CN104592826A - An antiskid composition - Google Patents
An antiskid composition Download PDFInfo
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- CN104592826A CN104592826A CN201310533694.0A CN201310533694A CN104592826A CN 104592826 A CN104592826 A CN 104592826A CN 201310533694 A CN201310533694 A CN 201310533694A CN 104592826 A CN104592826 A CN 104592826A
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Abstract
An antiskid composition is provided. The composition comprises colloid silica, acrylic polymer, a film coalescing aid, and water that is adopted as a medium. The composition is used for increasing the surface COF (coefficient of friction) value without influences on appearance, and even for increasing surface gloss.
Description
Technical field
The embodiments of the present invention relate to the anti-skidding composition that can be used for various ground.
Background technology
The mode of anti-skidding process is implemented in current existence two kinds.Wherein one is so-called " skid-resistant coating " (defining " nonskidcoating ").This coating improves surfaceness, by adding some irregular frictional coefficient (coefficient of friction, COF) adding substrate that gather materials.Similar with embossment, this coating prevents object to be moved on the surface processed.But, this method reduce the gloss on surface, and the pore (stoma) on surface that the coating containment formed such as is formed by lithotome.Another kind of common method is for using anti-skidding treatment agent.So-called anti-skidding treatment agent normally based on the liquid of water, and can penetrate in the capillary channel of patch block or stone material, then reacts with the latter thus expands this capillary channel.Aperture on this surface plays the effect of suction cup, and thus can be effectively anti-skidding.But anti-skidding treatment agent is harmful to floor or its surface usually to a certain extent, and is not therefore suitable for the floor base material of all kinds.
U.S. Patent application US20090022979Al, " Anti-slip floor coating compositionand anti-slip floor material made therefrom ", describe a kind of abrasive floor coating, it comprises propionic acid acid resin, inorganic additives (comprising particle diameter at the particle of 20 ~ 600 μm) and cement flour.Such coating is opaque, and has hidden the lines of treated surface.
U.S. Patent application US5885339A, " Non-slip fomulations ", describes and prevents natural or inorganic materials or cement products becomes smooth, particularly wet and slippery preparation and method.Calcium preparation comprises: not fluorine-containing acid; Fluorine-containing acid, hydrosulfate or acetic acid; And tensio-active agent.New sanitising agent is further disclosed in this article.But this anti-skid preparation has effect by means of only generating special anti-skid structure with contained calcium carbonate reaction in surface to the surface based on calcium.Therefore, being of limited application of said preparation.On the other hand, said preparation can be very remarkable for the harm of treated surface and environment, because the acidity of said preparation is stronger.
Therefore, still need so a kind of anti-skidding composition, this anti-skidding composition is not only transparent and is " sightless ", and can be used for the base material of all kinds or surface and do not affect their original appearance.Use this anti-skidding composition, can obtain surface frictional coefficient (COF) value and outward appearance as the balance between gloss.In addition, the outstanding performance of this anti-skidding composition can bring extra benefit, that is, even can help the liability for damage avoided any employee or human consumer in growing infringement action atmosphere.
The content of innovation and creation
Anti-skidding composition of the present invention comprises colloid silica, acrylic polymers, film coalescence aid and vehicular water, does not affect its outward appearance for increasing the COF value on surface, and even increases the glossiness on this surface.An embodiment is a kind of anti-skidding composition, and it comprises colloid silica, the acrylic polymers of 0.1 ~ 10 % by weight, the film coalescence aid of 0.1 ~ 12 % by weight of 2.5 ~ 50 % by weight, and is added into the water of 100 % by weight, based on the gross weight of composition.Have been found that composition according to the present invention is shown in various floor surface, and be particularly suitable for smooth surface, the example includes but not limited to, the lithotome (as marble and grouan) of crystal face process, polished tile and vitrified tile.
Another aspect provides the purposes of above-mentioned anti-skidding composition in surface treatment, particularly anti-skidding process.
Another aspect of the invention provides the method for process floor surface, comprising: be administered on described floor surface by above-mentioned anti-skidding composition.
The embodiments of the present invention additionally provide a kind of multifunctional preparation, it comprises anti-skidding composition of the present invention and one or more other floor treatment agents, as sanitising agent, stain control agent, optical brightener and sterilizing agent, thus achieve the floor treatment agent with two or more functions.
Embodiment
In order to more clearly show object of the present invention, technical scheme and advantage, below by the clear technical scheme fully describing the embodiments of the present invention.Obviously, described each embodiment is only more of the present invention instead of whole embodiment.
The present inventor have been surprisingly found that, the anti-skidding composition comprising following component has previously described outstanding character, that is, said composition is being applied to any surface afterwards for sightless, and can give this surface with described anti-skidding effect and bright outward appearance:
(1) colloid silica;
(2) acrylic polymers;
(3) film coalescence aid; With
(4) water.
In some embodiments, anti-skidding composition of the present invention can be made up of colloid silica, acrylic polymers, film coalescence aid and water.
Colloid silica
Generally speaking, colloid silica is silicon-dioxide (SiO
2) dispersion of particle in aqueous phase.Silicon-dioxide (SiO in aqueous phase
2) particle can be meticulous amorphous, atresia and normally spherical.The preparation method of colloid silica is well known in the art, such as, have ion exchange method, sour neutralisation and hydrolysis method etc.Colloid silica being widely used in the industry.Such as, it can be used as the abradant of drainage aids, tackiness agent, moisture adsorbent, support of the catalyst and polished silicon slice in paper-making process, etc.Containing the composition of colloid silica as necessity in anti-skidding composition of the present invention.
Depend on concrete preparation process or as required, colloid silica can have the SiO of different concns
2particle.In the present invention, the concentration of the colloid silica used in the present invention is not particularly limited.Generally speaking, colloid silica can containing the SiO of 10 ~ 50 % by weight, such as 20 ~ 45 % by weight
2particle.More specifically, colloid silica can containing the SiO of 10 ~ 50 % by weight, such as 30 ~ 40 % by weight
2particle.
Depend on concrete preparation process or as required, colloid silica can have different SiO
2grain diameter.In the present invention, the particle diameter of the colloid silica used in the present invention is not particularly limited.Generally speaking, SiO
2the particle diameter that particle can have is 4 ~ 75nm.More specifically, SiO
2the particle diameter that particle can have is 10 ~ 20nm.
Colloid silica commercially can buy acquisition.Such as, colloid silica can obtain from Nalco company with the purchase such as trade(brand)name Nalco1034A, Nalco2327, or obtains from AkzoNobel company with the purchase such as trade(brand)name AkzoNobel R301, AkzoNobel R900.
The colloid silica used in the present invention can also be prepared according to procedures known in the art.Those of ordinary skill in the art know how to regulate SiO according to actual needs
2the concentration of particle and SiO
2particle diameter.The preparation method of colloid silica can be see, and such as, US6372806B1, is incorporated herein by reference its full content.
Generally speaking, this anti-skidding composition comprises the colloid silica of about 1 ~ 60 % by weight, based on the gross weight of composition.In some embodiments, this anti-skidding composition comprises the colloid silica of about 2.5 ~ 50 % by weight, based on the gross weight of composition.Such as, the amount of the colloid silica in anti-skidding composition can be 3 ~ 40 % by weight or 4 ~ 25 % by weight, more specifically, can be 5 ~ 20 % by weight, based on the gross weight of composition.
Acrylic polymers
Acrylic polymers is also referred to as acrylic polymer emulsions, that is, the emulsion of acrylic polymer particles, wherein acrylic polymers is dispersed in emulsion as uniform particles.Acrylic polymers is typically used as the solvent in coating or paint systems.It can be prepared according to methods known in the art.Generally speaking, the solid content of acrylic polymers is 30 % by weight ~ 60 % by weight.In some embodiments, the solid content of acrylic polymers is 30 % by weight to 50 % by weight.More specifically, the solid content of acrylic polymers can be 40 % by weight to 50 % by weight.
Acrylic polymers is intended to multipolymer or the ter-polymers of the ester, hydroxyethyl methylacrylate, methacrylonitrile, vinyl cyanide etc. representing acrylic or methacrylic acid and acrylic or methacrylic acid.Also other monomer be can use in the present invention, methyl methacrylate, butyl acrylate, ethyl propenoate and 2-EHA comprised.
Other unsaturated acid monomer also can with being used for also partly to substitute preferred methacrylic acid.Such unsaturated acid monomer comprises toxilic acid, β-crotonic acid, fumaric acid and methylene-succinic acid.
Unsaturated monomer is usually containing at least one vinyl.Like this be preferably vinylbenzene or mono alkenyl aromatic monomer as vinyl toluene or t-butyl styrene containing the composition of vinyl.A part wherein can be replaced with water-fast vinyl monomer or be slightly soluble in the vinyl monomer of water, such as ethyl acetate or methyl acrylate.
The preferred polymer/copolymer of typical case comprises: styrene/acrylic butyl ester/Sipacril 2739OF, styrene/acrylic ethyl ester/Sipacril 2739OF, styrene/acrylic butyl ester/vinylformic acid second multipolymer and methacrylate polymer.Other polymer/copolymer comprises: styrene/acrylic butyl ester/acrylic copolymer, styrene/acrylic ethyl ester/acrylic copolymer, styrene/acrylic butyl ester/ethyl propenoate/acrylic copolymer and vinyl toluene/styrene/acrylic butyl ester/ethyl propenoate/methacrylic acid/acrylic copolymer.
The particle diameter of the acrylic polymers be dispersed in emulsion and size distribution are not particularly limited.Generally speaking, acrylic polymers can have the median size of 150 ~ 300 nanometers (nm).In some embodiments, median size is 150nm ~ 250nm.Generally speaking, size distribution is Gaussian distribution, and wherein the particle of 80% is in the scope of median size +/-30nm.
Generally speaking, anti-skidding composition comprises the acrylic polymers of 0.1 ~ 10 % by weight, based on the gross weight of composition.In some embodiments, anti-skidding composition comprises the acrylic polymers of 1 ~ 5 % by weight, based on the gross weight of composition.
Acrylic polymers commercially can buy acquisition.Such as, acrylic polymers can obtain as MorGlo2 buys from Omnova Co. with trade(brand)name, or obtains from Rohm Haas Co. with the purchase such as trade(brand)name Primal2133 or Rhoplex wl91.
Acrylic polymers is generally nonvolatile.Therefore, anti-skidding composition of the present invention is being applied to surface and after drying, acrylic polymers constitutes film itself.According to the present invention, be understandable that, replace used acrylic polymers here, the polymkeric substance that can be formed film by drying process can be used in the present invention.The example of such polymkeric substance includes, but are not limited to: urethane, polycarbonate and polyethers.
Film coalescence aid
Anti-skidding composition of the present invention comprises one or more film coalescence aid further.Film coalescence aid at least has the function promoting film forming, and usually vapors away between film stage.Generally speaking, film coalescence aid total amount is in the composition 0.1 to 12 % by weight, based on the gross weight of composition.
In the present invention, anti-skidding composition of the present invention comprises furtherance membrane solvent (coalescent) and softening agent at least further as film coalescence aid.Be understandable that, when this anti-skidding composition only containing furtherance membrane solvent and softening agent as film coalescence aid, furtherance membrane solvent and softening agent total amount is in the composition 0.1 ~ 12 % by weight, based on the gross weight of composition.
Softening agent in the present invention can be selected from: tricresyl phosphate (butoxyethyl group) ester, 2,2,4-trimethylammonium-1,3-pentanediol diisobutyrates, dibutyl phthalate, dioctyl phthalate (DOP) and hexanolactam, or its combination.Generally speaking, tricresyl phosphate (butoxyethyl group) ester and dibutyl phthalate are respectively preferred softening agent.The amount of the softening agent that said composition can contain, for being up to 10 % by weight, is generally 0.5 ~ 5 % by weight, based on the gross weight of composition.
The furtherance membrane solvent used in the present invention can be selected from ethylene glycol, diethylene, diethylene glycol ethyl ether, dipropylene glycol methyl ether, dipropylene monoethylether, diethylene glycol monobutyl ether acetic ester, ethylene glycol-2-ethylhexyl ether and 2,2,4-trimethylammonium-1,3-pentanediol list (2-methyl propionate), or its combination.Generally speaking, diethylene glycol ethyl ether and dipropylene glycol methyl ether are respectively preferred furtherance membrane solvent.The amount of the softening agent that said composition can contain is maximum 10 % by weight, is generally 0.5 ~ 3 % by weight, based on the gross weight of composition.
Other component
Anti-skidding composition can regulate composition itself containing other component or the physics of film that formed by it and/or chemical property further.Such character can comprise stability, dispersiveness, color, smell, storage life etc.Such as, anti-skidding composition can contain one or more tensio-active agents, one or more optical brighteners, one or more solvents, one or more perfume compound further.Their respective amounts in the composition can regulate according to practical application or as requested.
Optionally, anti-skidding composition of the present invention contains other component as film coalescence aid.Such as, said composition can contain one or more tensio-active agents.Kinds of surface promoting agent can be used in anti-skidding composition, include but not limited to: anionic, non-ionic type, cationic and amphoteric (comprising amphoteric ion type) tensio-active agent.Operable exemplary surfactants can obtain from a lot of source purchase.When this anti-skidding composition comprises the composition of tensio-active agent or tensio-active agent, the amount of the tensio-active agent provided will provide the functional of aspiration level effectively, such as wettability, stability, foam property and spatter property.Available tensio-active agent, such as, see mention in US2012/0149623A1 those, its entirety is incorporated herein by reference.
In some embodiments, anti-skidding composition of the present invention comprises:
The colloid silica of (1) 2.5 ~ 50 % by weight;
The acrylic polymers of (2) 0.1 ~ 10 % by weight;
The film coalescence aid of (3) 0.1 ~ 12 % by weight; With
(4) water of 100 % by weight is added into,
Based on the gross weight of composition.
In some embodiments, anti-skidding composition of the present invention can be made up of colloid silica, the acrylic polymers of 0.1 ~ 10 % by weight, the film coalescence aid of 0.1 ~ 12 % by weight and the water that is added into 100 % by weight of 2.5 ~ 50 % by weight.
In a particular embodiment, anti-skidding composition comprises the colloid silica of 5 ~ 20 % by weight, based on the gross weight of composition.
In a particular embodiment, anti-skidding composition comprises the acrylic polymers of 1 ~ 5 % by weight, based on the gross weight of composition.
In a particular embodiment, anti-skidding composition comprises furtherance membrane solvent and softening agent as film coalescence aid.In embodiment more specifically, anti-skidding composition comprises the furtherance membrane solvent of 0.5 ~ 3 % by weight, based on the gross weight of composition.In embodiment more specifically, anti-skidding composition comprises the softening agent of 0.5 ~ 5 % by weight, based on the gross weight of composition.
In a preferred embodiment, anti-skidding composition of the present invention comprises:
The colloid silica of (1) 5 ~ 20 % by weight;
The acrylic polymers of (2) 1 ~ 5 % by weight;
The furtherance membrane solvent of (3) 0.5 ~ 3 % by weight;
The softening agent of (4) 0.5 ~ 5 % by weight; With
(5) water of 100 % by weight is added into,
Based on the gross weight of composition.
Composition according to the present invention is inertia, and can easily prepare.In addition, said composition imparts the balance between anti-skidding character and glossy appearance to the surface that wherethrough is managed, and does not destroy or hide the texture of treated surface (such as floor tile, marble, grouan or terrazzo).Composition according to the present invention is suitable for various ground, and is particularly suitable for smooth surface, and the example includes but not limited to the lithotome (as marble and grouan) of crystal face process, polished tile and vitrified tile.
Anti-skidding composition of the present invention can mix with other floor treatment agent or floor finishing composition, such as sanitising agent, stain control agent, optical brightener and/or sterilizing agent, etc.In other words, anti-skidding composition can be mixed with multifunctional preparation by adding known or new floor finishing composition, and described floor finishing composition includes but not limited to sanitising agent, stain control agent, optical brightener and/or sterilizing agent.For concrete sanitising agent, stain control agent, optical brightener and/or the sterilizing agent that may be used in the present invention, see U.S. Patent application US2012/0149623A1, its entirety can be incorporated herein by reference.
The add-on of sanitising agent, stain control agent, optical brightener and/or sterilizing agent is as the criterion to be enough to realizing their corresponding functions.According to actual requirement, those skilled in the art will know that and how to determine their corresponding components and corresponding suitable amount.Anti-skidding composition can mix in a usual manner with mixing of sanitising agent, stain control agent, optical brightener and/or sterilizing agent.Such as, the difunctional preparation of anti-skidding/sanitising agent can be prepared by being added in anti-skidding composition of the present invention by the activeconstituents of sanitising agent, or prepares by being mixed by all components.Such as, the multifunctional preparation of anti-skidding/clean/sterilizing agent can be prepared by being added in anti-skidding composition of the present invention with any order by the activeconstituents of sanitising agent and sterilizing agent, or prepares by being mixed by all components simply.
Alternatively, anti-skidding composition of the present invention can use with any sequential combination with sanitising agent, stain control agent, optical brightener and/or sterilizing agent.
Application process
Anti-skidding composition of the present invention this as instant, that is, can directly use.Alternatively, before this anti-skidding composition of use, this anti-skidding composition can be diluted with water to diluting soln and use.Such as, the Dilution ratio of said composition and water can be about 1:10 to about 1:1.
In order to the cost saving transport or store, sometimes by reducing part water, this anti-skidding composition can be condensed into conc forms.In this case, before administration, conc forms can be about 1:256 ~ about 1:128 to about 1:64 ~ about 1:11 to the Dilution ratio of water, depends on practical use.
The solution of this use can be applied in the substrate of cated or uncoated, porous or the atresia of various tool, comprise stone surface such as marble, concrete (polishing concrete), grouan, terrazzo and ceramic tile, and other surface, such as timber, veneer sheet, oilcloth (linoleum) and vinyl composite floor board (vinyl composition tile).Every day or weekly anti-skidding composition is applied on the surface.In one embodiment, said composition was applied to surface in one week at least three days.In an alternative embodiment, once a day said composition is applied to surface.Application process comprises: use this anti-skidding composition by any known mode.Such as, said composition can use cleanser, mop, cylinder or atomizer to use.The example of suitable cleanser comprises manual and automatic floor cleaning device.The example of suitable mop comprises line formula mop and board-like mop.
The surface of anti-skidding compositions-treated is used generally composition to be applied to 1 hour inner drying on the surface.But the surface being coated with composition to the dry time is depended on and composition is applied to the method and envrionment conditions that surface uses.Use the surface of compositions-treated can about 30 minutes, about 15 minutes, about 5 minutes and about 1 minute inner drying after composition is applied to surface.Such as, if use mop and bucket to use composition, so surface can at about 5 ~ 15 minutes inner dryings.If use automatic cleaning machine to use said composition, so this surface will be almost dry immediately.
Cover box/cleaning system
According to further embodiment of the present invention, anti-skidding composition of the present invention can be packed and provide with the form of overlapping box.According to the embodiment of the present invention, system can comprise, formed by following and/or be substantially made up of following: the operation instruction of spreading implement (applicator), this system, anti-skidding composition of the present invention, optional remove the stain remover of various dirt, optional sanitising agent, optional scale remover, optional stain control agent and optional different slipproofing agent, optional optical brightener from treat surface, and/or optional sterilizing agent.Exemplary spreading implement includes but not limited to: cleanser, mop, cylinder or atomizer.The example of suitable cleanser comprises manual and automatic floor cleaning device.The example of suitable mop comprises line formula mop and board-like mop.
As described above, this anti-skidding composition can mix and combine by the floor finishing composition known with other, and other floor finishing composition includes but not limited to sanitising agent, stain control agent, optical brightener and/or sterilizing agent.Anti-skidding composition and other floor finishing composition can provide in the container separated.The inclusion of each container can combined administration or be applied directly on pending flooring substrate, or first dilute with water uses solution to be formed, and then uses.Alternatively, this anti-skidding composition and other floor finishing composition (if present) can dilute before each inclusion of combination forms use solution.
Embodiment
The present invention more specifically describes in embodiment hereafter, and these embodiments are only intended to explain, because adjustment numerically within the scope of the present invention and change are all obvious for those skilled in the art.Except as otherwise noted, all numbers, per-cent and the ratio reported in embodiment are all based on weight, and all reagent etc. used in an embodiment all obtains maybe can obtaining from chemical supplier hereinafter described, or can be synthesized by routine techniques.
Testing method
I. the measuring method of the glossiness of the substrate of anti-skidding composition is coated with
1. should measure glossiness in the substrate through applying of drying.Typically, coating drying at room temperature at least 24 hours, then should can obtain accurate glossiness.For applying the situation of carrying out glossiness research (coat-by-coat gloss studies) successively, glossiness should be recorded after coating is fully solidified.
2. guarantee that the surface through coating that will measure is without any dust or particle.
3. use glossiness measuring apparatus in the glossiness of the substrate of measurement of angle through applying of 60 °.Use typical BYK Gardner Tri-gloss.Record the mean value of at least five differences on the coating surface.Same record standard is deteriorated.
Relevant ASTM method: D1455
Relevant Europe superscript testing method (European Test Method): 6.5.5.7
II. the measuring method of the anti-skid of the substrate of anti-skidding composition is coated with
Utilize ANSIINFSI B101.1, B101.3 uses BOT-3000 (Digital Tribometer, Regan Scientific Instruments provides) to measure the frictional coefficient being coated with the common crust flooring substrate of anti-skidding composition.In this measurement, marble or grouan are used as test substrate.In this measurement, the frictional coefficient surveyed is static friction coefficient.The mean value of at least five differences on record coatingsurface.Same record standard deviation.
The exemplary formulations of anti-skidding composition
Below anti-skidding composition by by each component of the amount of giving to be added in water and fully prepared by mixing.All components is all by stirring 30 ~ 720 minutes to mix.Then, the surface of extremely being skidded by each mixture spray is also applied.
In following formula, TC and dipropylene glycol methyl ether are buied from DowChemical; Tricresyl phosphate (butoxyethyl group) ester and dibutyl phthalate are buied from Rhodia.All components all can commercially obtain, such as, from Dow Chemical, and Rhodia, RohmHaas or Nalco company.As acrylic polymers, use Primal2133 (41%, pH7.00 ~ 7.80, Rohm Haas).
Formula I:
Formula I I:
Formula I II:
Formula I V:
In following anti-skidding measurement, grouan is used as test substrate.According to aforesaid method, above-mentioned formula I is coated in substrate respectively to IV.Measure the COF reading be coated with at the bottom of formula I to the different granitic batholiths of IV.Acquired results row in table 1 below.
Table 1 is coated with the COF reading at the bottom of formula I to the granitic batholith of IV
| Formula | COF reading |
| Without (contrast) * | 0.32±0.03 |
| I | 0.49±0.02 |
| II | 0.54±0.02 |
| III | 0.60±0.02 |
| IV | 0.62±0.02 |
* without the COF reading that the former substrate of any process is measured
In following anti-skidding measurement, marble is used as test substrate.According to aforesaid method, above-mentioned formula I is coated in substrate respectively to IV.Measure and be coated with the COF reading of formula I to the different marble substrates of IV.Acquired results is listed in following table 2.
Table 2 is coated with the COF reading of formula I to the marble substrate of IV
| Formula | COF reading |
| Without (contrast) * | 0.36±0.02 |
| I | 0.50±0.02 |
| II | 0.59±0.02 |
| III | 0.62±0.02 |
| IV | 0.64±0.02 |
* without the COF reading that the former substrate of any process is measured
Formula V
Formula VI
Formula VII
In following glossiness is measured, grouan is used as test substrate.According to aforesaid method, above-mentioned formula I II, V to VII are coated in substrate respectively.Measure the glossiness reading at the bottom of different granitic batholiths being coated with formula I II, V to VII.Acquired results is listed in following table 3.
Table 3 is coated with the glossiness reading at the bottom of the granitic batholith of formula I II, V to VII
| Formula | Glossiness reading |
| III | 71.2±1.69 |
| V | 70.1±0.94 |
| VI | 65.7±1.50 |
| VII | 60.9±1.56 |
In following glossiness is measured, marble is used as test substrate.According to aforesaid method, above-mentioned formula I II, V to VII are coated in substrate respectively.Measure the glossiness reading of different marble substrates being coated with formula I II, V to VII.Acquired results is listed in following table 4.
Table 4 is coated with the glossiness reading of marble substrate of formula I II, V to VII
| Formula | Glossiness reading |
| III | 92.1±1.39 |
| V | 90.8±1.20 |
| VI | 81.8±2.71 |
| VII | 74.8±2.78 |
Following anti-skidding composition is prepared further according to similar method.All sightless with the anti-skidding composition of following preparation after in substrate being coated to above, the existence of naked eyes these compositions imperceptible, and the lines of substrate and clear patterns visible.The glossiness of these anti-skidding composition tests and COF reading is used all to show: anti-skidding composition of the present invention achieves the gratifying balance between substrate outward appearance and non-skid property, particularly for tested substrate.
Formula VIII
Formula I X
Formula X
Formula XI
Show the multifunctional preparation using anti-skidding composition of the present invention to prepare below.
Exemplary multifunctional preparation
Formula X: for abrasive floor sanitising agent that is clean and anti-skidding process
Formula X: for sterilizing and the abrasive floor sterilizing agent of anti-skidding process
Mentioned abovely be only illustrative embodiments of the present invention, do not limit the scope of the invention, scope of the present invention determined by appending claims.
Claims (15)
1. an anti-skidding composition, comprises:
The colloid silica of (1) 2.5 ~ 50 % by weight;
The acrylic polymers of (2) 0.1 ~ 10 % by weight;
The film coalescence aid of (3) 0.1 ~ 12 % by weight; With
All the other be added into 100 % by weight water,
Based on the gross weight of composition.
2. the composition of claim 1, wherein said colloid silica contains the SiO of 10 ~ 50 % by weight
2particle, and described SiO
2the particle diameter of particle is 4 ~ 75nm, is preferably 10 ~ 20nm.
3. the composition of claim 1, the solid content of wherein said acrylic polymers is 30 % by weight ~ 50 % by weight.
4. the composition of claim 3, wherein said acrylic polymers is selected from: styrene/acrylic butyl ester/Sipacril 2739OF, styrene/acrylic ethyl ester/Sipacril 2739OF, styrene/acrylic butyl ester/ethyl acrylate copolymer, methacrylate polymer, styrene/acrylic butyl ester/acrylic copolymer, styrene/acrylic ethyl ester/acrylic copolymer, styrene/acrylic butyl ester/ethyl propenoate/acrylic copolymer, vinyl toluene/styrene/acrylic butyl ester/ethyl propenoate/methacrylic acid/acrylic copolymer, or its mixture.
5. the composition of claim 4, the particle diameter of wherein said acrylic polymers is 150nm to 300nm.
6. the composition any one of Claims 1 to 5, the amount that wherein said anti-skidding composition contains colloid silica is 3 ~ 40 % by weight, preferably 4 ~ 25 % by weight, based on the gross weight of composition.
7. the composition any one of Claims 1 to 5, the amount that wherein said anti-skidding composition contains acrylic polymers is 1 ~ 5 % by weight, based on the gross weight of composition.
8. the composition of claim 1, wherein said film coalescence aid comprises furtherance membrane solvent and/or softening agent.
9. the composition of claim 8, it comprises:
The colloid silica of (1) 5 ~ 20 % by weight;
The acrylic polymers of (2) 1 ~ 5 % by weight;
The furtherance membrane solvent of (3) 0.5 ~ 3 % by weight;
The softening agent of (4) 0.5 ~ 5 % by weight; With
(5) water of 100 weight is added into,
Based on the gross weight of composition.
10. the composition of claim 8 or 9, wherein said furtherance membrane solvent is selected from ethylene glycol, diethylene, diethylene glycol ethyl ether, dipropylene glycol methyl ether, dipropylene monoethylether, diethylene glycol monobutyl ether acetic ester, ethylene glycol-2-ethylhexyl ether and 2,2,4-trimethylammonium-1,3-pentanediol list (2-methyl propionate), or its mixture.
The composition of 11. claims 8 or 9, wherein said softening agent is selected from tricresyl phosphate (butoxyethyl group) ester, 2,2,4-trimethylammoniums-1,3-pentanediol diisobutyrate, dibutyl phthalate, dioctyl phthalate (DOP) and hexanolactam, or its mixture.
Composition any one of 12. claims 1 to 11, comprises sanitising agent, stain control agent, optical brightener and/or sterilizing agent further.
The purposes of composition any one of 13. claims 1 to 12 in surface treatment, particularly anti-skidding process.
The method of 14. process floor surfaces, comprising:
Anti-skidding composition any one of claim 1 to 12 is administered on described floor surface.
15. cover boxes, it comprises:
Spreading implement;
From the stain remover on the surface except crude removal;
The operation instruction of this cover box; With
Anti-skidding composition any one of claim 1 to 12.
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| CN201310533694.0A CN104592826A (en) | 2013-11-01 | 2013-11-01 | An antiskid composition |
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| CN201310533694.0A CN104592826A (en) | 2013-11-01 | 2013-11-01 | An antiskid composition |
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| CN201310533694.0A Pending CN104592826A (en) | 2013-11-01 | 2013-11-01 | An antiskid composition |
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Cited By (2)
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| CN104845468A (en) * | 2015-05-15 | 2015-08-19 | 上海海悦涂料有限公司 | Hydrophilic deck finishing coat, preparation method thereof and anti-skid treatment method of deck |
| CN107880848A (en) * | 2017-10-25 | 2018-04-06 | 刘彦麟 | A kind of floor tile decontamination antilubricant and floor tile decontaminate anti-skidding method |
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| CN104845468A (en) * | 2015-05-15 | 2015-08-19 | 上海海悦涂料有限公司 | Hydrophilic deck finishing coat, preparation method thereof and anti-skid treatment method of deck |
| CN107880848A (en) * | 2017-10-25 | 2018-04-06 | 刘彦麟 | A kind of floor tile decontamination antilubricant and floor tile decontaminate anti-skidding method |
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