CN104592966A - Method for preparing thickened oil viscosity reducer based on gutter oil as raw material - Google Patents
Method for preparing thickened oil viscosity reducer based on gutter oil as raw material Download PDFInfo
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- CN104592966A CN104592966A CN201410842853.XA CN201410842853A CN104592966A CN 104592966 A CN104592966 A CN 104592966A CN 201410842853 A CN201410842853 A CN 201410842853A CN 104592966 A CN104592966 A CN 104592966A
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/584—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
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Abstract
The invention relates to a method for preparing a thickened oil viscosity reducer based on gutter oil as a raw material. The method comprises the following steps of carrying out amidation reaction on gutter oil which is rich in source and is enriched in triglyceride and N,N-dimethyl-1,3-propanediamine to produce oleamide having terminal groups containing tertiary amide and reacting bimolecular oleamide having terminal groups containing tertiary amide with monomolecular 1,4-butanediol diglycidyl ether to produce Gemini amphiphilic molecules containing quaternary ammonium ions. The compound has thickened oil emulsifying capability. The preparation method is simple and low in cost and provides a new way to treat gutter oil.
Description
Technical field
The invention belongs to oilfield oil extraction additive field, particularly relating to a kind of is that raw material is to prepare the method for heavy crude thinner with sewer oil.
Background technology
In recent years, the most oil field of China has entered the tail period stage, along with the continuous increase of viscous oil recovery amount, highly dense, high characteristic that is sticky, poor fluidity brings extreme difficulties to Oil extraction and conveying, and the key of heavy oil development is how to reduce viscosity of crude, improves the aspects such as its mobility.Although existing various viscosity-depression agent, still needs cost lower in field produces in prior art, stable performance and effective viscosity-depression agent.
Sewer oil is the inedible oil of quality, health extreme difference, the index severe overweights such as peroxide value, acid value, moisture, carbonyl valency, mda.The raw material of China's sewer oil is sufficient, produces at least about 5,000,000 tons every year, is rich in triglyceride level.
The present invention is with the sewer oil of abundance for raw material, and the viscosity-depression agent of preparation can be penetrated in crude oil by water-oil interface by aqueous phase, and weakens the intermolecular reactive force of crude oil, thus reduces viscosity of crude, increases the mobility of crude oil in stratum.
Summary of the invention
The present invention take sewer oil as raw material, itself and N, N-dimethyl-1,3-propylene diamine is reacted, then reacts with ethylene glycol diglycidylether, generates the oleylamide of end group containing tertiary amine; Then two exposed terminated groupses react with the BDDE of a part containing the oleylamide of tertiary amine again, generate the double type amphiphile, amphiphilic molecule containing quaternary amine ion.This compounds has emulsification viscous crude ability.Preparation method's technique is simple, with low cost, and provides a kind of new way of processing and utilizing sewer oil.
Embodiment
Embodiment 1
(1) 100g sewer oil and 0.3molN, N-dimethyl-1,3-propylene diamine are added in the reaction vessel with division box, add 0.1g sodium hydroxide, after mixing, in 160 DEG C of oil baths, isothermal reaction is about 5h, when anhydrous separating, is cooled to room temperature stand-by;
(2) above-mentioned reaction product is added in the reaction vessel with whipping appts, pass into nitrogen and be about 15min, drive air in most reactor, be warming up to 105 DEG C, slowly instill 0.15mol ethylene glycol diglycidylether with dropping funnel, react about 4h, obtain product.It is 825 that mass spectroscopy records molecular weight of product.
Embodiment 2
(1) 150g sewer oil and 0.3molN, N-dimethyl-1,3-propylene diamine are added in the reaction vessel with division box, add 0.1g sodium hydroxide, after mixing, in 160 DEG C of oil baths, isothermal reaction is about 5h, when anhydrous separating, is cooled to room temperature stand-by;
(2) above-mentioned reaction product is added in the reaction vessel with whipping appts, pass into nitrogen and be about 15min, drive air in most reactor, be warming up to 105 DEG C, slowly instill 0.15mol ethylene glycol diglycidylether with dropping funnel, react about 4h, obtain product.It is 830 that mass spectroscopy records molecular weight of product.
Embodiment 3
(1) 200g sewer oil and 0.3molN, N-dimethyl-1,3-propylene diamine are added in the reaction vessel with division box, add 0.1g sodium hydroxide, after mixing, be placed in 160 DEG C of oil bath isothermal reactions and be about 5h, when anhydrous separating,, stop heating, be cooled to room temperature stand-by;
(2) above-mentioned reaction product is added in the reaction vessel with whipping appts, pass into nitrogen and be about 15min, drive air in most reactor, be warming up to 105 DEG C, slowly instill 0.15mol neopentylglycol diglycidyl ether with dropping funnel, about 4h, obtain product.It is 970 that mass spectroscopy records molecular weight of product.
Embodiment 4
Crude oil sample is for breathing out shallow 1-1 well dewatered oil (Shengli Oil Field), and recording its viscosity at 60 DEG C with BROOKFILD DV-III+ type rheometer is 6.6 × 10
4mPas, by product prepared in embodiment 1 ~ 3, is mixed with the aqueous solution of 0.5% weight percent respectively, is be added in crude oil at 8: 2, leaves standstill 48h, at 60 DEG C, survey viscosity of crude at 60 DEG C with profit mass ratio.Result is as shown in table 1: visible, and in embodiment 1 ~ 3, the product of preparation can reduce former oil viscosity effectively, and the product wherein implementing preparation in 3 is the most remarkable to the viscosity reducing effect of crude oil.
Shallow viscosity of crude table breathed out by table 1
Embodiment | Viscosity of crude/mPa.s before process | Viscosity of crude/mPa.s after process | Viscosity break ratio/% |
1 | 6.6×10 4 | 6040 | 90.85 |
2 | 6.6×10 4 | 2297 | 96.52 |
3 | 6.6×10 4 | 450 | 99.32 |
Embodiment 5
Viscosity-reducing performance evaluation to different crude oils sample: product in embodiment 3 is mixed with the aqueous solution that mass percent is 0.5%.Adopt and conditions of similarity in embodiment 4, at 60 DEG C, with prepared solution-treated different crude oils sample (each oil well of Shengli Oil Field) 48h, former oil viscosity before and after process is measured at 60 DEG C, result is as shown in table 2: visible, and viscosity-depression agent of the present invention can reduce the former oil viscosity of various different sources effectively.
The viscosity reducing effect of table 2 pair different crude oils sample
Pound sign | Viscosity of crude (mPas) | Viscosity of crude (mPas) after process | Viscosity break ratio (%) |
Zheng 418 | 98.2×10 4 | 3928 | 99.60 |
Breathe out shallow 1-1 | 6.6×10 4 | 450 | 99.32 |
Single 56-9-21 | 27114 | 394 | 98.55 |
Single 56-7-11 | 27040 | 271 | 99.00 |
Single 56-7-9 | 73600 | 780 | 98.94 |
Old 373 | 22976 | 322 | 98.60 |
Battalion 47 × 23 | 5280 | 110 | 97.92 |
Battalion 8-43 | 3467 | 105 | 96.97 |
Claims (1)
1. be the method that heavy crude thinner prepared by raw material with sewer oil, comprise the following steps:
(1) by 100 ~ 200g triglyceride level mass percent be 85 ~ 95% sewer oil and 0.3molN, N-dimethyl-1,3-propylene diamine adds in the reaction vessel with division box, add 0.1g sodium hydroxide, after mixing, constant temperature in 160 DEG C of oil baths, when anhydrous separating, be about 5h, stop heating, be cooled to room temperature stand-by;
(2) above-mentioned reaction product is added in the reaction vessel with whipping appts, pass into nitrogen and be about 15min, drive air in most reactor, be warming up to 105 DEG C, 0.15mol ethylene glycol diglycidylether or neopentylglycol diglycidyl ether is slowly instilled with dropping funnel, reaction is about 4h, obtains final product.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106244126A (en) * | 2016-07-03 | 2016-12-21 | 青岛大学 | A kind of method preparing heavy crude thinner for raw material with aphthenic acids |
CN106243276A (en) * | 2016-07-03 | 2016-12-21 | 青岛大学 | A kind of method improving oil recovery factor polymer for raw material preparation with aphthenic acids |
CN106279330A (en) * | 2016-07-03 | 2017-01-04 | 青岛大学 | A kind of method preparing viscous crude pour-point depressant for raw material with cholic acid |
CN109971448A (en) * | 2019-04-23 | 2019-07-05 | 中国海洋石油集团有限公司 | A kind of heavy crude thinner of twin chain surfactant types |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106244126A (en) * | 2016-07-03 | 2016-12-21 | 青岛大学 | A kind of method preparing heavy crude thinner for raw material with aphthenic acids |
CN106243276A (en) * | 2016-07-03 | 2016-12-21 | 青岛大学 | A kind of method improving oil recovery factor polymer for raw material preparation with aphthenic acids |
CN106279330A (en) * | 2016-07-03 | 2017-01-04 | 青岛大学 | A kind of method preparing viscous crude pour-point depressant for raw material with cholic acid |
CN106279330B (en) * | 2016-07-03 | 2017-12-26 | 青岛大学 | A kind of method that viscous crude pour-point depressant is prepared using cholic acid as raw material |
CN106243276B (en) * | 2016-07-03 | 2018-07-31 | 青岛大学 | A method of it is prepared as raw material using aphthenic acids and improves oil recovery factor polymer |
CN106244126B (en) * | 2016-07-03 | 2019-01-25 | 青岛大学 | A method of heavy crude thinner is prepared by raw material of aphthenic acids |
CN109971448A (en) * | 2019-04-23 | 2019-07-05 | 中国海洋石油集团有限公司 | A kind of heavy crude thinner of twin chain surfactant types |
CN109971448B (en) * | 2019-04-23 | 2021-06-29 | 中国海洋石油集团有限公司 | Twin-chain surfactant type thickened oil viscosity reducer |
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