CN104592788B - A kind of blue disperse dye composition of stamp - Google Patents
A kind of blue disperse dye composition of stamp Download PDFInfo
- Publication number
- CN104592788B CN104592788B CN201410819550.6A CN201410819550A CN104592788B CN 104592788 B CN104592788 B CN 104592788B CN 201410819550 A CN201410819550 A CN 201410819550A CN 104592788 B CN104592788 B CN 104592788B
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- dyestuff
- stamp
- weight fraction
- disperse dye
- dye composition
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- 239000000986 disperse dye Substances 0.000 title claims abstract description 24
- 239000000203 mixture Substances 0.000 title claims abstract description 17
- 239000000975 dye Substances 0.000 claims abstract description 56
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 239000007859 condensation product Substances 0.000 claims description 2
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims 1
- 238000005406 washing Methods 0.000 abstract description 9
- 238000000859 sublimation Methods 0.000 abstract description 7
- 230000008022 sublimation Effects 0.000 abstract description 7
- 239000000428 dust Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- JSFUMBWFPQSADC-UHFFFAOYSA-N Disperse Blue 1 Chemical compound O=C1C2=C(N)C=CC(N)=C2C(=O)C2=C1C(N)=CC=C2N JSFUMBWFPQSADC-UHFFFAOYSA-N 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- LEGWLJGBFZBZSC-UHFFFAOYSA-N n-[2-[(2,6-dicyano-4-nitrophenyl)diazenyl]-5-(diethylamino)phenyl]acetamide Chemical compound CC(=O)NC1=CC(N(CC)CC)=CC=C1N=NC1=C(C#N)C=C([N+]([O-])=O)C=C1C#N LEGWLJGBFZBZSC-UHFFFAOYSA-N 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 229920005610 lignin Polymers 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- ZRLYFONGBAKSBB-OFWBYEQRSA-N 2-[(2z)-2-[[4-(dihexylamino)-2-methylphenyl]methylidene]-1,1-dioxo-1-benzothiophen-3-ylidene]propanedinitrile Chemical compound CC1=CC(N(CCCCCC)CCCCCC)=CC=C1\C=C\1S(=O)(=O)C2=CC=CC=C2C/1=C(C#N)C#N ZRLYFONGBAKSBB-OFWBYEQRSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 0 CCCCCCN(CCCCC*)C1=CC[C@@](C=C(C(c2c3cccc2)=C(C#N)C#N)S3(=*)=O)C(C)=C1 Chemical compound CCCCCCN(CCCCC*)C1=CC[C@@](C=C(C(c2c3cccc2)=C(C#N)C#N)S3(=*)=O)C(C)=C1 0.000 description 1
- 229920004934 Dacron® Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
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- Coloring (AREA)
Abstract
The present invention relates to the blue disperse dye composition of a kind of stamp, this dyestuff is composed of the following components: weight fraction is the dyestuff A of 3 50%, and weight fraction is the dyestuff B of 0 50%, and weight fraction is the dyestuff C of 0 10%, and remaining is auxiliary agent.This disperse dye composition has high sublimation reliability and washing fastness, efficiently solves stamp blue disperse dye and easily runs the problem of color, and this compatbility of dyestuff is good simultaneously, and other color fastness are excellent, is a kind of to be applicable to the high-grade dyestuff of the gorgeous stamp of coloured light.
Description
Technical field
The present invention relates to a kind of blue disperse dye composition, particularly relate to the blue disperse dye combination of a kind of stamp
Thing, this dye composite is applicable to the printing and dyeing of hydrophobic fiber material.
Background technology
In recent years, along with the raising of people's living standard, the comfortableness of garment material was required more and more higher, simultaneously by people
Color fastness for textile requires more and more higher.Such as some stamp kind fabrics, do not require nothing more than bright-colored, and wash
Fastness also to be got well.Some stamp blue dyess in the market, generally also exist the problem that washing fastness is poor；And some
The preferable disperse dyes of washing fastness, self sublimation reliability is the most relatively low cannot be used for stamp.
Such as C.I. disperse blue 183 color is more bright-coloured, but its sublimation reliability and washing fastness are the most poor, is not suitable for using
Stamp in Polyester Textiles；C.I. disperse blue 284 washing fastness is preferable, but its coloured light withers secretly, it is impossible to meet people to color
Demand；Therefore the cobalt blue disperse dyes of research and development stamp are the problems that solution needed badly by current dyestuff circle.
Summary of the invention
The technical issues that need to address of the present invention are to provide the blue disperse dye composition of a kind of stamp.
In order to solve above-mentioned technical problem, the present invention is achieved by the following technical solutions:
The blue disperse dye composition of a kind of stamp, it is characterised in that this dyestuff is made up of following component:
Weight fraction is the dyestuff A of the chemical formula I of 3-50%,
Weight fraction is the dyestuff B of the chemical formula II of 0-50%,
The dyestuff C of the chemical formula III of mark is heavily measured for 0-10%,
In formula (3), R is-CN or-NO2；
Wherein the content of dyestuff B with C is 0 time different；Remaining is auxiliary agent.
As limitation of the invention further, the weight fraction of dyestuff A of the present invention is 3-45%, described dye
The weight fraction of material B is 1-50%, and the weight fraction of described dyestuff C is 0-10%；Described auxiliary agent includes lignin sulfonic acid
In sodium (lignin 85A, 83A), condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF) or naphthalene sulfonic acid-formaldehyde condensation product (NNO) one
Plant or multiple.
As limitation of the invention further, the blue disperse dye composition formula of a kind of stamp is preferably: dye
The weight fraction of material A is 3-40%, and the weight fraction of dyestuff B is 3-50%, and the weight fraction of dyestuff C is 0-10%.
As limitation of the invention further, the blue disperse dye composition formula of a kind of stamp is preferably: dye
The weight fraction of material A is 3-30%, and the weight fraction of dyestuff B is 10-50%, and the weight fraction of dyestuff C is 0-10%.
As limitation of the invention further, described dyestuff C is the mixture of structure shown in III-1 and III-2；
Disperse dyes of the present invention can be prepared in accordance with the following methods: by the metering former dyestuff A of ratio, dyestuff B, dyestuff
C after pre-dispersed smashing, add auxiliary agent and warm water dispersed with stirring dissolve (generally, the weight ratio of auxiliary agent and former dyestuff be 0.8～
7:1), repeat through continuously grinding and filtering, sand milling to terminal after, sent by pipeline and put spray drying tower and be dried, the most uniformly
Spraying into dust laying oil and dispersant, end product is packed.In spray drying, the waste gas of output is by cyclone dust collector, by mistake for several times
Filtering dust collecting.
The dyestuff A that the present invention uses be C.I. disperse blue 354, dyestuff B be C.I. Disperse Green 9, dyestuff C is C.I. disperse blue
165 or disperse blue 165:1, above dyestuff A, dyestuff B, dyestuff C can select commercially available prod, such as Asia, Jiangsu nation dyestuff share
C.I. the disperse blue 354 and C.I. Disperse Green 9 that company limited produces, the C.I. disperse blue that Zhejiang Wanfeng Chemical Co., Ltd. produces
165 or disperse blue 165:1.
Color Index (C.I.) is the meaning of " Colour index number ", and it is international dyestuff title.Use above-mentioned
After technical scheme, the present invention obtains and provides the benefit that: this disperse dye composition has high sublimation reliability and washing jail
Degree, efficiently solves stamp blue disperse dye and easily runs the problem of color, and this compatbility of dyestuff is good simultaneously, and other color fastness are excellent
Good, it is a kind of to be applicable to the high-grade dyestuff of the gorgeous stamp of coloured light.This dye sublimation fastness is the most superior, is stained with various fibers
Color is little, dyeing loose colour is few, is particularly suitable for the stamp of dacron, can reach the highest washing fastness, simultaneously after Colour Difference
The dye colour prepared by the present invention is the most gorgeous, compares and meets the requirement that people are beautiful in colour to fabric.Can give simultaneously
Dye-works makes contributions on reduction cost and environmental conservation.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further detailed explanation, but protection scope of the present invention is not limited to
This.
Reagent used by the present invention, is commercially available prod.
Embodiment 1-10
Data as shown in table 1, by metering the former dyestuff A of ratio, dyestuff B, dyestuff C after pre-dispersed smashing, add auxiliary agent and
Warm water dispersed with stirring dissolve, through continuously grinding and filter repeat, sand milling to terminal after, sent by pipeline put spray drying tower do
Dry, uniformly spray into dust laying oil and dispersant simultaneously, end product is packed.
Proportioning raw materials in each embodiment of table 1
The disperse dyes that above-described embodiment prepares are carried out composite performance test, and method of testing is as follows:
Respectively take the disperse dyes that 1.0g embodiment 1-11 prepares, be configured to the dispersion that concentration is 1.0g/500mL with water respectively
Dye suspension thing, the water taking 20mL with 80mL mixes, and regulates dye bath pH to 4.5-5.0 with acetic acid, is then warmed up to 60 DEG C, simultaneously
It is respectively put into polyester fiber and carries out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 DEG C, be incubated 30 minutes, be cooled to 80 DEG C
Time sampling.Observe cloth specimen coloured light and use American Standard AATCC 16E-1987 (Xenon Arc, 20hr) to evaluate light fastness, GB
GB/T3921, GB/T3920-1997, GB/T5718-1997 evaluate its washing fastness and sublimation reliability, and measurement result is shown in Table 2.
The performance unit of the disperse dyes that each embodiment of table 2 prepares: level
From table 2 it can be seen that dyestuff of the present invention is either from washing fastness, light fastness or sublimation reliability
All effects are fine, it is possible to meet the current market demand, are the blue dyess of a kind of function admirable.
Particular embodiments described above simultaneously, has carried out entering one to the purpose of the present invention, technical scheme and beneficial effect
Step describes in detail, be it should be understood that above are only the specific embodiment of the present invention, is not limited to the present invention,
All within the spirit and principles in the present invention, any modification, equivalent substitution and improvement etc. done, should be included in the present invention's
Within protection domain.
Claims (5)
1. the blue disperse dye composition of a stamp, it is characterised in that this dyestuff is made up of following component:
Weight fraction is the dyestuff A of the chemical formula I of 3-45%,
Weight fraction is the dyestuff B of the chemical formula II of 1-50%,
Weight fraction is the dyestuff C of the chemical formula III of 0-10%,
In formula (3), R is-CN or-NO2；
Remaining is auxiliary agent.
The blue disperse dye composition of stamp the most according to claim 1, it is characterised in that: the weight of described dyestuff A
Amount mark is 3-40%, and the weight fraction of described dyestuff B is 3-50%, and the weight fraction of described dyestuff C is 0-10%.
The blue disperse dye composition of stamp the most according to claim 1, it is characterised in that: the weight of described dyestuff A
Amount mark is 3-30%, and the weight fraction of described dyestuff B is 10-50%, and the weight fraction of described dyestuff C is 0-10%.
4. according to the blue disperse dye composition of the stamp described in any one of claim 1-3, it is characterised in that help described in:
Agent includes one or more in sodium lignin sulfonate, condensation compound of methyl naphthalene sulfonic acid and formaldehyde or naphthalene sulfonic acid-formaldehyde condensation product.
5. according to the blue disperse dye composition of the stamp described in any one of claim 1-3, it is characterised in that described dye
Material C is the mixture of structure shown in III-1 and III-2；
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410819550.6A CN104592788B (en) | 2014-12-25 | 2014-12-25 | A kind of blue disperse dye composition of stamp |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410819550.6A CN104592788B (en) | 2014-12-25 | 2014-12-25 | A kind of blue disperse dye composition of stamp |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104592788A CN104592788A (en) | 2015-05-06 |
| CN104592788B true CN104592788B (en) | 2016-11-23 |
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| CN201410819550.6A Active CN104592788B (en) | 2014-12-25 | 2014-12-25 | A kind of blue disperse dye composition of stamp |
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| Country | Link |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105131650A (en) * | 2015-07-31 | 2015-12-09 | 杭州福莱蒽特精细化工有限公司 | Dispersed sapphire blue dye composition with high dyeing degree |
| CN106084887A (en) * | 2016-06-07 | 2016-11-09 | 陈立国 | A kind of blue disperse dye composition |
| CN108395732B (en) * | 2018-04-09 | 2019-11-08 | 九江富达实业有限公司 | A kind of black disperse dye composition and black disperse dye |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06329927A (en) * | 1993-05-17 | 1994-11-29 | Nippon Kayaku Co Ltd | Ink composition for ink jet printing and dyeing method using the same |
| CN101384767A (en) * | 2006-02-17 | 2009-03-11 | 亨斯迈先进材料（瑞士）有限公司 | Method for dyeing polyester |
| CN102558908A (en) * | 2011-12-31 | 2012-07-11 | 浙江博澳染料工业有限公司 | Compound high-strength disperse dye |
| CN102732061A (en) * | 2012-06-18 | 2012-10-17 | 绍兴奇彩化工有限公司 | Blue disperse dye compound |
| CN103408968A (en) * | 2013-09-10 | 2013-11-27 | 江苏亚邦染料股份有限公司 | Blue disperse dye mixture |
-
2014
- 2014-12-25 CN CN201410819550.6A patent/CN104592788B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06329927A (en) * | 1993-05-17 | 1994-11-29 | Nippon Kayaku Co Ltd | Ink composition for ink jet printing and dyeing method using the same |
| CN101384767A (en) * | 2006-02-17 | 2009-03-11 | 亨斯迈先进材料（瑞士）有限公司 | Method for dyeing polyester |
| CN102558908A (en) * | 2011-12-31 | 2012-07-11 | 浙江博澳染料工业有限公司 | Compound high-strength disperse dye |
| CN102732061A (en) * | 2012-06-18 | 2012-10-17 | 绍兴奇彩化工有限公司 | Blue disperse dye compound |
| CN103408968A (en) * | 2013-09-10 | 2013-11-27 | 江苏亚邦染料股份有限公司 | Blue disperse dye mixture |
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| Publication number | Publication date |
|---|---|
| CN104592788A (en) | 2015-05-06 |
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Application publication date: 20150506 Assignee: JIANGSU HUAER CHEMICAL Co.,Ltd. Assignor: Jiangsu Yabang Dye Co.,Ltd. Contract record no.: 2018320000064 Denomination of invention: Blue disperse dye composition for printing Granted publication date: 20161123 License type: Exclusive License Record date: 20180319 |
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Effective date of registration: 20180516 Address after: 222523 heggou town (Chemical Industrial Park), Ganyan County, Jiangsu Patentee after: JIANGSU HUAER CHEMICAL Co.,Ltd. Address before: 213163, No. 105, Renmin West Road, Niu Tong Town, Wujin District, Jiangsu, Changzhou Patentee before: Jiangsu Yabang Dye Co.,Ltd. |
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Address after: 222523 heggou town (Chemical Industrial Park), Ganyan County, Jiangsu Patentee after: Jiangsu Yabang Wall Dyestuff Co.,Ltd. Country or region after: China Address before: 222523 heggou town (Chemical Industrial Park), Ganyan County, Jiangsu Patentee before: JIANGSU HUAER CHEMICAL Co.,Ltd. Country or region before: China |