CN104692677A - Graphene hollow glass - Google Patents

Graphene hollow glass Download PDF

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Publication number
CN104692677A
CN104692677A CN201510101620.9A CN201510101620A CN104692677A CN 104692677 A CN104692677 A CN 104692677A CN 201510101620 A CN201510101620 A CN 201510101620A CN 104692677 A CN104692677 A CN 104692677A
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CN
China
Prior art keywords
graphene
glass
double glazing
spacer bar
spacing strip
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Pending
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CN201510101620.9A
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Chinese (zh)
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朱正唯
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Individual
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Individual
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Priority to CN201510101620.9A priority Critical patent/CN104692677A/en
Publication of CN104692677A publication Critical patent/CN104692677A/en
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Abstract

The invention discloses a graphene hollow glass. The graphene hollow glass comprises glass sheets, a spacing strip, a drying agent and a sealant, wherein the spacing strip is arranged between the edges of the two glass sheets; the spacing strip can be an aluminum spacing strip, the drying agent is arranged in the inner cavity of the aluminum spacing strip, the two sides of the aluminum spacing strip are glued to the two glass streets by use of the butyl sealant, and the sealant is applied secondarily to the outer side of the spacing strip; the spacing strip also can be a hollow composite rubber strip; the first structure of the spacing strip is characterized in that the inner cavity of the sheets of the hollow glass is covered with a graphene layer; the second structure of the spacing strip is characterized in that the outer surfaces of the sheets of the hollow glass is covered with the graphene layer. The graphene hollow glass is better than the existing low-e glass or heat-reflecting glass in properties such as transmission of light, low radiativity and stability, and is applicable to regions hot in summer and cold in winter. The graphene hollow glass is good in energy saving effect, long in service life and stable in properties, and also has self-cleaning and anti-scratching functions.

Description

A kind of Graphene double glazing
Technical field
The invention belongs to energy-saving building technology field, particularly a kind of Graphene double glazing with the function such as energy-conservation being applicable to hot-summer and cold-winter area.
Background technology
Current building or decoration double glazing, the general common white glass that adopts manufactures, although cost is low, its heat-insulating property is not good, and its heat transfer coefficient (K value) is about 3.0.
Also the building had or decoration adopt low-e double glazing, its heat-insulating property is better, heat transfer coefficient (K value) is about 2.4, but it has two shortcomings: when 1, people need sunlight in the winter time, glass is owing to there being LOW-E rete block sunlight, its shading coefficient is below 0.60, and this affects winter heating, is not suitable for being applied to hot-summer and cold-winter area; 2, off-line low-e membrane stability is poor, as easy as rolling off a log oxidized, and double glazing is after the use several years, and low-e film properties is decayed, and its low radiance reduces, and heat-insulating property can decline; Online low-e film antioxidant property is better, but low radiance is poor.
Also the building had or decoration employing three glass two chamber double glazing, its good heat insulating, heat transfer coefficient (K value) is 2.2, and shading coefficient is more than 0.6, and can be applicable to being applied to hot-summer and cold-winter area, its shortcoming is: glass is too heavy, too thick.
Summary of the invention
The object of the invention is to solve weak point of the prior art, a kind of Graphene double glazing is provided.It has multinomial premium properties as described below: have good insulation, heat-proof quality, have higher transmittance; Also can have self-cleaning function, anti-scratch function, be applicable to being applied to hot-summer and cold-winter area.
To achieve these goals, the present invention adopts following two kinds of technical schemes, specifically describes as follows:
A kind of Graphene double glazing, comprise original sheet glass, spacer bar, siccative and seal gum, spacer bar is located between two original sheet glass edge, spacer bar can be the aluminium spacer bar that inner chamber is equipped with siccative, its both sides butyl sealant is bonding with two original sheet glasses, also have second seal gum outside spacer bar, spacer bar can be also hollow composite rubber strip, it is characterized in that: have graphene layer at the surface of internal cavity of former of double glazing.
A kind of Graphene double glazing, comprise original sheet glass, spacer bar, siccative and seal gum, spacer bar is located between two original sheet glass edge, spacer bar can be the aluminium spacer bar that inner chamber is equipped with siccative, its both sides butyl sealant is bonding with two original sheet glasses, also have second seal gum outside spacer bar, spacer bar can be also hollow composite rubber strip, it is characterized in that: have graphene layer at the outside surface of former of double glazing.
Two kinds of Graphene double glazings as above, is characterized in that: described graphene layer thickness is 10nm to 1000nm.
Two kinds of Graphene double glazings as above, is characterized in that: described graphene layer thickness is 30nm to 500nm.
Two kinds of Graphene double glazings as above, is characterized in that: described graphene layer thickness is 50nm to 200nm.
Two kinds of Graphene double glazings as above, is characterized in that: the number of plies of described graphene layer is 1 layer.
Two kinds of Graphene double glazings as above, is characterized in that: the number of plies of described graphene layer is 2 layers.
Two kinds of Graphene double glazings as above, is characterized in that: the number of plies of described graphene layer is 3 layers.
The present invention has the following advantages:
1, good energy-saving effect can be reached.
Because glass of the present invention have employed, double glazing inner chamber original sheet glass surface is provided with graphene layer.This is for the low-e double glazing technology used at present, and the light transmission of Graphene rete, electroconductibility, low diathermaneity, stability will well much than silverskin or other metallic membranes.So double glazing of the present invention is not only good than existing low-e glass properties, and is applicable to hot-summer and cold-winter area because graphene layer has high transmittance.Its high insulating effect, long service life, stable performance.
2, self-cleaning and scratch Be very effective.
Because glass of the present invention also uses, the outside surface of former of double glazing is provided with graphene layer, the advantage of this double glazing is: graphene layer can play the effect of thermal reflecting coating, and heat-proof quality is good, energy-saving effect is obvious; Graphene is good nano material, easily decomposes if it is not easily stained with after ash is stained with ash or dirt, and be easy to wash away totally through rainwater, self-cleaning performance is good; Graphene layer has the hardness also higher than diamond, so the scratch Be very effective of glass.
3, good reliability, long service life.
Because Graphene has extraordinary stability, so no matter it is positioned at the surface of internal cavity of double glazing, or outer surface, its performance does not have any change, good reliability, the long service life of a kind of Graphene double glazing of the present invention in the work-ing life of whole double glazing.
Accompanying drawing explanation
Fig. 1 is a kind of structural representation of the present invention.
Fig. 2 is another kind of structural representation of the present invention.
1,2 be that the Aluminum Hollow spacer bar, 4 that original sheet glass, 3 is equipped with siccative for inner chamber is butyl rubber in figure, 5 TR sealant, 6 and 8 are for graphene layer; 7 is hollow space.
Embodiment
Contrast Fig. 1 is described further a kind of embodiment of the present invention.
In FIG, double glazing of the present invention comprises original sheet glass 1,2, the inner side that inner chamber is equipped with the Aluminum Hollow spacer bar 3 of siccative, butyl rubber 4, TR sealant 5, hollow space 7, graphene layer 6 are arranged at double glazing former 1.
The making of double glazing is very ripe prior art, what adopt in figure is the double glazing (aluminum groove hollow glass) made of the aluminium spacer bar that inner chamber is equipped with siccative, and hollow composite rubber strip also can be adopted to make double glazing (glue strip type hollow glass) as spacer bar.
It is new prior art that original sheet glass 1 arranges graphene layer, just there are many methods at present, can adopt if the disclosed patent No. is 201110253152.9, the technology that name is called disclosed in " a kind of preparation method of graphene transparent conductive film on glass substrate "; Also can adopt if the disclosed patent No. is 201320167604.6, the technology that name is called disclosed in " transparent conducting glass with graphene layer ".
Glass of the present invention have employed and double glazing inner chamber original sheet glass surface is provided with graphene layer 6, and its thickness is 45nm.This is for the low-e double glazing technology used at present, and the light transmission of Graphene rete, electroconductibility, low diathermaneity, stability will well much than silverskin or other metallic membranes.So double glazing of the present invention is not only good than existing low-e glass properties, and high transmittance is had to be applicable to hot-summer and cold-winter area because of graphene layer.Its high insulating effect, good energy-conserving effect, long service life, stable performance.
Contrast Fig. 2 is described further another kind of embodiment of the present invention.
In fig. 2, double glazing of the present invention comprises original sheet glass 1,2, is arranged at the outside of double glazing former 1 containing siccative Aluminum Hollow spacer bar 3, butyl rubber 4, TR sealant 5, hollow space 7, graphene layer 8.
Glass of the present invention have employed and the outside surface of former of double glazing is provided with graphene layer 8, and its thickness is 60nm.The advantage of this double glazing is: graphene layer can play the effect of thermal reflecting coating, and heat-proof quality is good, and energy-saving effect is obvious; Graphene is good nano material, and it is not stained with ash, or is easy to wash away totally through rainwater after being stained with ash; Graphene layer has the hardness also higher than diamond, so the scratch Be very effective of glass.
Because Graphene has extraordinary stability, so no matter it is positioned at the inner surface of double glazing, or outer surface, its performance does not have any change in the work-ing life of whole double glazing.The light transmission of Graphene double glazing of the present invention, low diathermaneity, stability than all than existing low-e glass or heat-reflecting glass performance good, and can hot-summer and cold-winter area be applicable to.Its good energy-conserving effect, long service life, stable performance, also can have self-cleaning and scratch function.

Claims (8)

1. a Graphene double glazing, comprise original sheet glass (1) (2), spacer bar, siccative and seal gum, spacer bar is located between two original sheet glass edge, spacer bar can be the aluminium spacer bar (3) that inner chamber is equipped with siccative, its both sides butyl sealant (4) is bonding with two original sheet glasses, second seal gum (5) is also had outside spacer bar, spacer bar can be also hollow composite rubber strip, it is characterized in that: have graphene layer (6) at the surface of internal cavity of former of double glazing.
2. a Graphene double glazing, comprise original sheet glass (1) (2), spacer bar, siccative and seal gum, spacer bar is located between two original sheet glass edge, spacer bar can be the aluminium spacer bar (3) that inner chamber is equipped with siccative, its both sides butyl sealant (4) is bonding with two original sheet glasses, second seal gum (5) is also had outside spacer bar, spacer bar can be also hollow composite rubber strip, it is characterized in that: have graphene layer (8) at the outside surface of former of double glazing.
3. a kind of Graphene double glazing according to claim 1,2, is characterized in that: described graphene layer thickness is 10nm to 1000nm.
4. a kind of Graphene double glazing according to claim 1,2, is characterized in that: described graphene layer thickness is 30nm to 500nm.
5. a kind of Graphene double glazing according to claim 1,2, is characterized in that: described graphene layer thickness is 50nm to 200nm.
6. a kind of Graphene double glazing according to claim 1,2, is characterized in that: the number of plies of described graphene layer is 1 layer.
7. a kind of Graphene double glazing according to claim 1,2, is characterized in that: the number of plies of described graphene layer is 2 layers.
8. a kind of Graphene double glazing according to claim 1,2, is characterized in that: the number of plies of described graphene layer is 3 layers.
CN201510101620.9A 2015-03-09 2015-03-09 Graphene hollow glass Pending CN104692677A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510101620.9A CN104692677A (en) 2015-03-09 2015-03-09 Graphene hollow glass

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510101620.9A CN104692677A (en) 2015-03-09 2015-03-09 Graphene hollow glass

Publications (1)

Publication Number Publication Date
CN104692677A true CN104692677A (en) 2015-06-10

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201386063Y (en) * 2009-01-08 2010-01-20 湖北弘毅建筑装饰工程有限公司 Double-layered, hollow and low-radiation toughened glass
CN203890237U (en) * 2014-04-12 2014-10-22 重庆福威工贸有限公司 Hollow decorative glass
CN203999381U (en) * 2014-08-08 2014-12-10 宁波江花玻璃科技有限公司 Fireproof hollow glass
CN104291691A (en) * 2014-09-03 2015-01-21 宁波市合鑫玻璃科技有限公司 Processing technique for bent aluminum strip double-silver LOW-E hollow glass

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201386063Y (en) * 2009-01-08 2010-01-20 湖北弘毅建筑装饰工程有限公司 Double-layered, hollow and low-radiation toughened glass
CN203890237U (en) * 2014-04-12 2014-10-22 重庆福威工贸有限公司 Hollow decorative glass
CN203999381U (en) * 2014-08-08 2014-12-10 宁波江花玻璃科技有限公司 Fireproof hollow glass
CN104291691A (en) * 2014-09-03 2015-01-21 宁波市合鑫玻璃科技有限公司 Processing technique for bent aluminum strip double-silver LOW-E hollow glass

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Application publication date: 20150610