CN104592837A - Superfast-dried hood surface varnish for repairing automobiles and preparation method of varnish - Google Patents

Superfast-dried hood surface varnish for repairing automobiles and preparation method of varnish Download PDF

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Publication number
CN104592837A
CN104592837A CN201510086480.2A CN201510086480A CN104592837A CN 104592837 A CN104592837 A CN 104592837A CN 201510086480 A CN201510086480 A CN 201510086480A CN 104592837 A CN104592837 A CN 104592837A
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China
Prior art keywords
varnish
organic solvent
stir
reactor
intermediates
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Pending
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CN201510086480.2A
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Chinese (zh)
Inventor
郭明东
朱忠敏
林在强
吴家刚
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Eastern Paint Technology (shanghai) Co Ltd
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Eastern Paint Technology (shanghai) Co Ltd
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Priority to CN201510086480.2A priority Critical patent/CN104592837A/en
Publication of CN104592837A publication Critical patent/CN104592837A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/56Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to a superfast-dried hood surface varnish for repairing automobiles and a preparation method of the varnish. The varnish comprises the following components in parts by weight: 45-60 parts of modified acrylic resin, 14-40 parts of an organic solvent, 0.01-0.05 part of a drying catalyst, 0.3-0.8 part of a flatting agent, 12-25 parts of a cross-linking curing agent and 0.3-1.2 parts of an anti-aging agent. The preparation method of the superfast-dried hood surface varnish for repairing automobiles comprises the following steps: mixing 1-15wt% of the organic solvent and the anti-ageing agent to obtain an intermediate product a; mixing 3-85wt% of the organic solvent and the flatting agent to obtain an intermediate product b; 3-70wt% of the organic solvent and the drying catalyst to obtain an intermediate product c; adding the modified acrylic resin and all the rest of the organic solvent or 6-70wt% of the organic solvent; adding the intermediate product a, the intermediate product b and the intermediate product c according to the required sequence to obtain a mixture d; adding the cross-linking curing agent resin and all the rest of the solvent; stirring and filtering to obtain a mixture e. When the superfast-dried hood surface varnish for repairing automobiles is used, the mixture e is added into the mixture d. Compared with the prior art, the varnish has the advantages that the varnish is superfast dried, and a varnish film is smooth and flat in appearance, high in hardness and high in luster.

Description

A kind of car repair ultrafast dry cover varnish and preparation method thereof
Technical field
The present invention relates to coating, especially relate to a kind of car repair ultrafast dry cover varnish and preparation method thereof.
Background technology
The coating of current use has applicable performance usually, but 1) time of drying is long, and when 25 DEG C, surface drying needs more than 20 minutes, and tack-free needs more than 4 hours; Need in drying process to take larger workyard.2) or be warmed to 60 DEG C of bakings and reach tack-free degree in more than 45 minutes, waste energy; 3) quick-drying product gloss is lower than 85/600, needs polishing more just can reach required effect; 4) common varnish is through 60 DEG C of bakings surface hardness of 45 minutes lower than 2B, easily scratches.
Summary of the invention
Object of the present invention is exactly that to provide one to have to overcome defect that above-mentioned prior art exists ultrafast dry, and paint film appearance is smooth, and hardness is high, car repair ultrafast dry cover varnish and preparation method thereof that gloss is high.
Object of the present invention can be achieved through the following technical solutions: the ultrafast dry cover varnish of a kind of car repair, it is characterized in that, this varnish comprises following component and weight part content: acrylic resin modified 45-60, organic solvent 14-40, siccative 0.01 ~ 0.05, flow agent 0.3-0.8, crosslinking and curing agent 12-25, protective agent 0.3-1.2.
Described acrylic resin modified be hydroxy-containing resin, the hydroxy radical content of resin is 4-5%, is preferred with primary, secondary hydroxyl content height.
The hydroxy radical content of described hydroxy resin is 4.2-4.6%, comprises Hypomer FS-4660P, setlux 1280,7313-X-70 be used alone or used in combination.
Described siccative is organometallic compound, comprises aerochemistry DABCO series product.
Described crosslinking and curing agent is isocyanurate compound, comprises the DESMODUR series product of BAYER company, BASF Basonat series product.
Described flow agent is organosilyl surface auxiliary agent, acrylic acid or the like leveling auxiliary agent; Comprise BYK-331, BYK-332, BYK-358, BYK-361, Levaslip 810, Levaslip 468, Levaslip 495, Levaslip835.
Described organic solvent comprises acetone, butanone, butylacetate, one or more in propylene glycol methyl ether acetate or dimethylbenzene.
Described protective agent comprises one or more in Tinuvin 1130, Tinuvin 292, Tinuvin 384-2.
A car repair preparation method for ultrafast dry cover varnish, it is characterized in that, the method comprises the following steps:
(1) first by recipe requirements 1 ~ 15wt% of organic solvent, protective agent are dropped in reactor, and stir, make and become intermediates a;
(2) first by recipe requirements 3 ~ 85wt% of organic solvent, flow agent are dropped in reactor, and stir, make and become intermediates b;
(3) first by recipe requirements 3 ~ 70wt% of organic solvent, siccative are dropped in reactor, and stir, make and become intermediates c;
(4) add acrylic resin modified resin in reactor, remain 6 ~ 70wt% of whole organic solvent or organic solvent; Stir 0.2 ~ 0.5 hour, order adds intermediates a, intermediates b, intermediates c on request, stirs 0.5 ~ 1 hour, filters, obtains mixture d;
(5) add crosslinking and curing agent resin in reactor, remain whole solvent; Stir 0.5 ~ 1 hour, filter, obtain Mischung;
(6) when using, Mischung is added mixture d, adjustment working viscosity, mixes rear construction.
Compared with prior art, this car repair ultrafast dry cover varnish and preparation method thereof, primarily of the composition such as acrylic resin modified, organic solvent, siccative, flow agent, crosslinking and curing agent, protective agent.The invention has the beneficial effects as follows: ultrafast dry, paint film appearance is smooth, and hardness is high, and gloss is high.
Embodiment
Elaborate to embodiments of the invention below, the present embodiment is implemented under premised on technical solution of the present invention, give detailed embodiment and concrete operating process, but protection scope of the present invention is not limited to following embodiment.
Embodiment 1
Hypomer FS-4660P 52g, butanone 5g, butylacetate 18g, propylene glycol methyl ether acetate 3g, dimethylbenzene 3g, DABCO T12 0.02g, BYK-358 0.3g, Levaslip 810 0.008g, DESMODUR3790 18.5g, Tinuvin 1130 0.4g, Tinuvin 292 0.2g.
Prepare the method for above-mentioned coating, comprise following processing step:
(1) by recipe requirements first by dimethylbenzene 3g, Tinuvin 1130 0.4g, Tinuvin 292 0.2g drop in reactor, and to stir, make and become intermediates a, make between each several part, to play collaborative usefulness, fully represent the effect of each component;
(2) by recipe requirements first by butylacetate 1g, Levaslip 810 0.008g drop in reactor, and to stir, make and become intermediates b, make between each several part, to play collaborative usefulness, fully represent the effect of each component; ;
(3) first butylacetate 1.8g, DABCO T12 0.02g is dropped in reactor by recipe requirements, and stir, make and become intermediates c, make between each several part, to play collaborative usefulness, fully represent the effect of each component;
(4) Hypomer FS-4660P 52g, remaining solvent is added in reactor; Stir 15 minutes, order adds intermediates a, b, c, stirs 45 minutes, filters, obtains mixture d;
(5) when using, DESMODUR 3790 18.5g is added d, construct after stirring;
Surface drying 3 minutes at 25 DEG C, hardness F after 20 minutes, gloss 95/60 °.
Embodiment 2
7313-X-70 60g, acetone 2g, butylacetate 7g, dimethylbenzene 5g, DABCO T12 0.03g, DABCO T120 0.02g, BYK-358 0.5g, Levaslip 835 0.03g, crosslinking and curing agent Basonat*HB 175MP/X 25g, Tinuvin 1130 0.8g, Tinuvin 384-2 0.4g.
Prepare the method for above-mentioned coating, comprise following processing step:
(1) first by recipe requirements acetone 2, Tinuvin 1130 0.8g, Tinuvin 384-2 0.4g are dropped in reactor, and stir, make and become intermediates a, make between each several part, to play collaborative usefulness, fully represent the effect of each component;
(2) first dimethylbenzene 2.5g, BYK-358 0.5g, Levaslip 835 0.03g is dropped in reactor by recipe requirements, and stir, make and become intermediates b, make between each several part, to play collaborative usefulness, fully represent the effect of each component; ;
(3) first dimethylbenzene 2.5g, DABCO T120 0.02g, DABCO T12 0.03g are dropped in reactor by recipe requirements, and stir, make and become intermediates c, make between each several part, to play collaborative usefulness, fully represent the effect of each component; ;
(4) add acrylic resin modified resin 7313-X-70 60g in reactor, butylacetate 2g stirs 5 minutes, be sequentially added into intermediates a, b, c, stir 0.5 ~ 1 hour, filter, obtain mixture d;
(5) crosslinking and curing agent resin B asonat*HB 175MP/X 25g, butylacetate 5g is added in reactor; Stir 0.5 ~ 1 hour, filter, obtain Mischung;
(6), when using, Mischung is added d, mixes rear spray plate;
Surface drying 4 minutes at 15 DEG C, can polishing after 18 minutes, gloss 96/60 ° after polishing.
Embodiment 3
Setlux 1280 50g, acetone 4g, butanone 4g, butylacetate 21g, dimethylbenzene 3g, DABCO T1200.024g, BYK-331 0.06g, BYK-361 0.3g, crosslinking and curing agent DESMODUR 3790 18g, Tinuvin 1130 0.4g, Tinuvin 292 0.2g.
Prepare the method for above-mentioned coating, comprise following processing step:
(2) first dimethylbenzene 0.6g, BYK-331 0.06g is dropped in reactor by recipe requirements, and stir, make and become intermediates b, make between each several part, to play collaborative usefulness, fully represent the effect of each component;
(3) first dimethylbenzene 2.4g, DABCO T120 0.024g is dropped in reactor by recipe requirements, and stir, make and become intermediates c, make between each several part, to play collaborative usefulness, fully represent the effect of each component;
(4) acrylic resin modified resin setlux 1280 50g, acetone 4g, butanone 4g, butylacetate 19g is added in reactor; Stir 10 minutes, add intermediates b, c, BYK-361 0.3g, Tinuvin 1130 0.4g, Tinuvin 292 0.2g, stirs 0.5 ~ 1 hour, filters, obtains mixture d;
(5) crosslinking and curing agent DESMODUR 3790 18g, butylacetate 2g is added in reactor; Stir 0.5 ~ 1 hour, filter, obtain Mischung;
(6), when using, Mischung is added d, mixes rear spraying;
Surface drying 4 minutes at 20 DEG C, hardness F after 25 minutes, gloss 93/60 °.
Embodiment 4
Setlux 1280 30g, 7313-X-70 15g, butanone 6g, butylacetate 22g, acetone 4g, dimethylbenzene 8g, DABCO T120 0.05g, BYK-331 0.5g, Levaslip 495 0.03g, crosslinking and curing agent DESMODUR 3390 15g, Tinuvin 1130 0.4g, Tinuvin 384-2 0.2g.
Prepare the method for above-mentioned coating, comprise following processing step:
(1) by recipe requirements first by dimethylbenzene 2g, Tinuvin 1130 0.4g, Tinuvin 384-2 0.2g drop in reactor, and to stir, make and become intermediates a, make between each several part, to play collaborative usefulness, fully represent the effect of each component;
(2) first butylacetate 2g, BYK-331 0.5g, Levaslip 495 0.03g is dropped in reactor by recipe requirements, and stir, make and become intermediates b, make between each several part, to play collaborative usefulness, fully represent the effect of each component;
(3) first acetone 4g, DABCO T120 0.05g is dropped in reactor by recipe requirements, and stir, make and become intermediates c, make between each several part, to play collaborative usefulness, fully represent the effect of each component; ;
(4) acrylic resin modified resin setlux 1280 32g, 7313-X-70 16g, butylacetate 15g, butanone 6g, dimethylbenzene 6g is added in reactor; Stir 10-15 minute, order adds intermediates a, b, c on request, stirs 0.5 ~ 1 hour, filters, obtains mixture d;
(5) crosslinking and curing agent DESMODUR 3390 15g, butylacetate 5g is added in reactor; Stir 0.5 ~ 1 hour, filter, obtain Mischung;
(6) when using, Mischung is added d, add a small amount of mixed solvent adjustment working viscosity if desired, mix rear construction;
Surface drying 4 minutes at 12 DEG C, hardness F after 25 minutes, gloss 93/60 °.
Embodiment 5
The ultrafast dry cover varnish of a kind of car repair, this varnish comprises following component and weight part content: acrylic resin modified 45, organic solvent 40, siccative 0.01, flow agent 0.8, crosslinking and curing agent 15, protective agent 0.3.
Described acrylic resin modified be hydroxy-containing resin, the hydroxy radical content of resin is 4%.Described siccative is aerochemistry DABCO series product.Described crosslinking and curing agent is aliphatic polymeric isocyanate.Described flow agent is BYK-331; Described organic solvent is acetone.Described protective agent is Tinuvin 1130.
The above-mentioned car repair preparation method of ultrafast dry cover varnish, the method comprises the following steps:
(1) first by recipe requirements the 15wt% of organic solvent, protective agent are dropped in reactor, and stir, make and become intermediates a;
(2) first by recipe requirements the 3wt% of organic solvent, flow agent are dropped in reactor, and stir, make and become intermediates b;
(3) first by recipe requirements the 70wt% of organic solvent, siccative are dropped in reactor, and stir, make and become intermediates c;
(4) 6wt% of acrylic resin modified resin, organic solvent is added in reactor; Stir 0.2 hour, order adds intermediates a, intermediates b, intermediates c on request, stirs 0.5 hour, filters, obtains mixture d;
(5) add crosslinking and curing agent resin in reactor, remain whole solvent; Stir 0.5 hour, filter, obtain Mischung;
(6) when using, Mischung is added mixture d, adjustment working viscosity, mixes rear construction.
Embodiment 6
The ultrafast dry cover varnish of a kind of car repair, this varnish comprises following component and weight part content: acrylic resin modified 60, organic solvent 14, siccative 0.03, flow agent 0.5, crosslinking and curing agent 20, protective agent 1.
Described acrylic resin modified be hydroxy-containing resin, the hydroxy radical content of resin is 5%.Described siccative is aerochemistry DABCO series product.Described crosslinking and curing agent is aliphatic polymeric isocyanate.Described flow agent is Levaslip 810; Described organic solvent is butanone.Described protective agent is Tinuvin 292.
The above-mentioned car repair preparation method of ultrafast dry cover varnish, the method comprises the following steps:
(1) first by recipe requirements the 1wt% of organic solvent, protective agent are dropped in reactor, and stir, make and become intermediates a;
(2) first by recipe requirements the 85wt% of organic solvent, flow agent are dropped in reactor, and stir, make and become intermediates b;
(3) first by recipe requirements the 3wt% of organic solvent, siccative are dropped in reactor, and stir, make and become intermediates c;
(4) 10wt% of acrylic resin modified resin, organic solvent is added in reactor; Stir 0.5 hour, order adds intermediates a, intermediates b, intermediates c on request, stirs 1 hour, filters, obtains mixture d;
(5) add crosslinking and curing agent resin in reactor, remain whole solvent; Stir 1 hour, filter, obtain Mischung;
(6) when using, Mischung is added mixture d, adjustment working viscosity, mixes rear construction.
Embodiment 7
The ultrafast dry cover varnish of a kind of car repair, this varnish comprises following component and weight part content: acrylic resin modified 55, organic solvent 20, siccative 0.05, flow agent 0.4, crosslinking and curing agent 20, protective agent 0.8.
Described acrylic resin modified be hydroxy-containing resin, the hydroxy radical content of resin is 4.2%.Described siccative is aerochemistry DABCO series product.Described crosslinking and curing agent is aliphatic polymeric isocyanate.Described flow agent is Levaslip 810; Described organic solvent is butanone.Described protective agent is Tinuvin 292.
The above-mentioned car repair preparation method of ultrafast dry cover varnish, the method comprises the following steps:
(1) first by recipe requirements the 5wt% of organic solvent, protective agent are dropped in reactor, and stir, make and become intermediates a;
(2) first by recipe requirements the 10wt% of organic solvent, flow agent are dropped in reactor, and stir, make and become intermediates b;
(3) first by recipe requirements the 5wt% of organic solvent, siccative are dropped in reactor, and stir, make and become intermediates c;
(4) 70wt% of acrylic resin modified resin, organic solvent is added in reactor; Stir 0.5 hour, order adds intermediates a, intermediates b, intermediates c on request, stirs 1 hour, filters, obtains mixture d;
(5) add crosslinking and curing agent resin in reactor, remain whole solvent; Stir 1 hour, filter, obtain Mischung;
(6) when using, Mischung is added mixture d, adjustment working viscosity, mixes rear construction.

Claims (9)

1. the ultrafast dry cover varnish of car repair, it is characterized in that, this varnish comprises following component and weight part content: acrylic resin modified 45-60, organic solvent 14-40, siccative 0.01 ~ 0.05, flow agent 0.3-0.8, crosslinking and curing agent 12-25, protective agent 0.3-1.2.
2. the ultrafast dry cover varnish of car repair according to claim 1, is characterized in that, described acrylic resin modified be hydroxy-containing resin, the hydroxy radical content of resin is 4-5%, is preferred with primary, secondary hydroxyl content height.
3. the ultrafast dry cover varnish of car repair according to claim 1 and 2, it is characterized in that, the hydroxy radical content of described hydroxy resin is 4.2-4.6%, comprises Hypomer FS-4660P, setlux 1280,7313-X-70 be used alone or used in combination.
4. the ultrafast dry cover varnish of car repair according to claim 1, it is characterized in that, described siccative is organometallic compound, comprises aerochemistry DABCO series product.
5. the ultrafast dry cover varnish of car repair according to claim 1, it is characterized in that, described crosslinking and curing agent is isocyanurate compound, comprises the DESMODUR series product of BAYER company, BASF Basonat series product.
6. the ultrafast dry cover varnish of car repair according to claim 1, is characterized in that, described flow agent is organosilyl surface auxiliary agent, acrylic acid or the like leveling auxiliary agent; Comprise BYK-331, BYK-332, BYK-358, BYK-361, Levaslip 810, Levaslip 468, Levaslip 495, Levaslip 835.
7. the ultrafast dry cover varnish of car repair according to claim 1, it is characterized in that, described organic solvent comprises acetone, butanone, butylacetate, one or more in propylene glycol methyl ether acetate or dimethylbenzene.
8. the ultrafast dry cover varnish of car repair according to claim 1, it is characterized in that, described protective agent comprises one or more in Tinuvin 1130, Tinuvin 292, Tinuvin 384-2.
9. a car repair as claimed in claim 1 preparation method for ultrafast dry cover varnish, it is characterized in that, the method comprises the following steps:
(1) first by recipe requirements 1 ~ 15wt% of organic solvent, protective agent are dropped in reactor, and stir, make and become intermediates a;
(2) first by recipe requirements 3 ~ 85wt% of organic solvent, flow agent are dropped in reactor, and stir, make and become intermediates b;
(3) first by recipe requirements 3 ~ 70wt% of organic solvent, siccative are dropped in reactor, and stir, make and become intermediates c;
(4) add acrylic resin modified resin in reactor, remain 6 ~ 70wt% of whole organic solvent or organic solvent; Stir 0.2 ~ 0.5 hour, order adds intermediates a, intermediates b, intermediates c on request, stirs 0.5 ~ 1 hour, filters, obtains mixture d;
(5) add crosslinking and curing agent resin in reactor, remain whole solvent; Stir 0.5 ~ 1 hour, filter, obtain Mischung;
(6) when using, Mischung is added mixture d, adjustment working viscosity, mixes rear construction.
CN201510086480.2A 2015-02-16 2015-02-16 Superfast-dried hood surface varnish for repairing automobiles and preparation method of varnish Pending CN104592837A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107629602A (en) * 2017-10-18 2018-01-26 王天石 A kind of automobile specified quick drying paint and preparation method thereof
CN107674529A (en) * 2017-09-13 2018-02-09 万建辉 A kind of automobile varnish and its production technology of efficiently quick service
CN109722156A (en) * 2018-12-28 2019-05-07 东来涂料技术(上海)股份有限公司 A kind of quick-dry type car refinishing paint bloom varnish and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101812261A (en) * 2010-02-10 2010-08-25 商丘市博大化工有限公司 Ultra-fast dry repair varnish for automobiles and preparation method thereof
CN102827501A (en) * 2012-08-02 2012-12-19 中山大桥化工企业集团中山智亨实业发展有限公司 Double-curing varnish paint

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101812261A (en) * 2010-02-10 2010-08-25 商丘市博大化工有限公司 Ultra-fast dry repair varnish for automobiles and preparation method thereof
CN102827501A (en) * 2012-08-02 2012-12-19 中山大桥化工企业集团中山智亨实业发展有限公司 Double-curing varnish paint

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107674529A (en) * 2017-09-13 2018-02-09 万建辉 A kind of automobile varnish and its production technology of efficiently quick service
CN107629602A (en) * 2017-10-18 2018-01-26 王天石 A kind of automobile specified quick drying paint and preparation method thereof
CN109722156A (en) * 2018-12-28 2019-05-07 东来涂料技术(上海)股份有限公司 A kind of quick-dry type car refinishing paint bloom varnish and preparation method thereof

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Application publication date: 20150506