CN104549815A - Two-component nonfatal viscous ammunition and firing device thereof - Google Patents

Two-component nonfatal viscous ammunition and firing device thereof Download PDF

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Publication number
CN104549815A
CN104549815A CN201410840365.5A CN201410840365A CN104549815A CN 104549815 A CN104549815 A CN 104549815A CN 201410840365 A CN201410840365 A CN 201410840365A CN 104549815 A CN104549815 A CN 104549815A
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China
Prior art keywords
component
viscous
ammunition
lethal
nozzle
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Chinese (zh)
Inventor
翟文
陈强
甄建军
陈青香
何金迎
胡文阁
李英健
王忠发
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No 53 Institute of China North Industries Group Corp
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No 53 Institute of China North Industries Group Corp
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Priority to CN201410840365.5A priority Critical patent/CN104549815A/en
Publication of CN104549815A publication Critical patent/CN104549815A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02Spray pistols; Apparatus for discharge
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B15/00Details of spraying plant or spraying apparatus not otherwise provided for; Accessories
    • B05B15/50Arrangements for cleaning; Arrangements for preventing deposits, drying-out or blockage; Arrangements for detecting improper discharge caused by the presence of foreign matter
    • B05B15/55Arrangements for cleaning; Arrangements for preventing deposits, drying-out or blockage; Arrangements for detecting improper discharge caused by the presence of foreign matter using cleaning fluids
    • B05B15/555Arrangements for cleaning; Arrangements for preventing deposits, drying-out or blockage; Arrangements for detecting improper discharge caused by the presence of foreign matter using cleaning fluids discharged by cleaning nozzles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02Spray pistols; Apparatus for discharge
    • B05B7/04Spray pistols; Apparatus for discharge with arrangements for mixing liquids or other fluent materials before discharge
    • B05B7/0416Spray pistols; Apparatus for discharge with arrangements for mixing liquids or other fluent materials before discharge with arrangements for mixing one gas and one liquid
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225Polyamines
    • C08G18/3228Polyamines acyclic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225Polyamines
    • C08G18/3237Polyamines aromatic
    • C08G18/324Polyamines aromatic containing only one aromatic ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3271Hydroxyamines
    • C08G18/3278Hydroxyamines containing at least three hydroxy groups
    • C08G18/3281Hydroxyamines containing at least three hydroxy groups containing three hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/38Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3802Low-molecular-weight compounds having heteroatoms other than oxygen having halogens
    • C08G18/3814Polyamines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/38Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3855Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
    • C08G18/3863Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms
    • C08G18/3865Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms containing groups having one sulfur atom between two carbon atoms
    • C08G18/3868Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms containing groups having one sulfur atom between two carbon atoms the sulfur atom belonging to a sulfide group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4804Two or more polyethers of different physical or chemical nature
    • C08G18/4812Mixtures of polyetherdiols with polyetherpolyols having at least three hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4804Two or more polyethers of different physical or chemical nature
    • C08G18/482Mixtures of polyethers containing at least one polyether containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/50Polyethers having heteroatoms other than oxygen
    • C08G18/5021Polyethers having heteroatoms other than oxygen having nitrogen
    • C08G18/5024Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666Compounds of group C08G18/48 or C08G18/52
    • C08G18/667Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6681Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
    • C08G18/6685Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3225 or polyamines of C08G18/38

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention belongs to the technical field of riot defense and discloses two-component nonfatal viscous ammunition and a firing device thereof. A two-component quick-curing adhesive is taken as an ammunition system and jetted by means of high-pressure spray and can be cured to form elastomers after being jetted onto human targets; a static mixing device and a conical convergent nozzle are adopted for increasing jet injection distance by means of forced negative-pressure pressurizing; cleaning and recyclability of pipelines of the mixing device are realized by the aid of a cleaning device. The nonfatal viscous ammunition forms the elastomers after being cured, an isocyanate-group compound serves as a normal-temperature-curing two-component system of a component A, a mass ratio of the component A to a component B is 2:1-1:2, viscosity (25 DEG C) is smaller than 500mPa s, and viscosity difference is not larger than 80mPa s. The ammunition is short in curing time, the cured ammunition is proper in tensile strength, the nonfatal viscous ammunition is applicable to nonfatal weapons, the viscous ammunition firing device is long in jet distance, and demounting-free cleaning of the static mixing device can be realized. Applicability to firing of two-component quick-curing viscous ammunitions in different proportions is achieved while applicability to remote construction of two-component quick-curing systems is achieved as well.

Description

A kind of two component non-lethal viscous ammunition agent and emitter thereof
Technical field
The invention belongs to anti-riot technical field, relate to BOUNDING NON-LETHAL MUNITION technology, particularly dual-component binder ammunition technology, relate to the lift-off technology of dual-component binder ammunition simultaneously.
Background technology
Nonlethal weapon and ammunition thereof refer to and make personnel temporarily lose resistivity for reaching, and can not produce mortality and kill and wound and permanent disability, or make equipment lose function and custom-designed armament systems.The nonlethal weapon system of research both at home and abroad mainly contains binding agent weapon, lubricant weapon, blinding laser weapons, chemical-biological soft destruction weapon (as stimulant) and acoustics soft destruction weapon etc. at present.
Media report, the non-lethal binding agent weapon " taffy rifle " of U.S.'s development is modified salt spray device, can spray Chemical Felter to ruffian, contacts and after solidifying, ruffian is just difficult to move even one step when Chemical Felter with air.In addition, the another kind of non-lethal binding agent weapon of U.S.'s development is a kind of foam gun being called as " spider's thread rifle ", piston is promoted by nitrogen, thermoplastic in the neoprene latex pipe of extruding " spider's thread rifle " rear portion, liquid when thermoplastic is just extruded, once volume expands 30 times immediately after exposing in atmosphere, become the viscosity rope of solid, the biology beyond 10 meters can be hit and it is snarled inflexibly and cannot take action.But do not disclose concrete technical scheme.
CN 101852575A disclosed " a kind of launch the bullet of liquid ammunition and a kind of device launching liquid ammunition ", adopt water or anesthetic as ammunition, adopt the transmitter with igniter and propellant powder as emitter, rely on the strike of kinetic energy realization to target of liquid ammunition, hitting power on the one hand associates closely with distance, and ammunition scatters after hitting the mark on the other hand, and an impulsive force is hit in dispersion, penetration power is poor, can not produce mortal injury to target.
Remote liquid emitter common is at present as giant, adopt high-pressure pump to provide expulsion pressure, the static pressure that high-pressure pump or booster provide is converted into the dynamic pressure of water, by the circular cone convergence type designs of nozzles of hydraulic giant, reduce the passage section area of water, improve water velocity, thus improve jet length, water jet is ejected into the distance of expection.Because the viscosity of water is relatively little, therefore the jet length of giant can reach tens meters of rice even up to a hundred.For the portable transmitter of launching the larger liquid of viscosity, because liquid flowing resistance is large, therefore the jet length of liquid jet is shorter.
CN 201482624U discloses one " two-component polyurethane spray gun ", the entry/exit material pipe, ribbon mixer and the nozzle that are arranged side by side by two groups form, feed and exhaust tube is connected by spring stifle, under pressure, two component fluent material enters mixing chamber, promote spiral agitator rotation and make mixing of materials, spray under helical pressure effect.The mixing material jet pressure of the ejection of this spray gun is little, by introducing pressure-air at jet hole place, by mixing material jet atomization, therefore can not form remote jet, and the mixing chamber of this spray gun is disposable, can not reuse.
Above-mentioned report and the disclosed device launching nonlethal weapon liquid ammunition of patent, all can not realize cleaning and the recycling of emitter.Dual-component polyurethane or two component polyurea materials are applied to nonlethal weapon material, and use transportable reaction device to carry out the patent of launching, be not reported both at home and abroad.
Summary of the invention
The object of the present invention is to provide a kind of non-lethal viscous bullet, while efficient solution is except personnel's fighting capacity, alleviate the injury to human body.The emitter of this ammunition is provided simultaneously.
The object of the present invention is achieved like this, adopts two component fast solidification adhesive as ammunition system, sprayed, be ejected into human body target Post RDBMS and form elastomer, hinder personnel activity by high-pressure spray.
Adopt high pressure static blender and pressurized nozzle to realize two component mixing and jet transmitting, realize ammunition and launch.Transmitter adopts gases at high pressure as power source, two component static mixing principle is adopted to carry out two component liquid mixing, adopt circular cone convergence type nozzle to improve mixing material jet jet length, adopt forced negative pressure pressurized nozzle to improve liquid jet transmitting range further; Utilize the design of negative pressure booster nozzle arrangements and negative pressure cleaning device, realize the effect that blender pipeline is capable of washing, can reuse.
The non-lethal viscous ammunition agent that the present invention relates to, solidfied material is elastomer, take isocyanate-based compound as the two Component System of normal temperature cure of component A, the mass ratio of A, B component is between 2:1 ~ 1:2, preferred proportion is 1.5:1 ~ 1:1.5, the viscosity (25 DEG C) of A, B component is less than 500mPas respectively, and differences in viscosity is not more than 80mPas; Described isocyanate-based compound is the MDI semi-prepolymer of NCO% content between 15% ~ 20%; Described B component is the compound system of polyethers and amine chain extender.
The non-lethal viscous ammunition agent that the present invention relates to, solidfied material is elastomer, take isocyanate-based compound as the two Component System of normal temperature cure of component A; A, B component mass ratio are between 2:1 ~ 1:2, preferred proportion is 1.5:1 ~ 1:1.5, the viscosity (25 DEG C) of A, B component is less than 500mPas respectively, differences in viscosity is not more than 80mPas, the compound system of described polyethers and amine chain extender, both mass ratioes are between 1.5:1 ~ 8.1:1.
The non-lethal viscous ammunition agent that the present invention relates to, solidfied material is elastomer, take isocyanate-based compound as the two Component System of normal temperature cure of component A; A, B component mass ratio are between 2:1 ~ 1:2, preferred proportion is 1.5:1 ~ 1:1.5, the viscosity (25 DEG C) of A, B component is less than 500mPas respectively, and differences in viscosity is not more than 80mPas, and described polyethers is the compound system of amine terminated polyether or amine terminated polyether and end hydroxy polyether.
The non-lethal viscous ammunition agent that the present invention relates to, solidfied material is elastomer, take isocyanate-based compound as the two Component System of normal temperature cure of component A; A, B component mass ratio are between 2:1 ~ 1:2, preferred proportion is 1.5:1 ~ 1:1.5, the viscosity (25 DEG C) of A, B component is less than 500mPas respectively, differences in viscosity is not more than 80mPas, the compound system that curing agent used (B component) is polyethers and amine chain extender, described amine terminated polyether is the compound system of the three-functionality-degree amine terminated polyether of molecular weight 400 ~ 5000 and two degree of functionality amine terminated polyethers of molecular weight 230 ~ 2000.
The non-lethal viscous ammunition agent that the present invention relates to, solidfied material is elastomer, take isocyanate-based compound as the two Component System of normal temperature cure of component A; A, B component mass ratio are between 2:1 ~ 1:2, preferred proportion is 1.5:1 ~ 1:1.5, the viscosity (25 DEG C) of A, B component is less than 500mPas respectively, differences in viscosity is not more than 80mPas, the compound system that curing agent used (B component) is polyethers and amine chain extender, described end hydroxy polyether is the compound system of one or more in the three-functionality-degree end hydroxy polyether of molecular weight 300 ~ 5000 and two degree of functionality end hydroxy polyethers of molecular weight 400 ~ 2000.
The non-lethal viscous ammunition agent that the present invention relates to, solidfied material is elastomer, take isocyanate-based compound as the two Component System of normal temperature cure of component A; A, B component mass ratio are between 2:1 ~ 1:2, preferred proportion is 1.5:1 ~ 1:1.5, the viscosity (25 DEG C) of A, B component is less than 500mPas respectively, differences in viscosity is not more than 80mPas, and described amine chain extender is selected from one or more in primary aromatic amine chain extender and steric hindrance type secondary amine chain extender.
The non-lethal viscous ammunition agent that the present invention relates to, solidfied material is elastomer, take isocyanate-based compound as the two Component System of normal temperature cure of component A; A, B component mass ratio are between 2:1 ~ 1:2, preferred proportion is 1.5:1 ~ 1:1.5, the viscosity (25 DEG C) of A, B component is less than 500mPas respectively, differences in viscosity is not more than 80mPas, and described B component is one or more that the compound system of end hydroxy polyether also comprises in tertiary amine catalyst, organic metal salt catalyst.
The two component viscous ball emitters that the present invention relates to, be made up of the power source 1 of band launch control system, two component material cylinder 2, blender 3 and nozzle 4, it is characterized in that: described pair of component material cylinder is a pair equal altitudes material cylinder with piston 5, nozzle 4 is circular cone convergence type nozzle, and structure as shown in Figure 1.
The two component viscous ball emitters that the present invention relates to, be made up of the power source 1 of band launch control system, two component material cylinder 2, blender 3 and nozzle 4, it is characterized in that: internal diameter of the pipeline change place 6 of circular cone convergence type nozzle is greater than the round-corner transition of 200mm for radius, and structure as shown in Figure 2.
The two component viscous ball emitters that the present invention relates to, are made up of the power source 1 of band launch control system, two component material cylinder 2, blender 3 and nozzle 4, it is characterized in that: described circular cone convergence type nozzle is with high-pressure air feed passage 7.
The two component viscous ball emitters that the present invention relates to, are made up of the power source 1 of band launch control system, two component material cylinder 2, blender 3 and nozzle 4, it is characterized in that: described high-pressure air feed passage 7 is not more than 15 ° with the angle of nozzle tapping channel 8.
The two component viscous ball emitters that the present invention relates to, are made up of the power source 1 of band launch control system, two component material cylinder 2, blender 3 and nozzle 4, it is characterized in that: between two component material cylinder and blender 3, arrange cleaning device 9, structure as shown in Figure 4.
The two component viscous ball emitters that the present invention relates to, are made up of the power source 1 of band launch control system, two component material cylinder 2, blender 3 and nozzle 4, it is characterized in that: two component material cylinder 2, blender 3 are connected by duplex three-way sphere valve 10 with cleaning device 9.
The two component viscous ball emitters that the present invention relates to, are made up of power source 1, two component material cylinder 2, blender 3 and nozzle 4, it is characterized in that: described power source is electronic dual-axle hydraulic cylinder or pneumatic twin shaft cylinder.
The non-lethal viscous ammunition agent that the present invention relates to is two component fast speed curing elastomer adhesive, this medicament is short for hardening time, the hot strength of solidfied material is moderate, be applicable to viscous formulation nonlethal weapon ammunition, only can produce constraint effect to the trunk and four limbs launching target, make it take action, stop its aggressive behavior, mortal injury can not be formed to target, be applicable to arrest or control suspicion of crime individual human and small-scale conflict and riot crowd.
The two component viscous bullet emitter of the non-lethal that the present invention relates to, effluxvelocity is fast, and far firing range, blender can reuse, and transmitting range reaches more than 8m.Be applicable in, closely to single target or on a small scale the crowd personnel of implementing arrest, anti-terrorism, the stability maintenance task such as situation control.By the sectional area ratio of adjustment material cylinder, be applicable to different proportion medicament and launch.Be applicable to two component fast speed solidification viscous bullet launch, be also applicable to two component fast solidification system and construct at a distance.
Accompanying drawing explanation
Two component viscous ball emitter structural representations that Fig. 1 the present invention relates to
A kind of nozzle section structural representation that Fig. 2 the present invention relates to
A kind of pressurized nozzle cross-sectional view that Fig. 3 the present invention relates to
The two component viscous ball emitter structural representation of the one that Fig. 4 the present invention relates to
The two component viscous ball emitter cleaning device structural representation of the one that Fig. 5 the present invention relates to
The structural representation of a kind of pair of component viscous ball emitter that Fig. 6 the present invention relates to
Wherein, 1-power source, the two component material cylinder of 2-, 3-blender, 4-nozzle, 5-piston, change place of 6-internal diameter of the pipeline, 7-high-pressure air feed passage, 8-nozzle tapping channel, 9-cleaning device, 10-duplex three-way sphere valve.
Detailed description of the invention
Be further described inventing the technical scheme related to below in conjunction with exemplary embodiments, but the present invention is not limited only to embodiment.B component formula in the following example is mass fraction.
Embodiment one
Component A:
NCO% is the MDI semi-prepolymer 100 of 20.0%
B component:
By above-mentioned formula, A, B component are respectively charged in A, B material cylinder of portable non-lethal viscous ball emitter, be cured time and transmitting range test, and A, B component mixture are poured in the thick mould of 2mm by portable non-lethal viscous ball emitter, the elastomer test piece of 2mm is formed after solidification, carry out hot strength test, test result is in table 1.
Table 1
The technical scheme that the two component viscous bullet material transmitters being 1:1 for drive of high-pressure gas mode, volume ratio the present invention relates in detail.
The basic structure of two component viscous ball emitter is as accompanying drawing 1 schematic diagram.Comprise power source 1, with piston 5 two component material cylinders 2, two ends are respectively with the tube connector of ring flange and loose joint, blender 3 and nozzle 4.
Power source 1 comprises high-pressure air source, control valve and twin shaft cylinder.High-pressure air source is 2L gas cylinder, and the gas pressure of output is set in 0.8MPa, using ball valve as control valve by pressure-reducing valve by bottled pressure-air.
Two component material cylinders 2 are the cylinder block of a pair length 200mm, internal diameter 50mm, matching circular piston 5.
Blender 3 is length 140mm, internal diameter 50mm, the spiral plate type static mixer of the flanged dish in two ends.
Nozzle 4 for one end be the circular cone convergence type nozzle of ring flange, the diameter end of convergence type nozzle is 50mm, and the other end is 5mm, and the reducing corner of nozzle inside diameter is round-corner transition, and radius of corner is 240mm, and structure is as shown in Figure 2.
Be connected with blender 3 with the discharging gate of ring flange by two component material cylinder 2 by loose joint with tube connector, by ring flange, blender 3 be connected with nozzle 4, the portable viscous ball emitter of the two components obtaining the present invention relates to.
This transmitter is applicable to two component viscous ammunitions transmittings that volume ratio is 1:1, and range can reach 8 meters.
Preferably, nozzle adopts pressurized construction (pressurized nozzle structure as shown in Figure 3), and air supply channel 7 is 13 ° with the angle α of nozzle 4 tapping channel.To using same medicament, jet length improves more than 10%.
Another kind of preferred version, arranges cleaning device 9 before mixing chamber, and cleaning device 9 connects two component material cylinder 2 and blender 3 (syndeton as shown in Figure 5) by duplex three-way sphere valve 10, realizes expecting that cylinder and nozzle repeatedly use.
Fig. 6 gives the structural representation of two component viscous ball emitters of preferred version, and this transmitter, while having good launching effect, is convenient to cleaning, and material cylinder and nozzle repeatedly use.
According to the compositing characteristic of medicament, adjustment material cylinder section area ratio, realizes the transmitting of different agents.
During use, by two component transmitter horizontal positioned, the jet hole head for target direction of nozzle 4, open the control valve of gas cylinder, piston 5 A, B liquid material promoted under gas pressure in two component material cylinder 2 is entered in blender 3 and fully mixes, sprayed by nozzle 4, simultaneously, by the gases at high pressure that high-pressure air feed passage 7 provides, further supercharging, thus the jet length increasing mixing material.Because A, B liquid material reaction speed is very fast, therefore namely curable in a few second after mixing material is ejected into the target of certain distance.
After injection completes, open the valve of cleaning device 9, the valve rod of duplex three-way sphere valve 10 is pulled to vertical position simultaneously, thus close conveying pipeline, open detergent line, the negative pressure that cleaning agent in cleaning agent bottle is produced by nozzle 4 place injects tube connector, blender 3 and pressurized nozzle 4, and sprays from nozzle, is cleaned out by liquid material residual in tube connector, blender and nozzle.
Embodiment two
Component A:
NCO% is the MDI semi-prepolymer 95 of 18.9%
Propyl carbonate 5
B component:
By above-mentioned formula, A, B component are respectively charged in A, B material cylinder of portable non-lethal viscous ball emitter, be cured time and transmitting range test, and A, B component mixture are poured in the thick mould of 2mm by portable non-lethal viscous ball emitter, the elastomer test piece of 2mm is formed after solidification, carry out hot strength test, test result is in table 2.
Table 2
Embodiment three
NCO% is the MDI semi-prepolymer 100 of 18.0%
B component:
By above-mentioned formula, A, B component are respectively charged in A, B material cylinder of portable non-lethal viscous ball emitter, be cured time and transmitting range test, and A, B component mixture are poured in the thick mould of 2mm by portable non-lethal viscous ball emitter, the elastomer test piece of 2mm is formed after solidification, carry out hot strength test, test result is in table 3.
Table 3
Embodiment four
Component A:
NCO% is the MDI semi-prepolymer 117 of 16.7%
Dioctyl phthalate 13
B component:
By above-mentioned formula, A, B component are respectively charged in A, B material cylinder of portable non-lethal viscous ball emitter, be cured time and transmitting range test, and A, B component mixture are poured in the thick mould of 2mm by portable non-lethal viscous ball emitter, the elastomer test piece of 2mm is formed after solidification, carry out hot strength test, test result is in table 4.
Table 4
Embodiment five
Component A:
NCO% is the MDI semi-prepolymer 150 of 18.0%
B component:
By above-mentioned formula, A, B component are respectively charged in A, B material cylinder of portable non-lethal viscous ball emitter, be cured time and transmitting range test, and A, B component mixture are poured in the thick mould of 2mm by portable non-lethal viscous ball emitter, the elastomer test piece of 2mm is formed after solidification, carry out hot strength test, test result is in table 5.
Table 5
Embodiment six
Component A:
NCO% is the MDI semi-prepolymer 180 of 15.0%
B component:
By above-mentioned formula, A, B component are respectively charged in A, B material cylinder of portable non-lethal viscous ball emitter, be cured time and transmitting range test, and A, B component mixture are poured in the thick mould of 2mm by portable non-lethal viscous ball emitter, the elastomer test piece of 2mm is formed after solidification, carry out hot strength test, test result is in table 6.
Table 6
Embodiment seven
Component A:
NCO% is the MDI semi-prepolymer 90 of 16.7%
Ethyl acetate 10
B component:
By above-mentioned formula, A, B component are respectively charged in A, B material cylinder of portable non-lethal viscous ball emitter, be cured time and transmitting range test, and A, B component mixture are poured in the thick mould of 2mm by portable non-lethal viscous ball emitter, the elastomer test piece of 2mm is formed after solidification, carry out hot strength test, test result is in table 7.
Table 7
Embodiment eight
Component A:
NCO% is the MDI semi-prepolymer 180 of 16.7%
Ethyl acetate 20
B component:
By above-mentioned formula, A, B component are respectively charged in A, B material cylinder of portable non-lethal viscous ball emitter, be cured time and transmitting range test, and A, B component mixture are poured in the thick mould of 2mm by portable non-lethal viscous ball emitter, the elastomer test piece of 2mm is formed after solidification, carry out hot strength test, test result is in table 8.
Table 8

Claims (14)

1. non-lethal viscous ammunition agent, solidfied material is elastomer, take isocyanate-based compound as the two Component System of normal temperature cure of component A, the mass ratio of A, B component is between 2:1 ~ 1:2, the viscosity (25 DEG C) of A, B component is less than 500mPas respectively, and differences in viscosity is not more than 80mPas; Described isocyanate-based compound is the MDI semi-prepolymer of NCO% content between 15% ~ 20%; Described B component is the compound system of polyethers and amine chain extender.
2. non-lethal viscous ammunition according to claim 1 agent, the mass ratio of described A, B component is between 1.5:1 ~ 1:1.5.
3. any one non-lethal viscous ammunition agent according to claim 1 and 2, the mass ratio of described polyethers and amine chain extender is between 1.5:1 ~ 8.1:1.
4. any one non-lethal viscous ammunition agent according to claim 1 and 2, described polyethers is the compound system of amine terminated polyether or amine terminated polyether and end hydroxy polyether.
5. non-lethal viscous ammunition according to claim 4 agent, described amine terminated polyether is the compound system of the three-functionality-degree amine terminated polyether of molecular weight 400 ~ 5000 and two degree of functionality amine terminated polyethers of molecular weight 230 ~ 2000.
6. non-lethal viscous ammunition according to claim 4 agent, described end hydroxy polyether is the compound system of one or more in the three-functionality-degree end hydroxy polyether of molecular weight 300 ~ 5000 and two degree of functionality end hydroxy polyethers of molecular weight 400 ~ 2000.
7. any one non-lethal viscous ammunition agent according to claim 1 and 2, described amine chain extender is selected from one or more in primary aromatic amine chain extender and steric hindrance type secondary amine chain extender.
8. any one non-lethal viscous ammunition agent according to claim 1 and 2, described B component also comprises one or more in tertiary amine catalyst, organic metal salt catalyst.
9. a two component viscous ball emitter, be made up of the power source (1) of band launch control system, two component material cylinder (2), blender (3) and nozzle (4), it is characterized in that: described pair of component material cylinder is a pair equal altitudes material cylinder with piston (5), nozzle (4) is circular cone convergence type nozzle.
10. according to claim 9 pair of component viscous ball emitter, is characterized in that: internal diameter of the pipeline change place (6) of circular cone convergence type nozzle is greater than the round-corner transition of 200mm for radius.
11. according to claim 10 pairs of component viscous ball emitters, is characterized in that: described circular cone convergence type nozzle is with high-pressure air feed passage (7).
12. according to claim 11 pairs of component viscous ball emitters, is characterized in that: described high-pressure air feed passage (7) is not more than 15 ° with the angle of nozzle tapping channel (8).
13., according to pair component viscous ball emitter of any one described in claim 9 ~ 12, is characterized in that: between two component material cylinder and blender (3), arrange cleaning device (9).
14. any one pair of component viscous ball emitters according to claim 13, is characterized in that: two component material cylinder (2), blender (3) are connected by duplex three-way sphere valve (10) with cleaning device (9).
CN201410840365.5A 2014-12-30 2014-12-30 Two-component nonfatal viscous ammunition and firing device thereof Pending CN104549815A (en)

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CN105413588A (en) * 2015-11-16 2016-03-23 宋波 Electrical positioning and abut pressing triggering mechanism thereof
CN106679499A (en) * 2015-11-06 2017-05-17 深圳中物光学精密机械有限公司 Nonfatal self-defense device with super viscid gum
CN108031578A (en) * 2018-01-16 2018-05-15 江苏冠达通电子科技有限公司 Injection valve and the dispenser system with the injection valve

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CN102066448A (en) * 2008-05-19 2011-05-18 Ppg工业俄亥俄公司 Coating compositions comprising polyurea and a phosphorus-containing polyol
CN101608025A (en) * 2009-07-24 2009-12-23 北京立高科技有限公司 Low molecular weight amino latent crosslinker and spray polyurea elastomer thereof
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CN106679499A (en) * 2015-11-06 2017-05-17 深圳中物光学精密机械有限公司 Nonfatal self-defense device with super viscid gum
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CN108031578A (en) * 2018-01-16 2018-05-15 江苏冠达通电子科技有限公司 Injection valve and the dispenser system with the injection valve

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Application publication date: 20150429