CN104710894B - A kind of preparation method of polymer matrix water-repellent paint - Google Patents
A kind of preparation method of polymer matrix water-repellent paint Download PDFInfo
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- CN104710894B CN104710894B CN201510158549.8A CN201510158549A CN104710894B CN 104710894 B CN104710894 B CN 104710894B CN 201510158549 A CN201510158549 A CN 201510158549A CN 104710894 B CN104710894 B CN 104710894B
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- 229920000642 polymer Polymers 0.000 title claims abstract description 23
- 239000003973 paint Substances 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000005871 repellent Substances 0.000 title claims abstract description 12
- 239000011159 matrix material Substances 0.000 title claims abstract description 11
- 239000011248 coating agent Substances 0.000 claims abstract description 12
- 238000000576 coating method Methods 0.000 claims abstract description 12
- 239000000839 emulsion Substances 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 3
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000013530 defoamer Substances 0.000 claims description 3
- 239000002270 dispersing agent Substances 0.000 claims description 3
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 claims description 3
- 239000004005 microsphere Substances 0.000 claims description 3
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- KBAFDSIZQYCDPK-UHFFFAOYSA-M sodium;octadecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCCCCS([O-])(=O)=O KBAFDSIZQYCDPK-UHFFFAOYSA-M 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims 1
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 4
- 230000004888 barrier function Effects 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- 239000000178 monomer Substances 0.000 abstract description 2
- 238000006116 polymerization reaction Methods 0.000 abstract description 2
- 239000011253 protective coating Substances 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000009849 vacuum degassing Methods 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D147/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of preparation method of polymer matrix water-repellent paint; employ specific raw material monomer and proportioning; under specific process conditions through high temperature polymerization obtain with good flexibility, viscosity, stability polymer emulsion; the coating prepared with the polymer emulsion is after coating film forming; coating has good barrier properties, intensity and corrosion resistance; for the protective coating of building, it can effectively extend the service life of building.
Description
Technical field
The present invention relates to a kind of preparation method of polymer matrix water-repellent paint.
Background technology
Water-repellent paint is mainly used in building, and it possesses two kinds of functions：One is to protect building from external environment condition shadow
Ring or influenceed to minimize, water-repellent paint can form continuous film on its surface after being coated on building, this
Film has the performances such as corrosion-resistant, anti-pollution, waterproof, to extend the life-span of building；Two be decoration building, and waterproof is applied
Material, which is painted on after building surface, can form the film with different colours, various luster and different texture, so as to play U.S.
Change the effect of environment.However, the water-repellent paint used at present is used for outdoor, its intensity, tear resistance, weather resisteant are poor, use
Short life, during for roof waterproof, protective layer generally need to be also done again on roof waterproof layer, add construction costs, also inconvenient
In maintenance.
The content of the invention
In order to overcome the deficiencies in the prior art, it is of the invention provide it is a kind of with good strength, corrosion resistance, water proofing property
The preparation method of polymer matrix coating.The above-mentioned purpose of the present invention is realized by the following method：
A kind of preparation method of polymer matrix water-repellent paint, comprises the following steps：
a）The preparation of polymer emulsion：In terms of parts by weight, 100 parts of ionized water is removed, is added in reactor, then successively
Add 2 parts of sodium stearyl sulfonate, 1.5 parts of Emulsifier EL-10,1.5 parts of pH value regulator, 20 parts of hexadiene, acrylic acid 6
Part, 10 parts of EMA, 10 parts of butyl methacrylate, 5 parts of glutaric acid, 5 parts of styrene, 1 part of ammonium persulfate, with
5 DEG C/min speed is warming up to 60 DEG C, is sufficiently stirred for 10 hours, then is warming up to 75 DEG C with 3 DEG C/min speed, and continuation is fully stirred
Mix 5 hours, then add 2 parts of EDTA, deaerate under vacuum, then with the NaOH solution that weight/mass percentage composition is 20%
It is 7 to adjust pH value, is cooled to room temperature, obtains polymer emulsion；
b）The preparation of coating：In terms of parts by weight, 1 part of dispersant, 1 part of defoamer, 1 part of levelling agent, nanometer titanium dioxide are taken
20 parts of titanium, 20 parts of silicon dioxide microsphere is added in container, the step a then added in terms of parts by weight）Obtained polymer
40 parts of emulsion, dispersed with stirring then adds 1.5 parts of montmorillonites, and 5 parts of filler continues to stir 2 hours, then grinds 2h, filters,
Obtain polymer matrix water-repellent paint.
Step a）In the stir speed (S.S.) being sufficiently stirred for be 400 turns/min, rate of temperature fall is 3 DEG C/min.
Step b）In stir speed (S.S.) be 400 turns/min, filtered using paint filter.
Beneficial effects of the present invention
Present invention employs specific raw material monomer and proportioning, had under special reaction condition through high temperature polymerization
Good flexibility, viscosity, the polymer emulsion of stability, the coating prepared with the polymer emulsion are obtained after coating film forming
Coating has good barrier properties, intensity and corrosion resistance, for the protective coating of building, can effectively extend making for building
Use the life-span.
Embodiment
With reference to embodiment, the present invention is further described.
Embodiment 1
The preparation of polymer emulsion：In terms of parts by weight, 100 parts of ionized water is removed, is added in reactor, is then added successively
Enter 2 parts of sodium stearyl sulfonate, 1.5 parts of Emulsifier EL-10,1.5 parts of pH value regulator, 20 parts of hexadiene, 6 parts of acrylic acid,
10 parts of EMA, 10 parts of butyl methacrylate, 5 parts of glutaric acid, 5 parts of styrene, 1 part of ammonium persulfate, with 5
DEG C/min speed is warming up to 60 DEG C, it is sufficiently stirred for 10 hours, stir speed (S.S.) is 400 turns/min, then with 3 DEG C/min speed liter
Temperature continues to be sufficiently stirred for 5 hours to 75 DEG C, and stir speed (S.S.) is 400 turns/min, then adds 2 parts of EDTA, under vacuum
Degassing, the NaOH solution for being then 20% with weight/mass percentage composition adjustment pH value is 7, is cooled to room temperature, rate of temperature fall is 3 DEG C/
Min, obtains polymer emulsion.
The preparation of coating：In terms of parts by weight, 1 part of dispersant, 1 part of defoamer, 1 part of levelling agent, nano titanium oxide are taken
20 parts, 20 parts of silicon dioxide microsphere is added in container, the step a then added in terms of parts by weight）Obtained polymer breast
40 parts of liquid, dispersed with stirring, stir speed (S.S.) is 400 turns/min, then adds 1.5 parts of montmorillonites, and 5 parts of filler continues stirring 2 small
When, stir speed (S.S.) is 400 turns/min, then grinds 2h, is filtered with paint filter, obtains polymer matrix water-repellent paint.
Coating after the paint spraying of embodiment 1 is tested, it is as a result as follows：
Claims (3)
1. a kind of preparation method of polymer matrix water-repellent paint, it is characterised in that comprise the following steps：
a）The preparation of polymer emulsion：In terms of parts by weight, 100 parts of ionized water is removed, adds in reactor, then sequentially adds
2 parts of sodium stearyl sulfonate, 1.5 parts of Emulsifier EL-10,1.5 parts of pH value regulator, 20 parts of hexadiene, 6 parts of acrylic acid, first
10 parts of base ethyl acrylate, 10 parts of butyl methacrylate, 5 parts of glutaric acid, 5 parts of styrene, 1 part of ammonium persulfate, with 5 DEG C/
Min speed is warming up to 60 DEG C, is sufficiently stirred for 10 hours, then is warming up to 75 DEG C with 3 DEG C/min speed, continues to be sufficiently stirred for 5
Hour, 2 parts of EDTA is then added, is deaerated under vacuum, is then adjusted with weight/mass percentage composition for 20% NaOH solution
PH value is 7, is cooled to room temperature, obtains polymer emulsion；
b）The preparation of coating：In terms of parts by weight, 1 part of dispersant, 1 part of defoamer, 1 part of levelling agent, nano titanium oxide 20 are taken
Part, 20 parts of silicon dioxide microsphere is added in container, the step a then added in terms of parts by weight）Obtained polymer emulsion
40 parts, dispersed with stirring then adds 1.5 parts of montmorillonites, and 5 parts of filler continues to stir 2 hours, then grinds 2h, filters, obtain
Polymer matrix water-repellent paint；
Coating after obtained paint spraying, moist bond matrix is slight >=1.0KPa, tensile strength 1.5MPa, elongation at break
170%。
2. preparation method as claimed in claim 1, it is characterised in that：Step a）In the stir speed (S.S.) being sufficiently stirred for be
400 turns/min, rate of temperature fall is 3 DEG C/min.
3. preparation method as claimed in claim 1, it is characterised in that：Step b）In stir speed (S.S.) be 400 turns/min, adopt
Filtered with paint filter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510158549.8A CN104710894B (en) | 2015-04-03 | 2015-04-03 | A kind of preparation method of polymer matrix water-repellent paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510158549.8A CN104710894B (en) | 2015-04-03 | 2015-04-03 | A kind of preparation method of polymer matrix water-repellent paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104710894A CN104710894A (en) | 2015-06-17 |
| CN104710894B true CN104710894B (en) | 2017-08-11 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510158549.8A Active CN104710894B (en) | 2015-04-03 | 2015-04-03 | A kind of preparation method of polymer matrix water-repellent paint |
Country Status (1)
| Country | Link |
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| CN (1) | CN104710894B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109053172A (en) * | 2018-09-13 | 2018-12-21 | 丁杨洋 | A kind of medium-frequency induction furnace Dry vibrating material and preparation method thereof and application method |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1206299C (en) * | 2003-03-26 | 2005-06-15 | 武汉理工大学 | Nano modified polymer-based roof waterproof paint and its production process |
| CN101724116B (en) * | 2009-12-08 | 2012-05-30 | 南京工业大学 | Polymer emulsion and preparation method thereof |
| CN104277172B (en) * | 2014-09-28 | 2017-03-22 | 广州大学 | Water-based waterproof acrylate emulsion and preparation method thereof |
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| Publication number | Publication date |
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| CN104710894A (en) | 2015-06-17 |
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| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Wang Chunyan Inventor after: Zhang Chuyun Inventor after: Wen Zirun Inventor before: Li Hailan |
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Effective date of registration: 20170713 Address after: No. 775 Tianhe town Longwan District Wenzhou City Yongqiang Avenue 325025 in Zhejiang Province Applicant after: Ding Yangyang Address before: 311800 Zhejiang city in Shaoxing Province, Zhuji City, East Street and East Road No. 469 Applicant before: Li Hailan |
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Effective date of registration: 20180208 Address after: Baini town Sanshui District National Torch Plan 528131 Guangdong city in Foshan province north of Foshan electronics industry base No. 73-1 F1 Patentee after: Foshan coating building materials Co., Ltd. worry free Address before: No. 775 Tianhe town Longwan District Wenzhou City Yongqiang Avenue 325025 in Zhejiang Province Patentee before: Ding Yangyang |