CN104673017A - 一种节能涂料制备方法 - Google Patents
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- 239000000463 material Substances 0.000 title claims abstract description 24
- 238000000576 coating method Methods 0.000 title claims abstract description 11
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000011248 coating agent Substances 0.000 title abstract description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 25
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- -1 dodecyl alcohol ester Chemical class 0.000 claims abstract description 6
- 239000000839 emulsion Substances 0.000 claims abstract description 6
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 4
- 239000008367 deionised water Substances 0.000 claims abstract description 4
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 230000008719 thickening Effects 0.000 claims description 7
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 7
- 230000003750 conditioning effect Effects 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 239000011941 photocatalyst Substances 0.000 abstract description 5
- 239000000843 powder Substances 0.000 abstract description 3
- 150000002500 ions Chemical class 0.000 abstract description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N ethyl butylhexanol Natural products CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 abstract 1
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 2
- VUGZGIRXHHTXKG-UHFFFAOYSA-N S1NCC=C1.CC1=CC=CC=C1 Chemical compound S1NCC=C1.CC1=CC=CC=C1 VUGZGIRXHHTXKG-UHFFFAOYSA-N 0.000 description 2
- MUCRYNWJQNHDJH-OADIDDRXSA-N Ursonic acid Chemical compound C1CC(=O)C(C)(C)[C@@H]2CC[C@@]3(C)[C@]4(C)CC[C@@]5(C(O)=O)CC[C@@H](C)[C@H](C)[C@H]5C4=CC[C@@H]3[C@]21C MUCRYNWJQNHDJH-OADIDDRXSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 210000000481 breast Anatomy 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 description 2
- 229960002887 deanol Drugs 0.000 description 2
- 239000012972 dimethylethanolamine Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 229940070527 tourmaline Drugs 0.000 description 2
- 229910052613 tourmaline Inorganic materials 0.000 description 2
- 239000011032 tourmaline Substances 0.000 description 2
- 241000233866 Fungi Species 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
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- 239000002386 air freshener Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
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- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
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- 239000003599 detergent Substances 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
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- 239000007789 gas Substances 0.000 description 1
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- 239000012535 impurity Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 239000003642 reactive oxygen metabolite Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
本发明涉及一种节能涂料制备方法,属于光触媒技术领域。本发明所用原料按照重量份为:去离子水20~32、防冻剂1~2.0、甘油0.15~0.25、液体石蜡0.55~0.7、防腐剂0.2、PH调节剂0.1~0.2、纳米二氧化钛1、负离子发生材料2~2,5、纳米钛白粉20~25、碳酸钙12~15、十二碳醇酯1~2、丙烯酸乳液25~45、增稠剂1~2。
Description
技术领域
本发明涉及一种节能涂料制备方法,属于光触媒技术领域。
背景技术
随着国民经济的快速发展,人们对室内装修的要求也日益提高。环保概念已深入人心,家居环境的改善迫在眉捷。家具、装修材料(板材、油涂料、粘胶等)中释放的甲醛、氨、苯类等有害气体,以及室内各种霉菌、病毒、异味已严重危害到人们的身体健康、生活环境等。现有技术中一般通过空气清新剂等芬芳剂遮盖原有气味。这种方法并不能真正地祛除空气中的有害物质。光触媒是一种纳米级的金属氧化物材料(二氧化钛比较常用),它涂布于基材表面,在光线的作用下,产生强烈催化降解功能:能有效地降解空气中有毒有害气体;能有效杀灭多种细菌,并能将细菌或真菌释放出的毒素分解及无害化处理;同时还具备除臭、抗污等功能。光触媒抗菌氧吧墙面涂料运用了负离子发生材料、光催化材料和纳米材料。负离子发生材料形成的永久电场通过其电极对空气和水分子产生微弱电解作用而产生羟基负离子(H302-),产生的羟基负离子对氮氧化物、氨、苯、甲醛等具有很好的祛除作用,同时对人体具氧吧的特殊功效;涂膜在阳光、日光灯等光源的照射下纳米光催化材料发生电子跃迁,价带电子被激发到导带并在价带上产生空穴,使空气中的氧和水分子活化,产生具高反应活性的活性氧和自由基,并释放在空气中对细菌等微生韧产生杀灭和分解作用,起到净化空气的目的;利用纳米材料的小尺寸效应,涂料膜更加致密,生活中常见污渍均不易粘污涂料膜表面,弄脏的墙面只需用干净清水和洗洁精就可轻松清洁,从而达到抗污易洁的目的。
发明内容
本发明一种节能涂料制备方法,所用原料按照重量份为:去离子水20~32、防冻剂1~2.0、甘油0.15~0.25、液体石蜡 0.55~0.7、防腐剂0.2、PH调节剂0.1~0.2、纳米二氧化钛1、负离子发生材料2~2,5、纳米钛白粉20~25、碳酸钙12~15、十二碳醇酯1~2、丙烯酸乳液25~45、增稠剂1~2。
上述的防腐剂为含氮有机杂环化合物、四氯间苯二甲腈、5氯2甲苯4异噻唑啉.3酮、2.正辛基-4-异噻唑啉-3-酮中一种或一种以上的混合物。
上述的增稠剂为改性聚丙烯酸钠、改性聚丙烯酸胺、非离子聚氨酯化合物中的一种或一种以上的混合物。
上述的PH调节剂为二甲基乙醇胺、乙醇胺、氢氧化钾中的一种或一种以上的混合物。
上述的负离子发生材料为高纯度的碧玺粉与纳米氧化锌、纳米二氧化钛等的混合物。
上述的纳米二氧化钛为锐钛型纳米二氧化钛。
上述配方用22KW高速变频搅拌机在配漆缸内边加料、边搅拌,料投完后提速至1500转/分钟,将上述混合料进行机械乳合,制成中间浆液,其细度需达到40~50um;然后再将制成的中间浆液在另一配漆缸中边搅拌边加入所述的乳液,搅拌速度为400~600转/分钟,搅拌均匀后再加入增稠剂,以及按配色要求加入色彩颜料浆,搅拌均匀,用80~100目网过滤,涂料产品粘度为90~100KU。
本发明具有如下优点:
1、以涂料为载体,涂料涂刷于墙壁后涂料膜能持续释放负离子抗菌抑菌率达90以上;
2、能有效祛除室内空气中的气体。
3、纳米材料改性,漆膜更加致密,利用纳米材料的小尺寸效应来达到漆膜抗污易洁的目的。
具体实施方式
本发明一种节能涂料制备方法,所用原料按照重量份为:去离子水20~32、防冻剂1~2.0、甘油0.15~0.25、液体石蜡 0.55~0.7、防腐剂0.2、PH调节剂0.1~0.2、纳米二氧化钛1、负离子发生材料2~2,5、纳米钛白粉20~25、碳酸钙12~15、十二碳醇酯1~2、丙烯酸乳液25~45、增稠剂1~2。
上述的防腐剂为含氮有机杂环化合物、四氯间苯二甲腈、5氯2甲苯4异噻唑啉.3酮、2.正辛基-4-异噻唑啉-3-酮中一种或一种以上的混合物。
上述的增稠剂为改性聚丙烯酸钠、改性聚丙烯酸胺、非离子聚氨酯化合物中的一种或一种以上的混合物。
上述的PH调节剂为二甲基乙醇胺、乙醇胺、氢氧化钾中的一种或一种以上的混合物。
上述的负离子发生材料为高纯度的碧玺粉与纳米氧化锌、纳米二氧化钛等的混合物。
上述的纳米二氧化钛为锐钛型纳米二氧化钛。
上述配方用22KW高速变频搅拌机在配漆缸内边加料、边搅拌,料投完后提速至1500转/分钟,将上述混合料进行机械乳合,制成中间浆液,其细度需达到40~50um;然后再将制成的中间浆液在另一配漆缸中边搅拌边加入所述的乳液,搅拌速度为400~600转/分钟,搅拌均匀后再加入增稠剂,以及按配色要求加入色彩颜料浆,搅拌均匀,用80~100目网过滤,涂料产品粘度为90~100KU。
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。
Claims (1)
1.一种节能涂料制备方法,其特征在于:所用原料按照重量份为:去离子水20~32、防冻剂1~2.0、甘油0.15~0.25、液体石蜡 0.55~0.7、防腐剂0.2、PH调节剂0.1~0.2、纳米二氧化钛1、负离子发生材料2~2,5、纳米钛白粉20~25、碳酸钙12~15、十二碳醇酯1~2、丙烯酸乳液25~45、增稠剂1~2。
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634348A (zh) * | 2016-12-16 | 2017-05-10 | 重庆浩申实业有限公司 | 镁玺方晶风道负离子喷剂及其制备方法和应用 |
| CN109054551A (zh) * | 2018-07-03 | 2018-12-21 | 广西神灯涂料有限公司 | 一种可释放远红外线的碧玺墙面漆及其制备方法 |
| CN113861788A (zh) * | 2021-10-14 | 2021-12-31 | 上海骋润高分子材料有限公司 | 一种面漆涂料及可实现仿铜拉丝效果的涂装方法 |
-
2013
- 2013-11-27 CN CN201310609576.3A patent/CN104673017A/zh active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634348A (zh) * | 2016-12-16 | 2017-05-10 | 重庆浩申实业有限公司 | 镁玺方晶风道负离子喷剂及其制备方法和应用 |
| CN109054551A (zh) * | 2018-07-03 | 2018-12-21 | 广西神灯涂料有限公司 | 一种可释放远红外线的碧玺墙面漆及其制备方法 |
| CN113861788A (zh) * | 2021-10-14 | 2021-12-31 | 上海骋润高分子材料有限公司 | 一种面漆涂料及可实现仿铜拉丝效果的涂装方法 |
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