CN104549050A - Hydrogen aqueous solution preparation device and preparation method of hydrogen aqueous solution - Google Patents
Hydrogen aqueous solution preparation device and preparation method of hydrogen aqueous solution Download PDFInfo
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- CN104549050A CN104549050A CN201410821999.6A CN201410821999A CN104549050A CN 104549050 A CN104549050 A CN 104549050A CN 201410821999 A CN201410821999 A CN 201410821999A CN 104549050 A CN104549050 A CN 104549050A
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- hydrogen
- aqueous solution
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
- B01J3/04—Pressure vessels, e.g. autoclaves
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2203/00—Processes utilising sub- or super atmospheric pressure
- B01J2203/06—High pressure synthesis
Abstract
The invention provides a hydrogen aqueous solution preparation device. The hydrogen aqueous solution preparation device comprises a water tank, a high-pressure hydrogen generator, a reaction tank, a reservoir and a vacuum pump, wherein a first outlet of the water tank is communicated with the reaction tank through a first pipeline; a first switch valve is arranged on the first pipeline; a second outlet of the high-pressure hydrogen generator is communicated with the reaction tank through a second pipline; a second switch valve is arranged on the second pipeline; a third outlet of the reaction tank is communicated with the reservoir through a third pipeline; a third switch valve is arranged on the third pipeline; the vacuum pump is arranged on the reaction tank; an outlet pipeline is arranged at an outlet of the reservoir; a fourth switch valve is arranged on the outlet pipeline. According to the hydrogen aqueous solution preparation device disclosed by the invention, the reaction tank is firstly vacuumized to eliminate interference of other gases; secondarily, the high-pressure hydrogen water is adopted to shorten the reaction time between the hydrogen and liquid water, and further increase the hydrogen solubility in the liquid water; at last the pure hydrogen aqueous solution is provided to lay a foundation for follow-up study.
Description
Technical field
The present invention relates to the process of water, be specifically related to the preparation method of a kind of hydrogen aqueous solution preparing device and a kind of hydrogen aqueous solution.
Background technology
The charge-site of molecular structure water is not overlapping, the relatively large aobvious negativity of cloud density on oxygen atom, and two hydrogen atoms then aobvious electropositive, hydrone shows as strong polar molecule.Can hydrogen bond be formed between hydrone, have the trend attracted each other.Such hydrone just can be interacted by hydrogen bond and multiple hydrone, is formed " water bunch (Water Cluster) "." Nature " magazine ran in 1969 tetrahedral configuration of water cluster.Within 2002, " Science " magazine ran UC Berkley scanning tunneling microscope observed crystallization clustered water." science " magazine ran in 2004 Yale University etc. observes the molecular cluster water of stable nanoscale structures.
The research of the clustering architecture feedwater molecular science that the water molecules of big figure is formed together brings very large difficulty, and the water molecules of big figure forms clustering architecture makes the activity of hydrone greatly reduce, certain puzzlement is also brought to the vital movement of organism, hydrogen can improve the activity of hydrogen bond in the aqueous solution, obtain little water cluster structure, but the gases such as the oxygen dissolved in water there is considerable influence to this; In addition, hydrogen is comparatively insoluble in water, also can affect hydrogen and play activation.
Summary of the invention
For solving the problem, the invention provides the preparation method of a kind of hydrogen aqueous solution preparing device and a kind of hydrogen aqueous solution.Described hydrogen aqueous solution preparing device is simple and practical, and the hydrogen bond that the hydrogen in the described hydrogen aqueous solution can improve in water cluster is active, contributes to forming little water cluster structure.The preparation method of the hydrogen aqueous solution provided by the invention is simple to operation.
First aspect present invention provides a kind of hydrogen aqueous solution preparing device, comprise tank, high pressure hydrogen maker, reaction tank, tank and vavuum pump, described tank is provided with the first outlet, described first outlet is communicated with described reaction tank by the first pipeline, described first pipeline is provided with the first switch valve, described high pressure hydrogen maker be provided with the second outlet, described second outlet is communicated with described reaction tank by second pipe, described second pipe is provided with second switch valve, described reaction tank is provided with the 3rd gas outlet, described 3rd gas outlet is communicated with described tank by the 3rd pipeline, described 3rd pipeline is provided with the 3rd switch valve, described vavuum pump is arranged on described reaction tank, for providing vacuum environment for described reaction tank, described tank is provided with the 4th outlet, and described 4th outlet is communicated with an outlet conduit, and described outlet conduit is provided with the 4th switch valve.
Described tank is equipped with ultra-pure water or distilled water, for providing water cluster.
Described high pressure hydrogen maker produces high pressure hydrogen, for providing hydrogen bond activator;
Described reaction tank is for providing the hybrid reaction space of water and hydrogen.
Described tank is used for the water after the activation of storage of water molecular cluster hydrogen bond and the hydrogen aqueous solution.
Described vavuum pump is used for providing required vacuum environment.
The outlet conduit of described tank can connect other experimental facilities, for studying the impact of hydrogen on water cluster size.
Preferably, described second pipe is provided with Hydrogen Vapor Pressure table, for monitoring the hydrogen-pressure force value that high pressure hydrogen maker second exports in real time.
Preferably, described reaction tank is provided with a Pressure gauge, for monitoring the force value in described reaction tank in real time.
Preferably, described high pressure hydrogen maker can be existing equipment, can be high pressure hydrogen gas cylinder, electrolytic hydrogen production device or hydrocarbon pyrolysis hydrogen production bioreactor particularly.
Hydrogen aqueous solution preparing device provided by the invention, the first outlet of tank is with reaction tank by the first pipeline communication, and the first pipeline is equipped with the first switch valve, the first switch valve can control the folding of the first pipeline.Ultra-pure water in tank or distilled water enter reaction tank by the first pipeline.High pressure hydrogen generator can provide required high pressure hydrogen, and the second outlet of high pressure hydrogen generator is communicated with by second pipe with reaction tank, second pipe is equipped with second switch valve, can controls the folding of second pipe.Hydrogen Vapor Pressure table is equipped with in second exit of high pressure hydrogen generator, can monitor the force value of high pressure hydrogen maker outlet in real time.High pressure hydrogen enters reaction tank by second pipe.In reaction tank, high pressure hydrogen mixes with aqueous water, Hydrogen activation hydrogen bond.Reaction tank is equipped with Pressure gauge, can monitor the force value in reaction tank in real time.3rd outlet of reaction tank by the 3rd pipeline communication with tank, the 3rd pipeline is equipped with switch valve, can be controlled the folding of the 3rd pipeline.Hydrone after activation and the hydrogen aqueous solution enter tank by the 3rd pipeline.Tank outlet is provided with outlet conduit, and described outlet conduit is provided with the 4th switch valve, can control the folding of outlet conduit.Reaction tank is provided with vavuum pump, before hydrogen and water reaction, is first vacuumized by reaction tank, eliminates the interference of other gases.
Under hydrogen gas environment, the oxygen atom outer-shell electron formed in the hydrone of hydrogen bond is easily combined with hydrogen molecule, form new hydrogen bond, and hydrogen molecule is to the control ability of hydrogen bond, and comparatively water cluster is strong, therefore the hydrone being bonded hydrogen bond with hydrogen molecule is easy to depart from from the large clustering architecture of hydrone, form little water cluster structure, reach the object improving hydrogen bond activity in water cluster, obtain the hydrogen aqueous solution.The hydrogen aqueous solution obtained can be stored in tank for subsequent use.
Hydrogen aqueous solution preparing device provided by the invention, first by evacuate space in reaction tank, eliminates the interference of other gases; Next adopts high pressure hydrogen, has both shortened the reaction time of hydrogen and aqueous water, in turn increases the solubility of hydrogen in aqueous water, and obtained the pure hydrogen aqueous solution, the Cluster Structures how affected in aqueous water for follow-up study hydrogen is laid a good foundation.
Second aspect present invention provides the method utilizing the hydrogen aqueous solution preparing device described in first aspect to prepare the hydrogen aqueous solution, comprises the following steps:
Water in described tank is entered reaction tank by the first pipeline, hydrogen in described high pressure hydrogen maker is entered reaction tank by second pipe, described water and described hydrogen mix in described reaction tank, described Hydrogen activation water cluster hydrogen bond, obtain the hydrogen aqueous solution, the described hydrogen aqueous solution is placed in tank for subsequent use.
Preferably, the Hydrogen Vapor Pressure of described high pressure hydrogen maker release is 1.5 atmospheric pressure.
Preferably, the purity of described hydrogen is greater than 99.5%.
Preferably, described incorporation time is 0.5-2 hour.
Preferably, the water in described tank is ultra-pure water or distilled water.
Preferably, before described water and the mixing of described hydrogen, vacuumized to described reaction tank half an hour.
To sum up, beneficial effect of the present invention comprises the following aspects:
(1) in water cluster provided by the invention, hydrogen bond priming reaction apparatus is simple and practical, by high pressure hydrogen and water are reacted, large bunch of hydrone is made to form little water cluster structure, greatly improve hydrogen bond in water cluster active, obtained the pure hydrogen aqueous solution, the Cluster Structures how affected in aqueous water for follow-up study hydrogen lays the foundation.
(2) method preparing the hydrogen aqueous solution provided by the invention is simple to operation, and the hydrogen bond that can improve in water cluster is active, obtains the pure hydrogen aqueous solution.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of hydrogen aqueous solution preparing device.
Detailed description of the invention
The following stated is the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.
Fig. 1 is the schematic diagram of hydrogen aqueous solution preparing device.As can be seen from Figure 1, a kind of hydrogen aqueous solution preparing device, comprise tank 1, high pressure hydrogen maker 2, reaction tank 3, tank 4 and vavuum pump 5, tank 1 is provided with the first outlet 11, first outlet 11 is communicated with reaction tank 3 by the first pipeline 12, first pipeline 12 is provided with the first switch valve 13, high pressure hydrogen maker 2 is provided with the second outlet 21, second outlet 21 is communicated with reaction tank 3 by second pipe 22, second pipe 22 is provided with second switch valve 23 and Hydrogen Vapor Pressure table 24, reaction tank 3 is provided with the 3rd outlet 31, 3rd outlet 31 is communicated with tank 4 by the 3rd pipeline 32, 3rd pipeline 32 is provided with the 3rd switch valve 33, reaction tank 3 is provided with a Pressure gauge 6, vavuum pump 5 is arranged on reaction tank 3, for providing vacuum environment for reaction tank 3, the outlet of tank 4 is provided with the 4th outlet the 41, four outlet and is communicated with an outlet conduit 42, and outlet conduit 42 is provided with the 4th switch valve 43.
When hydrogen aqueous solution preparing device runs, first closing switch valve 13,23 and 33, adopts vavuum pump 5 pairs of reaction tanks 3 to vacuumize, half an hour time, ensures the vacuum of reaction tank 3.Then open the first switch valve 13, be communicated with tank 1, tank 1, built with water body, as ultra-pure water or distilled water, makes the water in tank 1 flow into reaction tank 3 through the first outlet 11 and the first pipeline 12 successively.Meanwhile, open second switch valve 23, make the high pressure hydrogen in high pressure hydrogen generator 2 enter reaction tank 3 through the second outlet 21 and second pipe 22 successively.Second pipe 22 is provided with Hydrogen Vapor Pressure table 24, can monitor the force value of high pressure hydrogen maker outlet in real time.In reaction tank, ultra-pure water or distilled water and hydrogen mix, and reaction tank 3 is equipped with Pressure gauge 6, can monitor the force value in reaction tank in real time.Wait for hydrogen and aqueous water mixing 0.5-2 hour.Open the 3rd switch valve 33, reacted aqueous water and the hydrogen aqueous solution are put into tank 4 and stores, wait until subsequent experimental and use.When needs use this hydrogen aqueous solution, the 4th switch valve 43 can be opened and by the outlet conduit 42 of tank 4, the hydrogen aqueous solution is transferred out.
Embodiment 1
Prepare a method for the hydrogen aqueous solution, comprise the following steps:
First reaction tank is vacuumized half an hour, then the water in tank is entered reaction tank by the first pipeline, hydrogen in high pressure hydrogen maker is entered reaction tank by second pipe, Hydrogen Vapor Pressure is 1.5 atmospheric pressure, water and hydrogen mix half an hour in reaction tank, Hydrogen activation water cluster hydrogen bond, obtains the hydrogen aqueous solution, the hydrogen aqueous solution is placed in tank for subsequent use.
The above embodiment only have expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but therefore can not be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
Claims (10)
1. a hydrogen aqueous solution preparing device, it is characterized in that, comprise tank, high pressure hydrogen maker, reaction tank, tank and vavuum pump, described tank is provided with the first outlet, described first outlet is communicated with described reaction tank by the first pipeline, described first pipeline is provided with the first switch valve, described high pressure hydrogen maker be provided with the second outlet, described second outlet is communicated with described reaction tank by second pipe, described second pipe is provided with second switch valve, described reaction tank is provided with the 3rd outlet, described 3rd outlet is communicated with described tank by the 3rd pipeline, described 3rd pipeline is provided with the 3rd switch valve, described vavuum pump is arranged on described reaction tank, for providing vacuum environment for described reaction tank, described tank is provided with the 4th outlet, and described 4th outlet is communicated with an outlet conduit, and described outlet conduit is provided with the 4th switch valve.
2. hydrogen aqueous solution preparing device as claimed in claim 1, it is characterized in that, described second pipe is provided with Hydrogen Vapor Pressure table, for monitoring the hydrogen-pressure force value that high pressure hydrogen maker second exports in real time.
3. hydrogen aqueous solution preparing device as claimed in claim 1, it is characterized in that, described reaction tank is provided with a Pressure gauge, for monitoring the force value in described reaction tank in real time.
4. hydrogen aqueous solution preparing device as claimed in claim 1, it is characterized in that, described high pressure hydrogen maker is high pressure hydrogen gas cylinder, electrolytic hydrogen production device or hydrocarbon pyrolysis hydrogen production bioreactor.
5. utilize the hydrogen aqueous solution preparing device as described in any one of claim 1-4 to prepare the method for the hydrogen aqueous solution, it is characterized in that, comprise the following steps:
Water in described tank is entered reaction tank by the first pipeline, hydrogen in described high pressure hydrogen maker is entered reaction tank by second pipe, described water and described hydrogen mix in described reaction tank, described Hydrogen activation water cluster hydrogen bond, obtain the hydrogen aqueous solution, the described hydrogen aqueous solution is placed in tank for subsequent use.
6. prepare the method for the hydrogen aqueous solution as claimed in claim 5, it is characterized in that, the Hydrogen Vapor Pressure of described high pressure hydrogen maker release is 1.5 atmospheric pressure.
7. prepare the method for the hydrogen aqueous solution as claimed in claim 5, it is characterized in that, the purity of described hydrogen is greater than 99.5%.
8. prepare the method for the hydrogen aqueous solution as claimed in claim 5, it is characterized in that, described incorporation time is 0.5-2 hour.
9. prepare the method for the hydrogen aqueous solution as claimed in claim 5, it is characterized in that, the water in described tank is ultra-pure water or distilled water.
10. prepare the method for the hydrogen aqueous solution as claimed in claim 5, it is characterized in that, before described water and the mixing of described hydrogen, vacuumized to described reaction tank half an hour.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410821999.6A CN104549050A (en) | 2014-12-25 | 2014-12-25 | Hydrogen aqueous solution preparation device and preparation method of hydrogen aqueous solution |
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| CN201410821999.6A CN104549050A (en) | 2014-12-25 | 2014-12-25 | Hydrogen aqueous solution preparation device and preparation method of hydrogen aqueous solution |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109110880A (en) * | 2018-08-03 | 2019-01-01 | 航天神舟生物科技集团有限公司 | Hydrogen molecule water preparation apparatus and method under space microgravity environment |
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| JP2006289289A (en) * | 2005-04-13 | 2006-10-26 | Aqua Energy Kk | Active hydrogen water production method and its production device |
| CN101401193A (en) * | 2006-03-13 | 2009-04-01 | 栗田工业株式会社 | Process and equipment for production of wash water containing dissolved gas, and cleaning equipment |
| CN202054655U (en) * | 2011-02-24 | 2011-11-30 | 林建凌 | Device using pressure to improve solubility of hydrogen in water |
| CN102962007A (en) * | 2012-11-26 | 2013-03-13 | 沈阳工业大学 | Pressure-controllable high-pressure hydration reaction device |
| CN103257203A (en) * | 2012-02-16 | 2013-08-21 | 中国科学院物理研究所 | High-pressure integrated experiment apparatus for novel energy hydrate |
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2014
- 2014-12-25 CN CN201410821999.6A patent/CN104549050A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2004074081A (en) * | 2002-08-21 | 2004-03-11 | Kurita Water Ind Ltd | Hydrothermal reaction treatment method and equipment therefor |
| JP2006289289A (en) * | 2005-04-13 | 2006-10-26 | Aqua Energy Kk | Active hydrogen water production method and its production device |
| CN101401193A (en) * | 2006-03-13 | 2009-04-01 | 栗田工业株式会社 | Process and equipment for production of wash water containing dissolved gas, and cleaning equipment |
| CN202054655U (en) * | 2011-02-24 | 2011-11-30 | 林建凌 | Device using pressure to improve solubility of hydrogen in water |
| CN103257203A (en) * | 2012-02-16 | 2013-08-21 | 中国科学院物理研究所 | High-pressure integrated experiment apparatus for novel energy hydrate |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109110880A (en) * | 2018-08-03 | 2019-01-01 | 航天神舟生物科技集团有限公司 | Hydrogen molecule water preparation apparatus and method under space microgravity environment |
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Application publication date: 20150429 |