CN104645934A - Active carbon industrial wastewater deodorant - Google Patents

Active carbon industrial wastewater deodorant Download PDF

Info

Publication number
CN104645934A
CN104645934A CN201310578511.7A CN201310578511A CN104645934A CN 104645934 A CN104645934 A CN 104645934A CN 201310578511 A CN201310578511 A CN 201310578511A CN 104645934 A CN104645934 A CN 104645934A
Authority
CN
China
Prior art keywords
parts
active carbon
deodorant
oxide
industrial wastewater
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310578511.7A
Other languages
Chinese (zh)
Inventor
李博
王鉴
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Water World Environmental Protection Technology Co Ltd
Original Assignee
Qingdao Water World Environmental Protection Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Water World Environmental Protection Technology Co Ltd filed Critical Qingdao Water World Environmental Protection Technology Co Ltd
Priority to CN201310578511.7A priority Critical patent/CN104645934A/en
Publication of CN104645934A publication Critical patent/CN104645934A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0281Sulfates of compounds other than those provided for in B01J20/045
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041Oxides or hydroxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/285Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/101Sulfur compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The invention discloses an active carbon industrial wastewater deodorant, which is composed of active carbon, calcium oxide, magnesium oxide, alumina, copper oxide, ferrous sulphate, benzoic acid and deionized water. The deodorant can uses an active carbon adsorption technology, the active carbon can react with offensive odor substances in waste water, stunk materials in waste water can be removed, atmosphere pollution can be prevented, raw materials are easy to obtain, and the production and usage cost is low.

Description

Active carbon industrial wastewater deodorant
Technical field
The present invention relates to a kind of deodorant, particularly relate to a kind of active carbon industrial wastewater deodorant, belong to technical field of chemistry and chemical engineering.
Background technology
Deodorizing promotes human health, the pith purifying and beautify the environment.
Stink, foul smell are from every aspect, and they all directly affect the health of the mankind.Smelly body (foul smell, smelly liquid) has two large classes and sulphur (S) based compound class and nitrogen (N) based compound class.S based compound class has hydrogen sulfide, methyl mercaptan and ethyl mercaptan etc., modal hydrogen sulfide gas (H 2s) stench, has severe toxicity, and the perception amount of people is 0.00037mg/m 3, containing 0.1%H 2the gas of S, can make human body poisoning, and the hydrogen sulfide that concentration is higher can make people lethal at short notice.Some sulfur-containing compound also can overflow and stink of, as ammonium sulfide, and dialkyl dithiophosphate, carbaminate and isothiocyanate etc.N based compound has ammonia and aminated compounds.The organs of vision of Ammonia intense stimulus people, make us suffocating, poisoning.
Absorbing and deodorizing be adopt that specific surface is large, the material with excellent adsorption capacity that pore volume is large to adsorb foul smell, common adsorbent has active carbon, NACF, all kinds of zeolite, some metal oxide and large pore macromolecular material etc.Specific surface exists
1900m 2active carbon adsorbable toluene 3.2g/g, more than the carbon tetrachloride 0.43g/g of more than g.Through the active carbon of plasma treatment, its adsorption capacity doubles.The zeolite carrying 0.5% (mass fraction) rare earth element can adsorb many organic solvent volatile matters.Metal oxide, particularly through the adsorbable various sulfurous gas of super fine zinc oxide and the liquid of airslide disintegrating mill pulverizing, as:
ZnO+H 2S+ZnS+H 2O
ZnO+C 2H 5SH=ZnS+C 2H 5OH
ZnO+C 2H 5SH=ZnS+C 2H 4+H 2O
After the copolymer adsorbed gas of making containing macropore by macromolecular material, expanding volume can be original volume tens times to hundred times.
In recent years, the deodorant that people develop makes one see with different eyes especially, is the atmospheric environment that protection people depend on for existence, for Ecological Stabilization is done one's bit, carries out the deodorant research of charcoal absorption emitting offensive odor gas.
Summary of the invention
The invention provides one and utilize active carbon adsorption technology, effective with waste water water body in produce stench material react, malodoring substance in removal waste water, prevents from polluting air, raw materials used being simple and easy to is sought, and produces and the lower active carbon industrial wastewater deodorant of use cost.
A kind of active carbon industrial wastewater deodorant, is made up of active carbon, calcium oxide, magnesia, aluminium oxide, cupric oxide, ferrous sulfate, benzoic acid and deionized water.
A kind of active carbon industrial wastewater deodorant, by mass parts, comprises following material:
Active carbon 30 ~ 70 parts, 20 ~ 30 parts, calcium oxide, 20 ~ 30 parts, magnesia, 5 ~ 15 parts, aluminium oxide, cupric oxide 3 ~ 8 parts, 40 ~ 80 parts, ferrous sulfate, 20 ~ 40 parts, benzoic acid, deionized water 80 ~ 100 parts.
A kind of active carbon industrial wastewater deodorant is obtained by following steps:
(1), after the method for the material machineries such as active carbon, calcium oxide, magnesia, aluminium oxide, cupric oxide being broken into powdery and fine granularity, add in proportion in container;
(2) add ferrous sulfate, benzoic acid and deionized water to cause it and dissolve remember deodorant of the present invention completely.
Deodorant of the present invention utilizes active carbon adsorption technology, effective with waste water water body in produce stench material react, malodoring substance in removal waste water; prevent from polluting air; raw materials used being simple and easy to is sought, produce and use cost lower, protect atmospheric environment to a certain extent.
Detailed description of the invention
Embodiment 1:
A kind of active carbon industrial wastewater deodorant, by mass parts, comprises following material:
Active carbon 30 parts, 20 parts, calcium oxide, 20 parts, magnesia, 6 parts, aluminium oxide, cupric oxide 3.5 parts, 40 parts, ferrous sulfate, 20 parts, benzoic acid, deionized water 80 parts.
This deodorant is obtained by following steps:
(1), after the method for the material machineries such as active carbon, calcium oxide, magnesia, aluminium oxide, cupric oxide being broken into powdery and fine granularity, add in proportion in container;
(2) add ferrous sulfate, benzoic acid and deionized water to cause it and dissolve remember deodorant of the present invention completely.
Deodorant of the present invention utilizes active carbon adsorption technology, effective with waste water water body in produce stench material react, prevent from polluting air, raw materials used being simple and easy to is sought, production and use cost lower, protect atmospheric environment to a certain extent.
Embodiment 2:
A kind of active carbon industrial wastewater deodorant, by mass parts, comprises following material:
Active carbon 40 parts, 24 parts, calcium oxide, 24 parts, magnesia, 7 parts, aluminium oxide, cupric oxide 4 parts, 50 parts, ferrous sulfate, 24 parts, benzoic acid, deionized water 88 parts.
This deodorant preparation method is with embodiment 1.
Deodorant of the present invention utilizes active carbon adsorption technology, effective with waste water water body in produce stench material react, malodoring substance in removal waste water.
Embodiment 3:
To the deodorant that hydrogen phosphide effectively purifies, by mass parts, comprise following material:
Active carbon 50 parts, 26 parts, calcium oxide, 26 parts, magnesia, 10 parts, aluminium oxide, cupric oxide 6 parts, 68 parts, ferrous sulfate, 30 parts, benzoic acid, deionized water 90 parts.
This deodorant preparation method is with embodiment 1.
Deodorant of the present invention utilizes active carbon adsorption technology, and malodoring substance in effective removal waste water, prevents from polluting air.
Deodorant of the present invention utilizes active carbon adsorption technology, effective with waste water water body in produce stench material react, malodoring substance in removal waste water; prevent from polluting air; raw materials used being simple and easy to is sought, produce and use cost lower, protect atmospheric environment to a certain extent.
Invention can be understood further by the invention process given above; above embodiment is only several specific embodiment of the present invention; but design concept of the present invention is not limited thereto; all changes utilizing this design the present invention to be carried out to unsubstantiality, all should belong to the behavior of invading scope.

Claims (4)

1. an active carbon industrial wastewater deodorant, is characterized in that, active carbon, calcium oxide, magnesia, aluminium oxide, cupric oxide, ferrous sulfate, benzoic acid and deionized water form.
2. active carbon industrial wastewater deodorant according to claim 1, it is characterized in that, by mass parts, comprise following material: active carbon 30 ~ 70 parts, 20 ~ 30 parts, calcium oxide, 20 ~ 30 parts, magnesia, 5 ~ 15 parts, aluminium oxide, cupric oxide 3 ~ 8 parts, 40 ~ 80 parts, ferrous sulfate, 20 ~ 40 parts, benzoic acid, deionized water 80 ~ 100 parts.
3. active carbon industrial wastewater deodorant according to claim 1, is characterized in that, by mass parts, comprises following material: active carbon 40 parts, 24 parts, calcium oxide, 24 parts, magnesia, 7 parts, aluminium oxide, cupric oxide 4 parts, 50 parts, ferrous sulfate, 24 parts, benzoic acid, deionized water 88 parts.
4. active carbon industrial wastewater deodorant according to claim 1, is characterized in that, by mass parts, comprises following material: active carbon 50 parts, 26 parts, calcium oxide, 26 parts, magnesia, 10 parts, aluminium oxide, cupric oxide 6 parts, 68 parts, ferrous sulfate, 30 parts, benzoic acid, deionized water 90 parts.
CN201310578511.7A 2013-11-18 2013-11-18 Active carbon industrial wastewater deodorant Pending CN104645934A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310578511.7A CN104645934A (en) 2013-11-18 2013-11-18 Active carbon industrial wastewater deodorant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310578511.7A CN104645934A (en) 2013-11-18 2013-11-18 Active carbon industrial wastewater deodorant

Publications (1)

Publication Number Publication Date
CN104645934A true CN104645934A (en) 2015-05-27

Family

ID=53237867

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310578511.7A Pending CN104645934A (en) 2013-11-18 2013-11-18 Active carbon industrial wastewater deodorant

Country Status (1)

Country Link
CN (1) CN104645934A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107335333A (en) * 2017-07-27 2017-11-10 宁国市南方耐磨材料有限公司 A kind of high-end casting waste gas purification inorganic agent
CN110280561A (en) * 2019-07-15 2019-09-27 三峡大学 A kind of application of city life garbage concentrates waste pit and its burying method
CN115259921A (en) * 2022-07-21 2022-11-01 安徽国祯环卫科技有限公司 Combined composting process of saturated deodorant material and kitchen garbage

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107335333A (en) * 2017-07-27 2017-11-10 宁国市南方耐磨材料有限公司 A kind of high-end casting waste gas purification inorganic agent
CN110280561A (en) * 2019-07-15 2019-09-27 三峡大学 A kind of application of city life garbage concentrates waste pit and its burying method
CN110280561B (en) * 2019-07-15 2021-04-13 三峡大学 Centralized landfill pit for urban domestic garbage and landfill method thereof
CN115259921A (en) * 2022-07-21 2022-11-01 安徽国祯环卫科技有限公司 Combined composting process of saturated deodorant material and kitchen garbage

Similar Documents

Publication Publication Date Title
Ko et al. Emissions and control of hydrogen sulfide at landfills: a review
Salehzadeh Removal of Heavy Metals Pb 2, Cu 2, Zn 2, Cd 2, Ni 2, Co 2 and Fe 3 from Aqueous Solutions by using Xanthium Pensylvanicum
CN109701489B (en) Sulfur-containing compound odor eliminating agent and preparation method and application thereof
CN101954241A (en) Method and device for removing odorous gas
CN104645934A (en) Active carbon industrial wastewater deodorant
CN104177654A (en) Regenerated plastic deodorant
CN103536950A (en) Iron-series high-efficiency deodorant
KR101896274B1 (en) Functional adsorbent composition having excellent acid gas removal efficiency
KR101451910B1 (en) Agent for removing hydrogen sulfide and recycling method of the same
CN105079846A (en) Compound indoor cleaning agent
US20060182709A1 (en) Treatment of landfill gas
CN103041425A (en) Air freshener with natural minerals
KR102012003B1 (en) Inorganic adsorbent for removal of hydrogen sulfide in nitrogen base
CN109928509B (en) Black and odorous river sediment purifying agent and preparation method thereof
KR101207565B1 (en) Method for deodorizing sludge comprising the step of treatment noxious odor-producing materials with sulfuric acid
KR102051502B1 (en) Inorganic adsorbent for removal of hydrogen sulfide
CN109794223A (en) A kind of industrial waste gas deodorant
Gholami Borujeni et al. Removal of heavy metal ions from aqueous solution by application of low cost materials
KR101411831B1 (en) Powdery deodorant
Andrès et al. Removal of rare earth elements and precious metal species by biosorption
ES2979383T3 (en) Procedure for removing heavy metals from liquids
CN105948458A (en) Novel deodorant for sewage treatment plant
KR101394628B1 (en) Solidifying agent for sludge using industrial by―product
WO2010095842A3 (en) Multifunctional adsorbent using sewage sludge or ashes, and livestock environment-improving agent
KR20200059972A (en) Adsorbent for removing ammonia comprising acid mine drainage sludge and alginate, method for producing the same, and method for removing ammonia using the same

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150527