CN104667874A - Preparation method of hydroxyapatite modified compound heavy metal adsorbent with eucalyptus structure - Google Patents
Preparation method of hydroxyapatite modified compound heavy metal adsorbent with eucalyptus structure Download PDFInfo
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- CN104667874A CN104667874A CN201510086083.5A CN201510086083A CN104667874A CN 104667874 A CN104667874 A CN 104667874A CN 201510086083 A CN201510086083 A CN 201510086083A CN 104667874 A CN104667874 A CN 104667874A
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- heavy metal
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- eucalyptus
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- 229910001385 heavy metal Inorganic materials 0.000 title claims abstract description 39
- 229910052588 hydroxylapatite Inorganic materials 0.000 title claims abstract description 26
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 244000166124 Eucalyptus globulus Species 0.000 title claims abstract 9
- 239000003463 adsorbent Substances 0.000 title abstract description 11
- 150000001875 compounds Chemical class 0.000 title abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 16
- 238000011065 in-situ storage Methods 0.000 claims abstract description 6
- 239000002250 absorbent Substances 0.000 claims description 21
- 230000002745 absorbent Effects 0.000 claims description 21
- 239000002131 composite material Substances 0.000 claims description 19
- 230000029087 digestion Effects 0.000 claims description 10
- 229920006395 saturated elastomer Polymers 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 229910021642 ultra pure water Inorganic materials 0.000 claims description 6
- 239000012498 ultrapure water Substances 0.000 claims description 6
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000007654 immersion Methods 0.000 claims description 3
- 239000004567 concrete Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 17
- 239000000463 material Substances 0.000 abstract description 11
- 238000001179 sorption measurement Methods 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 9
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 8
- 238000005516 engineering process Methods 0.000 abstract description 7
- 239000002023 wood Substances 0.000 abstract description 7
- 230000015572 biosynthetic process Effects 0.000 abstract description 5
- 239000003607 modifier Substances 0.000 abstract description 4
- 238000003786 synthesis reaction Methods 0.000 abstract description 4
- 241000196324 Embryophyta Species 0.000 abstract description 3
- 229910052793 cadmium Inorganic materials 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 238000000746 purification Methods 0.000 abstract description 2
- 238000003723 Smelting Methods 0.000 abstract 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical class [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 abstract 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 abstract 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 abstract 1
- 235000019838 diammonium phosphate Nutrition 0.000 abstract 1
- 238000001308 synthesis method Methods 0.000 abstract 1
- 239000002351 wastewater Substances 0.000 abstract 1
- 241000219927 Eucalyptus Species 0.000 description 28
- 239000000243 solution Substances 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000010355 oscillation Effects 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- WLZRMCYVCSSEQC-UHFFFAOYSA-N cadmium(2+) Chemical compound [Cd+2] WLZRMCYVCSSEQC-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000006378 damage Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000000705 flame atomic absorption spectrometry Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000000386 microscopy Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- ZAJAQTYSTDTMCU-UHFFFAOYSA-N 3-aminobenzenesulfonic acid Chemical compound NC1=CC=CC(S(O)(=O)=O)=C1 ZAJAQTYSTDTMCU-UHFFFAOYSA-N 0.000 description 1
- 241000167854 Bourreria succulenta Species 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 210000003484 anatomy Anatomy 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003462 bioceramic Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 210000005056 cell body Anatomy 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000009388 chemical precipitation Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002905 metal composite material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 231100000701 toxic element Toxicity 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
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CN201510086083.5A CN104667874B (en) | 2015-02-21 | 2015-02-21 | The preparation method of hydroxyapatite modified Eucalyptus structure composite heavy metal absorbent |
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CN201510086083.5A CN104667874B (en) | 2015-02-21 | 2015-02-21 | The preparation method of hydroxyapatite modified Eucalyptus structure composite heavy metal absorbent |
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CN104667874A true CN104667874A (en) | 2015-06-03 |
CN104667874B CN104667874B (en) | 2017-06-30 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106111067A (en) * | 2016-07-27 | 2016-11-16 | 中国科学院新疆理化技术研究所 | A kind of preparation method and application of silane coupler modified magnetic halloysite material |
CN106268634A (en) * | 2016-08-09 | 2017-01-04 | 江苏陆博环保科技有限公司 | Preparation method for the inorganic compound particles of effluent containing heavy metal ions advanced treating |
CN108636339A (en) * | 2018-04-26 | 2018-10-12 | 桂林理工大学 | The preparation method of hydroxyapatite modified moso bamboo structure composite heavy metal absorbent |
CN111229156A (en) * | 2020-01-20 | 2020-06-05 | 齐鲁工业大学 | Preparation and application of hydroxyapatite modified mesoporous silica adsorption material |
CN111495315A (en) * | 2020-04-23 | 2020-08-07 | 齐鲁工业大学 | Pb in water body2+Application and preparation method of adsorbing material |
WO2021007986A1 (en) * | 2019-07-12 | 2021-01-21 | 华南理工大学 | Carboxylated banyan aerial root fiber adsorbent and preparation method therefor and application thereof |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6270212A (en) * | 1985-09-23 | 1987-03-31 | Toa Nenryo Kogyo Kk | Calcium phosphate based hydroxyapatite and production thereof |
EP0342932A1 (en) * | 1988-05-16 | 1989-11-23 | MITSUI TOATSU CHEMICALS, Inc. | Solid support and column for liquid chromatography |
CN102258976A (en) * | 2011-05-20 | 2011-11-30 | 桂林理工大学 | Preparation method of eucalyptus biomorphic Fe2O3/Fe3O4 composite heavy metal adsorbent |
CN102380350A (en) * | 2011-10-24 | 2012-03-21 | 上海海洋大学 | Method for removing hydroxyapatite modified eggshell adsorbent material and recycling phosphate from wastewater |
CN102895957A (en) * | 2012-11-11 | 2013-01-30 | 桂林理工大学 | Preparation method of moso bamboo biomorphic Fe2O3/Fe3O4 compound heavy metal absorbent |
CN103861567A (en) * | 2014-03-21 | 2014-06-18 | 桂林理工大学 | Preparation method of hydroxyapatite/bagasse active carbon |
-
2015
- 2015-02-21 CN CN201510086083.5A patent/CN104667874B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6270212A (en) * | 1985-09-23 | 1987-03-31 | Toa Nenryo Kogyo Kk | Calcium phosphate based hydroxyapatite and production thereof |
EP0342932A1 (en) * | 1988-05-16 | 1989-11-23 | MITSUI TOATSU CHEMICALS, Inc. | Solid support and column for liquid chromatography |
CN102258976A (en) * | 2011-05-20 | 2011-11-30 | 桂林理工大学 | Preparation method of eucalyptus biomorphic Fe2O3/Fe3O4 composite heavy metal adsorbent |
CN102380350A (en) * | 2011-10-24 | 2012-03-21 | 上海海洋大学 | Method for removing hydroxyapatite modified eggshell adsorbent material and recycling phosphate from wastewater |
CN102895957A (en) * | 2012-11-11 | 2013-01-30 | 桂林理工大学 | Preparation method of moso bamboo biomorphic Fe2O3/Fe3O4 compound heavy metal absorbent |
CN103861567A (en) * | 2014-03-21 | 2014-06-18 | 桂林理工大学 | Preparation method of hydroxyapatite/bagasse active carbon |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106111067A (en) * | 2016-07-27 | 2016-11-16 | 中国科学院新疆理化技术研究所 | A kind of preparation method and application of silane coupler modified magnetic halloysite material |
CN106111067B (en) * | 2016-07-27 | 2018-10-26 | 中国科学院新疆理化技术研究所 | A kind of preparation method and application of silane coupler modified magnetic halloysite material |
CN106268634A (en) * | 2016-08-09 | 2017-01-04 | 江苏陆博环保科技有限公司 | Preparation method for the inorganic compound particles of effluent containing heavy metal ions advanced treating |
CN108636339A (en) * | 2018-04-26 | 2018-10-12 | 桂林理工大学 | The preparation method of hydroxyapatite modified moso bamboo structure composite heavy metal absorbent |
CN108636339B (en) * | 2018-04-26 | 2021-05-25 | 桂林理工大学 | Preparation method of hydroxyapatite modified moso bamboo structure composite heavy metal adsorbent |
WO2021007986A1 (en) * | 2019-07-12 | 2021-01-21 | 华南理工大学 | Carboxylated banyan aerial root fiber adsorbent and preparation method therefor and application thereof |
CN111229156A (en) * | 2020-01-20 | 2020-06-05 | 齐鲁工业大学 | Preparation and application of hydroxyapatite modified mesoporous silica adsorption material |
CN111229156B (en) * | 2020-01-20 | 2021-07-13 | 齐鲁工业大学 | Preparation and application of hydroxyapatite modified mesoporous silica adsorption material |
CN111495315A (en) * | 2020-04-23 | 2020-08-07 | 齐鲁工业大学 | Pb in water body2+Application and preparation method of adsorbing material |
CN111495315B (en) * | 2020-04-23 | 2021-05-25 | 齐鲁工业大学 | Pb in water body2+Application and preparation method of adsorbing material |
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Publication number | Publication date |
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CN104667874B (en) | 2017-06-30 |
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Application publication date: 20150603 Assignee: Guangxi Borui Engineering Management Consulting Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980044225 Denomination of invention: Preparation method of hydroxyapatite modified eucalyptus wood structure composite heavy metal adsorbent Granted publication date: 20170630 License type: Common License Record date: 20231023 Application publication date: 20150603 Assignee: Guangxi Borui Engineering Management Consulting Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980044176 Denomination of invention: Preparation method of hydroxyapatite modified eucalyptus wood structure composite heavy metal adsorbent Granted publication date: 20170630 License type: Common License Record date: 20231024 |
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EE01 | Entry into force of recordation of patent licensing contract | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20150603 Assignee: Guangxi Huayuan Environmental Protection Technology Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980045403 Denomination of invention: Preparation method of hydroxyapatite modified eucalyptus wood structure composite heavy metal adsorbent Granted publication date: 20170630 License type: Common License Record date: 20231103 |
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EE01 | Entry into force of recordation of patent licensing contract |