The method of semicoke formula continuous seepage dithiocarbonic anhydride and system thereof and special equipment
Technical field
The invention belongs to carbon disulphide production technical field, specifically a kind of production method of dithiocarbonic anhydride and a kind of method of system and special equipment, particularly semicoke formula continuous seepage dithiocarbonic anhydride thereof and system thereof and special equipment.
Background technology
The method of current production dithiocarbonic anhydride mainly contains charcoal sulfur method, semicoke formula batch production method, and natural gas act.
Charcoal sulfur method fires wooden carbon because using timber in a large number, and destroy the forest reserves, country eliminates with explicit order.
Natural gas act because of one-time investment large, production cost is high, by reasons such as natural air-air sources, only has minority area to have ready conditions use at present.
Semicoke formula batch production method, it is a very ripe carbon disulphide production technology, raw material resources enriches, production cost is low, good product quality, but be batch production, cause successionally to add sulphur in every ten days concentrated scarfing cinder processes once, because of empty stove and the monthly interval stopping production 3-4 days that heats up, add energy consumption, reduce output, it is open operation in the process of slagging tap, the warm sludge cleared directly is deposited on slag notch, transport after watering water cooling, containing the curing sulphur do not reacted completely and sulphur in slag, the obnoxious flavoures such as a large amount of dithiocarbonic anhydride and thiocyanogen are produced after contacting with water, and exhaust gas dust, because open operation causes a large amount of obnoxious flavour uncontrollable discharge, serious pollutes environment, do not meet environmental requirement.Slag is that naked light is slagged tap, and open stacking, to equipment, fire-fighting, personnel safety causes great hidden danger.In tapping process, labor strength is large, directly contacts high temperature furnace slag and obnoxious flavour, is easy to damage operator.
CN204039064U discloses a kind of automatic slag removal double-enclosure continuous seepage dithiocarbonic anhydride Reaktionsofen, by the residue outlet on furnace bottom sidewall, the deslagging device that residue outlet gate valve and transmitting device are formed is slagged tap, the problem such as obnoxious flavour uncontrollable discharge in the unresolved process about slag and operating process.
CN203998966U discloses a kind of internal heat type continuous semicoke method dithiocarbonic anhydride Reaktionsofen, slag notch is provided with at bottom of furnace body, spiral tapping machine is not fixed below slag notch, screw slag tap mouth connects sealed cistern, sealed cistern is entered from screw machine breeze out, to prevent carbon disulfide gas from overflowing, but this technical scheme also fails to solve the problem that leaks of furnace gas in operating process, particularly fixes spiral and cannot realize slagging tap operation in external heat semicoke continuous seepage.
The all attached Reaktionsofen of deslagging device of above-mentioned Reaktionsofen, need from newly-built body of heater and affiliated facility, and existing facility can not be completely supporting, can cause the significantly raising of production unit cost thus,
" dithiocarbonic anhydride industry access condition " regulation that Ministry of Industry and Information of country implemented on May 1st, 2013, to eliminate seriously polluted, the charcoal process carbon disulphide production device that technique falls behind, eliminating in two years take coke as the interval coke method carbon disulphide production device of raw material, carbon disulphide production device must adopt serialization vanguard technology and equipment, support carbon disulphide production novel process simultaneously, the research and development of new equipment, encourage dithiocarbonic anhydride heat energy and the development and application of tail gas comprehensive utilization modern technique, carry out Evaluation on Energy Saving and assessment for cleaner production, implement prevention and cure of occupational disease.
Therefore, one easy and conveniently can carry out scarfing cinder by machinery quickly, and need not stopped reaction furnaceman do during scarfing cinder, the method for the semicoke formula continuous seepage dithiocarbonic anhydride that particularly can effectively prevent furnace gas in tapping process from leaking and system thereof and special equipment just arise at the historic moment.
Summary of the invention
The object of this invention is to provide one and easy and conveniently can carry out scarfing cinder by mechanism quickly, and need not stopped reaction furnaceman do during scarfing cinder, a kind of method of the method for the production dithiocarbonic anhydride that can effectively prevent furnace gas in tapping process from leaking and system and special equipment, particularly semicoke formula continuous seepage dithiocarbonic anhydride and system thereof and special equipment.
The present invention is for solving the problems of the technologies described above, the technical solution used in the present invention is: the Reaktionsofen (1) of more than at least two comprising cluster arrangement, tail gas clean-up recovery system (3) and mobile platform, mobile platform at least comprises platform B(262), and platform B(262) be provided with road wheel.
Described Reaktionsofen at least comprises body of heater (103), furnace bottom (104), charging opening (102), discharge port (101) and slag notch (121).
Its improvement is: described mobile platform is provided with slag cleaning device (2), this slag cleaning device (2) comprises one can penetrate furnace bottom (104) transfer lime (212) from the slag notch of Reaktionsofen (1) (121), one section, this transfer lime (212) front portion is for top is in open channel-shaped, conveying auger (211) is provided with in transfer lime (212), described transfer lime (212) is provided with transfer lime driving mechanism, this transfer lime driving mechanism comprises drive screw A(213) and nut A(217), nut A(217) be connected with transfer lime (212), drive screw A(213) be provided with screw driver A(219), screw driver A(219) be the one in wind or motor drive mechanism.
Conveying auger (211) is provided with conveying auger driving mechanism, this conveying auger driving mechanism comprises drive-motor (220), main driving gear (215) and follower gear (218), and main driving gear (215) is a spline axis body and is meshed with follower gear (218).
Described transfer lime (212) below is provided with guiding support roller group, and this guiding support roller group is multiple rollers (214) composition arranged side by side; Described roller (214) connects preferably by a support, and support is provided with buffer spring.
Described mobile platform is provided with slag charge case (244), this slag charge case (244) comprises casing, casing is provided with opening for feed (241) and discharge port (242), and be equipped with flashboard in the passage of opening for feed (241) and discharge port (242), i.e. flashboard B(240) and flashboard C(243), the below of described transfer lime (212) is provided with slag-drip opening (216), and this slag-drip opening (216) can connect with the opening for feed of slag charge case (244) (241) in the advancing of transfer lime (212).
Above-mentioned slag cleaning device is also provided with seal bootr (232), this seal bootr (232) is the volume of a box-shaped, volume is wrapped up wherein to the trip segment of major general's transfer lime (212) slag-drip opening (216) and the opening for feed (241) of slag charge case (244), seal bootr (232) is provided with the venting port (233) that can connect with tail gas clean-up recovery system (3), flashboard is provided with in the passage of venting port (233), i.e. flashboard A(234), the leading section of transfer lime (212) passes from described volume, and the exit that transfer lime (212) passes from volume is provided with docking port A(231).
The Reaktionsofen of above-mentioned cluster arrangement, slide gate is provided with in passage between described slag notch (121) and furnace bottom (104), be preferably the panel turnover sluice gate A(112 of butterfly), at this panel turnover sluice gate A(112) side in the passage at place is provided with recessed flashboard room A(113), described panel turnover sluice gate A(112) bearing pin be arranged in panel turnover sluice gate A(112) side and be arranged at flashboard room A(113), described panel turnover sluice gate A(112) flashboard room A(113 can be taken in completely when being in opened condition) in.
Described slag notch (121) is provided with docking port B(122), this docking port B(122) be configured to the channel-shaped of annular with the passage of slag notch (121), closed weighting material can be set as rock wool, docking port B(122 in the groove of annular) place is provided with the closing cap A(123 be connected through the hinge).
Move between the Reaktionsofen arranged at cluster by above-mentioned mobile platform, slag in each Reaktionsofen is cleared up: before mobile platform being moved to need the Reaktionsofen of scarfing cinder, venting port (233) on seal bootr (232) is docked with tail gas clean-up recovery system (3) and opens flashboard A(234), open flashboard B(240), close flashboard C(243), transfer lime (212) is aimed at the slag notch (121) of Reaktionsofen and opens closing cap A(123), close slide gate or panel turnover sluice gate A(112), transfer lime (212) is inserted slag notch (121), open slide gate or panel turnover sluice gate A(112 afterwards again), start conveying auger (211) and continue transfer lime (212) to insert slag notch (121) until Reaktionsofen furnace bottom (104), by conveying auger (211) slag of furnace bottom cleared up and be transported in slag charge case (244), clean out then inverted running and extract transfer lime (212) out, close flashboard B(240) simultaneously, finally close docking port B(122) the closing cap A(123 at place), namely cleaning is completed.
Afterwards mobile platform is moved to slag storage place to unload.
Above-mentioned slag storage place is preferably puts out grit chamber, this puts out grit chamber is a volume, except being provided with air outlet and tail gas clean-up recovery system (3) UNICOM, it is an enclosed space, the slag cleaned out from Reaktionsofen is inserted and is put out in grit chamber and be hedged off from the outer world, under anaerobic state, slag is extinguished, can by tail gas by tail gas recycle and claus oven system converting become dithiocarbonic anhydride crude product and sulphur, after slag after extinguishing screens, add in Reaktionsofen again after the carbon of not fully reaction is reclaimed and recycle, the discharge of waste residue can be reduced further.
As improvement, above-mentioned transfer lime (212) be preferably at least two sections of formations, the bottom of two sections of adjacent transfer limes (212) is hinged by hinge (222), the junction of two sections of transfer limes is inclined-plane and makes junction have V-shaped breach, simultaneously, described conveying auger (211) is also formed by having at least two sections mutually, connected by universal joint (223) between two sections of adjacent conveying augers, the Reaktionsofen of different structure can be adapted to, particularly can realize multi-angle transmission, as the Reaktionsofen not on same straight line also can scarfing cinder easily to slag notch and furnace bottom.
Further again, the platform B(262 of described mobile platform) top is preferably provided with platform A(261), platform A(261) with platform B(262) between up and down overlapping and be provided with at least one group of hoisting appliance (250), be in the platform A(261 on top by this hoisting appliance (250) adjustable device) obliquity, enter the propelling angle of transfer lime (212) in face adjustment slag cleaning device (2).
Above-mentioned hoisting appliance comprises drive screw B(251) and nut B(252), drive screw B(251) on be preferably provided with worm drive mechanism (253), worm drive mechanism (253) by wind (254) or motor drive mechanism one drive.
Again further, above-mentioned mobile platform is preferably provided with platform C(264), platform C(264) be provided with the track A(263 that advances), the road wheel of described platform B is and the track A(263 that advances) corresponding rail wheel, meanwhile, described platform C(264) be provided with rail wheel and the track B(265 that advances accordingly).
Further again, above-mentioned transfer lime (212) is preferably provided with tail rod (221).
Further again, above-mentioned slag charge case (244) is preferably provided with roller and links with transfer lime (212), when transfer lime (212) can be kept to advance, transfer lime (212) below slag-drip opening (216) connects with the opening for feed (241) of slag charge case (244) all the time, reduces furnace gas or slag leakage.
As improvement, the furnace bottom (104) of above-mentioned Reaktionsofen preferably in a flute profile, the lower cross section of groove in be below arc U-shaped, both sides, top are herringbone inclined-plane or cambered surface.
Further again, the passage of above-mentioned Reaktionsofen slag notch is preferably made up of more than one nodular component, namely the passage of slag notch is made up of slag tap panel turnover sluice gate component (110) and slag notch interface component (120), is connected between component with component by ring flange.
Further again, the panel turnover sluice gate B(142 of butterfly is preferably provided with) in the passage of above-mentioned charging opening (102), at this panel turnover sluice gate B(142) side in the passage at place is provided with recessed flashboard room B(141), described panel turnover sluice gate B(142) bearing pin be arranged in panel turnover sluice gate B(142) side and be arranged at flashboard room B(141), described panel turnover sluice gate B(142) flashboard room B(141 can be taken in completely when being in opened condition) in, charging opening (102) is also provided with the closing cap B(152 be connected through the hinge).
Further again, the passage of above-mentioned charging opening is preferably made up of more than one nodular component, and namely the passage of charging opening is made up of charging opening panel turnover sluice gate component (140) and charging opening closing cap component (150), is connected between component with component by ring flange.
Compared with prior art, the present invention is reinforced and need not blowing out when slagging tap, and therefore can realize working continuously, greatly enhance productivity, particularly can effectively prevent the furnace gas in tapping process from leaking, environmental protection more, the security of operation also improves greatly
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Accompanying drawing explanation
Fig. 1 is structural representation of the present invention.
Fig. 2 is the structural representation of the embodiment of the present invention 1 slag cleaning device.
Fig. 3 is the structural representation of Fig. 2 A-A section.
Fig. 4 is the structural representation of the embodiment of the present invention 1 roller.
Fig. 5 is the structural representation of the embodiment of the present invention 2 slag cleaning device.
Fig. 6 is the structural representation of the embodiment of the present invention 3 slag cleaning device.
Fig. 7 is the structural representation of the embodiment of the present invention 4 Reaktionsofen.
Fig. 8 is the structural representation of Fig. 7 A-A section.
Fig. 9 is the structural representation of Fig. 7 B-B section.
Figure 10 is the structural representation of the embodiment of the present invention 5 Reaktionsofen.
Figure 11 is the structural representation of the embodiment of the present invention 6 Reaktionsofen.
Shown in figure: 1 is Reaktionsofen, 101 is discharge port, 102 is charging opening, 103 is body of heater, 104 is furnace bottom, 110 is panel turnover sluice gate component of slagging tap, 111 are, 112 is panel turnover sluice gate A, 113 is flashboard room A, 114 is panel turnover sluice gate A handle, 120 is slag notch interface component, 121 is slag notch, 122 is docking port B, 123 is closing cap A, 124 is fixing snap close, 131 is slag notch furnace gas recovery tube, 140 is charging opening panel turnover sluice gate component, 141 is flashboard room B, 142 is panel turnover sluice gate B, 150 is charging opening closing cap component, 151 is gasket A, 152 is closing cap B, 2 is slag cleaning device, 211 is conveying auger, 212 is transfer lime, 213 is drive screw A, 214 is roller, 215 is main driving gear, 216 is slag-drip opening, 217 is nut A, 218 is follower gear, 219 is screw driver A, 220 is drive-motor, 221 is tail rod, 222 is hinge, 223 is universal joint, 231 is docking port A, 232 is seal bootr, 233 is venting port, 234 is flashboard A, 240 is flashboard B, 241 is opening for feed, 242 is discharge port, 243 is flashboard C, 244 is slag charge case, 250 is hoisting appliance, 251 is drive screw B, 252 is nut B, 253 is worm drive mechanism, 254 is wind, 260 are, 261 is platform A, 262 platform B are, 263 is the track A that advances, 264 is platform C, 265 is the track B that advances.
Embodiment
embodiment 1:with reference to Fig. 1 ~ Fig. 4, for the structural representation of the embodiment of the present invention 1, comprise the Reaktionsofen (1) of more than at least two of cluster arrangement, tail gas clean-up recovery system (3) and mobile platform, mobile platform comprises platform B(262), and platform B(262) be provided with road wheel, platform B(262) top is provided with platform A(261), platform A(261) with platform B(262) between up and down overlapping and be respectively provided with one group of hoisting appliance (250) at both ends, be in the platform A(261 on top by this hoisting appliance (250) adjustable device) obliquity, enter the propelling angle of the transfer lime (212) in face adjustment slag cleaning device (2).
Described Reaktionsofen comprises body of heater (103), furnace bottom (104), charging opening (102), discharge port (101) and slag notch (121), the panel turnover sluice gate A(112 of butterfly is provided with) in passage between described slag notch (121) and furnace bottom (104), at this panel turnover sluice gate A(112) side in the passage at place is provided with recessed flashboard room A(113), described panel turnover sluice gate A(112) bearing pin be arranged in panel turnover sluice gate A(112) side and be arranged at flashboard room A(113), described panel turnover sluice gate A(112) flashboard room A(113 can be taken in completely when being in opened condition) in.Certainly, the panel turnover sluice gate A(112 in the passage between above-mentioned slag notch (121) and furnace bottom (104)) also can be replaced by easy slide gate.
Described slag notch (121) is provided with docking port B(122), this docking port B(122) be configured to the channel-shaped of annular with the passage of slag notch (121), in the groove of annular, closed weighting material can be set as rock wool, docking port B(122) place is provided with the closing cap A(123 be connected through the hinge), closing cap A(123) on fixing snap close (124) is set.
Described mobile platform is provided with slag cleaning device (2), this slag cleaning device (2) comprises one can penetrate furnace bottom (104) transfer lime (212) from the slag notch of Reaktionsofen (1) (121), one section, this transfer lime (212) front portion is for top is in open channel-shaped, conveying auger (211) is provided with in transfer lime (212), described transfer lime (212) is provided with transfer lime driving mechanism, this transfer lime driving mechanism comprises drive screw A(213) and nut A(217), nut A(217) be connected with transfer lime (212), drive screw A(213) be provided with screw driver A(219), screw driver A(219) be wind, certainly also can be motor drive mechanism, transfer lime (212) is also provided with tail rod (221), to ensure the unlikely skew of stroke of transfer lime (212).
Conveying auger (211) is provided with conveying auger driving mechanism, this conveying auger driving mechanism comprises drive-motor (220), main driving gear (215) and follower gear (218), main driving gear (215) is a spline axis body and is meshed with follower gear (218), when transfer lime (212) is pushed into, the follower gear (218) of conveying auger (211) is in engagement with main driving gear (215) all the time.
Described transfer lime (212) below is provided with guiding support roller group, and this guiding support roller group is two rows multiple rollers (214) compositions arranged side by side, and described roller (214) is connected by a support, and support is provided with buffer spring.
Described mobile platform is provided with slag charge case (244), this slag charge case (244) comprises casing, casing is provided with opening for feed (241) and discharge port (242), and be equipped with flashboard in the passage of opening for feed (241) and discharge port (242), i.e. flashboard B(240) and flashboard C(243), the below of described transfer lime (212) is provided with slag-drip opening (216), and this slag-drip opening (216) can connect with the opening for feed of slag charge case (244) (241) in the advancing of transfer lime (212).
Described slag cleaning device is provided with seal bootr (232), this seal bootr (232) is the volume of a box-shaped, volume is wrapped up wherein to the trip segment of major general's transfer lime (212) slag-drip opening (216) and the opening for feed (241) of slag charge case (244), seal bootr (232) is provided with the venting port (233) that can connect with tail gas clean-up recovery system (3), flashboard is provided with in the passage of venting port (233), i.e. flashboard A(234), the leading section of transfer lime (212) passes from described volume, and the exit that transfer lime (212) passes from volume is provided with docking port A(231).
Move between the Reaktionsofen arranged at cluster by above-mentioned mobile platform, slag in each Reaktionsofen is cleared up: before mobile platform being moved to need the Reaktionsofen of scarfing cinder, venting port (233) on seal bootr (232) is docked with tail gas clean-up recovery system (3) and opens flashboard A(234), open flashboard B(240), close flashboard C(243).
Transfer lime (212) is aimed at the slag notch (121) of Reaktionsofen and is opened closing cap A(123), close panel turnover sluice gate A(112), transfer lime (212) is inserted slag notch (121), open panel turnover sluice gate A(112 more afterwards), start conveying auger (211) and continue transfer lime (212) to insert slag notch (121) until Reaktionsofen furnace bottom (104), by conveying auger (211) slag of furnace bottom cleared up and be transported in slag charge case (244), clean out then inverted running and extract transfer lime (212) out, close flashboard B(240) simultaneously, finally close docking port B(122) the closing cap A(123 at place), namely cleaning is completed.
Afterwards mobile platform is moved to slag storage place to unload.
Above-mentioned slag storage place is preferably puts out grit chamber, this puts out grit chamber is a volume, except being provided with air outlet and tail gas clean-up recovery system (3) UNICOM, it is an enclosed space, the slag cleaned out from Reaktionsofen is inserted and is put out in grit chamber and be hedged off from the outer world, under anaerobic state, slag is extinguished, can by tail gas by tail gas recycle and claus oven system converting become dithiocarbonic anhydride crude product and sulphur, after slag after extinguishing screens, add in Reaktionsofen again after the carbon of not fully reaction is reclaimed and recycle, the discharge of waste residue can be reduced further.
embodiment 2:with reference to Fig. 5, for the structural representation of the embodiment of the present invention 2, compared with embodiment 1, the difference of the present embodiment is: described transfer lime (212) be two sections of formations, the bottom of two sections of adjacent transfer limes (212) is hinged by hinge (222), the junction of two sections of transfer limes is inclined-plane and makes junction have V-shaped breach, simultaneously, described conveying auger (211) is also formed by having at least two sections mutually, connected by universal joint (223) between two sections of adjacent conveying augers, the Reaktionsofen of different structure can be adapted to, particularly can realize multi-angle transmission, as to slag notch and furnace bottom, the Reaktionsofen not on same straight line also can scarfing cinder easily.
Certainly, transfer lime (212) and conveying auger (211) also can be formed by more than two sections.
embodiment 3:with reference to Fig. 6, for the structural representation of the embodiment of the present invention 3, compared with embodiment 1 or 2, the difference of the present embodiment is: described hoisting appliance comprises drive screw B(251) and nut B(252), drive screw B(251) on be preferably provided with worm drive mechanism (253), worm drive mechanism (253) is driven by wind (254), certainly also can drive by motor drive mechanism.
In the present embodiment, described slag charge case (244) is provided with roller and links with transfer lime (212), when transfer lime (212) can be kept to advance, transfer lime (212) below slag-drip opening (216) connects with the opening for feed (241) of slag charge case (244) all the time, reduces furnace gas or slag leakage further.
embodiment 4:with reference to Fig. 7 ~ Fig. 9, for the structural representation of the embodiment of the present invention 4 Reaktionsofen, compared with embodiment before, the difference of the present embodiment is: the furnace bottom (104) of above-mentioned Reaktionsofen is in a flute profile, the lower cross section of groove in be below arc U-shaped, both sides, top are herringbone inclined-plane or cambered surface.
The passage of described Reaktionsofen slag notch is made up of two nodular components, namely the passage of slag notch is made up of slag tap panel turnover sluice gate component (110) and slag notch interface component (120), be connected by ring flange between component with component, can conveniently safeguard.
Also the panel turnover sluice gate B(142 of butterfly is provided with) in the passage of described charging opening (102), at this panel turnover sluice gate B(142) side in the passage at place is provided with recessed flashboard room B(141), described panel turnover sluice gate B(142) bearing pin be arranged in panel turnover sluice gate B(142) side and be arranged at flashboard room B(141), described panel turnover sluice gate B(142) flashboard room B(141 can be taken in completely when being in opened condition) in, charging opening (102) is also provided with the closing cap B(152 be connected through the hinge).
And the passage of described charging opening is also made up of two nodular components, namely the passage of charging opening is made up of charging opening panel turnover sluice gate component (140) and charging opening closing cap component (150), is connected between component with component by ring flange.
embodiment 4:with reference to Figure 10, be the structural representation of the embodiment of the present invention 5 Reaktionsofen, compared with embodiment before, the difference of the present embodiment is: the passage of furnace bottom (104) slag notch of above-mentioned Reaktionsofen is from the inside to the outside in upwards skewed.
embodiment 6:with reference to Figure 11, be the structural representation of the embodiment of the present invention 6 Reaktionsofen, compared with embodiment before, the difference of the present embodiment is: the furnace bottom (104) of above-mentioned Reaktionsofen is level, and the passage of slag notch is from the inside to the outside in upwards skewed.
Below be only the preferred embodiment of the present invention, it should be pointed out that above-mentioned preferred implementation should not be considered as limitation of the present invention, protection scope of the present invention should be as the criterion with claim limited range.For those skilled in the art, without departing from the spirit and scope of the present invention, some improvements and modifications can also be made and also should be considered as protection scope of the present invention.