CN1046324A - The method of acrylic acid from vinylformic acid waste oil - Google Patents
The method of acrylic acid from vinylformic acid waste oil Download PDFInfo
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- CN1046324A CN1046324A CN 89102172 CN89102172A CN1046324A CN 1046324 A CN1046324 A CN 1046324A CN 89102172 CN89102172 CN 89102172 CN 89102172 A CN89102172 A CN 89102172A CN 1046324 A CN1046324 A CN 1046324A
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- acrylic acid
- waste oil
- vinylformic acid
- acid
- vinylformic
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Abstract
The present invention for a kind of from the waste oil that contains vinylformic acid and acrylic acid dimer the method for acrylic acid.Its specific embodiments is to adopt the thermal degradation water distilling apparatus, the waste oil that will contain vinylformic acid and acrylic acid dimer is warming up to 110-150 ℃ under normal pressure, carry out destructive distillation, add solvent process water simultaneously, be convenient to decomposition and acrylic acid distillation of acrylic acid dimer.
Adopt the vinylformic acid more than 80% in the recyclable waste oil of the present invention, the vinylformic acid total yield that makes the vinylformic acid refining system is brought up to 99-99.5% by original 98.5%, is equivalent to increase output 1%, remarkable in economical benefits.
Description
The present invention for a kind of from the waste oil that contains vinylformic acid and acrylic acid dimer the method for acrylic acid.
In acrylic acid production process, always there are a certain amount of vinylformic acid and acrylic acid dimer and other high boiling material to discharge with waste oil, be to adopt thin-film evaporator that the vinylformic acid in the waste oil, acrylic acid dimer and hydroquinone of polymerization retarder are once reclaimed at present, this method is better to the recovering effect of hydroquinone of polymerization retarder, but because it is not good to conduct heat, it is bad that acrylic acid dimer decomposes effect, and the material thickness, easily stop up and fall the liquid mouth, still have a certain amount of vinylformic acid and acrylic acid dimer to can not get reclaiming.Produce 30000 tons of acrylic acid production equipments per year as a cover and discharge 650 tons of waste oil approximately every year, wherein have to be vinylformic acid and acrylic acid dimer more than 50%.The waste oil of the discharging use that only acts as a fuel at present causes great waste.
The objective of the invention is further to adopt physical method, the acrylic acid dimer in the vinylformic acid waste oil is decomposed, and vinylformic acid is fully reclaimed.
Technical solution of the present invention is to adopt thermal degradation distillatory device, the waste oil that will contain vinylformic acid and acrylic acid dimer is warming up to 110～150 ℃ under normal pressure, carry out destructive distillation, for reducing waste oil viscosity, be easy to decomposition and acrylic acid distillation of acrylic acid dimer, also add solvent process water simultaneously, the add-on of process water is vinylformic acid and acrylic acid dimer gross weight 1.5～5 times in the waste oil.Turn back in the vinylformic acid refining system decomposing the acrylic acid solution that reclaims, again process water is separated.
Reclaim process flow diagram with reference to vinylformic acid, the invention will be further described.
Waste oil after thin-film evaporator 1 primary treatment enters storage tank 2, join continuously in the storage tank 3 with pump 6, be warming up to 110～150 ℃ by chuck, process water also adds in the storage tank 3 after metering, the acrylic acid solution that obtains behind the destructive distillation returns the vinylformic acid refining system, raffinate enters in the storage tank 4 continuously, is sent to waste oil storage tank 6 through pump 7 again.
Accompanying drawing: the third bright acid recovery process schematic flow sheet
The 1-thin-film evaporator
2,3,4,5-storage tank
6,7-pump
The 8-steam jacket
The 9-heating coil
W-solvent process water
The AA-acrylic acid aqueous solution
Ls-steam
The Lc-steam condensate
Several embodiments of the present invention are provided below.
Embodiment 1: get waste oil 1000 grams that contain vinylformic acid and acrylic acid dimer, it consists of, vinylformic acid 12.79%, acrylic acid dimer 54.25%, phenylformic acid 3.25%, Resorcinol 8.81%, other 20.9%, drop in 1000 milliliters of matrasss, be warming up to 145 ℃, add process water 1500 grams, when distillation yield is 2500 milliliters, record in the distillate, vinylformic acid 24.51%, acrylic acid dimer 0.3%, raffinate 337.1 grams, wherein vinylformic acid 9.06%, acrylic acid dimer 11.18%.This shows that the rate of decomposition of acrylic acid dimer is 91.35%, acrylic acid rate of recovery is 95%.
Embodiment 2: get waste oil 1000 grams that contain vinylformic acid and acrylic acid dimer, wherein vinylformic acid 12.13%, acrylic acid dimer 43.81%, phenylformic acid 3.52%, Resorcinol 11.55%, drop in 1000 milliliters of matrasss, be warming up to 140 ℃ under the normal pressure, add process water 1400 grams, when distillate is 2750 milliliters, wherein vinylformic acid is 17.84%, acrylic acid dimer 0.19%, and this moment, raffinate was 423 grams, wherein vinylformic acid 10.58%, acrylic acid dimer 8.15%, the rate of decomposition of acrylic acid dimer are 91.2%, and acrylic acid rate of recovery is 86.8%.
Embodiment 3: will contain vinylformic acid waste oil and put into continuously in the storage tank by 80Kg/hr, and feed 6Kg/cm by steam jacket
2Steam, keep the interior temperature of storage tank at 143 ℃, continuously join storage tank in by 140Kg/hr process water, continuous distilled acrylic acid aqueous solution is turned back in the vinylformic acid refining system by 180Kg/hr with pump, record the distillate composition and contain vinylformic acid 22.2%, acrylic acid dimer 0.3%, raffinate also are continuously discharged in another storage tank, with the past waste oil basin of pumping.Contain vinylformic acid 9.98% in this raffinate, acrylic acid dimer 10.25%, acrylic acid rate of recovery is 90.1%.
Advantage of the present invention is: equipment, technology are simple, easy to operate, and solvent is inexpensive, and wide material sources adopt acrylic acid and acrylic acid dimer more than 80% in the recyclable waste oil of the present invention, The rate of recovery that makes the acrylic acid refining system can be equivalent to increase output 1%, remarkable in economical benefits after bringing up to 99～99.5%, one cover acrylic acid production device and adopt the present invention by original 98.5%.
Claims (2)
1, a kind of from vinylformic acid waste oil the method for acrylic acid, it is characterized in that: the waste oil that will contain vinylformic acid and acrylic acid dimer is warming up to 110～150 ℃ under normal pressure, add solvent process water simultaneously, carry out destructive distillation, the acrylic acid aqueous solution that reclaims is turned back in the vinylformic acid refining system separation of propylene acid and solvent process water.
2, according to claim 1 from vinylformic acid waste oil the method for acrylic acid, the add-on that it is characterized in that solvent process water is vinylformic acid and acrylic acid dimer gross weight 1.5～5 times in the propionic acid acid waste oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 89102172 CN1019011B (en) | 1989-04-15 | 1989-04-15 | Recovery process of acrylic acid from waste oil containing acrylic acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 89102172 CN1019011B (en) | 1989-04-15 | 1989-04-15 | Recovery process of acrylic acid from waste oil containing acrylic acid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1046324A true CN1046324A (en) | 1990-10-24 |
| CN1019011B CN1019011B (en) | 1992-11-11 |
Family
ID=4854562
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 89102172 Expired CN1019011B (en) | 1989-04-15 | 1989-04-15 | Recovery process of acrylic acid from waste oil containing acrylic acid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1019011B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6870066B2 (en) | 2002-04-25 | 2005-03-22 | Nippon Shokubai Co., Ltd | Method for decomposition of Michael type adduct |
| CN100398505C (en) * | 2006-07-28 | 2008-07-02 | 沈福昌 | Treatment method of acrylic acid and esters waste oil resource |
| CN1938256B (en) * | 2004-04-29 | 2011-01-26 | Lg化学株式会社 | Method for recovering acrylic acid |
| CN105753688A (en) * | 2016-03-29 | 2016-07-13 | 黄河三角洲京博化工研究院有限公司 | Method for lowering acrylic acid dimer in acrylic acid |
| CN108774124A (en) * | 2018-08-07 | 2018-11-09 | 陈惠双 | A method of the acrylic acid from the waste oil containing acrylic acid dimer |
-
1989
- 1989-04-15 CN CN 89102172 patent/CN1019011B/en not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6870066B2 (en) | 2002-04-25 | 2005-03-22 | Nippon Shokubai Co., Ltd | Method for decomposition of Michael type adduct |
| CN1938256B (en) * | 2004-04-29 | 2011-01-26 | Lg化学株式会社 | Method for recovering acrylic acid |
| CN100398505C (en) * | 2006-07-28 | 2008-07-02 | 沈福昌 | Treatment method of acrylic acid and esters waste oil resource |
| CN105753688A (en) * | 2016-03-29 | 2016-07-13 | 黄河三角洲京博化工研究院有限公司 | Method for lowering acrylic acid dimer in acrylic acid |
| CN105753688B (en) * | 2016-03-29 | 2018-01-05 | 黄河三角洲京博化工研究院有限公司 | A kind of method of acrylic acid dimer in reduction acrylic acid |
| CN108774124A (en) * | 2018-08-07 | 2018-11-09 | 陈惠双 | A method of the acrylic acid from the waste oil containing acrylic acid dimer |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1019011B (en) | 1992-11-11 |
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Free format text: CORRECT: PATENTEE; FROM: DONGFANG CHEMICAL PLANT, BEIJING, THE EAST CHEMICAL PLANT,BEIJING TO: DONGFANG CHEMICAL FACTORY, BEIJING CHEMICAL INDUSTRY GROUP CO., LTD. |
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| CP01 | Change in the name or title of a patent holder |
Patentee after: Dongfang Chemical Plant, Beijing Chemical Industry Group Co., Ltd. Patentee before: Dongfang Chemical Plant, Beijing |
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| C15 | Extension of patent right duration from 15 to 20 years for appl. with date before 31.12.1992 and still valid on 11.12.2001 (patent law change 1993) | ||
| OR01 | Other related matters | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |