CN104595877B - Multi-step pressure reduction reclaims the device and its recovery method of hot waste water waste heat - Google Patents

Multi-step pressure reduction reclaims the device and its recovery method of hot waste water waste heat Download PDF

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Publication number
CN104595877B
CN104595877B CN201510022450.5A CN201510022450A CN104595877B CN 104595877 B CN104595877 B CN 104595877B CN 201510022450 A CN201510022450 A CN 201510022450A CN 104595877 B CN104595877 B CN 104595877B
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waste water
level
pressure reduction
vacuum flashing
blender
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CN104595877A (en
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王伟东
赵建涛
吴勃
黄海
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Xi'an Yizhong Environmental Protection Industry Co ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

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  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Physical Water Treatments (AREA)

Abstract

Multi-step pressure reduction reclaims the device and its recovery method of hot waste water waste heat.Heat-exchange apparatus easily causes heat exchange pipeline to block, cause system be unable to long-term operation and cleaning difficulty it is big.The composition of the present invention includes:Multi-step pressure reduction tower(1), multi-step pressure reduction tower is interior to be provided with one-level vacuum flashing device(2), second depressurized flash vessel(3), three-level vacuum flashing device(4), one-level blender(5), secondary mixer(6), three-level blender(7);Foam removal brokenly bubble plate is provided with vacuum flashing device(8), flash vessel column plate(9), foam removal brokenly bubble plate top is provided with saturated vapor outlet(10);By dividing plate between blender(11)Separate, top is provided with heated waste water import(12), bottom is exported provided with heated waste water(13);Saturated vapor outlet, heated waste water import and Venturi transmission ejector(2)Connection, heated waste water outlet passes through waste water circulation pump(3)It is connected with Venturi transmission ejector.The present invention is used to reclaim hot waste water waste heat.

Description

Multi-step pressure reduction reclaims the device and its recovery method of hot waste water waste heat
Technical field:
The present invention relates to the device and its recovery method that a kind of multi-step pressure reduction reclaims hot waste water waste heat.
Background technology:
The industrial circles such as the coal chemical industry, petrochemical industry, electric power, papermaking, printing and dyeing of China discharge substantial amounts of hot waste water, and its is net Change process is related to the processes such as extraction, distillation, absorption, biochemical treatment, and different workshop sections are different to temperature requirement, it is necessary to frequently lifting Temperature, causes the energy consumption of sewage disposal very high.For example, the high temperature produced in coal chemical technology, pressurization static bed lurgi gasifier gasification Sewage, temperature reaches 140-200 DEG C, to reach that discharge standard must be by stripping deamination and desulfurization, extracting and dephenolizing, biochemical treatment, activity The processes such as charcoal absorption, energy consumption and operating cost are high, and production cost remains high.How to ensure that coal gasification wastewater processing is up to standard Meanwhile, the problem of reduction sewage disposal energy consumption is urgent solves.Currently, energy-conserving and environment-protective turn into Sustainable Socioeconomic Development Focal issue, requirement of the China to wastewater discharge standard is increasingly improved, waste water treatment process technical requirements also more and more higher how The energy consumption of reduction system is the problem of enterprise must take into consideration, and is also to evaluate the advanced key index of water technology.
The heat recovery of high temperature sewage can significantly energy resource consumption, improve energy utilization rate, with very high environmental protection Benefit and economic benefit.The heat-exchange apparatus of pipe heat exchanger and use heat pump principle is generally to use waste heat recovery plant, but Salt, organic-flocculation thing that bulky grain, suspended impurity, low temperature in sewage are separated out etc. easily causes heat exchange pipeline fouling, blocking, System is caused to be unable to long-term operation, and cleaning difficulty is big, workload is big, working environment is poor.
The content of the invention:
It is an object of the invention to provide the device and its recovery method that a kind of multi-step pressure reduction reclaims hot waste water waste heat.
Above-mentioned purpose is realized by following technical scheme:
A kind of multi-step pressure reduction reclaims the device of hot waste water waste heat, and its composition includes:Multi-step pressure reduction tower, described multistage subtracts One-level vacuum flashing device, second depressurized flash vessel, three-level vacuum flashing device, one-level mixing are sequentially provided with pressure tower from top to bottom Device, secondary mixer, three-level blender;Described one-level, two grades, the top of three-level vacuum flashing device be provided with foam removal brokenly bubble plate, Bottom is provided with above flash vessel column plate, described foam removal brokenly bubble plate provided with saturated vapor outlet;Described one-level, two grades, three-level Separated between blender by dividing plate, top is provided with heated waste water import, bottom is exported provided with heated waste water;Described saturated vapor Outlet, described heated waste water import be connecteds with Venturi transmission ejector, described heated waste water outlet pass through waste water circulation pump and Described Venturi transmission ejector connection.
Described multi-step pressure reduction reclaims useless provided with high temperature in the device of hot waste water waste heat, described one-level vacuum flashing device Water distributor, described hot waste water distributor is connected with hot waste water import.
Described multi-step pressure reduction reclaims the device of hot waste water waste heat, the sudden strain of a muscle in described one-level, second depressurized flash vessel The bottom of steaming device column plate is connected with down-comer.
Described multi-step pressure reduction reclaims the flash vessel tower in the device of hot waste water waste heat, described three-level vacuum flashing device Plate bottom is provided with high temperature sewage draining exit.
Described multi-step pressure reduction reclaims the device of hot waste water waste heat, and described hot waste water distributor can be shower nozzle And/or antipriming pipe, pressure drop 1-20KPa.
Described multi-step pressure reduction reclaims the device of hot waste water waste heat, and described foam removal brokenly bubble plate can be porous plate, silk Net or packing layer.
Described multi-step pressure reduction reclaims flash vessel and mixing in the device of hot waste water waste heat, described multi-step pressure reduction tower The series of device can be set as 1-6 grades according to technological requirement.
A kind of described multi-step pressure reduction reclaims the recovery method of the device of hot waste water waste heat, and this method step is as follows:
Hot waste water of the temperature higher than 70 DEG C enters first order vacuum flashing from the hot waste water distributor of multi-step pressure reduction tower Device;The low-temperature wastewater of temperature to be heated less than 60 DEG C, by Venturi transmission ejector, aspirates multi-step pressure reduction tower with 1-5m/s flow velocitys The low-pressure steam produced in third level vacuum flashing device, waste water is mixed with steam, and low-temperature wastewater temperature improves 10-50 DEG C and flowed into Multi-step pressure reduction tower bottom first order blender;
Waste water in first order blender is through waste water circulation pump, with 1-5m/s flow velocitys by Venturi transmission ejector, suction the The low-pressure steam that second depressurized level flash vessel is produced, waste water mix with steam, 10-50 DEG C of entrance tower bottom of wastewater temperature raising the Secondary mixer;The saturation water of second level vacuum flashing device flows into third level vacuum flashing device by down-comer;
Waste water in the blender of the second level is passed through in Venturi transmission ejector, suction through waste water circulation pump with 1-5m/s flow velocitys The low-pressure steam that multi-step pressure reduction tower first order vacuum flashing device is produced, waste water is mixed with steam, and wastewater temperature improves 10-50 DEG C and entered Enter tower bottom third level blender;The saturation water of first order vacuum flashing device flows into second level vacuum flashing device by down-comer;
Waste water after being heated in bottom of towe blender flows out from delivery port, into next processing workshop section;Heat is reclaimed in vacuum flashing Hot waste water after amount processing, flows out from the sewage draining exit of third level vacuum flashing device bottom, send treatment and finishing section.
Beneficial effects of the present invention:
The present invention proposes the heat recovering process that the method flashed using multi-step pressure reduction carries out high temperature sewage, hot waste water Flashed through multi-step pressure reduction, contained high temperature sensible heat is converted into saturated vapor latent heat step by step, Venturi transmission ejector is provided needed for flash distillation Vacuum, while saturated vapor is mixed in Venturi transmission ejector with waste water to be heated, heating low-temperature wastewater is to certain Temperature, so as to reach recovery waste water residual heat, reduces the purpose of the energy consumption of heated waste water, reduction unit sewage disposal energy consumption 30- 80%。
The present invention realizes the heat exchange of high temperature sewage and pretreating sewage by the way of step heat exchange of flash evaporation, solves often Advise the shortcoming that heat exchanger reclaims the easy fouling and clogging of pipeline during heat;The main equipment of invention is with multistage flash evaporation function Low Pressure Flashing Column, the equipment is made up of multilayer column plate and inner member, and flash column top is multistage flash evaporation section, and bottom is Hybrid Heating The series of section, flash zone and mixing section can be set according to technological requirement;The suction and mixing of flash column combination Venturi transmission ejector The sensible heat of hot waste water, is converted into the latent heat of saturated vapor by effect step by step, heats pending low-temperature sewage, reaches energy-conservation drop Consumption, and low, the stable purpose of system investments.
The present invention reclaims the sensible heat of high temperature sewage, low-pressure steam cleaning, process heat exchange effect using multi-step pressure reduction flash evaporation Rate is high;The pollutant that hot waste water vacuum flashing temperature-fall period is separated out can be discharged along down-comer, and the blocking of pipeline is not easily caused, real The long-period stable operation of existing equipment;Multistage flash evaporator and blender combination are in a tower, compact equipment, occupation of land face Product is small;Operational control is simple, and production capacity is big.
The present invention is suitable for handling the processing procedure of coal chemical industry high-temperature wash waste water, in stripping deamination depickling-extracting and dephenolizing In technical process, high temperature sewage can be effectively reclaimed, reduction System steam consumption realizes macrocyclic stable operation, is coal chemical industry The energy-saving of wastewater treatment process provides feasible technology path, it can also be used to the sewage of the industry such as petrochemical industry, printing and dyeing, papermaking Processing procedure, be particularly suitable for use in the solubility salt containing high concentration, flocculate, organic matter, it is easy to which low temperature, which is separated out, causes pipeline Fouling, the energy recovery process of the hot industry waste water blocked, alternative common pipe heat exchanger reduce unit sewage disposal Energy consumption more than 50%, has the advantages that heat recovery efficiency height, long-period stable operation.
Brief description of the drawings:
Accompanying drawing 1 is the process chart of the present invention.
Accompanying drawing 2 is the structural representation of multi-step pressure reduction tower of the present invention.
Embodiment:
Embodiment 1:
A kind of multi-step pressure reduction reclaims the device of hot waste water waste heat, and its composition includes:Multi-step pressure reduction tower 1, described multistage One-level vacuum flashing device 4, second depressurized flash vessel 5, three-level vacuum flashing device 6, one-level are sequentially provided with vacuum tower from top to bottom Blender 7, secondary mixer 8, three-level blender 9;Described one-level, two grades, the top of three-level vacuum flashing device be provided with foam removal Brokenly bubble plate 10, bottom is provided with above flash vessel column plate 11, described foam removal brokenly bubble plate provided with saturated vapor outlet 12;Described one Level, two grades, separated by dividing plate 13 between three-level blender, top is provided with heated waste water import 14, and bottom goes out provided with heated waste water Mouth 15;Described saturated vapor is exported, described heated waste water import is connected with Venturi transmission ejector 2, described heated waste water Outlet is connected by waste water circulation pump 3 with described Venturi transmission ejector.
Embodiment 2:
Multi-step pressure reduction according to embodiment 1 reclaims the device of hot waste water waste heat, described one-level vacuum flashing device Interior to be provided with hot waste water distributor 16, described hot waste water distributor is connected with hot waste water import 17.
Embodiment 3:
Multi-step pressure reduction according to embodiment 1 or 2 reclaims the device of hot waste water waste heat, described one-level, two grades subtract The bottom of flash vessel column plate in pressure flash vessel is connected with down-comer 18.
Embodiment 4:
Multi-step pressure reduction according to embodiment 1 or 2 reclaims the device of hot waste water waste heat, described three-level vacuum flashing Flash vessel column plate bottom in device is provided with high temperature sewage draining exit 19.
Embodiment 5:
Multi-step pressure reduction according to embodiment 1 or 2 reclaims the device of hot waste water waste heat, described hot waste water distribution Device can be shower nozzle and/or antipriming pipe, pressure drop 1-20KPa.
Embodiment 6:
Multi-step pressure reduction according to embodiment 1 or 2 reclaims the device of hot waste water waste heat, and described foam removal brokenly bubble plate can To be porous plate, silk screen or packing layer.
Embodiment 7:
Multi-step pressure reduction according to embodiment 1 or 2 is reclaimed in the device of hot waste water waste heat, described multi-step pressure reduction tower Flash vessel and the series of blender can be set as 1-6 grades according to technological requirement.
Embodiment 8:
Multi-step pressure reduction described in a kind of one of embodiment 1-7 reclaims the recovery method of the device of hot waste water waste heat, the party Method step is as follows:
Hot waste water of the temperature higher than 70 DEG C enters first order vacuum flashing from the hot waste water distributor of multi-step pressure reduction tower Device;The low-temperature wastewater of temperature to be heated less than 60 DEG C, by Venturi transmission ejector, aspirates multi-step pressure reduction tower with 1-5m/s flow velocitys The low-pressure steam produced in third level vacuum flashing device, waste water is mixed with steam, and low-temperature wastewater temperature improves 10-50 DEG C and flowed into Multi-step pressure reduction tower bottom first order blender;
Waste water in first order blender is through waste water circulation pump, with 1-5m/s flow velocitys by Venturi transmission ejector, suction the The low-pressure steam that second depressurized level flash vessel is produced, waste water mix with steam, 10-50 DEG C of entrance tower bottom of wastewater temperature raising the Secondary mixer;The saturation water of second level vacuum flashing device flows into third level vacuum flashing device by down-comer;
Waste water in the blender of the second level is passed through in Venturi transmission ejector, suction through waste water circulation pump with 1-5m/s flow velocitys The low-pressure steam that multi-step pressure reduction tower first order vacuum flashing device is produced, waste water is mixed with steam, and wastewater temperature improves 10-50 DEG C and entered Enter tower bottom third level blender;The saturation water of first order vacuum flashing device flows into second level vacuum flashing device by down-comer;
Waste water after being heated in bottom of towe blender flows out from delivery port, into next processing workshop section;Heat is reclaimed in vacuum flashing Hot waste water after amount processing, flows out from the sewage draining exit of third level vacuum flashing device bottom, send treatment and finishing section.
Embodiment 9:
Multi-step pressure reduction described in embodiment reclaims the device and its recovery method of hot waste water waste heat, multi-step pressure reduction tower diameter 0.4m, total high 15m;Wherein, the high 9m of flash zone, is divided into three stages of flashing, and mixing section 6m is divided into three-level blender;Coal plant's gas Change producer gas wash water, after pressurized stripping deamination depickling, 150-160 DEG C of stripper bottom of towe discharge high temperature sewage temperature, stream Measure 20t/h;20-25 DEG C of pretreating sewage temperature to be heated, flow 30t/h;The operation of the three stages of flashing device of multi-step pressure reduction tower Pressure is respectively:0.08 ~ 0.12MPa of primary flash device operating pressure(G), 0.02 ~ -0.02MPa of two-stage flash device operating pressure (G), -0.06 ~ -0.08MPa of three stages of flashing device operating pressure(G).
Embodiment 10:
Multi-step pressure reduction described in embodiment reclaims the device and its recovery method of hot waste water waste heat, the discharge of stripper bottom 150-160 DEG C of hot waste water temperature, flow 20t/h, from multi-step pressure reduction tower tower distributor into the vacuum tower first order dodge Steaming device, primary flash section operating pressure 0.1MPa(G);20-30 DEG C pending of low-temperature wastewater temperature, flow 30t/h, flow velocity 1- The low-pressure steam that 2m/s is produced by Venturi transmission ejector, suction vacuum tower third level flash vessel, keeps third level flash vessel behaviour Make pressure -0.08MPa(G), waste water mixes with steam, and wastewater temperature improves 15-20 DEG C of inflow vacuum tower bottom first order mixing Device;Waste water in first order blender is through waste water circulation pump, and flow velocity 1-2m/s is by Venturi transmission ejector, aspirating vacuum tower two The low-pressure steam that level flash vessel is produced, keeps second level flash vessel operating pressure 0.01MPa(G), waste water mixes with steam, waste water Temperature improves 15-20 DEG C and enters vacuum tower bottom second level blender;The saturation water of second level flash vessel is flowed into by down-comer Third level flash vessel;Waste water in the blender of the second level is through waste water circulation pump, with 1-2m/s flow velocitys by Venturi transmission ejector, The low-pressure steam that vacuum tower first order flash vessel is produced is aspirated, primary flash device operating pressure 0.1MPa is kept(G), waste water is with steaming Vapour is mixed, and wastewater temperature improves 10-15 DEG C and enters vacuum tower bottoms third level blender;The saturation water of first order flash vessel passes through Down-comer flows into second level flash vessel;Waste water after being heated in bottom of towe blender flows out from delivery port, 60-70 DEG C of wastewater temperature, Into next processing workshop section;Hot waste water temperature after vacuum flashing processing is reduced to 60 DEG C, from third level flash vessel bottom Sewage draining exit flows out, and send treatment and finishing section.
Embodiment 11:
Multi-step pressure reduction described in embodiment reclaims the device and its recovery method of hot waste water waste heat, coal plant's gasification furnace Gas wash water, after pressurized stripping deamination depickling, 140-150 DEG C of stripper bottom of towe discharge high temperature sewage temperature, flow 25t/h;20-30 DEG C of pretreating sewage temperature to be heated, flow 30t/h;The operation of three stages of flashing device in multi-step pressure reduction tower Pressure is respectively:Primary flash device operating pressure 0.02MPa(G), two-stage flash device operating pressure -0.02MPa(G), three-level sudden strain of a muscle Steaming device operating pressure -0.09MPa(G);80-85 DEG C of the heated waste water temperature of bottom of towe outflow, into next processing workshop section;Decompression is dodged Hot waste water temperature after steaming processing is reduced to 50 DEG C, send treatment and finishing section.
Embodiment 12:
Multi-step pressure reduction described in embodiment reclaims the device and its recovery method of hot waste water waste heat, the height that chemical plant is produced Warm high pressure waste water, 180-200 DEG C of wastewater temperature, flow 10t/h;20-30 DEG C of pretreating sewage temperature to be heated, flow 30t/ h;In multi-step pressure reduction tower three stages of flashing section operating pressure be respectively:Primary flash device operating pressure 0.1MPa(G), two grades of sudden strains of a muscle Steaming device operating pressure -0.01MPa(G), three stages of flashing device operating pressure -0.08MPa(G);The heated waste water temperature of bottom of towe outflow 65-70 DEG C, into next processing workshop section;Hot waste water temperature after vacuum flashing processing is reduced to 60 DEG C, send treatment and finishing section.
Embodiment 13:
Multi-step pressure reduction described in embodiment reclaims the device and its recovery method of hot waste water waste heat, the height that chemical plant is produced Warm high pressure waste water, 110-120 DEG C of wastewater temperature, flow 30t/h;20-30 DEG C of pretreating sewage temperature to be heated, flow 30t/ h;In multi-step pressure reduction tower three stages of flashing section operating pressure be respectively:Primary flash device operating pressure -0.01MPa(G), two grades Flash vessel operating pressure -0.04MPa(G), three stages of flashing device operating pressure -0.08MPa(G);The heated waste water temperature of bottom of towe outflow 70-75 DEG C of degree, into next processing workshop section;Hot waste water temperature after vacuum flashing processing is reduced to 60 DEG C, send post processing work Section.

Claims (1)

1. a kind of multi-step pressure reduction reclaims the recovery method of the device of hot waste water waste heat, it is characterized in that:This method step is as follows:
Hot waste water of the temperature higher than 70 DEG C enters first order vacuum flashing device from the hot waste water distributor of multi-step pressure reduction tower;
The low-temperature wastewater of temperature to be heated less than 60 DEG C is with 1-5m/s flow velocitys by Venturi transmission ejector, and suction multistage subtracts The low-pressure steam produced in tower third level vacuum flashing device is pressed, waste water is mixed with steam, low-temperature wastewater temperature improves 10-50 DEG C And flow into multi-step pressure reduction tower bottom first order blender;
Waste water in first order blender passes through Venturi transmission ejector, suction second through waste water circulation pump with 1-5m/s flow velocitys The low-pressure steam that level pressure reduction stage flash vessel is produced, waste water mix with steam, 10-50 DEG C of entrance tower bottom of wastewater temperature raising the Secondary mixer;
The saturation water of second level vacuum flashing device flows into third level vacuum flashing device by down-comer;It is useless in the blender of the second level Water is through waste water circulation pump, with 1-5m/s flow velocitys by Venturi transmission ejector, aspirating multi-step pressure reduction tower first order vacuum flashing The low-pressure steam that device is produced, waste water is mixed with steam, and wastewater temperature improves 10-50 DEG C and enters tower bottom third level blender;The The saturation water of one-level vacuum flashing device flows into second level vacuum flashing device by down-comer;
Waste water after being heated in bottom of towe blender flows out from delivery port, into next processing workshop section;Vacuum flashing is reclaimed at heat Hot waste water after reason, flows out from the sewage draining exit of third level vacuum flashing device bottom, send treatment and finishing section;
Described multi-step pressure reduction reclaims the device of hot waste water waste heat, and its composition includes:Multi-step pressure reduction tower, described multi-step pressure reduction Be sequentially provided with from top to bottom in tower one-level vacuum flashing device, second depressurized flash vessel, three-level vacuum flashing device, one-level blender, Secondary mixer, three-level blender;Described one-level, two grades, the top of three-level vacuum flashing device be provided with foam removal brokenly bubble plate, bottom Provided with flash vessel column plate, exported above described foam removal brokenly bubble plate provided with saturated vapor;Described one-level, two grades, three-level mixing Separated between device by dividing plate, top is provided with heated waste water import, bottom is exported provided with heated waste water;Described saturated vapor goes out Mouth, described heated waste water import are connected with Venturi transmission ejector, and described heated waste water outlet passes through waste water circulation pump and institute The Venturi transmission ejector connection stated;
Hot waste water distributor is provided with described one-level vacuum flashing device, described hot waste water distributor enters with hot waste water Mouth connection;
Described one-level, the bottom of the flash vessel column plate in second depressurized flash vessel are connected with down-comer;
Flash vessel column plate bottom in described three-level vacuum flashing device is provided with high temperature sewage draining exit;
Described hot waste water distributor is shower nozzle or antipriming pipe, pressure drop 1-20KPa;
Described foam removal brokenly bubble plate is porous plate or silk screen or packing layer;
The series of flash vessel and blender in described multi-step pressure reduction tower is set as 1-6 grades according to technological requirement.
CN201510022450.5A 2015-01-16 2015-01-16 Multi-step pressure reduction reclaims the device and its recovery method of hot waste water waste heat Expired - Fee Related CN104595877B (en)

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