CN104594024B - Method for preparing antibacterial mildew-proof textile - Google Patents
Method for preparing antibacterial mildew-proof textile Download PDFInfo
- Publication number
- CN104594024B CN104594024B CN201510047309.0A CN201510047309A CN104594024B CN 104594024 B CN104594024 B CN 104594024B CN 201510047309 A CN201510047309 A CN 201510047309A CN 104594024 B CN104594024 B CN 104594024B
- Authority
- CN
- China
- Prior art keywords
- solution
- textile
- zinc chloride
- zinc oxide
- antibacterial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention provides a method for preparing antibacterial mildew-proof textile. Catalytic zinc oxide antibacterial liquid is contained in the antibacterial mildew-proof textile, the antibacterial mildew-proof textile refers to a natural textile, a synthetic textile or a mixture of the natural textile and the synthetic textile; and the main component of the antibacterial mildew-proof textile refers to catalytic zinc oxide with the average particle size of 23 nanometers. The preparation method comprises the following steps: preparing dispersion liquid, and dipping the textile in the diluent of the dispersion liquid, thereby obtaining the antibacterial mildew-proof textile. The antibacterial mildew-proof textile disclosed by the invention does not cause color change, is an antibacterial agent with the antibacterial rate of 99.99 percent, has excellent characteristics such as bacteria and mildew resistance, ultraviolet resistance, far infrared emission resistance, continuous release of negative ions and the like and can be applied to the wide fields such as beach umbrellas, medical and hygienic materials, outdoor sports wear, underwear, bedding articles and air filtration equipment. Moreover, the antibacterial mildew-proof textile has the advantages of powerful functions, high safety and the like.
Description
Technical field
The present invention relates to a kind of method preparing antibiotic-mould proof textile fabric.
Background technology
Textile is indispensable the articles for daily use in people's daily life, but textile is under appropriate conditions, very
Easily attacked by microorganism, damp and hot and in the presence of having its food source, microorganism is bred rapidly in textile,
Result makes textile impaired, leads to wearer not feel well, and sometimes also can produce stench.In order to reduce harmful microorganism to people's
Harm, prevents the propagation between person to person, people and animal, animal and animal, we must artificially control micro- in textile
Biological growth and breeding.Therefore antibacterial fabric progresses into the visual field of people, and antibacterial fabric not only can avoid textile
Impaired because of the erosion of microorganism, and the approach that textile transmits pathogenic bacteria can be blocked, stop pathogenic bacteria on the textile numerous
Grow and eliminate the stink that pathogenic bacteria is decomposed the dirt on fabric and produces, prevention dermatitis and Other diseases.
Weaving of the prior art is a lot of with antibacterial finishing agent, can be divided mainly into mineral-type, organic and natural antibacterial agent
Three big species.Mineral-type antibacterial mostly is metal ion, some photocatalysis antibacterial agent and composite finishing antibacterial, such as metal, gold
Belong to salt and some photocatalyst-type anti-biotic agent；Organic mostly is classical antibacterial agents, with organic acid, phenol, alcohol as main component, to destroy
Cell membrane, so that protein denaturation metabolism is obstructed etc. be Antibacterial Mechanism, such as quaternary ammonium salt, organosilicone quaternary ammonium salt, guanidine (phmb),
Halogen amines etc.；Natural antimicrobial agent is mainly chitin and its derivant, chitin structure and cellulose family seemingly, such as carapace
Element and shitosan, plant extract, microbial fermentation product and insecticide antibiotic property protein etc..
At present, Chinese patent application cn1296548c of Lie group discloses a kind of textile function finishing agent and preparation method
With application.This finishing agent modifies nano zine oxide by silver surface and adjuvant forms, and described silver surface modifies nano zine oxide
Particle diameter is 1-300nm, and consumption is the 0.01%-80% (w/w) of finishing agent total amount.
The palace of Japan originally virtuous one discloses a kind of antibacterial for fiber in Chinese patent application cn1264408c, and it is special
Levy the cationic polymer being to comprise the repetitives with formula representative, plurality of group represents different alkyl or hydroxyl
Base.
Chinese patent application cn1274900c of Zhang Jiancun discloses a kind of textile of the argentiferous with anti-microbial property
Simplify preparation method.The method of this invention comprises the following steps: 1) prepares containing h4ag2o6Solution；2) with obtained
h4ag2o6Solution impregnation, drip washing, injection or coating textile；3) this wet spinning fabric is dried.
In existing weaving antibacterial, organic antibacterial effect is good, wide in variety, is the most widely used at present anti-
Microbial inoculum, but there is following defect: (1) heat-resistant stable difference is it is difficult to be used for synthetic fibers spinning technique；(2) natural
Class antibacterial generally has good safety, but its range of application is narrow, and majority has a strong impact on the coloured light of fabric；(3) inorganic anti-
Microbial inoculum is heat-resist, but for being difficult to obtain durable effect after textile, and there is the toxicity of heavy metal in most of kind
Problem；(4) there is no good protection effect to ultraviolet；(5) do not have protective action to far infrared transmitting, there is no obvious guarantor
Strong, heat-preserving function；(6) there is zest；(7) production process energy consumption original text, saves into height；(8) production process has acutely chemistry anti-
Should, bring other impurities into and cause the decomposition of product to deform；(9) reach concentration deduction purpose at normal temperatures, cause effective ingredient
Destruction, technical process yield is low；(10) device structure complexity, floor space are big；(11) complex operation is it is impossible to realize automatization
Operation, stability is poor, safeguards inconvenient.
Content of the invention
In order to the problems such as solving (1) heat-resistant stable difference that existing but technology exists it is difficult to be used for synthetic fibers spinning
Technique；(2) natural antimicrobial agent generally has good safety, but its range of application is narrow, and majority has a strong impact on the color of fabric
Light；(3) inorganic antiseptic is heat-resist, but is difficult to obtain durable effect for after textile, and most of kind exists
The toxicity problem of heavy metal；(4) there is no good protection effect to ultraviolet；(5) do not have protective action to far infrared transmitting, no
There is obvious health care, heat-preserving function；(6) there is zest；(7) production process energy consumption original text, saves into height；(8) production process
There is violent chemical reaction, bring other impurities into and cause the decomposition of product to deform；(9) reach concentration deduction purpose at normal temperatures,
Cause the destruction of effective ingredient, technical process yield is low；(10) device structure complexity, floor space are big；(11) complex operation, no
Enable automated job, stability is poor, safeguard inconvenient defect.
Present invention offer technical scheme below:
A kind of method preparing antibiotic-mould proof textile fabric, described antibiotic-mould proof textile fabric is contained within catalyst zinc oxide antibacterial
Liquid, described antibiotic-mould proof textile fabric is the mixture of natural fabric, synthesis textile or natural fabric and synthesis textile,
Including following making step:
First, the preparation of catalyst zinc oxide antimicrobial fluid:
(1) calculated with mass fraction, (a) 35-70 part zinc chloride is dissolved in 10-20 part aqueous solvent, and zinc chloride is in water
Hydrolysis occur, reaction equation is as follows:Precipitation in water for the zinc ion leads to
Solution is muddy, after dissolving reaches saturation, when solution muddy, adds 0.5-2.5 part dilute hydrochloric acid, limpid to solution, makes
Zinc chloride saturated solution；B () zinc chloride saturated solution is placed in semipermeable membrane device, plus 0.2mpa pressure, filters out and chlorination
The suitable dilute hydrochloric acid solution of zincification solution mother solution ph value, now, controls zinc chloride saturated solution mother solution temperature to be maintained at 0-5 DEG C
Between, the water content of zinc chloride saturated solution mother solution reduces, and leads to have crystal to separate out, adds 10-45 part deionized water in advance and protect
The homogeneity of card mother solution；C, with the rising of zinc chloride saturated solution mother solution ph value, retrogradation or the phenomenon of caking in (), increase
The speed of zinc chloride saturated solution Recycling Mother Solution, is simultaneously introduced 0.5-1 part fumaric acid auxiliary agent and keeps zinc chloride saturated solution mother solution
Viscosity and stable system, monitoring zinc chloride saturated solution mother solution ph value, when ph is in 5.5-7, stop dialyse, by zinc chloride
Saturated solution mother solution gets out with ammonia and ph value is to 7, obtaining catalyst zinc oxide fluid dispersion, adjusts concentration so as to percent mass
Content is 20%-40%, obtains catalyst zinc oxide antimicrobial fluid；
(2) the catalyst zinc oxide antimicrobial fluid that (1) step system arrives is diluted 10 times, now catalyst zinc oxide antimicrobial fluid concentration exists
2%-4%, under room temperature, takes one piece of two meters of long cotton, and concentration is passed through dipping, drenched for 2%-4% catalyst zinc oxide antimicrobial fluid
Wash, spray or coating textile on, then cloth is pulled out, spreads out, at 70 DEG C -105 DEG C be dried.
Catalyst zinc oxide antimicrobial fluid prepared by the present invention, Antibacterial Mechanism has following two:
1. catalytic antimicrobial mechanism, that is, catalyst zinc oxide under the irradiation of natural light, can voluntarily decomposite in water and air
Electronegative electronics (e-), leaves the hole (h+) of positively charged simultaneously, and this hole can excite the oxygen of in the air to be changed into alive
Property oxygen, have extremely strong chemism, can with multiple-microorganism occur oxidation reaction, thus antibacterial is killed；
2. digestion of metallic ion Antibacterial Mechanism: the zinc ion in zinc oxide can gradual separate out, when it and bacterial body
When contacting, will combine with active protease in antibacterial body makes it lose activity, thus antibacterial is killed.
Beneficial effects of the present invention:
The antibiotic-mould proof textile fabric of the present invention, has the advantage that (1) has excellent anti-microbial property, for common
Gold-coloured staphylococci, Candida albicans, escherichia coli etc. have obvious inhibitory action；(2) ultraviolet protection is had well
Effect, detection upf value up to 528；(3) launching ratio to far infrared is 92%, has obvious health care, heat-preserving function；(4)
There is stronger water-fast sexual function, washing detects that the bacteriostasis rate to gold-coloured staphylococci still has 99.8% for 50 times afterwards；(5) apply
In extensive range it is adaptable to all clothes；(6) rabbit transdermal stimulation test, nonirritant；(7) avoid direct use with much money
Belong to, without formaldehyde and harmful heavy metal.
The method preparing antibiotic-mould proof textile fabric of the present invention, has the advantage that (1) energy consumption is low, cost-effective；(2)
The no violent chemical reaction of process, does not bring other impurities into and causes the decomposition of product to deform；(3) reach concentration deduction at normal temperatures
Purpose, does not cause the destruction of effective ingredient, technical process high income；(4) device structure concision and compact, floor space are little；(5) grasp
Make easy, enable automated job, good stability, easy to maintenance.
Specific embodiment
Further illustrate the present invention with reference to the preferred embodiments of the present invention.
Embodiment 1
A kind of method preparing antibiotic-mould proof textile fabric, described antibiotic-mould proof textile fabric is contained within catalyst zinc oxide antibacterial
Liquid, described antibiotic-mould proof textile fabric is the mixture of natural fabric, synthesis textile or natural fabric and synthesis textile,
Including following making step:
First, the preparation of catalyst zinc oxide antimicrobial fluid:
(1) calculated with mass fraction, (a) 35 parts of zinc chloride are dissolved in 10 parts of aqueous solvents, and zinc chloride occurs in water
Hydrolysis, reaction equation is as follows:Precipitation in water for the zinc ion leads to solution muddy
Turbid, after dissolving reaches saturation, when solution muddy, add 0.5 part of dilute hydrochloric acid, limpid to solution, make chlorination zincification
Solution；B () zinc chloride saturated solution is placed in semipermeable membrane device, plus 0.2mpa pressure, filters out and zinc chloride saturated solution
The suitable dilute hydrochloric acid solution of mother solution ph value.Now, zinc chloride saturated solution mother solution temperature is controlled to be maintained between 0-5 DEG C, chlorination
The water content of zincification solution mother solution reduces, and leads to have crystal to separate out, adds 45 parts of deionized waters in advance and ensure the homogeneous of mother solution
Property；C, with the rising of zinc chloride saturated solution mother solution ph value, retrogradation or the phenomenon of caking in (), increase chlorination zincification molten
The speed of liquid Recycling Mother Solution, is simultaneously introduced 0.5 part of fumaric acid auxiliary agent and keeps the viscosity of zinc chloride saturated solution mother solution and system steady
Fixed, the ph value of monitoring zinc chloride saturated solution mother solution, when ph is in 5.5-7, stop dialysis, zinc chloride saturated solution mother solution is contained
Go out with ammonia and ph value is to 7, obtaining catalyst zinc oxide fluid dispersion, adjusting concentration so as to weight/mass percentage composition is 20%, obtain
Catalyst zinc oxide antimicrobial fluid；
(2) the catalyst zinc oxide antimicrobial fluid that (1) step system arrives is diluted 10 times, now catalyst zinc oxide antimicrobial fluid concentration exists
2%, under room temperature, take one piece of two meters of long cotton, by concentration be 2% catalyst zinc oxide antimicrobial fluid pass through dipping, drip washing, injection or
On coating textile, then cloth is pulled out, spread out, be dried at 70 DEG C.
Embodiment 2
A kind of method preparing antibiotic-mould proof textile fabric, described antibiotic-mould proof textile fabric is contained within catalyst zinc oxide antibacterial
Liquid, described antibiotic-mould proof textile fabric is the mixture of natural fabric, synthesis textile or natural fabric and synthesis textile.
Including following making step:
First, the preparation of catalyst zinc oxide antimicrobial fluid:
(1) calculated with mass fraction, (a) 49.5 parts of zinc chloride are dissolved in 15 parts of aqueous solvents, and zinc chloride can go out in water
Existing hydrolysis, reaction equation is as follows:Precipitation in water for the zinc ion leads to solution
Muddiness, after dissolving reaches saturation, when solution muddy, adds 1 part of dilute hydrochloric acid, limpid to solution, makes chlorination zincification
Solution；B () zinc chloride saturated solution is placed in semipermeable membrane device, plus 0.2mpa pressure, filters out and zinc chloride saturated solution
The suitable dilute hydrochloric acid solution of mother solution ph value.Now, zinc chloride saturated solution mother solution temperature is controlled to be maintained between 0-5 DEG C, chlorination
The water content of zincification solution mother solution reduces, and leads to have crystal to separate out, adds 33 parts of deionized waters in advance and ensure the homogeneous of mother solution
Property；C, with the rising of zinc chloride saturated solution mother solution ph value, retrogradation or the phenomenon of caking in (), increase chlorination zincification molten
The speed of liquid Recycling Mother Solution, is simultaneously introduced 0.5 part of fumaric acid auxiliary agent and keeps the viscosity of zinc chloride saturated solution mother solution and system steady
Fixed, the ph value of monitoring zinc chloride saturated solution mother solution, when ph is in 5.5-7, stop dialysis, zinc chloride saturated solution mother solution is contained
Go out with ammonia and ph value is to 7, obtaining catalyst zinc oxide fluid dispersion, adjusting concentration so as to weight/mass percentage composition is 30%, obtain
Catalyst zinc oxide antimicrobial fluid；
(2) the catalyst zinc oxide antimicrobial fluid that (1) step system arrives is diluted 10 times, now catalyst zinc oxide antimicrobial fluid concentration exists
3%, under room temperature, take one piece of two meters of long cotton, by concentration be 3% catalyst zinc oxide antimicrobial fluid pass through dipping, drip washing, injection or
On coating textile, then cloth is pulled out, spread out, be dried at 85 DEG C.
Embodiment 3
A kind of method preparing antibiotic-mould proof textile fabric, described antibiotic-mould proof textile fabric is contained within catalyst zinc oxide antibacterial
Liquid, described antibiotic-mould proof textile fabric is the mixture of natural fabric, synthesis textile or natural fabric and synthesis textile.
Including following making step:
First, the preparation of catalyst zinc oxide antimicrobial fluid:
(1) calculated with mass fraction, (a) 70 parts of zinc chloride are dissolved in 20 parts of aqueous solvents, and zinc chloride occurs in water
Hydrolysis, reaction equation is as follows:Precipitation in water for the zinc ion leads to solution muddy
Turbid, after dissolving reaches saturation, when solution muddy, add 2.5 parts of dilute hydrochloric acid, limpid to solution, make chlorination zincification
Solution；B () zinc chloride saturated solution is placed in semipermeable membrane device, plus 0.2mpa pressure, filters out and zinc chloride saturated solution
The suitable dilute hydrochloric acid solution of mother solution ph value.Now, zinc chloride saturated solution mother solution temperature is controlled to be maintained between 0-5 DEG C, chlorination
The water content of zincification solution mother solution reduces, and leads to have crystal to separate out, adds 10 parts of deionized waters in advance and ensure the homogeneous of mother solution
Property；C, with the rising of zinc chloride saturated solution mother solution ph value, retrogradation or the phenomenon of caking in (), increase chlorination zincification molten
The speed of liquid Recycling Mother Solution, is simultaneously introduced viscosity and the stable system that 1 part of fumaric acid auxiliary agent keeps zinc chloride saturated solution mother solution,
The ph value of monitoring zinc chloride saturated solution mother solution, when ph is in 5.5-7, stops dialysis, zinc chloride saturated solution mother solution is got out
With in ammonia and ph value is to 7, obtaining catalyst zinc oxide fluid dispersion, adjusting concentration so as to weight/mass percentage composition is 40%, touched
Matchmaker's zinc oxide antimicrobial fluid；
(2) the catalyst zinc oxide antimicrobial fluid that (1) step system arrives is diluted 10 times, now catalyst zinc oxide antimicrobial fluid concentration exists
4%, under room temperature, take one piece of two meters of long cotton, by concentration be 4% catalyst zinc oxide antimicrobial fluid pass through dipping, drip washing, injection or
On coating textile, then cloth is pulled out, spread out, be dried at 105 DEG C.
Catalyst zinc oxide antimicrobial fluid prepared by the present invention, Antibacterial Mechanism has following two:
1. catalytic antimicrobial mechanism, that is, catalyst zinc oxide under the irradiation of natural light, can voluntarily decomposite in water and air
Electronegative electronics (e-), leaves the hole (h+) of positively charged simultaneously, and this hole can excite the oxygen of in the air to be changed into alive
Property oxygen, have extremely strong chemism, can with multiple-microorganism occur oxidation reaction, thus antibacterial is killed；
2. digestion of metallic ion Antibacterial Mechanism: the zinc ion in zinc oxide can gradual separate out, when it and bacterial body
When contacting, will combine with active protease in antibacterial body makes it lose activity, thus antibacterial is killed.
The antibiotic-mould proof textile fabric of the present invention, has the advantage that (1) has excellent anti-microbial property, for common
Gold-coloured staphylococci, Candida albicans, escherichia coli etc. have obvious inhibitory action；(2) ultraviolet protection is had well
Effect, detection upf value up to 528；(3) launching ratio to far infrared is 92%, has obvious health care, heat-preserving function；(4)
There is stronger water-fast sexual function, washing detects that the bacteriostasis rate to gold-coloured staphylococci still has 99.8% for 50 times afterwards；(5) apply
In extensive range it is adaptable to all clothes；(6) rabbit transdermal stimulation test, nonirritant；(7) avoid direct use with much money
Belong to, without formaldehyde and harmful heavy metal.The method preparing antibiotic-mould proof textile fabric of the present invention, has the advantage that (1) energy consumption
Low, cost-effective；(2) the no violent chemical reaction of process, does not bring other impurities into and causes the decomposition of product to deform；(3) normal
Temperature is issued to concentration deduction purpose, does not cause the destruction of effective ingredient, technical process high income；(4) device structure concision and compact,
Floor space is little；(5) easy and simple to handle, enable automated job, good stability, easy to maintenance.
The catalyst material of the embodiment of the present invention, in microbiological analysiss inspection center of Guangdong Province, detects antibacterium function, report
Numbering: 2014fm3199, on July 29 2014 date of issuance, antibiotic rate is more than 99.99%；
The catalyst material of the embodiment of the present invention, in microbiological analysiss inspection center of Guangdong Province, detects that mould proof grade is 0 grade；Connect
2014 sample dates August 4 days, detection -2014 years on the 4th Septembers of 2014 dates August 9 days；2014 dates of issuance September 10 days；Report
Accuse numbering: 2014fm3378.
The catalyst material of the embodiment of the present invention, on July 23rd, 2014, delivers to microbiological analysiss inspection center of Guangdong Province, sample
Product specification and lot number hqfl20140628, detection project negative ion concentration, report number 2014fm3200, detection method anion
Instrument direct-reading, connects sample loading mode and quantity, censorship 1；Sample state and characteristic, liquid；Detection 2014 dates August 19 days, signs and issues
2014 dates September 15 days；Analysis testing result: detection project, negative ion concentration (at air outlet 5cm), testing result, 1.5
×103Individual/cm3.
The above, only invention preferred embodiment, therefore the scope that invention is implemented can not be limited according to this, that is, according to invention
Equivalence changes and modification that the scope of the claims and description are made, all should still belong in the range of the present invention covers.
Claims (1)
1. a kind of method preparing antibiotic-mould proof textile fabric, described antibiotic-mould proof textile fabric is contained within catalyst zinc oxide antimicrobial fluid,
It is characterized in that, including following making step:
First, the preparation of catalyst zinc oxide antimicrobial fluid:
(1) calculated with mass fraction, (a) 35-70 part zinc chloride is dissolved in 10-20 part aqueous solvent, and zinc chloride can go out in water
Existing hydrolysis, reaction equation is as follows:Precipitation in water for the zinc ion leads to molten
Liquid is muddy, after dissolving reaches saturation, when solution muddy, adds 0.5-2.5 part dilute hydrochloric acid, limpid to solution, makes chlorine
Change zincification solution；B () zinc chloride saturated solution is placed in semipermeable membrane device, plus 0.2mpa pressure, filters out and zinc chloride
The suitable dilute hydrochloric acid solution of saturated solution mother solution ph value, now, control zinc chloride saturated solution mother solution temperature be maintained at 0-5 DEG C it
Between, the water content of zinc chloride saturated solution mother solution reduces, and leads to have crystal to separate out, adds 10-45 part deionized water in advance and ensure
The homogeneity of mother solution；C, with the rising of zinc chloride saturated solution mother solution ph value, retrogradation or the phenomenon of caking in (), increase chlorine
Change the speed of zincification solution Recycling Mother Solution, be simultaneously introduced 0.5-1 part fumaric acid auxiliary agent and keep zinc chloride saturated solution mother solution
Viscosity and stable system, the ph value of monitoring zinc chloride saturated solution mother solution, when ph is in 5.5-7, stops dialysis, zinc chloride is satisfied
Get out with ammonia and ph value is to 7, obtaining catalyst zinc oxide fluid dispersion, adjusting concentration so as to percent mass contains with solution mother solution
Measure as 20%-40%, obtain catalyst zinc oxide antimicrobial fluid；
(2) the catalyst zinc oxide antimicrobial fluid that (1) step system arrives is diluted 10 times, now catalyst zinc oxide antimicrobial fluid concentration is in 2%-
4%, under room temperature, take one piece of two meters of long cotton, concentration is passed through dipping, drip washing, spray for 2%-4% catalyst zinc oxide antimicrobial fluid
Penetrate or coating textile on, then cloth is pulled out, spreads out, at 70 DEG C -105 DEG C be dried.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510047309.0A CN104594024B (en) | 2015-01-30 | 2015-01-30 | Method for preparing antibacterial mildew-proof textile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510047309.0A CN104594024B (en) | 2015-01-30 | 2015-01-30 | Method for preparing antibacterial mildew-proof textile |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104594024A CN104594024A (en) | 2015-05-06 |
| CN104594024B true CN104594024B (en) | 2017-02-01 |
Family
ID=53120058
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510047309.0A Expired - Fee Related CN104594024B (en) | 2015-01-30 | 2015-01-30 | Method for preparing antibacterial mildew-proof textile |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104594024B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105925007A (en) * | 2016-05-25 | 2016-09-07 | 南通富之岛寝具发展有限公司 | Vegetable dye for fabric |
| CN111206435A (en) * | 2020-02-12 | 2020-05-29 | 常德集智生物科技有限公司 | Green antibacterial breathable baby mattress |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1541598A (en) * | 2003-04-29 | 2004-11-03 | 清展塑胶股份有限公司 | Yarn net with self-cleaning ability and its production method |
| CN103015166A (en) * | 2012-12-13 | 2013-04-03 | 北京航空航天大学 | Nano-silver antibacterial fabric and preparation method thereof |
| CN103334292A (en) * | 2013-06-27 | 2013-10-02 | 江苏华艺服饰有限公司 | Real silk fabric nano-zinc oxide antibacterial production method |
| CN104005226A (en) * | 2013-02-21 | 2014-08-27 | 江苏南纬悦达纺织研究院有限公司 | Composite antibacterial mould-proof coated fabric and manufacturing method thereof |
| CN104294604A (en) * | 2014-09-03 | 2015-01-21 | 江苏阳光股份有限公司 | Antistatic after-finishing process for woolen fabric |
-
2015
- 2015-01-30 CN CN201510047309.0A patent/CN104594024B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1541598A (en) * | 2003-04-29 | 2004-11-03 | 清展塑胶股份有限公司 | Yarn net with self-cleaning ability and its production method |
| CN103015166A (en) * | 2012-12-13 | 2013-04-03 | 北京航空航天大学 | Nano-silver antibacterial fabric and preparation method thereof |
| CN104005226A (en) * | 2013-02-21 | 2014-08-27 | 江苏南纬悦达纺织研究院有限公司 | Composite antibacterial mould-proof coated fabric and manufacturing method thereof |
| CN103334292A (en) * | 2013-06-27 | 2013-10-02 | 江苏华艺服饰有限公司 | Real silk fabric nano-zinc oxide antibacterial production method |
| CN104294604A (en) * | 2014-09-03 | 2015-01-21 | 江苏阳光股份有限公司 | Antistatic after-finishing process for woolen fabric |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104594024A (en) | 2015-05-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102669179B (en) | Antibacterial antiviral treating agent, preparation method and application thereof | |
| CN101613946B (en) | Antibiotic fiber, preparation method thereof and application thereof in home textile | |
| CN102733184B (en) | Finishing technology for aromatic anti-bacteria cotton textile | |
| CN101812801B (en) | Antibacterial functional fibers | |
| CN105586652A (en) | Preparation method of regenerated cellulose fiber with antibacterial and mosquito repellent functions | |
| CN105296192A (en) | Nano silver added powerful sterilizing and lasting bacteria-resisting laundry detergent and manufacturing method therefor | |
| CN104294595A (en) | Production process for anti-bacterial deodorant textile | |
| CN103556250A (en) | Antibacterial viscose containing artemisia argyi oil component and production method of antibacterial viscose | |
| CN102505171A (en) | Natural antimicrobial contained viscose fiber and preparation method thereof | |
| CN101336640A (en) | Tetrasilver tetroxide bactericide, preparation method and use thereof | |
| CN106924803B (en) | A kind of high-performance medical use liquid adhesive bandage and preparation method thereof | |
| CN101967753A (en) | Nanometer antibiosis cashmere knit fabric and production method thereof | |
| CN104631115A (en) | Antibacterial anti-odor finishing application technology for textiles | |
| CN104878589A (en) | Preparation method of finishing agent of textiles | |
| CN101886338A (en) | Biological antibiotic cotton fibers or cotton cloth and method for preparing same | |
| CN104594024B (en) | Method for preparing antibacterial mildew-proof textile | |
| CN111280178A (en) | Multicolor graphene antibacterial liquid and preparation method and application thereof | |
| CN103147310A (en) | Method for finishing cotton fabrics through spraying plant essential oil | |
| CN106120313A (en) | The preparation method of a kind of antimildew and antibacterial agent and the application in weaving face fabric thereof | |
| CN102742601A (en) | Disinfectant for rearing instrument of rearing house and application thereof | |
| CN106234388B (en) | A kind of composition pesticide of alkene containing benzo fluorine bacterium azoles and jamaicin | |
| CN107675292A (en) | A kind of nano-silver bamboo charcoal fiber and its Bactericidal underwear product | |
| CN112853747B (en) | Preparation method of long-acting antibacterial polyester fiber based on composite nano silver and special device thereof | |
| CN103975919B (en) | A kind of preparation method of Java rod spore mycete conidium microcapsule | |
| CN111424427A (en) | Non-dissolution type antibacterial finishing agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170201 Termination date: 20180130 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |