CN104672659A - 一种环保pvc软管材料 - Google Patents

一种环保pvc软管材料 Download PDF

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CN104672659A
CN104672659A CN201310623086.9A CN201310623086A CN104672659A CN 104672659 A CN104672659 A CN 104672659A CN 201310623086 A CN201310623086 A CN 201310623086A CN 104672659 A CN104672659 A CN 104672659A
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parts
pvc
environment
resin
low
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范开娟
李文勇
李长敏
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Qingdao Jiashang Creative Culture Co Ltd
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Qingdao Jiashang Creative Culture Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L11/00Hoses, i.e. flexible pipes
    • F16L11/04Hoses, i.e. flexible pipes made of rubber or flexible plastics
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/017Additives being an antistatic agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/04Thermoplastic elastomer

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

一种环保PVC软管材料,由以下重量份的成分组成:聚氯乙烯树脂40~80;热塑性聚氨酯弹性体10~15;硬脂酸10~20;酚醛树脂4~5;季戊四醇2~4;环氧树脂0.4~0.6;碘酊4~5;碳黑1~5;聚碳酸酯10~20;纳米碳酸钙2~4。本发明采用在PVC树脂中加入热塑性聚氨酯弹性体、增塑剂、热稳定剂、抗静电剂、阻燃剂,增强了PVC软管的耐低温性能、柔韧性、抗静电性能和阻燃性,制备的PVC复合软管综合性能好,不易老化,可运用于低温油,气体或液体的储藏和使用过程中。

Description

一种环保PVC软管材料
技术领域
本发明涉及一种环保PVC软管材料。
背景技术
聚氯乙烯(PVC)为微黄色半透明状,有光泽。透明度优于聚乙烯、聚苯烯,差于聚苯
乙烯,随助剂用量不同,分为软、硬聚氯乙烯,软制品柔而韧、手感粘,硬制品的硬度高于低密度聚乙烯,而低于聚丙烯,在屈折处会出现白化现象。聚氯乙烯的性能比较稳定,不易被酸、碱腐蚀,对热比较耐受;具有阻燃、耐化学药品性高、机械强度和电绝缘性能高等优点。
 聚氯乙烯(PVC)用于制造各种软硬管材,并被广泛应用到工业、农业和广大居民生
活中。随着社会经济的不断发展,对聚氯乙烯质量的要求也越来越高。现有技术中的聚氯
乙烯软管,常用的PVC 软管的耐低温性能差、脆性大、韧性强度低、抗老化性能差、安全性能低、运输和安装不便,制作成本高,达不到生产和生活的的要求。现有技术中提到一种卫浴洁具用纳米碳酸钙改性螺旋缠绕PVC 软管的组合屋及其制备方法,但是这种材料制得的软
管耐热性能较好,耐低温性能较差。
发明内容
    针对现有技术存在的不足,本发明所要解决的技术问题是,提供一种耐低温、性能优良、有效提高PVC软管使用寿命的高韧性环保PVC软管材料。
为解决上述技术问题,本发明所采取的技术方案是:一种环保PVC软管材料,由以下重量份的成分组成:
聚氯乙烯树脂                      40~80;
热塑性聚氨酯弹性体                10~15;
硬脂酸                            10~20;
酚醛树脂                          4~5;
季戊四醇                          2~4;
环氧树脂                          0.4~0.6;
碘酊                              4~5;
碳黑                              1~5;
聚碳酸酯                          10~20;
纳米碳酸钙                        2~4。
本发明高韧性环保PVC软管材料的优点是:本发明采用在PVC 树脂中加入热塑性聚氨酯弹性体、增塑剂、热稳定剂、抗静电剂、阻燃剂,增强了PVC 软管的耐低温性能、柔韧性、抗静电性能和阻燃性,制备的PVC 复合软管综合性能好,不易老化,可运用于低温油,气体或液体的储藏和使用过程中。
具体实施方式
下面结合具体实施例对本发明做进一步详细说明;
一种环保PVC软管材料,由以下重量份的成分组成:
聚氯乙烯树脂                      40~80;
热塑性聚氨酯弹性体                10~15;
硬脂酸                            10~20;
酚醛树脂                          4~5;
季戊四醇                          2~4;
环氧树脂                          0.4~0.6;
碘酊                              4~5;
碳黑                              1~5;
聚碳酸酯                          10~20;
纳米碳酸钙                        2~4。
当然,上述说明并非是对本发明的限制,本发明也并不限于上述举例,本技术领域的普通技术人员,在本发明的实质范围内,作出的变化、改型、添加或替换,都应属于本发明的保护范围。

Claims (1)

1.一种环保PVC软管材料,其特征在于,由以下重量份的成分组成:
聚氯乙烯树脂                      40~80;
热塑性聚氨酯弹性体                10~15;
硬脂酸                            10~20;
酚醛树脂                          4~5;
季戊四醇                          2~4;
环氧树脂                          0.4~0.6;
碘酊                              4~5;
碳黑                              1~5;
聚碳酸酯                          10~20;
纳米碳酸钙                        2~4。
CN201310623086.9A 2013-11-30 2013-11-30 一种环保pvc软管材料 Pending CN104672659A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310623086.9A CN104672659A (zh) 2013-11-30 2013-11-30 一种环保pvc软管材料

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Application Number Priority Date Filing Date Title
CN201310623086.9A CN104672659A (zh) 2013-11-30 2013-11-30 一种环保pvc软管材料

Publications (1)

Publication Number Publication Date
CN104672659A true CN104672659A (zh) 2015-06-03

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ID=53308276

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Country Status (1)

Country Link
CN (1) CN104672659A (zh)

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Application publication date: 20150603