CN104514013B - A kind of aluminum electrolyzing cell used anode carbon block group - Google Patents

A kind of aluminum electrolyzing cell used anode carbon block group Download PDF

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Publication number
CN104514013B
CN104514013B CN201310445324.1A CN201310445324A CN104514013B CN 104514013 B CN104514013 B CN 104514013B CN 201310445324 A CN201310445324 A CN 201310445324A CN 104514013 B CN104514013 B CN 104514013B
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China
Prior art keywords
gooseneck
carbon block
steel
anode carbon
aluminum
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CN104514013A (en
Inventor
杨晓东
刘雅锋
邱阳
周东方
邹智勇
刘铭
曹曦
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Shenyang Aluminum and Magnesium Engineering and Research Institute Co Ltd
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Shenyang Aluminum and Magnesium Engineering and Research Institute Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/08Cell construction, e.g. bottoms, walls, cathodes
    • C25C3/12Anodes
    • C25C3/125Anodes based on carbon

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)

Abstract

The present invention relates to a kind of anode carbon block group structure, more particularly to a kind of energy-conservation, the aluminum electrolyzing cell used anode carbon block group of easy care.A kind of aluminum electrolyzing cell used anode carbon block group, including aluminum guide, conductive steel column and anode carbon block, aluminum guide is connected by gooseneck with conductive steel column, the bottom of conductive steel column is inserted into anode block, gooseneck is made up of the aluminium sheet on upper strata and the steel plate of lower floor, aluminum guide is welded with gooseneck upper strata aluminium sheet or is connected with connection sheet, gooseneck lower floor steel plate and conductive steel column steel steel welding or founding.Advantages of the present invention and effect:The present invention has very strong practicality, and one is the aluminum steel blast welding block for eliminating conventional anode group, and two be that steel pawl conduction replaces part steel pawl using connection sheet, reduces steel pawl pressure drop.

Description

A kind of aluminum electrolyzing cell used anode carbon block group
Technical field
The present invention relates to a kind of anode carbon block group structure, more particularly to a kind of energy-conservation, the aluminum electrolyzing cell used anode of easy care Carbon block group.
Background technology
Metallic aluminium is industrially produced using fused salt electrolysis process, i.e. electrodissolution is main component in molten cryolitic Electrolyte in aluminum oxide, the method mainly used at present is Hall-Ai Lu(Hall-Heroult)Electrolysis.
The direct equipment for producing electrolytic aluminium is electrolytic cell, and electrolytic cell is mainly made up of two large divisions, and a part is anode, separately One is negative electrode, and anode carbon block group participates in the normal reaction of electrolytic cell, anode carbon block is in electrolytic process as the positive pole of electrolytic cell In constantly consume, after certain time, anode scrap is changed, and is assembled new anode carbon block after being handled in anode assembling workshop, is returned to electricity Workshop is solved to recycle.
Generally, anode electrolytic cell carbon block group structure is made up of anode carbon block, aluminum guide, blast welding block, steel pawl and the phosphorus pig iron, Anode carbon block group assemble when, first by aluminum guide, blast welding block and steel pawl weld together composition guide rod group, then by guide rod group with sun Pole carbon block group pair, the steel pawl of guide rod group is inserted into the charcoal of anode carbon block bowl, and the phosphorus pig iron for melting of casting, the phosphorus pig iron after cooling Guide rod group and anode carbon block are linked together, anode carbon block group is constituted.Electric current passes sequentially through anode rod, blast welding block, steel Pawl, ferrophosphorus and anode block, therefore, steel pawl are not only the weight for undertaking anode block, are also electric conductor.
Usual steel pawl is formed using evaporative pattern cast, and the evaporative pattern that will have been manufactured by steel pawl size is put into sandbox, will be molten Melt under state in molten steel injection sandbox, evaporative pattern melts, and molten steel substitutes the space of original evaporative pattern, forms steel pawl.This structure Steel pawl, influenceed by pouring technology, the design of such as mould, the temperature of molten steel, the mobility of molten steel in a mold, exhaust is set Meter etc., it will usually cause stomata, trachoma, the defect of apparent mass difference, cause resistivity to raise, the voltage drop of anode steel claw increases Plus.Further, since steel pawl should generally carry carbon block weight, while be electric conductor again, because the resistivity of steel is larger, therefore, Also the voltage drop of steel pawl is increased.
The content of the invention
A kind of aluminum electrolyzing cell used anode carbon block group is provided to solve the above-mentioned technical problem present invention, purpose is solved because steel pawl is poured The inside caused and visual defects are noted, steel pawl crossbeam is mainly bonding strength, it is ensured that anode is not fallen off, while having the work(of conduction concurrently Can, attachment structure is responsible for conduction, anode unit pressure drop can be greatly lowered, is significantly reduced from the small material of resistivity ratio steel Ton aluminium energy consumption.
To achieve these goals, the present invention is realized in:A kind of aluminum electrolyzing cell used anode carbon block group, including aluminium are led Bar, conductive steel column and anode carbon block, aluminum guide are connected by gooseneck with conductive steel column, and the bottom of conductive steel column is inserted into anode carbon In block, gooseneck is made up of the aluminium sheet on upper strata and the steel plate of lower floor, and aluminum guide welds or used connection sheet with gooseneck upper strata aluminium sheet Connection, gooseneck lower floor steel plate and conductive steel column steel-steel welding or founding.
Described aluminum guide is connected with gooseneck crown center position, conductive steel column and gooseneck bottom steel plate weld or molten Casting, the one end of the two ends of gooseneck upper strata aluminium sheet respectively with two connection sheets is connected, the other end and aluminum guide of two connection sheets Connection.
The aluminium sheet of gooseneck can be a monoblock or the small aluminium sheet composition of polylith.
The aluminium sheet gross thickness of gooseneck is 10~100mm.
The cross section of the steel plate of gooseneck is square, circular or ellipse.
Connection sheet is band, plate or bus.
Gooseneck and conductive steel column are integrated.
Connection sheet is aluminium or copper.
Advantages of the present invention and effect:The present invention has very strong practicality, and one is the aluminum steel for eliminating conventional anode group Explode welding block, and two be that steel pawl conduction replaces part steel pawl using connection sheet, reduces steel pawl pressure drop.
Brief description of the drawings
Fig. 1 is existing anode carbon block group structural representation.
Fig. 2 is the positive schematic diagram of the present invention.
In figure:1st, aluminum guide;2nd, connection sheet;3rd, gooseneck;4th, anode carbon block;5th, the phosphorus pig iron;6th, conductive steel column.
Embodiment
Below in conjunction with example and figure, further the present invention will be described, but protection scope of the present invention is not by embodiment Limited.
Embodiment 1
A kind of aluminum electrolyzing cell used anode carbon block group of the present invention, including aluminum guide 1, conductive steel column 6 and anode carbon as shown in Figure 2 Block 4, aluminum guide 1 is connected by gooseneck 3 with conductive steel column 6, and the bottom of conductive steel column 6 is inserted into anode block 4, gooseneck 3 It is made up of the aluminium sheet on upper strata and the steel plate of lower floor, aluminum guide 1 is connected with the upper strata aluminium sheet welding of gooseneck 3 or with connection sheet, with even When contact pin is connected, connection sheet is aluminium or copper, and the lower floor's steel plate of gooseneck 3 is welded with 6 steel of conductive steel column-steel.Aluminum guide 1 and gooseneck 3 crown center positions are connected, conductive steel column 6 and the bottom steel plate weld of gooseneck 3, the two ends of the upper strata aluminium sheet of gooseneck 3 respectively with One end connection of two connection sheets 2, the other end of two connection sheets 2 is connected with aluminum guide 1.
The aluminium sheet of gooseneck 3 is a monoblock or the small aluminium sheet composition of polylith.
The aluminium sheet gross thickness of gooseneck 3 is 10~100mm.
The cross section of the steel plate of gooseneck 3 is square, circular or ellipse.
Connection sheet 2 is band, plate or bus.
The material of connection sheet 2 is aluminium.
The connection of conductive steel column 6 and anode carbon block 4 uses ferrophosphorus pouring type.
Embodiment 2
Gooseneck and conductive steel column in embodiment 1 are integrated.The other the same as in Example 1.

Claims (8)

1. aluminum electrolyzing cell used anode carbon block group, including aluminum guide, conductive steel column and anode carbon block, it is characterised in that aluminum guide passes through Gooseneck is connected with conductive steel column, the bottom of conductive steel column is inserted into anode block, aluminium sheet and lower floor of the gooseneck by upper strata Steel plate is constituted, and aluminum guide is connected with gooseneck upper strata aluminium sheet with connection sheet, the two ends of gooseneck upper strata aluminium sheet respectively with two companies One end connection of contact pin, the other end of two connection sheets is connected with aluminum guide, and gooseneck lower floor steel plate is welded with conductive steel column steel-steel Connect or founding.
2. a kind of aluminum electrolyzing cell used anode carbon block group according to claim 1, it is characterised in that described conductive steel column with Gooseneck bottom steel plate weld.
3. a kind of aluminum electrolyzing cell used anode carbon block group according to claim 2, it is characterised in that the aluminium sheet of gooseneck is one Monoblock or some fritter aluminium sheets.
4. a kind of aluminum electrolyzing cell used anode carbon block group according to claim 3, it is characterised in that the aluminium sheet total thickness of gooseneck Spend for 10~100mm.
5. a kind of aluminum electrolyzing cell used anode carbon block group according to claim 2, it is characterised in that the horizontal stroke of the steel plate of gooseneck Section is square, circular or ellipse.
6. a kind of aluminum electrolyzing cell used anode carbon block group according to claim 2, it is characterised in that connection sheet is band, plate or mother Line.
7. a kind of aluminum electrolyzing cell used anode carbon block group according to claim 2, it is characterised in that gooseneck and conductive steel column It is integrated.
8. a kind of aluminum electrolyzing cell used anode carbon block group according to claim 1, it is characterised in that connection sheet is aluminium or copper.
CN201310445324.1A 2013-09-27 2013-09-27 A kind of aluminum electrolyzing cell used anode carbon block group Active CN104514013B (en)

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105332005A (en) * 2015-09-24 2016-02-17 新疆生产建设兵团农八师天山铝业有限公司 Welding structure for prolonging use cycle of anode rod

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1834297A (en) * 2005-03-15 2006-09-20 贵阳铝镁设计研究院 Prodn. method of anode for small pre-calcining electrolytic cell
CN2887894Y (en) * 2006-03-27 2007-04-11 河南中孚实业股份有限公司 Anode electrode in aluminium cell
CN201037155Y (en) * 2007-05-31 2008-03-19 中国铝业股份有限公司 Anode for aluminum electrolysis production

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1834297A (en) * 2005-03-15 2006-09-20 贵阳铝镁设计研究院 Prodn. method of anode for small pre-calcining electrolytic cell
CN2887894Y (en) * 2006-03-27 2007-04-11 河南中孚实业股份有限公司 Anode electrode in aluminium cell
CN201037155Y (en) * 2007-05-31 2008-03-19 中国铝业股份有限公司 Anode for aluminum electrolysis production

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
节能型铝钢复合结构阳极钢爪;高德金;《世界有色金属》;20051231(第10期);第18页右栏第1-5段 *

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