CN104672548A - Corrosion resistant environment-friendly rubber tube material - Google Patents
Corrosion resistant environment-friendly rubber tube material Download PDFInfo
- Publication number
- CN104672548A CN104672548A CN201310636095.1A CN201310636095A CN104672548A CN 104672548 A CN104672548 A CN 104672548A CN 201310636095 A CN201310636095 A CN 201310636095A CN 104672548 A CN104672548 A CN 104672548A
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- tube material
- rubber tube
- corrosion resistant
- rubber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a corrosion resistant environment-friendly rubber tube material which is characterized by being prepared from the following components in parts by weight: 50-60 parts of chlorinated polyethylene, 20-30 parts of an ethylene propylene diene monomer, 3-5 parts of biological ceramics, 3-5 parts of sulfur, 1-2 parts of zinc methacrylate, 0.6-0.8 part of a plasticizer DOP, 2-3 parts of carbon black, 1-1.2 parts of dibutyltin dilaurate and 1-2 parts of an anti-aging agent RD. The adhesion peeling strength of the rubber tube material disclosed by the invention is greatly improved by 7-8%, the service life of the rubber tube material is prolonged by more than 1 year, the cost is reduced, and furthermore the environment is protected. By optimizing the formula, the rubber tube material is good in comprehensive mechanical properties such as weather resistance, fatigue resistance and tearing resistance.
Description
Technical field
The invention belongs to rubber item technical field, be specifically related to a kind of corrosion resistant environment-friendlyadhesive adhesive tube material.Background technology
Sebific duct is in order to class tubular rubber goods of delivering gas, liquid, pulpous state or particulate materials.Be made up of inside and outside glue-line and casing ply, the material of casing ply can use cotton fibre, various synthon, carbon fiber or asbestos, steel wire etc.The inside and outside glue line material of general sebific duct adopts natural rubber, styrene-butadiene rubber(SBR) or cis-1,4-polybutadiene rubber; Oil resisting rubber hose adopts chloroprene rubber, paracril; Acid and alkali-resistance, high-temp .-resistant rubber duct adopts ethylene-propylene rubber(EPR), viton or silicon rubber etc.
The sebific duct oil resistant that butyronitrile rubber is formed but not acid and alkali-resistance, the sebific duct acid and alkali-resistance be made up of chloroprene rubber but oil-proofness is poor, use different rubber unvulcanizate tube materials, different sebific ducts is made to scrap time limit difference, and the work-ing life of various sebific duct shorter (long four, five months, short two, three months), in process of production, the sebific duct needing the replacing of not timing different and change frequent, has had a strong impact on production efficiency.Chlorinatedpolyethylene is saturated macromolecular material, and outward appearance is white powder, nonpoisonous and tasteless, has excellent weather resisteant, resistance to ozone, chemical-resistant resistance and ageing-resistant performance, has good oil-proofness, flame retardant resistance and tinctorial property.Toughness good (still having snappiness at-30 DEG C), have good consistency with other macromolecular material, decomposition temperature is higher, decomposes the dechlorination reaction producing HCl, HCL energy catalysis CPE.Existing sebific duct only plays the effect of conveying, can not produce more beneficial effect while conveying, such as, reduce harmful gas emission, increase output rating and extend the working life etc. of engine.The major ingredient of biological ceramics is magnesium, zinc, germanium, strontium, manganese, selenium, palladium etc., after ten multiple element mixing, forms through high-temperature exercise.This material makes full use of in hose material, produces huge economic benefit.Polychloroethylene with high polymerization degree has the excellent properties such as wear-resisting, corrosion-resistant, but its shortcoming such as poor toughness, poor heat resistance existed limits it and further applies.How producing a kind of excellent anti-corrosion performance, and have good weathering resistance, antifatigue, the environment-friendly type hose material of advantage such as to tear, is the technical problem to be solved in the present invention.
Summary of the invention
The object of the present invention is to provide a kind of corrosion resistant environment-friendlyadhesive adhesive tube material, make it to improve mechanics of elastic bodies performance, reduce costs.
The technical scheme that the present invention takes is:
A kind of corrosion resistant environment-friendlyadhesive adhesive tube material, it is characterized in that, feed components is composed as follows according to weight part:
Chlorinated polyethylene rubber 50-60 part, terpolymer EP rubber 20-30 part, biological ceramics 3-5 part, sulphur 3-5 part, zinc methacrylate 1-2 part, plasticizer DOP 0.6-0.8 part, carbon black 2-3 part, dibutyl tin laurate 1-1.2 part, anti-aging agent RD 1-2 part.
The polymerization degree of above-mentioned chlorinated polyethylene rubber is 2300-2500.
Above-mentioned chlorinated polyethylene rubber is paracril and polyvinyl chloride is proportionally 7:3 mixing.
Beneficial effect of the present invention is:
The present invention utilizes the characteristic of biological ceramics; can reduce harmful gas emission, increase output rating, the bonding stripping strength of obtained hose material significantly improves 7-8%, increases by more than 1 year work-ing life; the economy expenditure that decreasing updates brings, cost protects environment while reducing.The excellent properties such as wear-resisting, corrosion-resistant of the raw materials such as chlorinated polyethylene rubber itself, through optimization of C/C composites, the comprehensive mechanical property such as make hose material have good weathering resistance, antifatigue, to tear.
Embodiment
Embodiment 1
A kind of corrosion resistant environment-friendlyadhesive adhesive tube material, it is characterized in that, feed components is composed as follows according to weight part:
The polymerization degree be 2500 be proportionally chlorinated polyethylene rubber 50 parts, terpolymer EP rubber 20 parts, biological ceramics 3 parts, 3 parts, sulphur, zinc methacrylate 1 part, plasticizer DOP 0.6 part, carbon black 2 parts, dibutyl tin laurate 1 part, the anti-aging agent RD 1 part that 7:3 mixes by paracril and polyvinyl chloride.
Embodiment 2
A kind of corrosion resistant environment-friendlyadhesive adhesive tube material, it is characterized in that, feed components is composed as follows according to weight part:
The polymerization degree be 2400 be proportionally chlorinated polyethylene rubber 55 parts, terpolymer EP rubber 25 parts, biological ceramics 4 parts, 4 parts, sulphur, zinc methacrylate 1 part, plasticizer DOP 0.7 part, carbon black 2 parts, dibutyl tin laurate 1.1 parts, the anti-aging agent RD 1.5 parts that 7:3 mixes by paracril and polyvinyl chloride.
Embodiment 3
A kind of corrosion resistant environment-friendlyadhesive adhesive tube material, it is characterized in that, feed components is composed as follows according to weight part:
The polymerization degree be 2400 be proportionally chlorinated polyethylene rubber 60 parts, terpolymer EP rubber 30 parts, biological ceramics 5 parts, 5 parts, sulphur, zinc methacrylate 2 parts, plasticizer DOP 0.8 part, carbon black 3 parts, dibutyl tin laurate 1.2 parts, the anti-aging agent RD 2 parts that 7:3 mixes by paracril and polyvinyl chloride.
Claims (3)
1. a corrosion resistant environment-friendlyadhesive adhesive tube material, it is characterized in that, feed components is composed as follows according to weight part:
Chlorinated polyethylene rubber 50-60 part, terpolymer EP rubber 20-30 part, biological ceramics 3-5 part, sulphur 3-5 part, zinc methacrylate 1-2 part, plasticizer DOP 0.6-0.8 part, carbon black 2-3 part, dibutyl tin laurate 1-1.2 part, anti-aging agent RD 1-2 part.
2. the corrosion resistant environment-friendlyadhesive adhesive tube material of one according to claim 1, is characterized in that, the polymerization degree of described chlorinated polyethylene rubber is 2300-2500.
3. the corrosion resistant environment-friendlyadhesive adhesive tube material of one according to claim 1, is characterized in that, described chlorinated polyethylene rubber is paracril and polyvinyl chloride is proportionally 7:3 mixing.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201310636095.1A CN104672548A (en) | 2013-12-03 | 2013-12-03 | Corrosion resistant environment-friendly rubber tube material |
Applications Claiming Priority (1)
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CN201310636095.1A CN104672548A (en) | 2013-12-03 | 2013-12-03 | Corrosion resistant environment-friendly rubber tube material |
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CN104672548A true CN104672548A (en) | 2015-06-03 |
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Family Applications (1)
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CN201310636095.1A Pending CN104672548A (en) | 2013-12-03 | 2013-12-03 | Corrosion resistant environment-friendly rubber tube material |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109691702A (en) * | 2019-01-24 | 2019-04-30 | 赞冰(上海)实业有限公司 | A kind of portable wearable air-conditioning device |
CN111356585A (en) * | 2017-11-17 | 2020-06-30 | 康蒂泰克美国公司 | CPE-based welded hose |
CN112268145A (en) * | 2020-10-28 | 2021-01-26 | 河北泽邦塑胶科技有限公司 | Shock insulation rubber hose and preparation method thereof |
-
2013
- 2013-12-03 CN CN201310636095.1A patent/CN104672548A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111356585A (en) * | 2017-11-17 | 2020-06-30 | 康蒂泰克美国公司 | CPE-based welded hose |
CN109691702A (en) * | 2019-01-24 | 2019-04-30 | 赞冰(上海)实业有限公司 | A kind of portable wearable air-conditioning device |
CN112268145A (en) * | 2020-10-28 | 2021-01-26 | 河北泽邦塑胶科技有限公司 | Shock insulation rubber hose and preparation method thereof |
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PB01 | Publication | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150603 |