CN104645934A - Active carbon industrial wastewater deodorant - Google Patents
Active carbon industrial wastewater deodorant Download PDFInfo
- Publication number
- CN104645934A CN104645934A CN201310578511.7A CN201310578511A CN104645934A CN 104645934 A CN104645934 A CN 104645934A CN 201310578511 A CN201310578511 A CN 201310578511A CN 104645934 A CN104645934 A CN 104645934A
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- CN
- China
- Prior art keywords
- parts
- active carbon
- deodorant
- oxide
- industrial wastewater
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
- B01J20/0281—Sulfates of compounds other than those provided for in B01J20/045
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/041—Oxides or hydroxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
- B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/101—Sulfur compounds
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention discloses an active carbon industrial wastewater deodorant, which is composed of active carbon, calcium oxide, magnesium oxide, alumina, copper oxide, ferrous sulphate, benzoic acid and deionized water. The deodorant can uses an active carbon adsorption technology, the active carbon can react with offensive odor substances in waste water, stunk materials in waste water can be removed, atmosphere pollution can be prevented, raw materials are easy to obtain, and the production and usage cost is low.
Description
Technical field
The present invention relates to a kind of deodorant, particularly relate to a kind of active carbon industrial wastewater deodorant, belong to technical field of chemistry and chemical engineering.
Background technology
Deodorizing promotes human health, the pith purifying and beautify the environment.
Stink, foul smell are from every aspect, and they all directly affect the health of the mankind.Smelly body (foul smell, smelly liquid) has two large classes and sulphur (S) based compound class and nitrogen (N) based compound class.S based compound class has hydrogen sulfide, methyl mercaptan and ethyl mercaptan etc., modal hydrogen sulfide gas (H
2s) stench, has severe toxicity, and the perception amount of people is 0.00037mg/m
3, containing 0.1%H
2the gas of S, can make human body poisoning, and the hydrogen sulfide that concentration is higher can make people lethal at short notice.Some sulfur-containing compound also can overflow and stink of, as ammonium sulfide, and dialkyl dithiophosphate, carbaminate and isothiocyanate etc.N based compound has ammonia and aminated compounds.The organs of vision of Ammonia intense stimulus people, make us suffocating, poisoning.
Absorbing and deodorizing be adopt that specific surface is large, the material with excellent adsorption capacity that pore volume is large to adsorb foul smell, common adsorbent has active carbon, NACF, all kinds of zeolite, some metal oxide and large pore macromolecular material etc.Specific surface exists
1900m
2active carbon adsorbable toluene 3.2g/g, more than the carbon tetrachloride 0.43g/g of more than g.Through the active carbon of plasma treatment, its adsorption capacity doubles.The zeolite carrying 0.5% (mass fraction) rare earth element can adsorb many organic solvent volatile matters.Metal oxide, particularly through the adsorbable various sulfurous gas of super fine zinc oxide and the liquid of airslide disintegrating mill pulverizing, as:
ZnO+H
2S+ZnS+H
2O
ZnO+C
2H
5SH=ZnS+C
2H
5OH
ZnO+C
2H
5SH=ZnS+C
2H
4+H
2O
After the copolymer adsorbed gas of making containing macropore by macromolecular material, expanding volume can be original volume tens times to hundred times.
In recent years, the deodorant that people develop makes one see with different eyes especially, is the atmospheric environment that protection people depend on for existence, for Ecological Stabilization is done one's bit, carries out the deodorant research of charcoal absorption emitting offensive odor gas.
Summary of the invention
The invention provides one and utilize active carbon adsorption technology, effective with waste water water body in produce stench material react, malodoring substance in removal waste water, prevents from polluting air, raw materials used being simple and easy to is sought, and produces and the lower active carbon industrial wastewater deodorant of use cost.
A kind of active carbon industrial wastewater deodorant, is made up of active carbon, calcium oxide, magnesia, aluminium oxide, cupric oxide, ferrous sulfate, benzoic acid and deionized water.
A kind of active carbon industrial wastewater deodorant, by mass parts, comprises following material:
Active carbon 30 ~ 70 parts, 20 ~ 30 parts, calcium oxide, 20 ~ 30 parts, magnesia, 5 ~ 15 parts, aluminium oxide, cupric oxide 3 ~ 8 parts, 40 ~ 80 parts, ferrous sulfate, 20 ~ 40 parts, benzoic acid, deionized water 80 ~ 100 parts.
A kind of active carbon industrial wastewater deodorant is obtained by following steps:
(1), after the method for the material machineries such as active carbon, calcium oxide, magnesia, aluminium oxide, cupric oxide being broken into powdery and fine granularity, add in proportion in container;
(2) add ferrous sulfate, benzoic acid and deionized water to cause it and dissolve remember deodorant of the present invention completely.
Deodorant of the present invention utilizes active carbon adsorption technology, effective with waste water water body in produce stench material react, malodoring substance in removal waste water; prevent from polluting air; raw materials used being simple and easy to is sought, produce and use cost lower, protect atmospheric environment to a certain extent.
Detailed description of the invention
Embodiment 1:
A kind of active carbon industrial wastewater deodorant, by mass parts, comprises following material:
Active carbon 30 parts, 20 parts, calcium oxide, 20 parts, magnesia, 6 parts, aluminium oxide, cupric oxide 3.5 parts, 40 parts, ferrous sulfate, 20 parts, benzoic acid, deionized water 80 parts.
This deodorant is obtained by following steps:
(1), after the method for the material machineries such as active carbon, calcium oxide, magnesia, aluminium oxide, cupric oxide being broken into powdery and fine granularity, add in proportion in container;
(2) add ferrous sulfate, benzoic acid and deionized water to cause it and dissolve remember deodorant of the present invention completely.
Deodorant of the present invention utilizes active carbon adsorption technology, effective with waste water water body in produce stench material react, prevent from polluting air, raw materials used being simple and easy to is sought, production and use cost lower, protect atmospheric environment to a certain extent.
Embodiment 2:
A kind of active carbon industrial wastewater deodorant, by mass parts, comprises following material:
Active carbon 40 parts, 24 parts, calcium oxide, 24 parts, magnesia, 7 parts, aluminium oxide, cupric oxide 4 parts, 50 parts, ferrous sulfate, 24 parts, benzoic acid, deionized water 88 parts.
This deodorant preparation method is with embodiment 1.
Deodorant of the present invention utilizes active carbon adsorption technology, effective with waste water water body in produce stench material react, malodoring substance in removal waste water.
Embodiment 3:
To the deodorant that hydrogen phosphide effectively purifies, by mass parts, comprise following material:
Active carbon 50 parts, 26 parts, calcium oxide, 26 parts, magnesia, 10 parts, aluminium oxide, cupric oxide 6 parts, 68 parts, ferrous sulfate, 30 parts, benzoic acid, deionized water 90 parts.
This deodorant preparation method is with embodiment 1.
Deodorant of the present invention utilizes active carbon adsorption technology, and malodoring substance in effective removal waste water, prevents from polluting air.
Deodorant of the present invention utilizes active carbon adsorption technology, effective with waste water water body in produce stench material react, malodoring substance in removal waste water; prevent from polluting air; raw materials used being simple and easy to is sought, produce and use cost lower, protect atmospheric environment to a certain extent.
Invention can be understood further by the invention process given above; above embodiment is only several specific embodiment of the present invention; but design concept of the present invention is not limited thereto; all changes utilizing this design the present invention to be carried out to unsubstantiality, all should belong to the behavior of invading scope.
Claims (4)
1. an active carbon industrial wastewater deodorant, is characterized in that, active carbon, calcium oxide, magnesia, aluminium oxide, cupric oxide, ferrous sulfate, benzoic acid and deionized water form.
2. active carbon industrial wastewater deodorant according to claim 1, it is characterized in that, by mass parts, comprise following material: active carbon 30 ~ 70 parts, 20 ~ 30 parts, calcium oxide, 20 ~ 30 parts, magnesia, 5 ~ 15 parts, aluminium oxide, cupric oxide 3 ~ 8 parts, 40 ~ 80 parts, ferrous sulfate, 20 ~ 40 parts, benzoic acid, deionized water 80 ~ 100 parts.
3. active carbon industrial wastewater deodorant according to claim 1, is characterized in that, by mass parts, comprises following material: active carbon 40 parts, 24 parts, calcium oxide, 24 parts, magnesia, 7 parts, aluminium oxide, cupric oxide 4 parts, 50 parts, ferrous sulfate, 24 parts, benzoic acid, deionized water 88 parts.
4. active carbon industrial wastewater deodorant according to claim 1, is characterized in that, by mass parts, comprises following material: active carbon 50 parts, 26 parts, calcium oxide, 26 parts, magnesia, 10 parts, aluminium oxide, cupric oxide 6 parts, 68 parts, ferrous sulfate, 30 parts, benzoic acid, deionized water 90 parts.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310578511.7A CN104645934A (en) | 2013-11-18 | 2013-11-18 | Active carbon industrial wastewater deodorant |
Applications Claiming Priority (1)
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CN201310578511.7A CN104645934A (en) | 2013-11-18 | 2013-11-18 | Active carbon industrial wastewater deodorant |
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CN104645934A true CN104645934A (en) | 2015-05-27 |
Family
ID=53237867
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CN201310578511.7A Pending CN104645934A (en) | 2013-11-18 | 2013-11-18 | Active carbon industrial wastewater deodorant |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107335333A (en) * | 2017-07-27 | 2017-11-10 | 宁国市南方耐磨材料有限公司 | A kind of high-end casting waste gas purification inorganic agent |
CN110280561A (en) * | 2019-07-15 | 2019-09-27 | 三峡大学 | A kind of application of city life garbage concentrates waste pit and its burying method |
CN115259921A (en) * | 2022-07-21 | 2022-11-01 | 安徽国祯环卫科技有限公司 | Combined composting process of saturated deodorant material and kitchen garbage |
-
2013
- 2013-11-18 CN CN201310578511.7A patent/CN104645934A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107335333A (en) * | 2017-07-27 | 2017-11-10 | 宁国市南方耐磨材料有限公司 | A kind of high-end casting waste gas purification inorganic agent |
CN110280561A (en) * | 2019-07-15 | 2019-09-27 | 三峡大学 | A kind of application of city life garbage concentrates waste pit and its burying method |
CN110280561B (en) * | 2019-07-15 | 2021-04-13 | 三峡大学 | Centralized landfill pit for urban domestic garbage and landfill method thereof |
CN115259921A (en) * | 2022-07-21 | 2022-11-01 | 安徽国祯环卫科技有限公司 | Combined composting process of saturated deodorant material and kitchen garbage |
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WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150527 |