chemical cleaning-tetra- time washing-pure water is cleaned-dried.
A kind of detailed process using seven grades of middle-high voltage electrode foil manufacture methods of different hair engaging aperture conditions is as follows：
1st step：Pre-treatment：Pre-treatment mixes the solution of 1%~10% hydrochloric acid using 8%~40% sulfuric acid solution,
At 30~70 DEG C, process 1~5 minute；
Second step：The direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% mixed in hydrochloric acid
Liquid, temperature is 50~90 DEG C, and process time is controlled at 30 seconds~120 seconds, and using direct current, electricity is 5~15C/cm2；
Third step：The treatment of paper tinsel surface second direct current hair engaging aperture：Corrosive liquid is 8~40% sulfuric acid and 1~10% mixed in hydrochloric acid
Liquid, temperature is 50~90 DEG C, and process time is controlled at 30 seconds~120 seconds, and using direct current, electricity is 5~15C/cm2, this step
Sulfuric acid content is the 98% of step 2 sulfuric acid content in rapid, and remaining condition is identical with previous step；
4th step：The three direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% mixed in hydrochloric acid
Liquid, temperature is 50~90 DEG C, and process time is controlled at 30 seconds~120 seconds, and using direct current, electricity is 5~15C/cm2, this step
Sulfuric acid content is 98% of sulfuric acid content in step 3 in rapid, and temperature increases by 0.3 DEG C compared with step 3, and remaining condition is identical with step 3；
5th step：The four direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% mixed in hydrochloric acid
Liquid, temperature is 50~90 DEG C, and process time is controlled at 30 seconds~120 seconds, and using direct current, electricity is 5~15C/cm2, this step
Sulfuric acid content is 96% of sulfuric acid content in step 3 in rapid, and remaining condition is identical with step 3；
6th step：The five direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% mixed in hydrochloric acid
Liquid, temperature is 50~90 DEG C, and process time is controlled at 30 seconds~120 seconds, and using direct current, electricity is 5~15C/cm2, this step
Sulfuric acid content is 96% of sulfuric acid content in step 3 in rapid, and temperature increases by 0.3 DEG C compared with step 3, and remaining condition is identical with step 3；
7th step：The six direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% mixed in hydrochloric acid
Liquid, temperature is 50~90 DEG C, and process time is controlled at 30 seconds~120 seconds, and using direct current, electricity is 5~15C/cm2, this step
Sulfuric acid content is 94% of sulfuric acid content in step 3 in rapid, and remaining condition is identical with step 3；
8th step：The seven direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% mixed in hydrochloric acid
Liquid, temperature is 50~90 DEG C, and process time is controlled at 30 seconds~120 seconds, and using direct current, electricity is 5~15C/cm2, this step
Sulfuric acid content is 94% of sulfuric acid content in step 3 in rapid, and temperature increases by 0.3 DEG C compared with step 3, and remaining condition is identical with step 3；
9th step：Paper tinsel surface expanding treatment：Corrosive liquid is 1~10% nitric acid, and temperature is 50~90 DEG C, process time
At 60 seconds~360 seconds, using direct current, electricity was 30~80C/cm for control2；
10th step：Chemical cleaning：Cleaning fluid is 1~10% nitric acid, and temperature is 30~70 DEG C, 1~5 point of scavenging period
Clock；
11st step：Under above-mentioned washing is normal temperature condition, clean 1~3 minute；
12nd step：Pure water is cleaned：Under normal temperature condition, clean 2~6 minutes；
13rd step：Dry：Under the conditions of 150~350 DEG C, dry 1~5 minute.
Beneficial effects of the present invention：By changing the concentration of reaming corrosive liquid and the height of temperature, can effective controlling paper tinsel hole
Generation and production, the increase of accurate control hole area reaches production Technology requirement, obtains high-quality middle-high voltage electrode foil,
Improve production efficiency.
The technology of the present invention and the electrode foil performance comparison table made by prior art
| Comparative example | Embodiment | |
| Bending (returning) | 60 | 65 |
| Specific volume (μ F/cm2) | 0.57(640vf) | 0.59(640vf) |
Embodiment
(1) pre-treatment：Pre-treatment mixes the solution of 1%~10% hydrochloric acid, 30 using 8%~40% sulfuric acid solution
At~70 DEG C, process 1~5 minute；
(2) wash：Under normal temperature condition, clean 1~3 minute；
(3) the direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% hydrochloric acid mixed solution, temperature
It is 50~90 DEG C to spend, and process time is controlled at 30 seconds~120 seconds, and using direct current, electricity is 5~15C/cm2；
(4) paper tinsel surface second direct current hair engaging aperture treatment：Corrosive liquid is 8~40% sulfuric acid and 1~10% hydrochloric acid mixed solution, temperature
It is 50~90 DEG C to spend, and process time is controlled at 30 seconds~120 seconds, and using direct current, electricity is 5~15C/cm2, sulphur in this step
Acid content is the 98% of step 3 sulfuric acid content, and remaining condition is identical with previous step；
(5) the three direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% hydrochloric acid mixed solution, temperature
It is 50~90 DEG C to spend, and process time is controlled at 30 seconds~120 seconds, and using direct current, electricity is 5~15C/cm2, sulphur in this step
Acid content is 98% of sulfuric acid content in step 3, and temperature increases by 0.3 DEG C compared with step 3, and remaining condition is identical with step 3；
(6) the four direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% hydrochloric acid mixed solution, temperature
It is 50~90 DEG C to spend, and process time is controlled at 30 seconds~120 seconds, and using direct current, electricity is 5~15C/cm2, sulphur in this step
Acid content is 96% of sulfuric acid content in step 3, and remaining condition is identical with step 3；
(7) the five direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% hydrochloric acid mixed solution, temperature
It is 50~90 DEG C to spend, and process time is controlled at 30 seconds~120 seconds, and using direct current, electricity is 5~15C/cm2, sulphur in this step
Acid content is 96% of sulfuric acid content in step 3, and temperature increases by 0.3 DEG C compared with step 3, and remaining condition is identical with step 3；
(8) the six direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% hydrochloric acid mixed solution, temperature
It is 50~90 DEG C to spend, and process time is controlled at 30 seconds~120 seconds, and using direct current, electricity is 5~15C/cm2, sulphur in this step
Acid content is 94% of sulfuric acid content in step 3, and remaining condition is identical with step 3；
(9) the seven direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% hydrochloric acid mixed solution, temperature
It is 50~90 DEG C to spend, and process time is controlled at 30 seconds~120 seconds, and using direct current, electricity is 5~15C/cm2, sulphur in this step
Acid content is 94% of sulfuric acid content in step 3, and temperature increases by 0.3 DEG C compared with step 3, and remaining condition is identical with step 3；
(10) wash：Under normal temperature condition, clean 1~3 minute；
(11) paper tinsel surface expanding treatment：Corrosive liquid is 1~10% nitric acid, and temperature is 50~90 DEG C, process time control
At 60 seconds~360 seconds, using direct current, electricity was 30~80C/cm2；
(12) wash：Under normal temperature condition, clean 1~3 minute；
(13) Chemical cleaning：Cleaning fluid is 1~10% nitric acid, and temperature is 30~70 DEG C, scavenging period 1~5 minute；
(14) wash：Under normal temperature condition, clean 1~3 minute；
(15) pure water cleaning：Under normal temperature condition, clean 2~6 minutes；
(16) dry：Under the conditions of 150~350 DEG C, dry 1~5 minute；
Comparative example
(1) pre-treatment：Pre-treatment mixes the solution of 1%~10% hydrochloric acid, 30 using 8%~40% sulfuric acid solution
At~70 DEG C, process 1~5 minute；
(2) wash：Under normal temperature condition, clean 1~3 minute；
(3) the direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% hydrochloric acid mixed solution, temperature
It is 50~90 DEG C to spend, and process time is controlled at 30 seconds~120 seconds, and using direct current, electricity is 5~15C/cm2；
(4) paper tinsel surface second direct current hair engaging aperture treatment：Corrosive liquid is 8~40% sulfuric acid and 1~10% hydrochloric acid mixed solution, temperature
It is 50~90 DEG C to spend, and process time is controlled at 30 seconds~120 seconds, and using direct current, electricity is 5~15C/cm2, sulphur in this step
Acid content is the 98% of step 3 sulfuric acid content, and remaining condition is identical with previous step；
(5) the three direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% hydrochloric acid mixed solution, temperature
It is 50~90 DEG C to spend, and process time is controlled at 30 seconds~120 seconds, and using direct current, electricity is 5~15C/cm2, sulphur in this step
Acid content is 98% of sulfuric acid content in step 3, and temperature increases by 0.3 DEG C compared with step 3, and remaining condition is identical with step 3；
(6) the four direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% hydrochloric acid mixed solution, temperature
It is 50~90 DEG C to spend, and process time is controlled at 30 seconds~120 seconds, and using direct current, electricity is 5~15C/cm2, sulphur in this step
Acid content is 96% of sulfuric acid content in step 3, and remaining condition is identical with step 3；
(7) wash：Under normal temperature condition, clean 1~3 minute；
(8) paper tinsel surface expanding treatment：Corrosive liquid is 1~10% nitric acid, and temperature is 50~90 DEG C, and process time control exists
60 seconds~360 seconds, using direct current, electricity was 30~80C/cm2；
(9) wash：Under normal temperature condition, clean 1~3 minute；
(10) Chemical cleaning：Cleaning fluid is 1~10% nitric acid, and temperature is 30~70 DEG C, scavenging period 1~5 minute；
(11) wash：Under normal temperature condition, clean 1~3 minute；
(12) pure water cleaning：Under normal temperature condition, clean 2~6 minutes；
(13) dry：Under the conditions of 150~350 DEG C, dry 1~5 minute；
As shown by data that embodiments of the invention and comparative example draw, by the concentration and temperature that change reaming corrosive liquid
Just, specific volume increases to 0.59 (640vf), and bending (returning) is 65, can effective controlling paper tinsel hole generation and production, accurate control hole
The increase of area, reaches production Technology requirement, obtains high-quality middle-high voltage electrode foil, improves production efficiency.
Claims (1)
1. a kind of using seven grades of middle-high voltage electrode foil manufacture methods of different hair engaging aperture conditions, it is characterised in that：The manufacture method bag
Include following steps：
（1）Pre-treatment：Pre-treatment mixes the solution of 1%~10% hydrochloric acid, 30~70 using 8%~40% sulfuric acid solution
At DEG C, process 1~5 minute；
（2）Washing：Under normal temperature condition, clean 1~3 minute；
（3）The direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% hydrochloric acid mixed solution, temperature
It it is 50~90 DEG C, process time is controlled at 30 seconds~120 seconds, using direct current, electricity is 5~15C/cm2；
（4）The treatment of paper tinsel surface second direct current hair engaging aperture：Corrosive liquid is 8~40% sulfuric acid and 1~10% hydrochloric acid mixed solution, temperature
It it is 50~90 DEG C, process time is controlled at 30 seconds~120 seconds, using direct current, electricity is 5~15C/cm2, sulphur in this step
Acid content is（3）The 98% of middle sulfuric acid content, remaining condition with（3）It is identical；
（5）The three direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% hydrochloric acid mixed solution, temperature
It it is 50~90 DEG C, process time is controlled at 30 seconds~120 seconds, using direct current, electricity is 5~15C/cm2, sulphur in this step
Acid content is（3）The 98% of middle sulfuric acid content, temperature compared with（3）It is middle increase by 0.3 DEG C, remaining condition with（3）It is identical；
（6）The four direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% hydrochloric acid mixed solution, temperature
It it is 50~90 DEG C, process time is controlled at 30 seconds~120 seconds, using direct current, electricity is 5~15C/cm2, sulphur in this step
Acid content is（3）The 96% of middle sulfuric acid content, remaining condition with（3）It is identical；
（7）The five direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% hydrochloric acid mixed solution, temperature
It it is 50~90 DEG C, process time is controlled at 30 seconds~120 seconds, using direct current, electricity is 5~15C/cm2, sulphur in this step
Acid content is（3）The 96% of middle sulfuric acid content, temperature compared with（3）It is middle increase by 0.3 DEG C, remaining condition with（3）It is identical；
（8）The six direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% hydrochloric acid mixed solution, temperature
It it is 50~90 DEG C, process time is controlled at 30 seconds~120 seconds, using direct current, electricity is 5~15C/cm2, sulphur in this step
Acid content（3）The 94% of middle sulfuric acid content, remaining condition with（3）It is identical；
（9）The seven direct current hair engaging aperture treatment in paper tinsel surface：Corrosive liquid is 8~40% sulfuric acid and 1~10% hydrochloric acid mixed solution, temperature
It it is 50~90 DEG C, process time is controlled at 30 seconds~120 seconds, using direct current, electricity is 5~15C/cm2, sulphur in this step
Acid content is（3）The 94% of middle sulfuric acid content, temperature compared with（3）It is middle increase by 0.3 DEG C, remaining condition with（3）It is identical；
（10）Washing：Under normal temperature condition, clean 1~3 minute；
（11）Paper tinsel surface expanding treatment：Corrosive liquid is 1~10% nitric acid, and temperature is 50~90 DEG C, and process time is controlled 60
Second~360 seconds, using direct current, electricity is 30~80C/cm2；
（12）Washing：Under normal temperature condition, clean 1~3 minute；
（13）Chemical cleaning：Cleaning fluid is 1~10% nitric acid, and temperature is 30~70 DEG C, scavenging period 1~5 minute；
（14）Washing：Under normal temperature condition, clean 1~3 minute；
（15）Pure water is cleaned：Under normal temperature condition, clean 2~6 minutes；
（16）Dry：Under the conditions of 150~350 DEG C, dry 1~5 minute.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310727798.5A CN104711663B (en) | 2013-12-15 | 2013-12-15 | It is a kind of to use seven grades of middle-high voltage electrode foil manufacture methods of different hair engaging aperture conditions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310727798.5A CN104711663B (en) | 2013-12-15 | 2013-12-15 | It is a kind of to use seven grades of middle-high voltage electrode foil manufacture methods of different hair engaging aperture conditions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104711663A CN104711663A (en) | 2015-06-17 |
| CN104711663B true CN104711663B (en) | 2017-05-31 |
Family
ID=53411371
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310727798.5A Active CN104711663B (en) | 2013-12-15 | 2013-12-15 | It is a kind of to use seven grades of middle-high voltage electrode foil manufacture methods of different hair engaging aperture conditions |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104711663B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105957717B (en) * | 2016-05-26 | 2018-11-30 | 乳源县立东电子科技有限公司 | The multiple hair engaging aperture method of the multistage of mesohigh anode foils |
| CN107254707B (en) * | 2017-06-16 | 2020-06-26 | 李晓天 | Method for manufacturing multi-stage pore-forming rapid medium-high voltage electrode foil |
| CN107946092A (en) * | 2017-11-09 | 2018-04-20 | 浙江七星电容器有限公司 | A kind of production technology for new-energy automobile capacitor |
| CN110783108B (en) * | 2019-10-18 | 2022-03-25 | 佛山科学技术学院 | Method for manufacturing corrosion foil |
| CN111519239B (en) * | 2020-05-18 | 2021-12-07 | 南通海星电子股份有限公司 | Etching method for ultrahigh-pressure etched foil |
| CN114197004B (en) * | 2021-12-10 | 2023-08-22 | 四川石棉华瑞电子有限公司 | Medium-high voltage foil formation method for aluminum electrolytic capacitor |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3450083B2 (en) * | 1995-02-09 | 2003-09-22 | 三菱アルミニウム株式会社 | Aluminum foil for electrode of electrolytic capacitor and method for producing the same |
| CN101029413B (en) * | 2006-12-19 | 2010-05-12 | 东莞市东阳光电容器有限公司 | Production of medium-high voltage anode corrosive foil |
| CN100559527C (en) * | 2007-03-28 | 2009-11-11 | 横店集团东磁有限公司 | The caustic solution of high pressure high specific volume anode foil |
| CN101275269B (en) * | 2008-04-22 | 2010-09-22 | 日丰（清远）电子有限公司 | Etching process for aluminum foil for electrolytic capacitor |
| CN102610396B (en) * | 2011-01-20 | 2015-04-01 | 四川雅安艾华电极箔制造有限公司 | Manufacturing method for formed foil of electrolytic capacitor of energy-saving lamp |
| CN102709059B (en) * | 2012-06-09 | 2015-06-03 | 永济粟海铝业有限公司 | Formation method for anode foil of intermediate-voltage aluminum electrolytic capacitor |
| CN102983008A (en) * | 2012-11-28 | 2013-03-20 | 广西贺州市桂东电子科技有限责任公司 | Ultrahigh voltage anode foil corrosion method for aluminum electrolytic capacitor |
| CN103160902B (en) * | 2012-12-13 | 2015-12-23 | 宝兴县剑锋制箔电子有限公司 | Middle-high voltage electrode foil 5 sections changes into 2 grades of liquid feedback production methods |
| CN103243369B (en) * | 2013-04-10 | 2015-09-30 | 宜都东阳光化成箔有限公司 | A kind of raising used in aluminium electrolytic capactiance mesohigh anode aluminium foil chemical synthesis technology |
-
2013
- 2013-12-15 CN CN201310727798.5A patent/CN104711663B/en active Active
Non-Patent Citations (3)
| Title |
|---|
| "中高压铝电解电容器用阳极箔腐蚀工艺的研究";宋洪洲;《电子产品可靠性与环境试验》;20061031;第24卷(第5期);第1-6页 * |
| "中高压铝电解电容器用阳极箔腐蚀扩面技术研究";吕根品等;《中高压铝电解电容器用阳极箔腐蚀扩面技术研究》;20060930;第27卷(第9期);第67-70页 * |
| "日本铝电极箔制造技术研究的新进展";冯哲圣等;《电子元件与材料》;20010430;第23-27页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104711663A (en) | 2015-06-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104711663B (en) | It is a kind of to use seven grades of middle-high voltage electrode foil manufacture methods of different hair engaging aperture conditions | |
| CN1873865B (en) | Manufacturing method for raising specific volume of electrode foil in use for aluminium electrolytic capacitor | |
| CN102709059B (en) | Formation method for anode foil of intermediate-voltage aluminum electrolytic capacitor | |
| CN106653373B (en) | A kind of aluminium electrolutic capacitor Waste Acid From Hua Cheng Foil and its production technology | |
| CN105788866A (en) | Middle-and-high-voltage electrode foil manufacturing method based on combination of electrochemical corrosion and chemical corrosion | |
| CN101826397B (en) | Five-stage manufacturing method of electrode foil for medium-high voltage aluminium electrolytic capacitor | |
| CN103160902B (en) | Middle-high voltage electrode foil 5 sections changes into 2 grades of liquid feedback production methods | |
| CN102610396B (en) | Manufacturing method for formed foil of electrolytic capacitor of energy-saving lamp | |
| CN104835647B (en) | A kind of anodic attack foil making method and a kind of aluminium foil corrosion electrolytic cell | |
| CN102800483A (en) | Formation processing method for reducing leaking current of low-voltage formation foil | |
| CN107254707B (en) | Method for manufacturing multi-stage pore-forming rapid medium-high voltage electrode foil | |
| CN113628888B (en) | Preparation method of corrosion aluminum foil with high consistency of hole length | |
| CN104103428B (en) | A kind of manufacture method of aluminium electrolutic capacitor high pressure high-dielectric formed foil | |
| CN104715929B (en) | A kind of direct current and the middle-high voltage electrode foil manufacture method for exchanging mixing power-up hair engaging aperture | |
| CN104480520B (en) | Manufacturing method of producing high-purity cathode foil by virtue of electrochemical corrosion | |
| CN104630871B (en) | A kind of etching process method of low pressure hard Fabrication of High Specific Capacitance aluminum electric pole foil | |
| CN205774913U (en) | Etched foil production line purging system | |
| CN103151174B (en) | The manufacture method of electrode foil of high-pressure aluminum electrolytic capacitor | |
| CN105887177A (en) | Middle-high voltage electrode foil manufacturing method combining electrochemical corrosion with chemical corrosion | |
| CN101593630A (en) | Improve the manufacture method of water resisting property of low voltage electrode foil | |
| CN204102723U (en) | A kind of process units of aluminum electrolysis capacitor formed foil and production line thereof | |
| CN202308019U (en) | Solar energy cell sheet phosphorosilicate glass removing device | |
| CN107227485A (en) | A kind of etching process method of hard state optical aluminum foil | |
| CN101154508A (en) | Four-stage manufacturing method for electrode foil of high-pressure aluminum electrolytic capacitor | |
| CN108109845A (en) | A kind of processing method for improving water resisting property of low voltage electrode foil and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A manufacturing method of medium and high voltage electrode foil with seven levels of different pore conditions Effective date of registration: 20210624 Granted publication date: 20170531 Pledgee: Xiangshui County sub branch of Agricultural Bank of China Ltd. Pledgor: JIANGSU RONGSHENG ELECTRONIC Co.,Ltd. Registration number: Y2021980005235 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20170531 Pledgee: Xiangshui County sub branch of Agricultural Bank of China Ltd. Pledgor: JIANGSU RONGSHENG ELECTRONIC CO.,LTD. Registration number: Y2021980005235 |