CN104610930A - Solar water heater - Google Patents

Solar water heater Download PDF

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Publication number
CN104610930A
CN104610930A CN201510052982.3A CN201510052982A CN104610930A CN 104610930 A CN104610930 A CN 104610930A CN 201510052982 A CN201510052982 A CN 201510052982A CN 104610930 A CN104610930 A CN 104610930A
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CN
China
Prior art keywords
oxide
heat
inner housing
solar water
water
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Pending
Application number
CN201510052982.3A
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Chinese (zh)
Inventor
孙建林
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Individual
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Individual
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Priority to CN201510052982.3A priority Critical patent/CN104610930A/en
Publication of CN104610930A publication Critical patent/CN104610930A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/08Materials not undergoing a change of physical state when used
    • C09K5/14Solid materials, e.g. powdery or granular
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24SSOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S60/00Arrangements for storing heat collected by solar heat collectors
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/40Solar thermal energy, e.g. solar towers

Abstract

The invention provides a solar water heater, belongs to the field of solar technologies, and solves the technical problem of short heat accumulation time of the existing solar water heaters. The solar water heater comprises a heat collector and a water tank connected with the heat collector, wherein the heat collector is arranged on a balcony; the water tank is arranged in a room; the water tank comprises an inner shell and an outer shell; the inner shell is fixed on the outer shell, and a gap is formed between the inner shell and the outer shell; a cavity is formed in the inner shell; the inner shell is provided with a water outlet tube and a water inlet tube communicated with the interior cavity; the other end of each of the water outlet tube and the water inlet tube penetrates out of the outer shell. The solar water heater is characterized in that the gap is filled with a heat accumulation material. The solar water heater disclosed by the invention has the advantage of more lasting heat accumulation.

Description

A kind of solar water heater
Technical field
The invention belongs to technical field of solar, relate to a kind of water-heater, particularly a kind of solar water heater.
Background technology
China is coal production state maximum in the world and country of consumption, and coal accounts for 76% of commercial energy resource consumption structure, has become the main source of China's topsoil.The technology that utilizes of Devoting Major Efforts To Developing new and renewable sources of energy will become the important measures reducing environmental pollution.Solar water heater generally comprises heat collector and water tank, the accumulation of heat effect of water tank is one of Main Bottleneck of restriction solar utilization technique, at present, existing water tank general sponge, foam these as heat-storing material, the heat storage performance of these heat-storing materials is poor, in vain waste the energy that heat collector collects.
Summary of the invention
The object of the invention is to there are the problems referred to above for existing technology, propose a kind of solar water heater, this solar water appliance has the feature of accumulation of heat better effects if.
Object of the present invention realizes by following technical proposal: a kind of solar water heater, the water tank comprising heat collector and be connected with heat collector, described heat collector is arranged on balcony, described water tank arranges in house, described water tank comprises inner housing and body skin, described inner housing is fixed on body skin, and between inner housing and body skin, there is gap, described inner housing inside has cavity, described inner housing has the rising pipe and water inlet pipe that are connected with internal cavities, described rising pipe and the other end of water inlet pipe all pass described body skin, it is characterized in that, be filled with heat-storing material in described gap, described heat-storing material it be obtained by the raw material of following weight percent: silicon-dioxide 20 ~ 30%, aluminum oxide 3.9 ~ 7.9%, calcium oxide 0.4 ~ 1.2%, magnesium oxide 0.6 ~ 1.2%, potassium oxide 0.6 ~ 1.2%, sodium oxide 1.2 ~ 1.8%, ferric oxide 0.2 ~ 0.4%, cupric oxide 1.8 ~ 2.0%, cement 1.8 ~ 5%, flyash 2.5 ~ 5.0%, closed perlite microballon 1.5 ~ 2.0%, hydrated barta 0.5 ~ 0.8%, carboxymethyl starch 0.2 ~ 0.5%, sodium acetate trihydrate 5.5 ~ 6.8%, carboxymethyl cellulose 0.1 ~ 0.2%, Magnesium dichloride hexahydrate 0.1 ~ 0.2%, Xylo-Mucine 0.1 ~ 0.2%, surplus is water.
Described silicon-dioxide 25%, aluminum oxide 4.9%, calcium oxide 0.6%, magnesium oxide 0.8%, potassium oxide 0.9%, sodium oxide 1.4%, ferric oxide 0.3%, cupric oxide 1.9%, cement 3.0%, flyash 2.8%, closed perlite microballon 1.8%, hydrated barta 0.6%, carboxymethyl starch 0.3%, sodium acetate trihydrate 6.1%, carboxymethyl cellulose 0.1%, Magnesium dichloride hexahydrate 0.1%, Xylo-Mucine 0.1%, surplus is water.
Described silicon-dioxide 20%, aluminum oxide 3.9%, calcium oxide 0.4%, magnesium oxide 0.6%, potassium oxide 0.6%, sodium oxide 1.2%, ferric oxide 0.2%, cupric oxide 1.8%, cement 1.8%, flyash 2.5%, closed perlite microballon 1.5%, hydrated barta 0.5%, carboxymethyl starch 0.2%, sodium acetate trihydrate 5.5%, carboxymethyl cellulose 0.1%, Magnesium dichloride hexahydrate 0.1%, Xylo-Mucine 0.1%, surplus is water.
Described silicon-dioxide 30%, aluminum oxide 7.9%, calcium oxide 1.2%, magnesium oxide 1.2%, potassium oxide 1.2%, sodium oxide 1.8%, ferric oxide 0.4%, cupric oxide 2.0%, cement 5%, flyash 5.0%, closed perlite microballon 2.0%, hydrated barta 0.8%, carboxymethyl starch 0.5%, sodium acetate trihydrate 6.8%, carboxymethyl cellulose 0.2%, Magnesium dichloride hexahydrate 0.2%, Xylo-Mucine 0.2%, surplus is water.
Be connected mutually by some pipe connectings between described inner housing and body skin.
Heat-storing material is prepared from by the following method, and the method comprises the following steps:
A, preparation agitation vat; Commercially buy an existing agitation vat, the volume of this agitation vat is 10-50L, and this agitation vat has stir shaft and agitating vane, and stir shaft is driven by motor, and agitating vane is fixed on stir shaft;
B, pour starting material into, by silicon-dioxide 20 ~ 30%, aluminum oxide 3.9 ~ 7.9%, calcium oxide 0.4 ~ 1.2%, magnesium oxide 0.6 ~ 1.2%, potassium oxide 0.6 ~ 1.2%, sodium oxide 1.2 ~ 1.8%, ferric oxide 0.2 ~ 0.4%, cupric oxide 1.8 ~ 2.0%, cement 1.8 ~ 5%, flyash 2.5 ~ 5.0%, closed perlite microballon 1.5 ~ 2.0%, hydrated barta 0.5 ~ 0.8%, carboxymethyl starch 0.2 ~ 0.5%, sodium acetate trihydrate 5.5 ~ 6.8%, carboxymethyl cellulose 0.1 ~ 0.2%, Magnesium dichloride hexahydrate 0.1 ~ 0.2%, Xylo-Mucine 0.1 ~ 0.2%, be poured into successively in agitation vat, fall back most,
C, to stir; Stirred to the material in bucket by agitating vane, churning time is 0.5-2 hour;
D, balling-up; Select existing dribbling balling machine on market, be poured in dribbling balling machine by the material stirred, thus form bead one by one, the diameter of this bead is 1-3cm;
E, oven dry; Utilize dryer to be dried by the bead obtained in steps d, obtain the heat-storing material of required solar water container most.
Data illustrate advantage of the present invention by experiment:
Prepare four identical water tanks:
Experimental group 1, fill completely in the heat-storing material made by following ratio in the gap of first water tank, silicon-dioxide 25%, aluminum oxide 4.9%, calcium oxide 0.6%, magnesium oxide 0.8%, potassium oxide 0.9%, sodium oxide 1.4%, ferric oxide 0.3%, cupric oxide 1.9%, cement 3.0%, flyash 2.8%, closed perlite microballon 1.8%, hydrated barta 0.6%, carboxymethyl starch 0.3%, sodium acetate trihydrate 6.1%, carboxymethyl cellulose 0.1%, Magnesium dichloride hexahydrate 0.1%, Xylo-Mucine 0.1%, surplus is water.
Experimental group 2, fill completely in the heat-storing material made by following ratio in the gap of second water tank, silicon-dioxide 20%, aluminum oxide 3.9%, calcium oxide 0.4%, magnesium oxide 0.6%, potassium oxide 0.6%, sodium oxide 1.2%, ferric oxide 0.2%, cupric oxide 1.8%, cement 1.8%, flyash 2.5%, closed perlite microballon 1.5%, hydrated barta 0.5%, carboxymethyl starch 0.2%, sodium acetate trihydrate 5.5%, carboxymethyl cellulose 0.1%, Magnesium dichloride hexahydrate 0.1%, Xylo-Mucine 0.1%, surplus is water.
Experimental group 3, fill completely in the heat-storing material made by following ratio in the gap of the 3rd water tank, silicon-dioxide 30%, aluminum oxide 7.9%, calcium oxide 1.2%, magnesium oxide 1.2%, potassium oxide 1.2%, sodium oxide 1.8%, ferric oxide 0.4%, cupric oxide 2.0%, cement 5%, flyash 5.0%, closed perlite microballon 2.0%, hydrated barta 0.8%, carboxymethyl starch 0.5%, sodium acetate trihydrate 6.8%, carboxymethyl cellulose 0.2%, Magnesium dichloride hexahydrate 0.2%, Xylo-Mucine 0.2%, surplus is water.
Experimental group 4, fills full foam beads as heat-storing material in the gap of the 4th water tank.
Inside the inner housing of four water tanks, add the hot water of 10L, the initial temperature of this hot water is 80 ° simultaneously; By place 7 days record every day temperature value thus make following chart:
From this chart, water tank in this solar water heater is filled with the heat-storing material made by silicon-dioxide, aluminum oxide, calcium oxide, magnesium oxide, potassium oxide, sodium oxide, ferric oxide, cupric oxide, cement, flyash, closed perlite microballon, hydrated barta, carboxymethyl starch, sodium acetate trihydrate, carboxymethyl cellulose, Magnesium dichloride hexahydrate, Xylo-Mucine and water, improve accumulation of heat persistence greatly, more effectively can utilize sun power.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention.
Fig. 2 is the structural representation of water tank.
In figure, A, heat collector; B, water tank; 1, body skin; 11, heat-storing material enters pipe; 12, valve; 2, inner housing; 21, rising pipe; 22, water inlet pipe; 3, heat-storing material; 4, pipe connecting.
Embodiment
Embodiment one:
As depicted in figs. 1 and 2, a kind of solar water heater, the water tank comprising heat collector and be connected with heat collector, described heat collector is arranged on balcony, described water tank arranges in house, described water tank comprises inner housing 2 and body skin 1, described inner housing 2 is fixed on body skin 1 by some pipe connectings 4, and between inner housing 2 and body skin 1, there is gap, inner housing 2 inside has cavity, described inner housing 2 has the rising pipe 21 and water inlet pipe 22 that are connected with internal cavities, described rising pipe 21 and the other end of water inlet pipe 22 all pass described body skin 1, heat-storing material 3 is filled with in described gap, body skin 1 is provided with heat-storing material 3 and enters pipe 11, heat-storing material 3 in gap enters pipe 11 by heat-storing material 3 and enters, be connected with a valve 12 to be used for controlling it and to open in the outer end that heat-storing material 3 enters pipe 11 or close.
In the present embodiment one, heat-storing material 3 it be obtained by the raw material of following weight percent: silicon-dioxide 25%, aluminum oxide 4.9%, calcium oxide 0.6%, magnesium oxide 0.8%, potassium oxide 0.9%, sodium oxide 1.4%, ferric oxide 0.3%, cupric oxide 1.9%, cement 3.0%, flyash 2.8%, closed perlite microballon 1.8%, hydrated barta 0.6%, carboxymethyl starch 0.3%, sodium acetate trihydrate 6.1%, carboxymethyl cellulose 0.1%, Magnesium dichloride hexahydrate 0.1%, Xylo-Mucine 0.1%, surplus is water.
Heat-storing material 3 is prepared from by the following method, and the method comprises the following steps:
A, preparation agitation vat; Commercially buy an existing agitation vat, the volume of this agitation vat is 10-50L, and this agitation vat has stir shaft and agitating vane, and stir shaft is driven by motor, and agitating vane is fixed on stir shaft.
B, pour starting material into; Silicon-dioxide 25%, aluminum oxide 4.9%, calcium oxide 0.6%, magnesium oxide 0.8%, potassium oxide 0.9%, sodium oxide 1.4%, ferric oxide 0.3%, cupric oxide 1.9%, cement 3.0%, flyash 2.8%, closed perlite microballon 1.8%, hydrated barta 0.6%, carboxymethyl starch 0.3%, sodium acetate trihydrate 6.1%, carboxymethyl cellulose 0.1%, Magnesium dichloride hexahydrate 0.1%, Xylo-Mucine 0.1% are poured in agitation vat successively, fall back most;
C, to stir; Stirred to the material in bucket by agitating vane, churning time is 0.5-2 hour;
D, balling-up; Select existing dribbling balling machine on market, be poured in dribbling balling machine by the material stirred, thus form bead one by one, the diameter of this bead is 1-3cm;
E, oven dry; Utilize dryer to be dried by the bead obtained in steps d, obtain the heat-storing material 3 of required solar water container most.
Embodiment two:
As depicted in figs. 1 and 2, a kind of solar water heater, the water tank comprising heat collector and be connected with heat collector, described heat collector is arranged on balcony, described water tank arranges in house, described water tank comprises inner housing 2 and body skin 1, described inner housing 2 is fixed on body skin 1 by some pipe connectings 4, and between inner housing 2 and body skin 1, there is gap, inner housing 2 inside has cavity, described inner housing 2 has the rising pipe 21 and water inlet pipe 22 that are connected with internal cavities, described rising pipe 21 and the other end of water inlet pipe 22 all pass described body skin 1, heat-storing material 3 is filled with in described gap, body skin 1 is provided with heat-storing material 3 and enters pipe 11, heat-storing material 3 in gap enters pipe 11 by heat-storing material 3 and enters, be connected with a valve 12 to be used for controlling it and to open in the outer end that heat-storing material 3 enters pipe 11 or close.Heat-storing material 3 it be obtained by the raw material of following weight percent: silicon-dioxide 20%, aluminum oxide 3.9%, calcium oxide 0.4%, magnesium oxide 0.6%, potassium oxide 0.6%, sodium oxide 1.2%, ferric oxide 0.2%, cupric oxide 1.8%, cement 1.8%, flyash 2.5%, closed perlite microballon 1.5%, hydrated barta 0.5%, carboxymethyl starch 0.2%, sodium acetate trihydrate 5.5%, carboxymethyl cellulose 0.1%, Magnesium dichloride hexahydrate 0.1%, Xylo-Mucine 0.1%, surplus is water.
Embodiment three:
As depicted in figs. 1 and 2, a kind of solar water heater, the water tank comprising heat collector and be connected with heat collector, described heat collector is arranged on balcony, described water tank arranges in house, described water tank comprises inner housing 2 and body skin 1, described inner housing 2 is fixed on body skin 1 by some pipe connectings 4, and between inner housing 2 and body skin 1, there is gap, inner housing 2 inside has cavity, described inner housing 2 has the rising pipe 21 and water inlet pipe 22 that are connected with internal cavities, described rising pipe 21 and the other end of water inlet pipe 22 all pass described body skin 1, heat-storing material 3 is filled with in described gap, body skin 1 is provided with heat-storing material 3 and enters pipe 11, heat-storing material 3 in gap enters pipe 11 by heat-storing material 3 and enters, be connected with a valve 12 to be used for controlling it and to open in the outer end that heat-storing material 3 enters pipe 11 or close.Heat-storing material 3 it be obtained by the raw material of following weight percent: silicon-dioxide 30%, aluminum oxide 7.9%, calcium oxide 1.2%, magnesium oxide 1.2%, potassium oxide 1.2%, sodium oxide 1.8%, ferric oxide 0.4%, cupric oxide 2.0%, cement 5%, flyash 5.0%, closed perlite microballon 2.0%, hydrated barta 0.8%, carboxymethyl starch 0.5%, sodium acetate trihydrate 6.8%, carboxymethyl cellulose 0.2%, Magnesium dichloride hexahydrate 0.2%, Xylo-Mucine 0.2%, surplus is water.

Claims (5)

1. a solar water heater, the water tank comprising heat collector and be connected with heat collector, described heat collector is arranged on balcony, described water tank arranges in house, described water tank comprises inner housing and body skin, described inner housing is fixed on body skin, and between inner housing and body skin, there is gap, described inner housing inside has cavity, described inner housing has the rising pipe and water inlet pipe that are connected with internal cavities, described rising pipe and the other end of water inlet pipe all pass described body skin, it is characterized in that, be filled with heat-storing material in described gap, described heat-storing material it be obtained by the raw material of following weight percent: silicon-dioxide 20 ~ 30%, aluminum oxide 3.9 ~ 7.9%, calcium oxide 0.4 ~ 1.2%, magnesium oxide 0.6 ~ 1.2%, potassium oxide 0.6 ~ 1.2%, sodium oxide 1.2 ~ 1.8%, ferric oxide 0.2 ~ 0.4%, cupric oxide 1.8 ~ 2.0%, cement 1.8 ~ 5%, flyash 2.5 ~ 5.0%, closed perlite microballon 1.5 ~ 2.0%, hydrated barta 0.5 ~ 0.8%, carboxymethyl starch 0.2 ~ 0.5%, sodium acetate trihydrate 5.5 ~ 6.8%, carboxymethyl cellulose 0.1 ~ 0.2%, Magnesium dichloride hexahydrate 0.1 ~ 0.2%, Xylo-Mucine 0.1 ~ 0.2%, surplus is water.
2. solar water heater according to claim 1, it is characterized in that, described silicon-dioxide 20%, aluminum oxide 3.9%, calcium oxide 0.4%, magnesium oxide 0.6%, potassium oxide 0.6%, sodium oxide 1.2%, ferric oxide 0.2%, cupric oxide 1.8%, cement 1.8%, flyash 2.5%, closed perlite microballon 1.5%, hydrated barta 0.5%, carboxymethyl starch 0.2%, sodium acetate trihydrate 5.5%, carboxymethyl cellulose 0.1%, Magnesium dichloride hexahydrate 0.1%, Xylo-Mucine 0.1%, surplus is water.
3. solar water heater according to claim 1, it is characterized in that, described silicon-dioxide 30%, aluminum oxide 7.9%, calcium oxide 1.2%, magnesium oxide 1.2%, potassium oxide 1.2%, sodium oxide 1.8%, ferric oxide 0.4%, cupric oxide 2.0%, cement 5%, flyash 5.0%, closed perlite microballon 2.0%, hydrated barta 0.8%, carboxymethyl starch 0.5%, sodium acetate trihydrate 6.8%, carboxymethyl cellulose 0.2%, Magnesium dichloride hexahydrate 0.2%, Xylo-Mucine 0.2%, surplus is water.
4. solar water heater according to claim 1, is characterized in that, is connected mutually between described inner housing and body skin by some pipe connectings.
5. solar water heater according to claim 1, is characterized in that, heat-storing material is prepared from by the following method, and the method comprises the following steps:
A, preparation agitation vat; Commercially buy an existing agitation vat, the volume of this agitation vat is 10-50L, and this agitation vat has stir shaft and agitating vane, and stir shaft is driven by motor, and agitating vane is fixed on stir shaft;
B, pour starting material into, by silicon-dioxide 20 ~ 30%, aluminum oxide 3.9 ~ 7.9%, calcium oxide 0.4 ~ 1.2%, magnesium oxide 0.6 ~ 1.2%, potassium oxide 0.6 ~ 1.2%, sodium oxide 1.2 ~ 1.8%, ferric oxide 0.2 ~ 0.4%, cupric oxide 1.8 ~ 2.0%, cement 1.8 ~ 5%, flyash 2.5 ~ 5.0%, closed perlite microballon 1.5 ~ 2.0%, hydrated barta 0.5 ~ 0.8%, carboxymethyl starch 0.2 ~ 0.5%, sodium acetate trihydrate 5.5 ~ 6.8%, carboxymethyl cellulose 0.1 ~ 0.2%, Magnesium dichloride hexahydrate 0.1 ~ 0.2%, Xylo-Mucine 0.1 ~ 0.2%, be poured into successively in agitation vat, fall back most,
C, to stir; Stirred to the material in bucket by agitating vane, churning time is 0.5-2 hour;
D, balling-up; Select existing dribbling balling machine on market, be poured in dribbling balling machine by the material stirred, thus form bead one by one, the diameter of this bead is 1-3cm;
E, oven dry; Utilize dryer to be dried by the bead obtained in steps d, obtain the heat-storing material of required solar water container most.
CN201510052982.3A 2015-02-02 2015-02-02 Solar water heater Pending CN104610930A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106556255A (en) * 2016-09-26 2017-04-05 西安建筑科技大学 A kind of heat-storing material, preparation method and applications
CN109233753A (en) * 2018-12-03 2019-01-18 安徽恒明工程技术有限公司 A kind of phase change heat storage material and preparation method thereof
CN110945965A (en) * 2017-06-01 2020-03-31 金叡院 Radiator with heating device

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3910356A1 (en) * 1988-03-30 1989-10-19 Nikolaos Dr Malatidis PCM device
CN2155532Y (en) * 1993-05-12 1994-02-09 韩进富 Sealed solar heat-collecting water-tank made of ceramic
CN2362064Y (en) * 1999-02-12 2000-02-02 黄永年 Pressure-bearing glass vacuum-tube solar water heater
CN101113323A (en) * 2007-08-02 2008-01-30 刘光文 Foam heat storage and method for preparing the same
US20110253126A1 (en) * 2010-04-15 2011-10-20 Huiming Yin Net Zero Energy Building System
CN102337105A (en) * 2010-07-26 2012-02-01 李宙确 Phase-change thermal storage material

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3910356A1 (en) * 1988-03-30 1989-10-19 Nikolaos Dr Malatidis PCM device
CN2155532Y (en) * 1993-05-12 1994-02-09 韩进富 Sealed solar heat-collecting water-tank made of ceramic
CN2362064Y (en) * 1999-02-12 2000-02-02 黄永年 Pressure-bearing glass vacuum-tube solar water heater
CN101113323A (en) * 2007-08-02 2008-01-30 刘光文 Foam heat storage and method for preparing the same
US20110253126A1 (en) * 2010-04-15 2011-10-20 Huiming Yin Net Zero Energy Building System
CN102337105A (en) * 2010-07-26 2012-02-01 李宙确 Phase-change thermal storage material

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106556255A (en) * 2016-09-26 2017-04-05 西安建筑科技大学 A kind of heat-storing material, preparation method and applications
CN110945965A (en) * 2017-06-01 2020-03-31 金叡院 Radiator with heating device
CN110945965B (en) * 2017-06-01 2022-02-15 金叡院 Radiator with heating device
CN109233753A (en) * 2018-12-03 2019-01-18 安徽恒明工程技术有限公司 A kind of phase change heat storage material and preparation method thereof

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Application publication date: 20150513