CN104529625A - Uniform addition mode of elemental sulfur in ammonium phosphate - Google Patents
Uniform addition mode of elemental sulfur in ammonium phosphate Download PDFInfo
- Publication number
- CN104529625A CN104529625A CN201410766629.7A CN201410766629A CN104529625A CN 104529625 A CN104529625 A CN 104529625A CN 201410766629 A CN201410766629 A CN 201410766629A CN 104529625 A CN104529625 A CN 104529625A
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- China
- Prior art keywords
- active agent
- elemental sulfur
- phosphoric acid
- sulfur
- phosphorus ammonium
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Classifications
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
Abstract
The invention discloses a uniform addition mode of elemental sulfur in ammonium phosphate. The uniform addition mode is characterized in that the elemental sulfur contained in ammonium sulphate phosphate contained in a final product is uniformly distributed in solid ammonium phosphate. The addition state of the elemental sulfur in the ammonium phosphate is a solid state or a liquid state. The uniform addition mode of solid sulfur comprises the following steps: mixing a sulfur solid with a nonionic surface active agent and water to prepare a uniform sulfur suspension liquid or a sulfur colloid, and then adding the sulfur suspension liquid or the sulfur colloid to raw material phosphoric acid or reaction slurry obtained after the phosphoric acid is neutralized by using ammonia. The uniform addition mode of the liquid sulfur comprises the following steps: mixing the liquid sulfur with the nonionic surface active agent, and then adding to the raw material phosphoric acid or the reaction slurry obtained after the phosphoric acid is neutralized by using the ammonia, or firstly adding the nonionic surface active agent and then adding the liquid sulfur to the raw material phosphoric acid or the reaction slurry obtained after the phosphoric acid is neutralized by using the ammonia.
Description
Technical field
The present invention relates to the preparation method containing ammonium phosphate sulfate, particularly, relate to the even addition manner of a kind of elemental sulfur in phosphorus ammonium.
Background technology
Simple substance sulfenyl phosphorus ammonium contains the sulphur of high density, and the expense transported and use is low compared with other sulfur fertilizers; Secondly, slowly, validity period is long, and simple substance sulfenyl phosphorus ammonium can replace the lower concentration sulfur fertilizers such as sulphur ammonium and calcium superphosphate, is just causing the extensive concern of people in recent years in its release.Due to the hydrophobic nature of sulphur, the avidity of sulphur and phosphorus ammonium is poor, adopts simple means to be difficult to make sulphur together with phosphorus ammonium Homogeneous phase mixing.At present; external common simple substance sulfenyl ammonium phosphate production method mainly wraps up one deck sulphur at phosphorus ammonium outside surface; namely in tablets press, spray one deck elemental sulfur to the outside surface of phosphorus ammonium, its shortcoming is that sulphur easily comes off in transport, transport process, and sulphur is not easily absorbed by farm crop in application.Another kind method is, in phosphorus ammonium production process, liquid sulfur is added to granulation together in phosphor ammonium slurry, by the dissemination of nozzle, spray granulating obtains simple substance sulfenyl ammonium phosphate product, due to the limitation of this technique, the uniform product of component can not be obtained, and leave potential safety hazard often to subsequent handling and transport.
Summary of the invention
The technical problem to be solved in the present invention is: the present invention realizes the scattering problem of sulphur in phosphorus ammonium by adding nonionic surface active agent, and the dispersing property of sulphur in phosphorus ammonium is better, and the danger in production is less.
Technical scheme of the present invention is: the even addition manner of a kind of elemental sulfur in phosphorus ammonium, and final product is evenly distributed in solid phosphorus ammonium containing elemental sulfur in ammonium phosphate sulfate.Phosphorus ammonium can be monoammonium phosphate, diammonium phosphate, ammonium polyphosphate, or the mixing prod of three, also can be the compound manure containing nutritive elements such as nitrogen, phosphorus, potassium, boron, zinc but mainly based on nitrogen and phosphorus.
The interpolation form of elemental sulfur in phosphorus ammonium, for solid-state or liquid.
The even addition manner of solid-state sulphur, sulphur solid is mixed with nonionic surface active agent and water, obtained homogeneous sulphur suspension or sulphur colloid, then this sulphur suspension or sulphur colloid are joined in raw material phosphoric acid or phosphoric acid by ammonia and after reaction slurry in.
The even addition manner of liquid sulfur: liquid sulfur is mixed with nonionic surface active agent, again it is joined in raw material phosphoric acid or phosphoric acid by ammonia and after reaction slurry in, or in raw material phosphoric acid or phosphoric acid by ammonia in and after reaction slurry in first add nonionic surface active agent, then add molten sulfur.
The add-on of nonionic surface active agent is the 0.0001-10% of elemental sulfur quality; The massfraction that elemental sulfur contains in ammonium phosphate sulfate at finished product is 1-40%, optimizes content 5-20%.
Nonionic surface active agent is the compounded combination of fatty alcohol-polyoxyethylene ether, fatty alcohol polyoxypropylene ether, polyoxyethylene alkylphenol ether, alkylphenol polyethenoxy ether, P type tensio-active agent, polyether-type nonionic type tensio-active agent, aliphatic acid polyethenoxy ether, lipid acid polyethenoxy ether, polyol type nonionic surface active agent or above several tensio-active agent.
Fatty alcohol-polyoxyethylene ether refers to the adduct of lipid acid and oxyethane, the carbonatoms of fatty alcohol is between 8-22, the number of polyoxyethylene groups is between 1-45, fatty alcohol polyoxypropylene ether refers to the adduct of lipid acid and propylene oxide, the carbonatoms of fatty alcohol is between 8-22, and the number of polyoxyethylene groups is between 1-50.
Polyoxyethylene alkylphenol ether refers to that the carbonatoms of alkyl in alkylbenzene phenolic group is between 8-22, and the number of polyoxyethylene groups is between 1-40; Alkylphenol polyethenoxy ether refers to that the carbonatoms of alkyl in alkylbenzene phenolic group is between 8-22, and the number of polyoxypropylene base is between 1-40.
P type tensio-active agent refers to the adduct of phenol and oxyethane or propylene oxide, and the number of polyoxyethylene groups or polyoxypropylene base is between 1-60.
Polyether-type nonionic type tensio-active agent refers to the adduct of polypropylene glycol and oxyethane or propylene oxide, and molecular weight is between 200-10000, and polyoxyethylene moities or polyoxypropylene portion molecular weight account for the 30-85% of whole molecular weight.
Aliphatic acid polyethenoxy ether refers to the adduct of lipid acid and oxyethane, and the carbon atom number in lipid acid is between 8-22, and lipid acid polyethenoxy ether refers to the adduct of lipid acid and propylene oxide, and the carbon atom number in lipid acid is between 8-22.
The ester that polyol type nonionic surface active agent refers to lipid acid and polyhydroxy-alcohol effect and generates, comprises department's Pan's type tensio-active agent and tween type tensio-active agent.
Beneficial effect of the present invention: the invention provides the even addition manner of a kind of elemental sulfur in phosphorus ammonium.Sulphur has hydrophobic nature, and phosphorus ammonium has wetting ability, and the avidity of sulphur and phosphorus ammonium is poor, and nonionic surface active agent can improve avidity between elemental sulfur and phosphorus ammonium, thus improves the dispersion effect of elemental sulfur in the middle of phosphoric acid or phosphor ammonium slurry.Some aniorfic surfactant unquestionable and cationic surfactant also can obtain identical dispersion effect.
Embodiment
Below the specific embodiment of the present invention is described in detail.Should be understood that, embodiment described herein, only for instruction and explanation of the present invention, is not limited to the present invention.
Embodiment 1
Joining crossing 200 object sulphur powder in the solution being dissolved with a kind of fatty alcohol-polyoxyethylene ether, mixing, obtained sulphur suspension, again this sulphur suspension is joined in phosphoric acid, mix, obtained sulfur-bearing phosphoric acid, then produces sulphur-containing diammonium phosphate by this sulfur-bearing phosphoric acid and ammonia gas react.The add-on of this kind of fatty alcohol-polyoxyethylene ether is 0.5% of elemental sulfur quality; The massfraction that elemental sulfur contains in ammonium phosphate sulfate at finished product is 10%.The method that sulfur-bearing phosphoric acid and ammonia react prepare sulphur-containing diammonium phosphate there is no different with the process using phosphoric acid and ammonia react to prepare phosphoric acid.Such as, after original phosphoric acid and ammonia reacts by tubular reactor spray granulating, so sulfur-bearing phosphoric acid also react by tubular reactor with ammonia after dry the obtaining of spray granulating contain ammonium phosphate sulfate product.If phosphoric acid and ammonia are reacted by pre-neutralization reactive tank in originally generating, then obtain ammonium phosphate product at rotary drum ammoniation-granulation, so sulfur-bearing phosphoric acid is also reacted by pre-neutralization reactive tank with ammonia, and then obtained containing ammonium phosphate sulfate product through rotary drum ammoniation-granulation.
Embodiment 2
A kind of aliphatic acid polyethenoxy ether is added in molten sulfur, mix, join in phosphoric acid under violent stirring condition again, mix, obtained sulfur-bearing phosphoric acid, then this sulfur-bearing phosphoric acid and ammonia gas react are produced sulphur-containing diammonium phosphate slip, then obtain sulphur-containing diammonium phosphate through the operation such as granulation, drying.The add-on controlling this kind of aliphatic acid polyethenoxy ether is 1.5% of elemental sulfur quality; The massfraction that elemental sulfur contains in ammonium phosphate sulfate at finished product is 20%.The method that sulfur-bearing phosphoric acid and ammonia react prepare sulphur-containing diammonium phosphate there is no different with the process using phosphoric acid and ammonia react to prepare phosphoric acid.
Embodiment 3
The sulphur powder being less than 100 microns is joined in the solution being dissolved with a kind of polyoxyethylene alkylphenol ether, mix, obtained sulphur suspension, in the monoammonium phosphate slip generated after then this sulphur suspending liquid being joined phosphoric acid and ammonia gas react, obtained sulfur-bearing monoammonium phosphate slip.The add-on controlling this polyoxyethylene alkylphenol ether is 3% of elemental sulfur quality; The massfraction that elemental sulfur contains in ammonium phosphate sulfate at finished product is 15%.And then obtain sulfur-bearing monoammonium phosphate through the operation such as granulation, drying.The method that sulfur-bearing phosphoric acid and ammonia react generate sulfur-bearing monoammonium phosphate Pulp preparation sulfur-bearing monoammonium phosphate there is no different with using the process of monoammonium phosphate Pulp preparation monoammonium phosphate.
Embodiment 4
Add in molten sulfur in the phosphoric acid solution containing a kind of lipid acid polyethenoxy ether and a kind of P type tensio-active agent, the mass ratio of lipid acid polyethenoxy ether and P type tensio-active agent is 1:1, mixes, then generates sulfur-bearing monoammonium phosphate slip with ammonia gas react.And then obtain sulfur-bearing monoammonium phosphate particle through the operation such as concentrated, granulation, drying.The method that sulfur-bearing phosphoric acid and ammonia react generate sulfur-bearing monoammonium phosphate Pulp preparation sulfur-bearing monoammonium phosphate there is no different with the process using phosphoric acid and ammonia react to generate monoammonium phosphate Pulp preparation monoammonium phosphate.The total add-on controlling lipid acid polyethenoxy ether and P type tensio-active agent is 5% of elemental sulfur quality; The massfraction that elemental sulfur contains in ammonium phosphate sulfate at finished product is 18%.
Claims (10)
1. the even addition manner of elemental sulfur in phosphorus ammonium, is characterized in that: final product is evenly distributed in solid phosphorus ammonium containing elemental sulfur in ammonium phosphate sulfate.
2. the even addition manner of a kind of elemental sulfur according to claim 1 in phosphorus ammonium, is characterized in that: the interpolation form of elemental sulfur in phosphorus ammonium is solid-state or liquid.
3. the even addition manner of a kind of elemental sulfur according to claim 2 in phosphorus ammonium, it is characterized in that: the even addition manner of solid-state sulphur, sulphur solid is mixed with nonionic surface active agent and water, obtained homogeneous sulphur suspension or sulphur colloid, then this sulphur suspension or sulphur colloid are joined in raw material phosphoric acid or phosphoric acid by ammonia and after reaction slurry in.
4. the even addition manner of a kind of elemental sulfur according to claim 2 in phosphorus ammonium, it is characterized in that: the even addition manner of liquid sulfur: liquid sulfur is mixed with nonionic surface active agent, again it is joined in raw material phosphoric acid or phosphoric acid by ammonia and after reaction slurry in, or in raw material phosphoric acid or phosphoric acid by ammonia in and after reaction slurry in first add nonionic surface active agent, then add molten sulfur.
5. the even addition manner of a kind of elemental sulfur according to claim 3 or 4 in phosphorus ammonium, is characterized in that: the add-on of nonionic surface active agent is the 0.0001-10% of elemental sulfur quality; The massfraction that elemental sulfur contains in ammonium phosphate sulfate at finished product is 1-40%, optimizes content 5-20%.
6. the even addition manner of a kind of elemental sulfur according to claim 3,4 or 5 in phosphorus ammonium, is characterized in that: nonionic surface active agent is the compounded combination of fatty alcohol-polyoxyethylene ether, fatty alcohol polyoxypropylene ether, polyoxyethylene alkylphenol ether, alkylphenol polyethenoxy ether, P type tensio-active agent, polyether-type nonionic type tensio-active agent, aliphatic acid polyethenoxy ether, lipid acid polyethenoxy ether, polyol type nonionic surface active agent or above several tensio-active agent.
7. the even addition manner of a kind of elemental sulfur according to claim 6 in phosphorus ammonium, it is characterized in that: fatty alcohol-polyoxyethylene ether refers to the adduct of lipid acid and oxyethane, the carbonatoms of fatty alcohol is between 8-22, the number of polyoxyethylene groups is between 1-45, fatty alcohol polyoxypropylene ether refers to the adduct of lipid acid and propylene oxide, the carbonatoms of fatty alcohol is between 8-22, and the number of polyoxyethylene groups is between 1-50.
8. the even addition manner of a kind of elemental sulfur according to claim 6 in phosphorus ammonium, is characterized in that: polyoxyethylene alkylphenol ether refers to that the carbonatoms of alkyl in alkylbenzene phenolic group is between 8-22, and the number of polyoxyethylene groups is between 1-40; Alkylphenol polyethenoxy ether refers to that the carbonatoms of alkyl in alkylbenzene phenolic group is between 8-22, and the number of polyoxypropylene base is between 1-40.
9. the even addition manner of a kind of elemental sulfur according to claim 6 in phosphorus ammonium, it is characterized in that: P type tensio-active agent refers to the adduct of phenol and oxyethane or propylene oxide, and the number of polyoxyethylene groups or polyoxypropylene base is between 1-60.
10. the even addition manner of a kind of elemental sulfur according to claim 6 in phosphorus ammonium, it is characterized in that: polyether-type nonionic type tensio-active agent refers to the adduct of polypropylene glycol and oxyethane or propylene oxide, molecular weight is between 200-10000, and polyoxyethylene moities or polyoxypropylene portion molecular weight account for the 30-85% of whole molecular weight; Aliphatic acid polyethenoxy ether refers to the adduct of lipid acid and oxyethane, and the carbon atom number in lipid acid is between 8-22, and lipid acid polyethenoxy ether refers to the adduct of lipid acid and propylene oxide, and the carbon atom number in lipid acid is between 8-22; The ester that polyol type nonionic surface active agent refers to lipid acid and polyhydroxy-alcohol effect and generates, comprises department's Pan's type tensio-active agent and tween type tensio-active agent.
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| CN201410766629.7A CN104529625A (en) | 2014-12-15 | 2014-12-15 | Uniform addition mode of elemental sulfur in ammonium phosphate |
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| CN201410766629.7A CN104529625A (en) | 2014-12-15 | 2014-12-15 | Uniform addition mode of elemental sulfur in ammonium phosphate |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106810321A (en) * | 2017-01-21 | 2017-06-09 | 云南三环中化化肥有限公司 | A kind of molten sulfur is added to the device and method of production sulfur-bearing phosphate fertilizer in gas phase |
| WO2017206744A1 (en) * | 2016-05-31 | 2017-12-07 | 湖北富邦科技股份有限公司 | Granular ammonium phosphate having quick- and long-acting sulfur and zinc, and preparation method therefor |
| CN108484295A (en) * | 2018-06-13 | 2018-09-04 | 贵阳开磷化肥有限公司 | A kind of preparation method of high-nitrogen compound fertilizer |
| CN108503449A (en) * | 2018-06-13 | 2018-09-07 | 贵阳开磷化肥有限公司 | A kind of ammonium sulphate phosphate slow-release fertilizer and preparation method thereof improving alkaline land soil structure |
| CN108558532A (en) * | 2018-06-13 | 2018-09-21 | 贵阳开磷化肥有限公司 | A kind of preparation method of phosphorus-ammonium compound fertilizer |
| CN108727133A (en) * | 2018-06-13 | 2018-11-02 | 贵阳开磷化肥有限公司 | A kind of preparation method of salt-soda soil special complex fertilizer |
| CN108752097A (en) * | 2018-06-13 | 2018-11-06 | 贵阳开磷化肥有限公司 | A kind of preparation method of simple substance sulfenyl phosphorus ammonium slow-release fertilizer |
| CN108794153A (en) * | 2018-06-13 | 2018-11-13 | 贵阳开磷化肥有限公司 | A kind of preparation process containing ammonium sulphate phosphate |
| CN108821848A (en) * | 2018-06-13 | 2018-11-16 | 贵阳开磷化肥有限公司 | A method of high quality slow-release compound fertilizer is prepared using phosphoric acid by wet process |
| CN108821849A (en) * | 2018-06-13 | 2018-11-16 | 贵阳开磷化肥有限公司 | A kind of diamines of phosphoric acid containing microelement compound fertilizer preparation method |
| CN111533614A (en) * | 2020-03-24 | 2020-08-14 | 贵州新东浩化工材料科技有限公司 | Preparation method for producing triple superphosphate containing elemental sulfur by using raffinate acid |
| CN112457090A (en) * | 2020-11-06 | 2021-03-09 | 云南磷化集团海口磷业有限公司 | Contain sulphur phosphorus fertilizer apparatus for producing and contain sulphur ammonium phosphate apparatus for producing |
| WO2021254072A1 (en) * | 2020-06-17 | 2021-12-23 | 云南磷化集团海口磷业有限公司 | Sulfur-containing enriched calcium superphosphate production device and preparation method |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017206744A1 (en) * | 2016-05-31 | 2017-12-07 | 湖北富邦科技股份有限公司 | Granular ammonium phosphate having quick- and long-acting sulfur and zinc, and preparation method therefor |
| CN106810321A (en) * | 2017-01-21 | 2017-06-09 | 云南三环中化化肥有限公司 | A kind of molten sulfur is added to the device and method of production sulfur-bearing phosphate fertilizer in gas phase |
| CN108752097A (en) * | 2018-06-13 | 2018-11-06 | 贵阳开磷化肥有限公司 | A kind of preparation method of simple substance sulfenyl phosphorus ammonium slow-release fertilizer |
| CN108503449A (en) * | 2018-06-13 | 2018-09-07 | 贵阳开磷化肥有限公司 | A kind of ammonium sulphate phosphate slow-release fertilizer and preparation method thereof improving alkaline land soil structure |
| CN108558532A (en) * | 2018-06-13 | 2018-09-21 | 贵阳开磷化肥有限公司 | A kind of preparation method of phosphorus-ammonium compound fertilizer |
| CN108727133A (en) * | 2018-06-13 | 2018-11-02 | 贵阳开磷化肥有限公司 | A kind of preparation method of salt-soda soil special complex fertilizer |
| CN108484295A (en) * | 2018-06-13 | 2018-09-04 | 贵阳开磷化肥有限公司 | A kind of preparation method of high-nitrogen compound fertilizer |
| CN108794153A (en) * | 2018-06-13 | 2018-11-13 | 贵阳开磷化肥有限公司 | A kind of preparation process containing ammonium sulphate phosphate |
| CN108821848A (en) * | 2018-06-13 | 2018-11-16 | 贵阳开磷化肥有限公司 | A method of high quality slow-release compound fertilizer is prepared using phosphoric acid by wet process |
| CN108821849A (en) * | 2018-06-13 | 2018-11-16 | 贵阳开磷化肥有限公司 | A kind of diamines of phosphoric acid containing microelement compound fertilizer preparation method |
| CN111533614A (en) * | 2020-03-24 | 2020-08-14 | 贵州新东浩化工材料科技有限公司 | Preparation method for producing triple superphosphate containing elemental sulfur by using raffinate acid |
| WO2021254072A1 (en) * | 2020-06-17 | 2021-12-23 | 云南磷化集团海口磷业有限公司 | Sulfur-containing enriched calcium superphosphate production device and preparation method |
| CN112457090A (en) * | 2020-11-06 | 2021-03-09 | 云南磷化集团海口磷业有限公司 | Contain sulphur phosphorus fertilizer apparatus for producing and contain sulphur ammonium phosphate apparatus for producing |
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Application publication date: 20150422 |