CN104562695B - A kind of halogen-free flameproof finishing agent and preparation method thereof - Google Patents
A kind of halogen-free flameproof finishing agent and preparation method thereof Download PDFInfo
- Publication number
- CN104562695B CN104562695B CN201510041445.9A CN201510041445A CN104562695B CN 104562695 B CN104562695 B CN 104562695B CN 201510041445 A CN201510041445 A CN 201510041445A CN 104562695 B CN104562695 B CN 104562695B
- Authority
- CN
- China
- Prior art keywords
- parts
- halogen
- finishing agent
- free flameproof
- phosphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Fireproofing Substances (AREA)
Abstract
The invention discloses a kind of halogen-free flameproof finishing agent and preparation method thereof, described finishing agent includes that zirconium hydroxide 59 parts, calcium hydroxy phosphate 5 12 parts, diammonium phosphate 37 parts, tetrakis hydroxymetyl phosphonium sulfuric 12 17 parts, hydroxyethyl methylacrylate 58 parts, 18-amine. polyoxyethylene ether 36 parts, PEG400 are 15 25 parts, 135 165 parts of water.Preparation method includes following step: (1) takes zirconium hydroxide, calcium hydroxy phosphate, diammonium phosphate carry out mechanical activation comminution；(2) take zirconium hydroxide 59 parts, calcium hydroxy phosphate 5 12 parts, diammonium phosphate 37 parts, tetrakis hydroxymetyl phosphonium sulfuric 12 17 parts, hydroxyethyl methylacrylate 58 parts, 18-amine. polyoxyethylene ether 36 parts, PEG400 are 15 25 parts, 135 165 parts of water, stirring, preserve, for the halogen-free flameproof finishing agent of preparation.
Description
Technical field
The invention belongs to textile finishing field, relate to a kind of antiflaming finishing agent and preparation method thereof, particularly relate to one
Halogen-free flameproof finishing agent and preparation method thereof.
Background technology
The showing of densification, the high stratification of residential housing, the centralization of the wealth of society and material life along with urban population
Dai Hua, the consumption figure of all kinds of textiles increases sharply, textile the fire caused also is continuously increased, cause body casualty accident and
Heavy economic losses.The most various interior decoration cloth such as curtain, curtain, wall paper, carpet, furniture stuff and bedding are easy to
Burning, and the fire prevention of industry, Aero-Space, military project textile is the most very urgent.According to statistics, the year of China's flame retardant textiles sells
About amount only 200 myriametres, the growing market demand can not be met far away.The flame retardant textiles in some field also to depend on now
Rely import.
For the flame-proof treatment of textile, method is more, and the kind of antiflaming finishing agent is the most more, fire-retardant containing halogen element
Finishing agent has been applied fewer and feweri, it would be desirable to develop the flame-proof treatment of the new Halogen possessing good flame retardant efficiency
Agent.
Summary of the invention
Solve the technical problem that: the antiflaming finishing agent kind of textile is more, has inorganic antiflaming finishing agent, halogenide
Antiflaming finishing agent, phosphorous flame-retardant finishing agent etc., halogen-free flameproof finishing agent is just becoming new development trend, it is an object of the invention to carry
For a kind of halogen-free flameproof finishing agent having possessed extraordinary anti-flaming function and preparation method thereof.
Technical scheme: in order to solve above-mentioned problem, the invention discloses a kind of halogen-free flameproof finishing agent and preparation side thereof
Method, described halogen-free flameproof finishing agent includes the constituent of following weight parts:
Further, described a kind of halogen-free flameproof finishing agent, including the constituent of following weight parts:
Further, described a kind of halogen-free flameproof finishing agent, including the constituent of following weight parts:
The preparation method of described a kind of halogen-free flameproof finishing agent, preparation method includes following step:
(1) pretreatment of raw material: take zirconium hydroxide, calcium hydroxy phosphate, diammonium phosphate, by zirconium hydroxide, calcium hydroxy phosphate
Carry out mechanical activation comminution with three kinds of material pulverizers of diammonium phosphate, be crushed to above-mentioned three kinds of compositions and be 200 mesh-400 mesh；
(2) the zirconium hydroxide 5-9 part after step (1) is pulverized, calcium hydroxy phosphate 5-12 part, diammonium phosphate 3-are taken by weight
7 parts, tetrakis hydroxymetyl phosphonium sulfuric 12-17 part, hydroxyethyl methylacrylate 5-8 part, 18-amine. polyoxyethylene ether 3-6 part, poly-second two
Alcohol 400 is 15-25 part, water 135-165 part, is put in water by above-mentioned various compositions and is stirred, and preserves after stirring 30min,
Halogen-free flameproof finishing agent for preparation.
The preparation method of described a kind of halogen-free flameproof finishing agent, is crushed to three kinds of compositions equal in preparation method step (1)
It is 300 mesh-400 mesh.
Beneficial effect: after the halogen-free flameproof finishing agent of pure cotton fabric and the 50% bafta present invention is arranged, its resistance
Combustion the highest grade, and the fabric arranged also has the highest limited oxygen index.Can meet in routine use fire-retardant
Needs.After the halogen-free flameproof finishing agent of the present invention adds hydroxyethyl methylacrylate, beyond expectation effectively raises it
Flame retardant rating, has extraordinary effect.
Detailed description of the invention
Embodiment 1
(1) pretreatment of raw material: take zirconium hydroxide, calcium hydroxy phosphate, diammonium phosphate, by zirconium hydroxide, calcium hydroxy phosphate
Carry out mechanical activation comminution with three kinds of material pulverizers of diammonium phosphate, be crushed to above-mentioned three kinds of compositions and be 400 mesh；
(2) take by weight step (1) pulverize after zirconium hydroxide 9 parts, calcium hydroxy phosphate 12 parts, diammonium phosphate 3 parts, four
17 parts of methylol sulphuric acid phosphorus, hydroxyethyl methylacrylate 8 parts, 18-amine. polyoxyethylene ether 3 parts, PEG400 are 25 parts, water
165 parts, being put in water by above-mentioned various compositions and be stirred, preserve after stirring 30min, the halogen-free flameproof for preparation arranges
Agent.
Embodiment 2
(1) pretreatment of raw material: take zirconium hydroxide, calcium hydroxy phosphate, diammonium phosphate, by zirconium hydroxide, calcium hydroxy phosphate
Carry out mechanical activation comminution with three kinds of material pulverizers of diammonium phosphate, be crushed to above-mentioned three kinds of compositions and be 200 mesh；
(2) take by weight step (1) pulverize after zirconium hydroxide 5 parts, calcium hydroxy phosphate 5 parts, diammonium phosphate 7 parts, four
12 parts of methylol sulphuric acid phosphorus, hydroxyethyl methylacrylate 5 parts, 18-amine. polyoxyethylene ether 6 parts, PEG400 are 15 parts, water
135 parts, being put in water by above-mentioned various compositions and be stirred, preserve after stirring 30min, the halogen-free flameproof for preparation arranges
Agent.
Embodiment 3
(1) pretreatment of raw material: take zirconium hydroxide, calcium hydroxy phosphate, diammonium phosphate, by zirconium hydroxide, calcium hydroxy phosphate
Carry out mechanical activation comminution with three kinds of material pulverizers of diammonium phosphate, be crushed to above-mentioned three kinds of compositions and be 400 mesh；
(2) take by weight step (1) pulverize after zirconium hydroxide 6 parts, calcium hydroxy phosphate 10 parts, diammonium phosphate 4 parts, four
16 parts of methylol sulphuric acid phosphorus, hydroxyethyl methylacrylate 7 parts, 18-amine. polyoxyethylene ether 5 parts, PEG400 are 18 parts, water
145 parts, being put in water by above-mentioned various compositions and be stirred, preserve after stirring 30min, the halogen-free flameproof for preparation arranges
Agent.
Embodiment 4
(1) pretreatment of raw material: take zirconium hydroxide, calcium hydroxy phosphate, diammonium phosphate, by zirconium hydroxide, calcium hydroxy phosphate
Carry out mechanical activation comminution with three kinds of material pulverizers of diammonium phosphate, be crushed to above-mentioned three kinds of compositions and be 300 mesh；
(2) take by weight step (1) pulverize after zirconium hydroxide 8 parts, calcium hydroxy phosphate 7 parts, diammonium phosphate 6 parts, four
14 parts of methylol sulphuric acid phosphorus, hydroxyethyl methylacrylate 6 parts, 18-amine. polyoxyethylene ether 4 parts, PEG400 are 22 parts, water
155 parts, being put in water by above-mentioned various compositions and be stirred, preserve after stirring 30min, the halogen-free flameproof for preparation arranges
Agent.
Embodiment 5
(1) pretreatment of raw material: take zirconium hydroxide, calcium hydroxy phosphate, diammonium phosphate, by zirconium hydroxide, calcium hydroxy phosphate
Carry out mechanical activation comminution with three kinds of material pulverizers of diammonium phosphate, be crushed to above-mentioned three kinds of compositions and be 400 mesh；
(2) take by weight step (1) pulverize after zirconium hydroxide 7 parts, calcium hydroxy phosphate 9 parts, diammonium phosphate 5 parts, four
15 parts of methylol sulphuric acid phosphorus, hydroxyethyl methylacrylate 7 parts, 18-amine. polyoxyethylene ether 4 parts, PEG400 are 20 parts, water
150 parts, being put in water by above-mentioned various compositions and be stirred, preserve after stirring 30min, the halogen-free flameproof for preparation arranges
Agent.
Comparative example
(1) pretreatment of raw material: take zirconium hydroxide, calcium hydroxy phosphate, diammonium phosphate, by zirconium hydroxide, calcium hydroxy phosphate
Carry out mechanical activation comminution with three kinds of material pulverizers of diammonium phosphate, be crushed to above-mentioned three kinds of compositions and be 400 mesh；
(2) take by weight step (1) pulverize after zirconium hydroxide 9 parts, calcium hydroxy phosphate 12 parts, diammonium phosphate 3 parts, four
17 parts of methylol sulphuric acid phosphorus, 18-amine. polyoxyethylene ether 3 parts, PEG400 are 25 parts, 165 parts of water, by above-mentioned various one-tenth
Divide to put in water and be stirred, preserve after stirring 30min, for the halogen-free flameproof finishing agent of preparation.
Cotton to pure cotton fabric and 50%, the blend fabric of 50% polyester fiber are immersed respectively embodiment 1 to 5 and comparative example
In finishing agent, soaking 2h at 40 DEG C, two leachings two are rolled, and pick-up is 65%, then dries at 85 DEG C, measure its limited oxygen index and
Flame retardant rating.Result is as follows:
Pure cotton fabric measurement result
| Limited oxygen index | Flame retardant rating | |
| Embodiment 1 | 28 | B1 |
| Embodiment 2 | 27 | B1 |
| Embodiment 3 | 32 | A2 |
| Embodiment 4 | 33 | A2 |
| Embodiment 5 | 35 | A1 |
| Comparative example | 22 | B2 |
50% cotton, the blend fabric measurement result of 50% polyester fiber
| Limited oxygen index | Flame retardant rating | |
| Embodiment 1 | 26 | B1 |
| Embodiment 2 | 26 | B1 |
| Embodiment 3 | 31 | B1 |
| Embodiment 4 | 32 | A2 |
| Embodiment 5 | 34 | A1 |
| Comparative example | 19 | B2 |
After adding hydroxyethyl methylacrylate in the present invention, the fire-retardant intensity of the medicated clothing after finishing agent arranges is the most significantly
Improving, its limited oxygen index reaches as high as 35.
Claims (1)
1. a halogen-free flameproof finishing agent, it is characterised in that described halogen-free flameproof finishing agent includes the composition of following weight parts
Composition:
Described a kind of halogen-free flameproof finishing agent is prepared by following preparation method:
(1) pretreatment of raw material: take zirconium hydroxide, calcium hydroxy phosphate, diammonium phosphate, by zirconium hydroxide, calcium hydroxy phosphate and phosphorus
Acid three kinds of material pulverizers of hydrogen diammonium carry out mechanical activation comminution, are crushed to above-mentioned three kinds of compositions and are 300 mesh-400 mesh；
(2) zirconium hydroxide 7 parts after step (1) is pulverized, calcium hydroxy phosphate 9 parts, diammonium phosphate 5 parts, four hydroxyl first are taken by weight
15 parts of base sulphuric acid phosphorus, hydroxyethyl methylacrylate 7 parts, 18-amine. polyoxyethylene ether 4 parts, PEG400 are 20 parts, water 150
Part, above-mentioned various compositions are put in water and is stirred, preserve after stirring 30min, for the halogen-free flameproof finishing agent of preparation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510041445.9A CN104562695B (en) | 2015-01-28 | 2015-01-28 | A kind of halogen-free flameproof finishing agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510041445.9A CN104562695B (en) | 2015-01-28 | 2015-01-28 | A kind of halogen-free flameproof finishing agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104562695A CN104562695A (en) | 2015-04-29 |
| CN104562695B true CN104562695B (en) | 2016-08-31 |
Family
ID=53079715
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510041445.9A Active CN104562695B (en) | 2015-01-28 | 2015-01-28 | A kind of halogen-free flameproof finishing agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104562695B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105256547A (en) * | 2015-11-13 | 2016-01-20 | 付淑珍 | Novel antibacterial and flame-retardant finishing agent and preparation method thereof |
| CN106758207A (en) * | 2016-12-08 | 2017-05-31 | 佛山迅拓奥科技有限公司 | A kind of formaldehydeless antiflaming finishing agent of Halogen for adding quinine |
| CN106592202A (en) * | 2016-12-15 | 2017-04-26 | 吴江市北厍盛源纺织品助剂厂 | Antifouling flame-retardant finishing agent special for textile and preparation method thereof |
| CN109281154B (en) * | 2018-09-26 | 2021-06-11 | 江南大学 | Textile flame retardant and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100553758C (en) * | 2003-01-16 | 2009-10-28 | 中国人民解放军63971部队 | Flame retardant type active carbon and preparation method thereof |
| CN1958936A (en) * | 2006-11-21 | 2007-05-09 | 苏州大学 | Flame retardant of textile, preparation and application |
| CN102965923A (en) * | 2012-12-04 | 2013-03-13 | 海泰纺织（苏州）有限公司 | Flame-retardant finishing agent for textiles and preparation method of agent |
| CN104151884A (en) * | 2014-06-30 | 2014-11-19 | 苏州萃智新技术开发有限公司 | Fireproof flame-retardant paint |
-
2015
- 2015-01-28 CN CN201510041445.9A patent/CN104562695B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN104562695A (en) | 2015-04-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104562695B (en) | A kind of halogen-free flameproof finishing agent and preparation method thereof | |
| CN104975497B (en) | Flame retardant, preparation method and applications thereof | |
| CN100545343C (en) | The flame-proof treatment method of light and thin natural fiber material | |
| CN104831542A (en) | Processing method of flame retardation fabric | |
| CN105178003A (en) | Phosphorus-containing flame retardant system polyester after-treatment and preparation and application thereof | |
| CN101812237A (en) | Flame-retardant wood-plastic composite material and preparation method thereof | |
| CN103232826A (en) | Heat-stabilized acrylate adhesive used for waterproof coiled material blank base cloth, and preparation method thereof | |
| CN108018715A (en) | A kind of preparation method of antiflaming finishing agent and fire-retardant regenerated cellulose fiber | |
| CN101613935B (en) | Organic boron antiflaming finishing agent for fabrics and preparation method thereof | |
| CN102585449B (en) | Composite flame retardant for polyesters and application method thereof | |
| CN103061121A (en) | Environmental-friendly flame-retardant finishing technology of real silk or real silk cellulosic fiber interwoven fabric | |
| CN110565370A (en) | preparation method of natural flame-retardant finishing agent | |
| CN103726318A (en) | Flame-retardant finishing agent special for textile | |
| CN105755827A (en) | Environment-friendly antibacterial flame-retardant finishing agent | |
| CN103897770A (en) | Aircraft grade high-pressure fire-resistant oil using trixylenyl phosphate as base oil and production method thereof | |
| CN101457475B (en) | Method for preparing melamine phosphonate flame-retardant-anti-crease integrated dressing agent for cotton | |
| CN105239378A (en) | Novel formaldehyde-free flame-retardant finishing agent for cotton and finishing method thereof | |
| CN106518923A (en) | Preparation method and application of nitrogen-phosphorus synergetic type phosphorus-containing flame retardant | |
| CN1814903A (en) | Multifunction environment-protection type durable fabric flame-retardant agent and producing method therefor | |
| CN103897768A (en) | Aircraft grade high-pressure fire-resistant oil using tritolyl phosphate as base oil and production method thereof | |
| CN106758207A (en) | A kind of formaldehydeless antiflaming finishing agent of Halogen for adding quinine | |
| CN106930106A (en) | Cotton is with without aldehyde permanent flame-retardant and its preparation method and application method | |
| CN107780201A (en) | A kind of flame retardant textiles | |
| CN114517407A (en) | Preparation method of cyclic borate flame retardant and flame-retardant polyester fiber product thereof | |
| CN105778930A (en) | Environment-friendly flame retardant |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190522 Address after: 215200 Hengfan Town Bridge Road, Wujiang District, Suzhou City, Jiangsu Province Patentee after: Suzhou Youjiuli Textile Co., Ltd. Address before: 215200 Hengfan Bridge Road, Songling Town, Wujiang District, Suzhou City, Jiangsu Province Patentee before: Cube dress ornament Co., Ltd is liked in Suzhou |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191018 Address after: Wujiang District of Suzhou City, Jiangsu province 215200 Song Ling Zhen Heng Shan Bridge Road Patentee after: Cube dress ornament Co., Ltd is liked in Suzhou Address before: 215200 Hengfan Town Bridge Road, Wujiang District, Suzhou City, Jiangsu Province Patentee before: Suzhou Youjiuli Textile Co., Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200602 Address after: Li Li Zhen Xiong Feng Cun, Wujiang District, Suzhou City, Jiangsu Province Patentee after: Wujiang Linhong Textile Co., Ltd Address before: Wujiang District of Suzhou City, Jiangsu province 215200 Song Ling Zhen Heng Shan Bridge Road Patentee before: SUZHOU AILIFANG CLOTHING Co.,Ltd. |
|
| TR01 | Transfer of patent right |