CN104693638A - Ultraviolet ray absorption improving computer protection film - Google Patents
Ultraviolet ray absorption improving computer protection film Download PDFInfo
- Publication number
- CN104693638A CN104693638A CN201310659572.6A CN201310659572A CN104693638A CN 104693638 A CN104693638 A CN 104693638A CN 201310659572 A CN201310659572 A CN 201310659572A CN 104693638 A CN104693638 A CN 104693638A
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- CN
- China
- Prior art keywords
- protection film
- computer protection
- pvc
- raw material
- ultraviolet radiation
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/28—Nitrogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The present invention discloses an ultraviolet ray absorption improving computer protection film which is characterized in that the computer protection film is prepared by adding modified tombarthite, pigment powder and crosslinking agent. The modified tombarthite is one or two of mixtures of lanthanum nitrate and yttrium nitrate. The computer protection film prepared by the method of the present invention has a high transparency, has significantly enhanced mechanical properties, and in particular has a strong absorption capacity for ultraviolet rays and can effectively prevent the damage of ultraviolet rays to eyes.
Description
Technical field
The present invention relates to a kind of computer protection film, be specifically related to a kind of computer protection film improving ultraviolet radiation absorption.
Background technology
The life of computer and modern has close relationship, a lot of people most of the time of one day facing to computer screen.The principle of work of computer can cause stored charge on computer screen, causes attract dust, with adverse consequencess such as surrounding objects electric discharges.Meanwhile, computer produces stronger ultraviolet, the microwave radiation light of low frequency, and when for a long time in the face of computer, eyes are easily tired, rubescent silk, and visual deterioration even has a strong impact on healthy, as dizziness, and headache, absent minded etc.
There is the radiation-resistant product much preventing computer radiate at present, as radiation proof computer protection film etc., but also effectively do not reduce the product of computer ultraviolet radiation.
Summary of the invention
The invention provides a kind of computer protection film improving ultraviolet radiation absorption.
Technical scheme of the present invention is as follows:
A kind of computer protection film improving ultraviolet radiation absorption; this computer protection film in PVC film raw material, adds modified RE, pigmented powder and linking agent be prepared from, and wherein said modified RE is one or both the mixture in lanthanum nitrate rare earth, Yttrium trinitrate rare earth.
In the present invention, the content of described modified RE is the 2-4% of PVC film raw material weight, and the content of described pigmented powder is the 0.0002-0.0004% of PVC film raw material weight, and the content of described linking agent is the 1-3% of PVC film raw material weight.
In the present invention, described PVC film raw material is prepared with the following method: be dissolved in by PVC in THF, adds photosensitizers and softening agent, and obtain the PVC solution that mass percentage is 5%, in described PVC solution, the content of photosensitizers is 1-3%, and the content of softening agent is 3-6%.
In the present invention, described pigmented powder is one or both the mixture in VK3 or T416.
In the present invention, the mass ratio of described VK3 and T416 is 1:1.
The present invention does not do special restriction to described linking agent, photosensitizers and softening agent, all can adopt at linking agent, photosensitizers and the softening agent that can realize this area of the present invention conventional.
Beneficial effect of the present invention: computer protection film transparency prepared by method of the present invention is high, mechanical property has
Remarkable enhancing, especially has very strong receptivity to ultraviolet, effectively prevents ultraviolet to the injury of eyes.
Embodiment
Following non-limiting example can make the present invention of those of ordinary skill in the art's comprehend, but does not limit the present invention in any way.Test method described in embodiment, if no special instructions, is ordinary method; Described reagent and material, if no special instructions, all can obtain from commercial channels, or can prepare in conventional manner.
Embodiment 1
Improve a computer protection film for ultraviolet radiation absorption, prepare with the following method:
(1) 5gPVC powder is dissolved in 50ml THF, then adds 2g benzophenone and the positive dioctyl ester of 3g phthalic acid stirs, then to add THT be 100ml to overall solution volume, obtain the PVC raw material that mass percentage is 5%;
(2) by adding 2g lanthanum nitrate rare earth in the PVC raw material of step (1), 2g Vinylstyrene, 0.2mgVK3 and 0.2mg T416 stir, until obtain clear solution;
(3) clear solution of step (3) is poured in sheet glass grinding tool, vacuum-drying demoulding after 7 hours.
Embodiment 2
Improve a computer protection film for ultraviolet radiation absorption, prepare with the following method:
(1) 5g PVC powder is dissolved in 50ml THF, then adds 4g benzophenone and the positive dioctyl ester of 5g phthalic acid stirs, then to add THT be 100ml to overall solution volume, obtain the PVC raw material that mass percentage is 5%;
(2) by adding 3g lanthanum nitrate rare earth in the PVC raw material of step (1), 2.5g Vinylstyrene, 0.2mgVK3 and 0.2mg T416 stir, until obtain clear solution;
(3) clear solution of step (3) is poured in sheet glass grinding tool, vacuum-drying demoulding after 10 hours.
Claims (5)
1. one kind is improved the computer protection film of ultraviolet radiation absorption; it is characterized in that; this computer protection film in PVC film raw material, adds modified RE, pigmented powder and linking agent be prepared from, and wherein said modified RE is one or both the mixture in lanthanum nitrate rare earth, Yttrium trinitrate rare earth.
2. the computer protection film of raising ultraviolet radiation absorption according to claim 1; it is characterized in that; the content of described modified RE is the 2-4% of PVC film raw material weight; the content of described pigmented powder is the 0.0002-0.0004% of PVC film raw material weight, and the content of described linking agent is the 1-3% of PVC film raw material weight.
3. the computer protection film of raising ultraviolet radiation absorption according to claim 1 and 2; it is characterized in that; described PVC film raw material is prepared with the following method: be dissolved in by PVC in THF; add photosensitizers and softening agent; obtain the PVC solution that mass percentage is 5%; in described PVC solution, the content of photosensitizers is 1-3%, and the content of softening agent is 3-6%.
4. the computer protection film of the raising ultraviolet radiation absorption according to any one of claim 1-3, is characterized in that, described pigmented powder is one or both the mixture in VK3 or T416.
5. the computer protection film of raising ultraviolet radiation absorption according to claim 4, is characterized in that, the mass ratio of described VK3 and T416 is 1:1.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310659572.6A CN104693638A (en) | 2013-12-06 | 2013-12-06 | Ultraviolet ray absorption improving computer protection film |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310659572.6A CN104693638A (en) | 2013-12-06 | 2013-12-06 | Ultraviolet ray absorption improving computer protection film |
Publications (1)
Publication Number | Publication Date |
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CN104693638A true CN104693638A (en) | 2015-06-10 |
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Family Applications (1)
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CN201310659572.6A Pending CN104693638A (en) | 2013-12-06 | 2013-12-06 | Ultraviolet ray absorption improving computer protection film |
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CN (1) | CN104693638A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107099085A (en) * | 2017-05-06 | 2017-08-29 | 安徽玉发塑业有限公司 | A kind of polyvinyl chloride screen protection material and preparation method thereof |
-
2013
- 2013-12-06 CN CN201310659572.6A patent/CN104693638A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107099085A (en) * | 2017-05-06 | 2017-08-29 | 安徽玉发塑业有限公司 | A kind of polyvinyl chloride screen protection material and preparation method thereof |
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C06 | Publication | ||
PB01 | Publication | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150610 |