CN104624060A - Environment-friendly reverse osmosis (RO) scale inhibitor and preparation method thereof - Google Patents
Environment-friendly reverse osmosis (RO) scale inhibitor and preparation method thereof Download PDFInfo
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- CN104624060A CN104624060A CN201510067219.8A CN201510067219A CN104624060A CN 104624060 A CN104624060 A CN 104624060A CN 201510067219 A CN201510067219 A CN 201510067219A CN 104624060 A CN104624060 A CN 104624060A
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- reverse osmosis
- antisludging agent
- hydroxyamphetamine
- deionized water
- hedp
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Abstract
The invention provides an environment-friendly reverse osmosis (RO) scale inhibitor and a preparation method thereof. The RO scale inhibitor comprises the following components by weight percent: 5-20% of 4-hydroxyamphetamine, 10-30% of polyamino polyether methylene phosphonate, 20-50% of hydroxyethylidene diphosphonic acid and the balance of deionized water. The RO membrane scale inhibitor product is prepared by adding the components to a reaction kettle in sequence and starting a stirring motor. When the scale inhibitor is used in an RO system for water treatment, the problem of deposition of dirt on an RO membrane, such as calcium carbonate, calcium sulfate, magnesium carbonate, calcium phosphate, barium sulfate, ferric oxide and colloidal silica, can be solved, thus improving the work efficiency of the RO system, prolonging the service lives of the RO membrane and RO equipment and reducing the RO cost.
Description
Technical field
The present invention relates to a kind of technical field of water treatment chemical, particularly a kind of environmental friendliness reverse osmosis antisludging agent and manufacture method thereof.
Background technology
Reverse osmosis antisludging agent is a kind of medicament in the water treatment systems such as counter-infiltration nanofiltration, prevents dirt deposition a kind of medicament that influential system runs on film.Counter-infiltration system is when running, and the ion concentration of reverse osmosis concentrated water side concentrates 3-4 doubly, so have calcium carbonate, calcium sulfate, magnesium carbonate, calcium phosphate, barium sulfate, the dirt deposition such as di-iron trioxide, colloidal silicon is on the surface of film.Stop water through film.Time, longer dirt deposition was more, and the normal operation of influential system, seriously then can cause the damage of film.
Reverse osmosis membrane is the core component in DW system demineralized water system, and counter-infiltration system, once occur dirty stifled, not only can have a strong impact on the aquifer yield of film, reduce salt rejection rate, and greatly reduce the life-span of film, when serious dirt is stifled, only 1 year service life of reverse osmosis membrane, even shorter.
Summary of the invention
For the weak point that prior art proposes, the present invention proposes one and can prevent face fouling, aquifer yield can be improved and produce water quality, reducing the reverse osmosis membrane antisludging agent of operating cost.
Technical scheme of the present invention is achieved in that a kind of environmental friendliness reverse osmosis antisludging agent and manufacture method thereof, it is characterized in that, its component and weight proportion thereof are: 4-hydroxyamphetamine 5-20%; Polyamino polyether base methylenephosphonic acid 10-30%; HEDP 20-50%; All the other are deionized water.
Preferably, its component and weight proportion thereof are: 4-hydroxyamphetamine 5%; Polyamino polyether base methylenephosphonic acid 30%; HEDP 50%; Deionized water 15%.
Preferably, its component and weight proportion thereof are: 4-hydroxyamphetamine 10%; Polyamino polyether base methylenephosphonic acid 20%; HEDP 35%; Deionized water 35%.
Preferably, its component and weight proportion thereof are: 4-hydroxyamphetamine 20%; Polyamino polyether base methylenephosphonic acid 10%; HEDP 20%; Deionized water 50%.
The processing step preparing reverse osmosis antisludging agent is: first by the component 4-hydroxyamphetamine in reverse osmosis membrane antisludging agent, polyamino polyether base methylenephosphonic acid, HEDP and deionized water weigh by proportioning, then join successively in reactor, start stirring motor, slowly be heated to 70-90 degree, and after constant temperature 4-6 hour, stop heating, naturally after cooling, mixed liquor is canned, obtained reverse osmosis antisludging agent product.
Preferably, heating-up temperature is 80 degree.
The beneficial effect that the present invention possesses:
When antisludging agent provided by the invention is used for counter-infiltration system water treatment, calcium carbonate on reverse osmosis membrane can be solved, calcium sulfate, magnesium carbonate, calcium phosphate, barium sulfate, the dirt deposition such as di-iron trioxide, colloidal silicon problem, improve the operating efficiency of counter-infiltration system, extend the service life of reverse osmosis membrane and reverse osmosis equipment, reduce the cost of counter-infiltration.
Detailed description of the invention
Embodiment 1
A kind of environmental friendliness reverse osmosis antisludging agent and manufacture method thereof, its component and weight proportion thereof are: 4-hydroxyamphetamine 5%; Polyamino polyether base methylenephosphonic acid 30%; HEDP 50%; Deionized water 15%.
The processing step preparing reverse osmosis antisludging agent is: first by the component in reverse osmosis membrane antisludging agent: 4-hydroxyamphetamine, polyamino polyether base methylenephosphonic acid, HEDP and deionized water weigh by above-mentioned proportioning, then join successively in reactor, start stirring motor, and constant temperature 6 hours when slowly heating and be heated to 70 degree, naturally after cooling, mixed liquor is canned, obtained reverse osmosis antisludging agent product.
Embodiment 2
A kind of environmental friendliness reverse osmosis antisludging agent and manufacture method thereof, its component and weight proportion thereof are: 4-hydroxyamphetamine 10%; Polyamino polyether base methylenephosphonic acid 20%; HEDP 35%; Deionized water 35%.
The processing step preparing reverse osmosis antisludging agent is: first by the component in reverse osmosis membrane antisludging agent: 4-hydroxyamphetamine, polyamino polyether base methylenephosphonic acid, HEDP and deionized water weigh by above-mentioned proportioning, then join successively in reactor, start stirring motor, slowly be heated to 80 degree, and after constant temperature 4-6 hour, stop heating, naturally after cooling, mixed liquor is canned, obtained reverse osmosis antisludging agent product.
Embodiment 3
A kind of environmental friendliness reverse osmosis antisludging agent and manufacture method thereof, its component and weight proportion thereof are: 4-hydroxyamphetamine 20%; Polyamino polyether base methylenephosphonic acid 10%; HEDP 20%; Deionized water 50%.
The processing step preparing reverse osmosis antisludging agent is: first by the component in reverse osmosis membrane antisludging agent: 4-hydroxyamphetamine, polyamino polyether base methylenephosphonic acid, HEDP and deionized water weigh by above-mentioned proportioning, then join successively in reactor, start stirring motor, slowly be heated to 90 degree, and after constant temperature 4-6 hour, stop heating, naturally after cooling, mixed liquor is canned, obtained reverse osmosis antisludging agent product.
Embodiment 4
A kind of environmental friendliness reverse osmosis antisludging agent and manufacture method thereof, its component and weight proportion thereof are: 4-hydroxyamphetamine 15%; Polyamino polyether base methylenephosphonic acid 25%; HEDP 20%; Deionized water 40%.
The processing step preparing reverse osmosis antisludging agent is: first by the component in reverse osmosis membrane antisludging agent: 4-hydroxyamphetamine, polyamino polyether base methylenephosphonic acid, HEDP and deionized water weigh by above-mentioned proportioning, then join successively in reactor, start stirring motor, slowly be heated to 70 degree, and after constant temperature 4-6 hour, stop heating, naturally after cooling, mixed liquor is canned, obtained reverse osmosis antisludging agent product.
Embodiment 5
A kind of environmental friendliness reverse osmosis antisludging agent and manufacture method thereof, its component and weight proportion thereof are: 4-hydroxyamphetamine 10%; Polyamino polyether base methylenephosphonic acid 25%; HEDP 40%; Deionized water 25%.
The processing step preparing reverse osmosis antisludging agent is: first by the component in reverse osmosis membrane antisludging agent: 4-hydroxyamphetamine, polyamino polyether base methylenephosphonic acid, HEDP and deionized water weigh by above-mentioned proportioning, then join successively in reactor, start stirring motor, slowly be heated to 90 degree, and after constant temperature 4-6 hour, stop heating, naturally after cooling, mixed liquor is canned, obtained reverse osmosis antisludging agent product.
Embodiment 6
A kind of environmental friendliness reverse osmosis antisludging agent and manufacture method thereof, its component and weight proportion thereof are: 4-hydroxyamphetamine 20%; Polyamino polyether base methylenephosphonic acid 30%; HEDP 35%; Deionized water 15%.
The processing step preparing reverse osmosis antisludging agent is: first by the component in reverse osmosis membrane antisludging agent: 4-hydroxyamphetamine, polyamino polyether base methylenephosphonic acid, HEDP and deionized water weigh by above-mentioned proportioning, then join successively in reactor, slowly be heated to 70 degree, and after constant temperature 4-6 hour, stop heating, naturally after cooling, mixed liquor is canned, obtained reverse osmosis antisludging agent product.
Experiment and result:
One: resistance CaCO3 experiment
Laboratory sample is originated:
1. the case study on implementation of this product invention
2. hinder CaCO3 experiment
2.1 experimental waters: water distribution, Ca2+320mg/L HCO3-780mg/L
2.2 experiment conditions: 50 DEG C of times of water temperature: 24 hours dosing: 5mg/L
2.3 experimental technique
2.4 experimental results: in table one
Scale inhibition performance is higher shows that the scale-inhibiting properties of medicament is better, shows that the scale-inhibiting properties of case study on implementation 4 couples of CaCO3 is best from upper experimental result.
Two resistance CaSO4 experiments
1, laboratory sample source: the invention process case
2, CaSO4 experiment is hindered
2.1 experimental waters: water distribution: Ca2+2200mg/L SO42900mg/L
2.2 experiment conditions: 50 DEG C of times of water temperature: 24 hours dosing: 4mg/L
2.3 experimental results: in table two
3, scale inhibition performance is higher shows that the scale-inhibiting properties of medicament is better, shows that the scale-inhibiting properties of case study on implementation 4 couples of CaSO4 is best from upper experimental result.
Three, dispersing iron oxide performance test
3.1 experimental technique
Configuration Ca2+ concentration is 200mg/L (in CaCO3), 5mg/L the invention process case antisludging agent, and 10mg/L Fe2+ aqueous solution 1000ml, is placed in the beaker of 1000ml, regulates pH value while stirring with the sodium tetraborate of 0.5g/L.After pH value reaches 8.77 and is stable, strong agitation 15 minutes, and then leave standstill 5-8 hour in the water-bath of 50 DEG C, get upper liquid, survey light transmittance with spectrophotometer (420nm).
3.2 experimental results are in table three
Light transmittance is less, shows that the dispersive property of medicament is better.Show that the dispersiveness of case study on implementation 4 is best from above-mentioned experimental result.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (6)
1. environmental friendliness reverse osmosis antisludging agent and a manufacture method thereof, is characterized in that, its component and weight proportion thereof are:
4-hydroxyamphetamine 5-20%; Polyamino polyether base methylenephosphonic acid 10-30%; HEDP 20-50%; All the other are deionized water.
2. a kind of environmental friendliness reverse osmosis antisludging agent according to claim 1 and manufacture method thereof, is characterized in that, its component and weight proportion thereof are: 4-hydroxyamphetamine 5%; Polyamino polyether base methylenephosphonic acid 30%; HEDP 50%; Deionized water 15%.
3. a kind of environmental friendliness reverse osmosis antisludging agent according to claim 1 and manufacture method thereof, is characterized in that, its component and weight proportion thereof are: 4-hydroxyamphetamine 10%; Polyamino polyether base methylenephosphonic acid 20%; HEDP 35%; Deionized water 35%.
4. a kind of environmental friendliness reverse osmosis antisludging agent according to claim 1 and manufacture method thereof, is characterized in that, its component and weight proportion thereof are: 4-hydroxyamphetamine 20%; Polyamino polyether base methylenephosphonic acid 10%; HEDP 20%; Deionized water 50%.
5. the method for preparation reverse osmosis antisludging agent as described in claim 1-5 any one, it is characterized in that processing step is: first by the component 4-hydroxyamphetamine in reverse osmosis membrane antisludging agent, polyamino polyether base methylenephosphonic acid, HEDP and deionized water weigh by proportioning, then join successively in reactor, start stirring motor, be slowly heated to 70-90 degree, and after constant temperature 4-6 hour, stop heating, naturally after cooling, mixed liquor is canned, obtained reverse osmosis antisludging agent product.
6. the method for preparation reverse osmosis antisludging agent as described in claim 1-5 any one, is characterized in that processing step is: heating-up temperature is 80 degree.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101172721A (en) * | 2006-10-31 | 2008-05-07 | 湖州欧美化学有限公司 | Antisludging agent of reverse osmosis water treatment system |
| CN101423299A (en) * | 2007-10-31 | 2009-05-06 | 中国石油化工股份有限公司 | Reverse osmosis membrane scale inhibitor and preparation and use method thereof |
| AU2010361425A1 (en) * | 2010-09-30 | 2013-02-21 | Amsa, Inc. | Formulations for use in Sulfur Scale Control in Industrial Water Systems |
| JP2014180586A (en) * | 2013-03-18 | 2014-09-29 | Kurita Water Ind Ltd | Method for preventing generation of scale in reverse osmosis membrane treatment and scale inhibitor for reverse osmosis membrane treatment |
| CN104258735A (en) * | 2014-10-16 | 2015-01-07 | 山东天庆科技发展有限公司 | Reverse osmosis membrane scale inhibitor and preparation method thereof |
-
2015
- 2015-02-09 CN CN201510067219.8A patent/CN104624060A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101172721A (en) * | 2006-10-31 | 2008-05-07 | 湖州欧美化学有限公司 | Antisludging agent of reverse osmosis water treatment system |
| CN101423299A (en) * | 2007-10-31 | 2009-05-06 | 中国石油化工股份有限公司 | Reverse osmosis membrane scale inhibitor and preparation and use method thereof |
| AU2010361425A1 (en) * | 2010-09-30 | 2013-02-21 | Amsa, Inc. | Formulations for use in Sulfur Scale Control in Industrial Water Systems |
| JP2014180586A (en) * | 2013-03-18 | 2014-09-29 | Kurita Water Ind Ltd | Method for preventing generation of scale in reverse osmosis membrane treatment and scale inhibitor for reverse osmosis membrane treatment |
| CN104258735A (en) * | 2014-10-16 | 2015-01-07 | 山东天庆科技发展有限公司 | Reverse osmosis membrane scale inhibitor and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 李东光: "《实用化工产品配方与制备（二）》", 31 July 2011, 北京：中国纺织出版社 * |
| 李本高等: "《现代工业水处理技术与应用》", 30 June 2004, 北京：中国石化出版社 * |
| 陈孝治等: "《药物处方手册【第二版】》", 30 June 2012, 长沙：湖南科学技术出版社 * |
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