CN104610590A - Rubber sheath for automobiles - Google Patents
Rubber sheath for automobiles Download PDFInfo
- Publication number
- CN104610590A CN104610590A CN201510049085.7A CN201510049085A CN104610590A CN 104610590 A CN104610590 A CN 104610590A CN 201510049085 A CN201510049085 A CN 201510049085A CN 104610590 A CN104610590 A CN 104610590A
- Authority
- CN
- China
- Prior art keywords
- parts
- rubber sheath
- aging agent
- carbon black
- nano titanium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a rubber sheath for automobiles, and relates to the technical field of sealing materials. The rubber sheath for automobiles disclosed by the invention is prepared from the following raw materials in parts by weight: 60-80 parts of natural rubber, 10-16 parts of stearate, 5-15 parts of an antiager, 2-8 parts of polyvinyl chloride, 10-20 parts of methylsilicone oil, 3-12 parts of carbon black, 5-12 parts of pine tar, 1-5 parts of an accelerant, and 1-6 parts of nano titanium dioxide. The rubber sheath for automobiles disclosed by the invention is low in production cost, and obtained products have good elasticity, ozone resistance, aging resistance, oil resistance and bonding properties, and long service life.
Description
Technical field
The present invention relates to sealing material technical field, especially a kind of automobile rubber sheath.
Background technology
Automobile industry competition, and the reliability requirement of human consumer to automobile is higher, although Hyundai Motor all improves constantly in the performance and configuration of entirety, the impact of automobile component on automobile can not be ignored equally.Automobile rubber sheath mainly comprises Automobile engine front cabin rubber sheath, automobile motor wire harness rubber sheath and automobile gimbal sheath etc.Automobile rubber sheath not only can improve aesthetics and constraint effect, and can extend the work-ing life of internal product.But due to raw material, manufacturing process or human factor, often there is aging, distortion, the situation such as damaged in most automobile rubber sheath in the market.
Summary of the invention
The object of this invention is to provide a kind of automobile rubber sheath, this automobile rubber sheath can solve easily aging, the distortion of existing rubber sheath, damaged problem.
In order to solve the problem, the technical solution used in the present invention is:
Automobile rubber sheath of the present invention is prepared from by the raw material of following parts by weight: natural rubber 60 parts ~ 80 parts, stearic acid 10 parts ~ 16 parts, 5 parts ~ 15 parts, anti-aging agent, polyvinyl chloride 2 parts ~ 8 parts, methyl-silicone oil 10 parts ~ 20 parts, carbon black 3 parts ~ 12 parts, Stockholm tar 5 parts ~ 12 parts, promotor 1 part ~ 5 parts, nano titanium oxide 1 part ~ 6 parts.
In technique scheme, scheme can also be more specifically:
The parts by weight of raw material are: natural rubber 60 parts, stearic acid 16 parts, 5 parts, anti-aging agent, polyvinyl chloride 2 parts, methyl-silicone oil 15 parts, carbon black 3 parts, Stockholm tar 5 parts, promotor 1 part, nano titanium oxide 3 parts.
Further, the parts by weight of raw material are: natural rubber 70 parts, stearic acid 13 parts, 10 parts, anti-aging agent, polyvinyl chloride 5 parts, methyl-silicone oil 10 parts, carbon black 7 parts, Stockholm tar 8 parts, promotor 3 parts, nano titanium oxide 6 parts.
Further, the parts by weight of raw material are: natural rubber 80 parts, stearic acid 10 parts, 15 parts, anti-aging agent, polyvinyl chloride 8 parts, methyl-silicone oil 20 parts, carbon black 12 parts, Stockholm tar 12 parts, promotor 5 parts, nano titanium oxide 1 part.
Further, anti-aging agent is N-Phenyl beta naphthylamine and blend of p phenylene diamine, and wherein, the mass ratio of N-Phenyl beta naphthylamine and Ursol D is 1:1.
Further, promotor is trolamine.
Owing to have employed technique scheme, the present invention compared with prior art has following beneficial effect:
Automobile rubber sheath of the present invention take natural rubber as basic raw material, auxiliary with stearic acid, anti-aging agent, promotor, polyvinyl chloride, methyl-silicone oil, carbon black, Stockholm tar, promotor and nano titanium oxide, production cost is low, products obtained therefrom has good elasticity and resistance to ozone and ageing-resistant performance, oil resistance and adhesive property, and work-ing life is longer.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
Embodiment 1
The present embodiment automobile rubber sheath is prepared from by the raw material of following parts by weight: natural rubber 60 parts, stearic acid 16 parts, 5 parts, anti-aging agent, polyvinyl chloride 2 parts, methyl-silicone oil 15 parts, carbon black 3 parts, Stockholm tar 5 parts, trolamine 1 part, nano titanium oxide 3 parts; Anti-aging agent in the present embodiment is N-Phenyl beta naphthylamine and blend of p phenylene diamine, and the mass ratio of N-Phenyl beta naphthylamine and Ursol D is 1:1.
Preparation method is: take each raw material by above-mentioned parts by weight, natural rubber, stearic acid, anti-aging agent, methyl-silicone oil, carbon black, Stockholm tar, nano titanium oxide are mixed, control temperature is at 80 DEG C, carry out once mixing 20 minutes, then proceed to mill, add trolamine, control temperature is 60 DEG C, mixing 5 minutes of secondary, lamination plastic emitting obtains finished product.
Embodiment 2
The present embodiment automobile rubber sheath is prepared from by the raw material of following parts by weight: natural rubber 70 parts, stearic acid 13 parts, 10 parts, anti-aging agent, polyvinyl chloride 5 parts, methyl-silicone oil 10 parts, carbon black 7 parts, Stockholm tar 8 parts, trolamine 3 parts, nano titanium oxide 6 parts; Anti-aging agent in the present embodiment is N-Phenyl beta naphthylamine and blend of p phenylene diamine, and the mass ratio of N-Phenyl beta naphthylamine and Ursol D is 1:1.
Preparation method is: take each raw material by above-mentioned parts by weight, natural rubber, stearic acid, anti-aging agent, methyl-silicone oil, carbon black, Stockholm tar, nano titanium oxide are mixed, control temperature is at 85 DEG C, carry out once mixing 15 minutes, then proceed to mill, add trolamine, control temperature is 65 DEG C, mixing 3 minutes of secondary, lamination plastic emitting obtains finished product.
Embodiment 3
The present embodiment automobile rubber sheath is prepared from by the raw material of following parts by weight: natural rubber 80 parts, stearic acid 10 parts, 15 parts, anti-aging agent, polyvinyl chloride 8 parts, methyl-silicone oil 20 parts, carbon black 12 parts, Stockholm tar 12 parts, trolamine 5 parts, nano titanium oxide 1 part; Anti-aging agent in the present embodiment is N-Phenyl beta naphthylamine and blend of p phenylene diamine, and the mass ratio of N-Phenyl beta naphthylamine and Ursol D is 1:1.
Preparation method is: take each raw material by above-mentioned parts by weight, natural rubber, stearic acid, anti-aging agent, methyl-silicone oil, carbon black, Stockholm tar, nano titanium oxide are mixed, control temperature is at 78 DEG C, carry out once mixing 20 minutes, then proceed to mill, add trolamine, control temperature is 65 DEG C, mixing 5 minutes of secondary, lamination plastic emitting obtains finished product.
Respectively to embodiment 1, in embodiment 2 and embodiment 3, gained automobile rubber sheath detects, and the results are shown in Table 1:
The product performance of table 1 automobile rubber sheath
Claims (6)
1. an automobile rubber sheath, it is characterized in that being prepared from by the raw material of following parts by weight: natural rubber 60 parts ~ 80 parts, stearic acid 10 parts ~ 16 parts, 5 parts ~ 15 parts, anti-aging agent, polyvinyl chloride 2 parts ~ 8 parts, methyl-silicone oil 10 parts ~ 20 parts, carbon black 3 parts ~ 12 parts, Stockholm tar 5 parts ~ 12 parts, promotor 1 part ~ 5 parts, nano titanium oxide 1 part ~ 6 parts.
2. automobile rubber sheath according to claim 1, is characterized in that the parts by weight of described raw material are: natural rubber 60 parts, stearic acid 16 parts, 5 parts, anti-aging agent, polyvinyl chloride 2 parts, methyl-silicone oil 15 parts, carbon black 3 parts, Stockholm tar 5 parts, promotor 1 part, nano titanium oxide 3 parts.
3. automobile rubber sheath according to claim 1, is characterized in that the parts by weight of described raw material are: natural rubber 70 parts, stearic acid 13 parts, 10 parts, anti-aging agent, polyvinyl chloride 5 parts, methyl-silicone oil 10 parts, carbon black 7 parts, Stockholm tar 8 parts, promotor 3 parts, nano titanium oxide 6 parts.
4. automobile rubber sheath according to claim 1, is characterized in that the parts by weight of described raw material are: natural rubber 80 parts, stearic acid 10 parts, 15 parts, anti-aging agent, polyvinyl chloride 8 parts, methyl-silicone oil 20 parts, carbon black 12 parts, Stockholm tar 12 parts, promotor 5 parts, nano titanium oxide 1 part.
5. the automobile rubber sheath according to claim 1 or 2 or 3 or 4, is characterized in that described anti-aging agent is N-Phenyl beta naphthylamine and blend of p phenylene diamine, and wherein, the mass ratio of N-Phenyl beta naphthylamine and Ursol D is 1:1.
6. the automobile rubber sheath according to claim 1 or 2 or 3 or 4, is characterized in that described promotor is trolamine.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510049085.7A CN104610590A (en) | 2015-01-30 | 2015-01-30 | Rubber sheath for automobiles |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510049085.7A CN104610590A (en) | 2015-01-30 | 2015-01-30 | Rubber sheath for automobiles |
Publications (1)
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CN104610590A true CN104610590A (en) | 2015-05-13 |
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Family Applications (1)
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CN201510049085.7A Pending CN104610590A (en) | 2015-01-30 | 2015-01-30 | Rubber sheath for automobiles |
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Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105482301A (en) * | 2015-12-22 | 2016-04-13 | 芜湖恒坤汽车部件有限公司 | High-temperature resistant rubber ring material composition and preparation method of high-temperature resistant rubber ring |
CN105885127A (en) * | 2016-06-13 | 2016-08-24 | 芜湖卓越线束系统有限公司 | Anti-aging automobile motor controller wire harness and preparing method thereof |
CN105885125A (en) * | 2016-06-13 | 2016-08-24 | 芜湖卓越线束系统有限公司 | Antibacterial automobile back door wire harness and preparing method thereof |
CN105885126A (en) * | 2016-06-13 | 2016-08-24 | 芜湖卓越线束系统有限公司 | Antibacterial cabin wire harness and preparing method thereof |
CN105906857A (en) * | 2016-06-13 | 2016-08-31 | 芜湖卓越线束系统有限公司 | Antibacterial rubber for automobile back door wire harnesses and preparation method thereof |
CN105906858A (en) * | 2016-06-13 | 2016-08-31 | 芜湖卓越线束系统有限公司 | Automobile left front door wiring harness and preparation method thereof |
CN105906856A (en) * | 2016-06-13 | 2016-08-31 | 芜湖卓越线束系统有限公司 | Antibacterial rubber for cabin wire harnesses and preparation method thereof |
CN105924692A (en) * | 2016-06-13 | 2016-09-07 | 芜湖卓越线束系统有限公司 | Antibacterial rubber applicable to automobile instrument wiring harness and preparation method of automobile instrument wiring harness |
CN105924693A (en) * | 2016-06-13 | 2016-09-07 | 芜湖卓越线束系统有限公司 | Antibacterial automobile instrument wire harness and preparation method thereof |
CN106084315A (en) * | 2016-06-13 | 2016-11-09 | 芜湖卓越线束系统有限公司 | Antibacterial automobile storage battery wire harness and preparation method thereof |
CN106084319A (en) * | 2016-06-13 | 2016-11-09 | 芜湖卓越线束系统有限公司 | Antibacterial rubber for Automobile Right Qianmen wire harness and preparation method thereof |
CN108976492A (en) * | 2018-07-02 | 2018-12-11 | 芜湖航天特种电缆厂股份有限公司 | Cold resistance cable insulation and preparation method thereof |
CN108976490A (en) * | 2018-07-02 | 2018-12-11 | 芜湖航天特种电缆厂股份有限公司 | Cold-resistant cable and preparation method thereof |
Citations (3)
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CN1263907A (en) * | 2000-03-06 | 2000-08-23 | 陈广田 | Fragrant compound plastic plate for driver's cab of car |
JP2002146087A (en) * | 2000-11-15 | 2002-05-22 | Tokai Kogyo Co Ltd | Decorative material and method for producing the same |
CN102924766A (en) * | 2012-11-26 | 2013-02-13 | 山东忠诚橡胶有限公司 | Mixed rubber for manufacturing rubber |
-
2015
- 2015-01-30 CN CN201510049085.7A patent/CN104610590A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1263907A (en) * | 2000-03-06 | 2000-08-23 | 陈广田 | Fragrant compound plastic plate for driver's cab of car |
JP2002146087A (en) * | 2000-11-15 | 2002-05-22 | Tokai Kogyo Co Ltd | Decorative material and method for producing the same |
CN102924766A (en) * | 2012-11-26 | 2013-02-13 | 山东忠诚橡胶有限公司 | Mixed rubber for manufacturing rubber |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105482301A (en) * | 2015-12-22 | 2016-04-13 | 芜湖恒坤汽车部件有限公司 | High-temperature resistant rubber ring material composition and preparation method of high-temperature resistant rubber ring |
CN105885127A (en) * | 2016-06-13 | 2016-08-24 | 芜湖卓越线束系统有限公司 | Anti-aging automobile motor controller wire harness and preparing method thereof |
CN105885125A (en) * | 2016-06-13 | 2016-08-24 | 芜湖卓越线束系统有限公司 | Antibacterial automobile back door wire harness and preparing method thereof |
CN105885126A (en) * | 2016-06-13 | 2016-08-24 | 芜湖卓越线束系统有限公司 | Antibacterial cabin wire harness and preparing method thereof |
CN105906857A (en) * | 2016-06-13 | 2016-08-31 | 芜湖卓越线束系统有限公司 | Antibacterial rubber for automobile back door wire harnesses and preparation method thereof |
CN105906858A (en) * | 2016-06-13 | 2016-08-31 | 芜湖卓越线束系统有限公司 | Automobile left front door wiring harness and preparation method thereof |
CN105906856A (en) * | 2016-06-13 | 2016-08-31 | 芜湖卓越线束系统有限公司 | Antibacterial rubber for cabin wire harnesses and preparation method thereof |
CN105924692A (en) * | 2016-06-13 | 2016-09-07 | 芜湖卓越线束系统有限公司 | Antibacterial rubber applicable to automobile instrument wiring harness and preparation method of automobile instrument wiring harness |
CN105924693A (en) * | 2016-06-13 | 2016-09-07 | 芜湖卓越线束系统有限公司 | Antibacterial automobile instrument wire harness and preparation method thereof |
CN106084315A (en) * | 2016-06-13 | 2016-11-09 | 芜湖卓越线束系统有限公司 | Antibacterial automobile storage battery wire harness and preparation method thereof |
CN106084319A (en) * | 2016-06-13 | 2016-11-09 | 芜湖卓越线束系统有限公司 | Antibacterial rubber for Automobile Right Qianmen wire harness and preparation method thereof |
CN108976492A (en) * | 2018-07-02 | 2018-12-11 | 芜湖航天特种电缆厂股份有限公司 | Cold resistance cable insulation and preparation method thereof |
CN108976490A (en) * | 2018-07-02 | 2018-12-11 | 芜湖航天特种电缆厂股份有限公司 | Cold-resistant cable and preparation method thereof |
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Application publication date: 20150513 |
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