CN104621107A - Mixed herbicide containing picloram and haloxyfop-R-methyl - Google Patents
Mixed herbicide containing picloram and haloxyfop-R-methyl Download PDFInfo
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- CN104621107A CN104621107A CN201310572617.6A CN201310572617A CN104621107A CN 104621107 A CN104621107 A CN 104621107A CN 201310572617 A CN201310572617 A CN 201310572617A CN 104621107 A CN104621107 A CN 104621107A
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- haloxyfop
- methyl
- acid
- fampridine
- herbicide
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Abstract
The invention discloses a mixed herbicide containing picloram and haloxyfop-R-methyl, and belongs to the technical field of pesticides. The herbicide is prepared from picloram and haloxyfop-R-methyl in a mass ratio of (0.1-80): (0.1-80) as main effective ingredients. The mixed herbicide has the advantages of quick response, wide herbicide controlling spectrum, long duration, complete weed control, low residue, low toxicity, safety, environmental friendliness and the like when applied to weeding of bare places, orchards, forest lands, cotton fields, oilseed rape fields and wheat paddocks, and is a high-quality chemical herbicide for bare places, orchards, forest lands, cotton fields, oilseed rape fields and wheat paddocks.
Description
Technical field
The invention belongs to technical field of pesticide, especially weed killer herbicide field, relate to the binary built agent of the acid of chlorine Fampridine and haloxyfop-r-methyl.This herbicidal composition can be applicable to uncultivated area, orchard, forest land, cotton and Rapeseed Field postemergence weed control.
Background technology
Chlorine Fampridine acid (aminopyralid), amino-3, the 6-dichloropyridine-2-carboxylic acids of chemical name: 4-, the acid of chlorine Fampridine is a kind of pyridines weed killer herbicide, is widely used in the control of weeds of mountain region, grassland, lawn, plantation and uncultivated area.Annual or perennial broadleaf weed can be prevented and treated.
Haloxyfop-r-methyl (haloxyfop-R-methyl), have another name called haloxyfop-r-methyl, chemical name: 2-[4-(the chloro-pyridine of 5-trifluoromethyl-3--2-oxygen base) phenoxy group] methyl propionate, a kind of phenoxy carboxylic acid herbicides, be fatty acid synthetic inhibitor, belong to selectivity inner sucting conduction type herbicide after seedling.Be absorbed by plants very soon after medicine, make Growth of Cells, division stopping, cell membranes etc. cause weeds dead containing fat structural deterioration, after being absorbed by broad leaf crop, some compound in the pyrrole fluorine second clever ortho acid of grass and plant corpus can be changed rapidly into and produce conjugation, be degraded to non-activity material, so to broad leaved plant safety, belong to fluorinated heterocycle highy potent herbicide of new generation.Be applicable to broad-leaved field crop, effectively can prevent and treat annual and perennial grassy weed.
Because current chlorine Fampridine acid residue problem is serious, usage amount and using method are strictly limited in a lot of countries and regions.In order to while minimizing herbicide carryover, guarantee the herbicidal effect of medicament, use being made into mixture after the acid of chlorine Fampridine and haloxyfop-r-methyl two kinds of suitable decrements of weed killer herbicide, so both expand herbicide spectrum, significantly improve herbicidal effect, it also avoid possibility succession crop being produced to residual hazard.
Summary of the invention
The object of this invention is to provide the mixed herbicide of a kind of chloride Fampridine acid and haloxyfop-r-methyl.
Another object of the present invention is to provide the application of this weed killer herbicide in uncultivated area, orchard, forest land, cotton, Rapeseed Field and wheat paddock weeding.
The mixed herbicide of a kind of chloride Fampridine acid and haloxyfop-r-methyl, it is characterized in that this weed killer herbicide with chlorine Fampridine acid with haloxyfop-r-methyl for principle active component, the acid of chlorine Fampridine is 0.1 ~ 80:0.1 ~ 80 with the mass ratio of haloxyfop-r-methyl, preferred chlorine Fampridine acid is 1 ~ 60:1 ~ 60 with the mass ratio of haloxyfop-r-methyl, and preferred chlorine Fampridine acid is 1:0.5 ~ 4 with the mass ratio of haloxyfop-r-methyl.
In mixed herbicide, the acid of chlorine Fampridine is 1 ~ 85% with the mass percentage of both haloxyfop-r-methyls in weed killer herbicide, and preferred mass percentage composition is 10 ~ 75%.
Mixed herbicide of the present invention, wherein the acid of chlorine Fampridine exists with the form of water soluble salt, and the water soluble salt of described chlorine Fampridine acid comprises the water soluble salts such as sodium salt, sylvite, ammonium salt, isopropyl amine salt, methylamine salt, dimethylamine salt, alcohol salt, triethanolamine salt, triisopropanolamine salt.
Chlorine Fampridine acid of the present invention is with the binary built preparation of haloxyfop-r-methyl, except the acid of chlorine Fampridine is with except haloxyfop-r-methyl active ingredient, the auxiliary agents such as conventional surfactants, thickener, solvent or the solid packing that pesticidal preparations allows can also be added and be mixed with any one formulation that agricultural chemicals allows.Preferably be processed into missible oil, aqueous emulsion, suspending agent, water dispersible granules, water solube powder, microemulsion, soluble liquid, wetting powder.
" % " of the present invention is mass percentage.
The application of mixed herbicide in uncultivated area, orchard, forest land, cotton, Rapeseed Field and wheat paddock weeding of chloride Fampridine acid of the present invention and haloxyfop-r-methyl, has remarkable result preventing and kill off the application in uncultivated area, orchard, forest land, cotton, Rapeseed Field and wheat paddock in various broad leaved weed.
Compared to the prior art, beneficial effect of the present invention:
Combinations of herbicides of the present invention, has instant effect, herbicide spectrum width, and the advantages such as the lasting period is long, weeding is thorough, it is low to remain, low toxicity, safety and environmental protection are chemical herbicides after the uncultivated area of high-quality, orchard, forest land, cotton, Rapeseed Field and wheat paddock seedling.
Specific embodiments
Embodiment 1
Haloxyfop-r-methyl 20%, chlorine Fampridine acid 5%, calcium dodecyl benzene sulfonate 5%, alkylphenol polyoxyethylene 3%, solvent naphtha to 100%, formulation method is conveniently mixed with the missible oil that mass percentage is 25%.Wherein the acid of chlorine Fampridine exists with isopropyl amine salt form.
Embodiment 2
Haloxyfop-r-methyl 10%, chlorine Fampridine acid 20%, alkylphenol polyoxyethylene 3%, castor oil polyoxyethylene ether 2%, xanthans 0.1%, dimethylbenzene 20%, ethylene glycol 5%, water to 100%, formulation method is conveniently mixed with the aqueous emulsion that mass percentage is 30%.Wherein the acid of chlorine Fampridine exists with sodium-salt form.
Embodiment 3
Haloxyfop-r-methyl 15%, chlorine Fampridine acid 10%, alkylphenol polyoxyethylene phosphate 5%, aluminium-magnesium silicate 2%, white carbon 2%, ethylene glycol 5%, water to 100%, formulation method is conveniently mixed with the suspending agent that mass percentage is 25%.Wherein the acid of chlorine Fampridine exists with methylamine salt form.
Embodiment 4
Haloxyfop-r-methyl 25%, chlorine Fampridine acid 50%, sodium lignin sulfonate 5%, lauryl sulfate 2%, ammonium sulfate 5%, kaolin to 100%, formulation method is conveniently mixed with the water dispersible granules that mass percentage is 75%.Wherein the acid of chlorine Fampridine exists with sodium-salt form.
Embodiment 5
Haloxyfop-r-methyl 20%, chlorine Fampridine acid 30%, neopelex 5%, alkylphenol polyoxyethylene 3%, ammonium sulfate 5%, kaolin to 100%, formulation method is conveniently mixed with the water solube powder that mass percentage is 50%.Wherein the acid of chlorine Fampridine exists with ammonium salts.
Embodiment 6
Haloxyfop-r-methyl 15%, chlorine Fampridine acid 60%, NNO(di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) wetting agent 5%, ammonium sulfate 3%, polyvinyl alcohol 2%, kaolin to 100%, formulation method is conveniently mixed with the water dispersible granules that mass percentage is 75%.Wherein the acid of chlorine Fampridine exists with potassium salt form.
Embodiment 7
Haloxyfop-r-methyl 60%, chlorine Fampridine acid 10%, NNO(di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) 6%, sodium lignin sulfonate 5%, kaolin to 100%, formulation method is conveniently mixed with the wetting powder that mass percentage is 70%.Wherein the acid of chlorine Fampridine exists with sodium-salt form.
Embodiment 8
Haloxyfop-r-methyl 9%, chlorine Fampridine acid 1%, calcium dodecyl benzene sulfonate 5%, castor oil polyoxyethylene ether 5%, solvent naphtha 15%, cyclohexanone 5%, ethylene glycol 5%, water to 100%, formulation method is conveniently mixed with the microemulsion that mass percentage is 10%.Wherein the acid of chlorine Fampridine exists with triisopropanolamine salt form.
Embodiment 9
Haloxyfop-r-methyl 1%, chlorine Fampridine acid 9%, neopelex 5%, alkyl glycoside 5%, isopropyl alcohol 15%, cyclohexanone 5%, ethylene glycol 5%, water to 100%, formulation method is conveniently mixed with the soluble liquid that mass percentage is 10%.Wherein the acid of chlorine Fampridine exists with methylamine salt form.
Embodiment 10
1, toxicity determination test
Utilize the preparation in embodiment 1 ~ 4, measure its co-toxicity coefficient to amur foxtail.
Test method: be seeded in respectively in the Disposable paper cup of 9cm by the seed of quantitative amur foxtail, sows 10 ~ 15 seeds in every glass, cultivates in illumination box, when amur foxtail 3 ~ 6 leaf phase, does composition spray to carry out spraying process in crawler type.Continue in greenhouse after process to cultivate, routine observation respectively processes the preventive effect to weeds, weighs the weeds fresh weight after each process after 30d, and the method proposed by nineteen sixties such as Sun Yunpei, calculates its toxicity regression curve and co-toxicity coefficient.Co-toxicity coefficient is greater than 100, and show that two kinds of active principles have synergistic effect, co-toxicity coefficient is less than 100, shows that two kinds of active principles have antagonism.Measurement result is as shown in table 1.
Table 1 toxicity measurement result
As can be seen from Table 1, the co-toxicity coefficient after two kinds of active principles are composite is all greater than 100, illustrates that the present invention has obvious synergistic effect.
2, field control effectiveness test
Reagent agent: 4 kinds of re-compounded binary herbicides in embodiment 1 ~ 4.
Contrast medicament: 10.8% haloxyfop-r-methyl missible oil (commercially available), 30% chlorine Fampridine sour water agent (commercially available).
Control crop: wheat.
Prevent and kill off object: the weeds such as dayflower, clearvers, kitchen garden, Alopecurus.
Test method: according to the area of experimental plot, the good various medicament of precise, and after being watered dilution, utilize knapsack sprayer, carry out even spraying, the Fan spray head that sprinkler selection weed killer herbicide is special.During spraying, liquid be noted evenly to spray application in experimental plot, accomplish the phenomenon not having drain spray, many sprays.
After test, after medicine, 20d, 40d observe weeds death condition respectively, and the activity of weeding of more various medicament.
Embodiments of the invention preparation Herbicidal Testing Trials effect sees the following form 20d after 1(medicine) and table 2(medicine after 40d)
Table 1 field control effectiveness test result (after medicine 20d)
Table 2 field control effectiveness test result (after medicine 40d)
As can be seen from Table 1 and Table 2, the present invention has significant preventive effect to weeds, significantly building performance, and instant effect, lasting period are long.
Claims (10)
1. the mixed herbicide of a chloride Fampridine acid and haloxyfop-r-methyl, it is characterized in that this weed killer herbicide with the acid of chlorine Fampridine with haloxyfop-r-methyl for principle active component, the acid of chlorine Fampridine is 0.1 ~ 80:0.1 ~ 80 with the mass ratio of haloxyfop-r-methyl.
2. chloride Fampridine acid according to claim 1 and the mixed herbicide of haloxyfop-r-methyl, is characterized in that in this weed killer herbicide, the acid of chlorine Fampridine is 1 ~ 60:1 ~ 60 with the mass ratio of haloxyfop-r-methyl.
3. chloride Fampridine acid according to claim 2 and the mixed herbicide of haloxyfop-r-methyl, is characterized in that in this weed killer herbicide, the acid of chlorine Fampridine is 1:0.5 ~ 4 with the mass ratio of haloxyfop-r-methyl.
4. chloride Fampridine acid according to claim 1 and the mixed herbicide of haloxyfop-r-methyl, is characterized in that the acid of chlorine Fampridine is 1 ~ 85% with the mass percentage of both haloxyfop-r-methyls in weed killer herbicide.
5. chloride Fampridine acid according to claim 4 and the mixed herbicide of haloxyfop-r-methyl, is characterized in that the acid of chlorine Fampridine is 10 ~ 75% with the mass percentage of both haloxyfop-r-methyls in weed killer herbicide.
6. the chloride Fampridine acid according to arbitrary one of claim 1-5 and the mixed herbicide of haloxyfop-r-methyl, it is characterized in that the acid of chlorine Fampridine exists with the form of water soluble salt, the water soluble salt of described chlorine Fampridine acid comprises sodium salt, sylvite, ammonium salt, isopropyl amine salt, methylamine salt, dimethylamine salt, alcohol salt, triethanolamine salt, triisopropanolamine salt.
7. the mixed herbicide of chloride Fampridine acid according to claim 1 and haloxyfop-r-methyl, it is characterized in that it with the acid of chlorine Fampridine with haloxyfop-r-methyl for the auxiliary agent that principle active component and agricultural chemicals allow is mixed with any one formulation.
8. chloride Fampridine acid according to claim 7 and the mixed herbicide of haloxyfop-r-methyl, is characterized in that described formulation is missible oil, aqueous emulsion, suspending agent, water dispersible granules, water solube powder, microemulsion, soluble liquid, wetting powder.
9. the application of mixed herbicide in uncultivated area, orchard, forest land, cotton, Rapeseed Field and wheat paddock weeding of chloride Fampridine acid according to claim 1 and haloxyfop-r-methyl.
10. chloride Fampridine acid according to claim 1 is preventing and kill off the application in uncultivated area, orchard, forest land, cotton, Rapeseed Field and wheat paddock in various broad leaved weed with the mixed herbicide of haloxyfop-r-methyl.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310572617.6A CN104621107A (en) | 2013-11-15 | 2013-11-15 | Mixed herbicide containing picloram and haloxyfop-R-methyl |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310572617.6A CN104621107A (en) | 2013-11-15 | 2013-11-15 | Mixed herbicide containing picloram and haloxyfop-R-methyl |
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| CN104621107A true CN104621107A (en) | 2015-05-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310572617.6A Pending CN104621107A (en) | 2013-11-15 | 2013-11-15 | Mixed herbicide containing picloram and haloxyfop-R-methyl |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106818826A (en) * | 2016-12-12 | 2017-06-13 | 安徽常泰化工有限公司 | A kind of crop phytocide composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1416419A (en) * | 2000-01-14 | 2003-05-07 | 美国陶氏益农公司 | 4-aminopicolinates and their use as herbicides |
| US20110190130A1 (en) * | 2010-01-29 | 2011-08-04 | Dow Agrosciences Llc | Synergistic herbicidal composition containing aminopyralid and 2,4-dichlorophenoxyacetic acid |
| CN102711469A (en) * | 2009-11-13 | 2012-10-03 | 陶氏益农公司 | Synergistic herbicidal composition containing aminopyralid and sulfonylureas |
-
2013
- 2013-11-15 CN CN201310572617.6A patent/CN104621107A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1416419A (en) * | 2000-01-14 | 2003-05-07 | 美国陶氏益农公司 | 4-aminopicolinates and their use as herbicides |
| CN102711469A (en) * | 2009-11-13 | 2012-10-03 | 陶氏益农公司 | Synergistic herbicidal composition containing aminopyralid and sulfonylureas |
| US20110190130A1 (en) * | 2010-01-29 | 2011-08-04 | Dow Agrosciences Llc | Synergistic herbicidal composition containing aminopyralid and 2,4-dichlorophenoxyacetic acid |
Non-Patent Citations (1)
| Title |
|---|
| K.C.HARRINGTON ET.AL: "Field assessment of herbicides to release native plants from weeds", 《NEW ZEALAND PLANT PROTECTION》, 31 December 2009 (2009-12-31), pages 368 - 373 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106818826A (en) * | 2016-12-12 | 2017-06-13 | 安徽常泰化工有限公司 | A kind of crop phytocide composition |
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Application publication date: 20150520 |