CN104524958A - Concentrated ammonia water online dilution device for SNCR denitration system - Google Patents
Concentrated ammonia water online dilution device for SNCR denitration system Download PDFInfo
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- CN104524958A CN104524958A CN201510038099.9A CN201510038099A CN104524958A CN 104524958 A CN104524958 A CN 104524958A CN 201510038099 A CN201510038099 A CN 201510038099A CN 104524958 A CN104524958 A CN 104524958A
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- ammonia water
- shell
- pipe
- concentrated ammonia
- dilution device
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- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 235000011114 ammonium hydroxide Nutrition 0.000 title claims abstract description 39
- 239000012895 dilution Substances 0.000 title claims abstract description 20
- 238000010790 dilution Methods 0.000 title claims abstract description 20
- 239000007921 spray Substances 0.000 claims abstract description 29
- 239000002893 slag Substances 0.000 claims abstract description 10
- 238000005507 spraying Methods 0.000 claims abstract description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- 239000012535 impurity Substances 0.000 abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 8
- 238000000889 atomisation Methods 0.000 abstract description 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 4
- 239000003546 flue gas Substances 0.000 abstract description 4
- 230000001976 improved effect Effects 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract 2
- 239000007788 liquid Substances 0.000 description 6
- 230000005484 gravity Effects 0.000 description 4
- 239000011259 mixed solution Substances 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
- 238000010586 diagram Methods 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 238000003113 dilution method Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000003260 vortexing Methods 0.000 description 1
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- Treating Waste Gases (AREA)
Abstract
Description
技术领域 technical field
本发明涉及一种SNCR脱硝系统,具体涉及一种SNCR脱硝系统中的浓氨水在线稀释装置。 The invention relates to an SNCR denitration system, in particular to an online dilution device for concentrated ammonia water in the SNCR denitration system.
背景技术 Background technique
SNCR脱硝是以锅炉炉膛为脱硝反应装置,在850℃到1100℃的温度区间喷入稀氨水溶液,外购氨水浓度在20%左右,需要在喷射前稀释到浓度为10%。 SNCR denitrification uses the boiler furnace as the denitrification reaction device, and sprays dilute ammonia solution in the temperature range of 850°C to 1100°C. The concentration of purchased ammonia water is about 20%, and it needs to be diluted to a concentration of 10% before spraying.
目前SNCR脱硝氨水稀释装置基本采用双层管道式或者在管道内设置混合叶片的结构,它们存在两个问题:首先是系统阻力过大,双层管道之间的阻力和管道内叶片对液体流动造成的阻力,会使稀释后的稀氨水喷射效果受影响;其次是稀释水和氨水中的杂质不能在进入炉膛喷枪的喷嘴前得到过滤,长期使用会使喷嘴容易积累溶液中的杂质而堵塞喷嘴,进一步降低喷嘴喷射稀氨水的雾化效果。 At present, the SNCR denitrification ammonia water dilution device basically adopts a double-layer pipe type or a structure with mixing blades in the pipe. They have two problems: first, the system resistance is too large, and the resistance between the double-layer pipes and the blades in the pipe cause the liquid flow. The resistance of the diluted ammonia water will affect the injection effect of the diluted ammonia water; the second is that the impurities in the diluted water and ammonia water cannot be filtered before entering the nozzle of the furnace spray gun. Long-term use will make the nozzle easy to accumulate impurities in the solution and block the nozzle. Further reduce the atomization effect of the nozzle spraying dilute ammonia water.
发明内容 Contents of the invention
本发明的目的在于提供一种性能稳定、阻力小、提高炉膛喷枪喷射稀氨水效果的浓氨水在线稀释装置,提高SNCR脱硝系统对烟气的脱硝率。 The purpose of the present invention is to provide an on-line diluting device for concentrated ammonia water with stable performance, low resistance, and improved effect of spraying dilute ammonia water from a furnace spray gun, so as to improve the denitrification rate of flue gas by the SNCR denitrification system.
本发明公开了一种用于SNCR脱硝系统的浓氨水在线稀释装置,包括由壳体和其纵向中心的中心管组成的稀释器,壳体外壁上部有连通其内腔的进口管,中心管的下端为开口端、上端连接有与锅炉炉膛内喷枪连通的出口管,壳体的上端封闭,下端连接有储渣管,进口管的前端为稀释水入口、侧壁有向稀释水流中喷射浓氨水的氨水喷嘴。 The invention discloses an on-line diluting device for concentrated ammonia water used in an SNCR denitrification system. The lower end is an open end, and the upper end is connected with an outlet pipe that communicates with the spray gun in the boiler furnace. The upper end of the shell is closed, and the lower end is connected with a slag storage pipe. ammonia nozzle.
所述壳体由圆筒和圆锥形斗上下连接而成,中心管的下端伸入圆锥形斗内、上端穿过圆筒的上端面。 The shell is formed by connecting a cylinder and a conical bucket up and down, the lower end of the central tube extends into the conical bucket, and the upper end passes through the upper surface of the cylinder.
所述进口管为方型管,沿所述圆筒外壁的切向连接。 The inlet pipe is a square pipe connected along the tangential direction of the outer wall of the cylinder.
所述氨水喷嘴有两排,对称布置于进口管前端的左、右两侧。 There are two rows of ammonia water nozzles, symmetrically arranged on the left and right sides of the front end of the inlet pipe.
所述储渣管的下端内壁通过螺纹连接有丝堵。 The inner wall at the lower end of the slag storage pipe is threadedly connected with a plug.
本发明在进口管垂直于稀释水流的两侧各设置一排喷嘴向稀释水流中喷入浓氨水,保证两侧喷嘴之间实现喷射覆盖面的互相弥补,即可对稀释水流进行无盲区喷射,实现氨水稀释混合的均匀性。浓氨水和稀释水在进口管内混合后沿壳体的切向进入壳体和中心管之间的空腔中涡旋下行,进一步加强混合效果,然后从中心管的下端进入其中后上行继续混合,从中心管的顶端转入出口管中,最后进入安装在锅炉炉膛的喷枪喷射雾化实现SNCR脱硝反应。 In the present invention, a row of nozzles is arranged on both sides of the inlet pipe perpendicular to the dilution water flow to spray concentrated ammonia water into the dilution water flow, so as to ensure mutual compensation of the spray coverage between the nozzles on both sides, so that the dilution water flow can be sprayed without blind spots, realizing The homogeneity of ammonia dilution mixing. After the concentrated ammonia water and dilution water are mixed in the inlet pipe, they enter the cavity between the shell and the central tube along the tangential direction of the shell and vortex downward to further strengthen the mixing effect, then enter it from the lower end of the central tube and continue mixing upwards. From the top of the central tube to the outlet tube, and finally into the spray gun installed in the boiler furnace to spray and atomize to realize the SNCR denitrification reaction.
上述结构使浓氨水从进入稀释过程到进入锅炉炉膛的喷枪喷射雾化,混合溶液流通的路径全部是空腔,没有任何阻挡物,没有增加额外的阻力,只有管路损耗,与传统的内外管式氨水混合器和内置叶片式氨水混合器相比,在整个流通路径上的能量损失很小,进入炉膛内喷枪中的流速快,提高喷枪喷嘴喷射时的雾化效果,从而提高系统对烟气的脱硝率。 The above-mentioned structure enables the concentrated ammonia water to spray and atomize from the spray gun that enters the boiler furnace from the dilution process, and the mixed solution circulation path is all cavities, without any obstacles, without adding additional resistance, only pipeline loss, which is different from the traditional inner and outer tubes. Compared with the built-in vane type ammonia mixer, the energy loss in the entire flow path is very small, and the flow rate into the spray gun in the furnace is fast, which improves the atomization effect of the spray gun nozzle, thereby improving the system's flue gas denitrification rate.
混合溶液在壳体和中心管之间的空腔中涡旋下行的同时,溶液中的杂质由于离心力的作用被甩到壳体的内壁上,然后在自身重力的作用下逐渐螺旋下降经圆锥形斗后进入储渣管内,除杂后的稀氨水溶液避免了喷枪的喷嘴被阻塞,进一步提高喷嘴喷射稀氨水时的雾化效果,从而进一步提高烟气的脱硝率,延长喷枪使用寿命。 While the mixed solution is vortexing downward in the cavity between the shell and the central tube, the impurities in the solution are thrown to the inner wall of the shell due to centrifugal force, and then gradually spiral down under the action of its own gravity through the conical tube. After the bucket enters the slag storage pipe, the dilute ammonia solution after removal of impurities prevents the nozzle of the spray gun from being blocked, and further improves the atomization effect when the nozzle sprays dilute ammonia water, thereby further improving the denitrification rate of the flue gas and prolonging the service life of the spray gun.
附图说明 Description of drawings
图1为本发明一个实例的主视结构示意图。 Fig. 1 is a schematic diagram of the front view structure of an example of the present invention.
图2为图1的俯视示意图。 FIG. 2 is a schematic top view of FIG. 1 .
图3为图1中进口管内喷嘴的布置示意图。 Fig. 3 is a schematic diagram of the arrangement of nozzles in the inlet pipe in Fig. 1 .
具体实施方式 Detailed ways
如图1至图3所示,本发明公开了一种用于SNCR脱硝系统的浓氨水在线稀释装置,包括壳体1、进口管2、中心管3、出口管4、储渣管5和丝堵6。壳体1由圆筒11和圆锥形斗12上下连接而成,圆筒11的上端为封闭端。进口管2为方型管,沿圆筒11外壁的切向连接,与圆筒11的内腔连通。中心管3位于壳体1的轴向中心,其下端伸入圆锥形斗12内、上端穿过圆筒11的上端面。出口管4连接于中心管3的上端,其出口端与锅炉炉膛内的喷枪连通。储渣管5连接于圆锥形斗12的出口端,其下端内壁通过螺纹连接丝堵6。进口管2的前端为稀释水入口,左、右两侧壁外对称布置有浓氨水管7,氨水管7上对应进口管段连接有若干伸入进口管2内的分接头8,分接头8的末端连接喷嘴9,喷嘴9的布置以两侧喷嘴的有效喷射范围100%覆盖进口管2的横截面为准,保证稀释水与浓氨水的100%充分混合。 As shown in Figures 1 to 3, the present invention discloses an on-line dilution device for concentrated ammonia water used in SNCR denitrification systems, including a housing 1, an inlet pipe 2, a center pipe 3, an outlet pipe 4, a slag storage pipe 5 and wire Block 6. The casing 1 is formed by connecting a cylinder 11 and a conical bucket 12 up and down, and the upper end of the cylinder 11 is a closed end. The inlet pipe 2 is a square pipe, which is connected tangentially to the outer wall of the cylinder 11 and communicates with the inner cavity of the cylinder 11 . The central pipe 3 is located at the axial center of the casing 1 , its lower end extends into the conical bucket 12 , and its upper end passes through the upper end surface of the cylinder 11 . The outlet pipe 4 is connected to the upper end of the central pipe 3, and its outlet end communicates with the spray gun in the boiler furnace. The slag storage pipe 5 is connected to the outlet end of the conical bucket 12, and the inner wall of its lower end is connected to the plug 6 by threads. The front end of the inlet pipe 2 is the dilution water inlet, and the left and right side walls are symmetrically arranged with thick ammonia water pipes 7, and the corresponding inlet pipe sections on the ammonia water pipe 7 are connected with several taps 8 extending into the inlet pipe 2. The end is connected to the nozzle 9, and the arrangement of the nozzle 9 is based on the fact that the effective spraying range of the nozzles on both sides covers 100% of the cross section of the inlet pipe 2, so as to ensure 100% full mixing of the dilution water and the concentrated ammonia water.
混合后的溶液以切向进入中心管外壁和壳体内壁之间的空腔内,在此空腔内混合溶液的行程为涡旋状,在加强混合效果的同时,比重与液体不同的杂质则由于离心力的作用被甩到壳体内壁,在重力作用下逐渐螺旋下降到圆锥形斗下端的储渣管内,实现清除杂质的作用,防止锅炉炉膛内的喷枪喷嘴被杂质阻塞。经过清除杂质后的稀释氨水溶液进入中心管内继续混合达到设计浓度后折向进入出口管,最终进入安装在锅炉炉膛的喷枪喷射雾化实现SNCR脱硝反应。 The mixed solution enters the cavity between the outer wall of the central tube and the inner wall of the shell in a tangential direction, and the stroke of the mixed solution in the cavity is a vortex shape. While strengthening the mixing effect, impurities with a specific gravity different from the liquid are Due to the action of centrifugal force, it is thrown to the inner wall of the shell, and gradually spirally descends into the slag storage pipe at the lower end of the conical bucket under the action of gravity to realize the function of removing impurities and prevent the spray gun nozzle in the boiler furnace from being blocked by impurities. After removing impurities, the diluted ammonia solution enters the center tube and continues to mix to reach the design concentration, then turns to enter the outlet tube, and finally enters the spray gun installed in the boiler furnace to spray and atomize to realize the SNCR denitrification reaction.
本发明的上述结构使浓氨水从进入稀释过程到进入锅炉炉膛的喷枪喷射雾化,混合液体沿合理的路径流通,没有任何阻挡物,与传统的内外管式氨水混合器和内置叶片式氨水混合器相比,混合液体的系统阻力大大降低,从而提高后续脱硝效果。同时在离心力和重力作用实现了清除混合液体中杂质的功能,避免了混合液体中的杂质阻塞锅炉炉膛内喷枪的隐患。储渣管内的杂质可通过拆卸丝堵来清除。 The above-mentioned structure of the present invention makes the concentrated ammonia water spray and atomize from entering the dilution process to the spray gun entering the boiler furnace, and the mixed liquid circulates along a reasonable path without any obstructions, and is mixed with the traditional inner and outer tube type ammonia water mixer and built-in blade type ammonia water Compared with the device, the system resistance of the mixed liquid is greatly reduced, thereby improving the subsequent denitrification effect. At the same time, the function of removing impurities in the mixed liquid is realized under the action of centrifugal force and gravity, and the hidden danger of impurities in the mixed liquid blocking the spray gun in the furnace of the boiler is avoided. Impurities in the slag storage pipe can be removed by removing the plug.
Claims (5)
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CN201510038099.9A CN104524958B (en) | 2015-01-27 | 2015-01-27 | For the concentrated ammonia liquor on-line dilution device of SNCR denitrating system |
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CN201510038099.9A CN104524958B (en) | 2015-01-27 | 2015-01-27 | For the concentrated ammonia liquor on-line dilution device of SNCR denitrating system |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS54120281A (en) * | 1978-03-13 | 1979-09-18 | Kawasaki Steel Co | Removing of water soluble harmful gas |
CN1669631A (en) * | 2005-01-31 | 2005-09-21 | 清华大学 | A liquid-liquid rapid mixing reactor |
CN201423316Y (en) * | 2009-06-22 | 2010-03-17 | 陆飞浩 | gas-liquid separator |
CN102304381A (en) * | 2011-08-05 | 2012-01-04 | 太原理工大学 | Combined type coal tar recovery equipment and coal tar recovery method using same |
CN203389783U (en) * | 2013-07-01 | 2014-01-15 | 江苏亿金环保科技股份有限公司 | Denitration spray gun |
CN204447713U (en) * | 2015-01-27 | 2015-07-08 | 湖南麓南脱硫脱硝科技有限公司 | For the concentrated ammonia liquor on-line dilution device of SNCR denitration system |
-
2015
- 2015-01-27 CN CN201510038099.9A patent/CN104524958B/en not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS54120281A (en) * | 1978-03-13 | 1979-09-18 | Kawasaki Steel Co | Removing of water soluble harmful gas |
CN1669631A (en) * | 2005-01-31 | 2005-09-21 | 清华大学 | A liquid-liquid rapid mixing reactor |
CN201423316Y (en) * | 2009-06-22 | 2010-03-17 | 陆飞浩 | gas-liquid separator |
CN102304381A (en) * | 2011-08-05 | 2012-01-04 | 太原理工大学 | Combined type coal tar recovery equipment and coal tar recovery method using same |
CN203389783U (en) * | 2013-07-01 | 2014-01-15 | 江苏亿金环保科技股份有限公司 | Denitration spray gun |
CN204447713U (en) * | 2015-01-27 | 2015-07-08 | 湖南麓南脱硫脱硝科技有限公司 | For the concentrated ammonia liquor on-line dilution device of SNCR denitration system |
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