CN104497903A - Composite optical adhesive tape capable of absorbing blue light - Google Patents

Composite optical adhesive tape capable of absorbing blue light Download PDF

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Publication number
CN104497903A
CN104497903A CN201410850437.4A CN201410850437A CN104497903A CN 104497903 A CN104497903 A CN 104497903A CN 201410850437 A CN201410850437 A CN 201410850437A CN 104497903 A CN104497903 A CN 104497903A
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China
Prior art keywords
blue light
layer
adhesive layer
adhesive tape
parts
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CN201410850437.4A
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Chinese (zh)
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CN104497903B (en
Inventor
金闯
张庆杰
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Taicang Sidike New Material Science and Technology Co Ltd
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Suzhou Sidike New Material Science and Technology Co Ltd
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Abstract

The invention discloses a composite optical adhesive tape capable of absorbing blue light. The adhesive tape comprises a transparent base material layer, wherein the upper and lower surfaces of the transparent base material layer are respectively coated with a first blue light-proof adhesive layer and a second optical adhesive layer; a first optical adhesive layer is coated between the first blue light-proof adhesive layer and a first release material layer; a second blue light-proof adhesive layer is coated between the second optical adhesive layer and a second release material layer; the first blue light-proof adhesive layer and the second blue light-proof adhesive layer both consist of the following components: 100 parts of an acrylate series adhesive, 0.075-0.1 part of an isocyanate curing agent, 10-20 parts of butanone, 2-5 parts of nanometer CeO2:Er fluorescent powder, 0.2-0.5 part of hexamethyl phosphoric triamide, 1-2 parts of benzoyl peroxide and 0.2-0.5 part of silicon oil. The composite optical adhesive tape capable of absorbing the blue light, disclosed by the invention, has a prevention effect on the blue light and a function of absorbing and transforming high-energy blue-purple short wave, and the filtration rate of the blue light wave band from 360nm to 500nm is above 90%.

Description

There is the composite optical adhesive tape absorbing blue light function
Technical field
The present invention relates to a kind of composite optical adhesive tape with absorption blue light function, particularly a kind of OCA optical adhesive tape can for touch-screen with better adhesive property.
Background technology
In recent years, the development of touch-screen is very rapid, and along with growing with each passing day to multimedia information inquiry, people get more and more to the application of touch-screen.OCA optical adhesive tape due to possess water white transparency, transmitance more than 90%, consolidation strength is good, it is little to have cure shrinkage, do not produce the advantages such as xanthochromia, especially to ito glass and the advantage such as optical element is corrosion-free, so rely on its excellent process based prediction model, be widely used in touch-screen industry most.
Simultaneously along with the fast development of electronics technology, the requisite that the electronic product such as portable computer, TV has become people to live, people need the expensive time in the face of these electronic products every day, but include the very large blue light of human injury in the light that sends of the LED of these electronic products.Blue light refers to that wavelength is the high-energy light of 380nm ~ 480nm, it can penetrate lens and arrive retina, the epithelial cell of retinochrome is become feeble and die, photaesthesia cell is caused to lack nutrient, thus cause irreversible vision impairment, and blue light scattering probability when running into the fine particle in air is higher, easily produces dazzle, in addition blue light also can stimulate brain, suppress melatonin secretion and improve corticoid generation thus destroy hormone secretion balance directly affect sleep quality.
Therefore, develop a kind of anti-blue light optical adhesive tape, use it in electronic product, under the prerequisite with preferred optical performance, can also absorb blue light, this has very great meaning by the health of protection human body.
Summary of the invention
The invention provides a kind of composite optical adhesive tape with absorption blue light function, this composite optical adhesive tape has the effect of anti-blue light, royal purple high energy shortwave is had to the function of sorption enhanced, and 360nm ~ 500nm blue wave band filterability reaches more than 90%.
For achieving the above object, the technical solution used in the present invention is: a kind of have the composite optical adhesive tape absorbing blue light function, comprise a transparent substrate layer, the upper and lower surface of this transparent substrate layer is coated with the first anti-blue light adhesive layer, the second optical cement adhesion coating respectively, be coated with the first optical cement adhesion coating between described first anti-blue light adhesive layer and the first separated type material layer, between described second optical cement adhesion coating and the second separated type material layer, be coated with the second anti-blue light adhesive layer;
Described first anti-blue light adhesive layer, the second anti-blue light adhesive layer are all composed of the following components:
Acrylic ester sizing agent 100 parts,
Isocyanate curing agent 0.075 ~ 0.1 part,
Butanone 10 ~ 20 parts,
Ceria nanopowder: 2 ~ 5 parts, Er fluorescent material,
HMPA 0.2 ~ 0.5 part,
Benzoyl peroxide 1 ~ 2 part,
Silicone oil 0.2 ~ 0.5 part;
Described isocyanate curing agent model is Bayer L-75;
The weight average molecular weight range 200 ~ 8,000,000 of described acrylic acid series sizing agent, second-order transition temperature is-60 ~-30 DEG C;
Described transparent substrate layer thickness is 50 ~ 100 μm, transmittance > 98%, mist degree < 1.0%.
The technical scheme improved further in technique scheme is as follows:
1., in such scheme, the thickness of described anti-blue light coating is 0.5 ~ 3 μm.
2., in such scheme, described transparent substrate layer is film layer or layer of polypropylene foil or laminated polyester film.
Because technique scheme is used, the present invention compared with prior art has following advantages and effect:
The present invention has the composite optical adhesive tape absorbing blue light function, and it had both had the effect of anti-blue light, royal purple high energy shortwave was had to the function of sorption enhanced, and 360nm-500nm blue wave band filterability reaches more than 90%, better protects eye health; Also to unorganic glass and organic plastics sheet, there is better adhesive property; Secondly, specific formula combination, solves liquid optical cement due to ceria nanopowder: Er fluorescent material adds and causes thickness wayward, and cure shrinkage easily produces the problem of bubble, thus effectively prevent the generation of bubble, touch display screen is better applied.
Accompanying drawing explanation
Accompanying drawing 1 has the composite optical adhesive tape structure schematic diagram absorbing blue light function for the present invention.
In above accompanying drawing: 1, transparent substrate layer; 2, the first anti-blue light adhesive layer; 3, the second anti-blue light adhesive layer; 4, the first separated type material layer; 5, the second separated type material layer; 6, the first optical cement adhesion coating; 7, the second optical cement adhesion coating.
Embodiment
Below in conjunction with drawings and Examples, the invention will be further described:
Embodiment 1 ~ 4: a kind of have the composite optical adhesive tape absorbing blue light function, comprise a transparent substrate layer 1, the upper and lower surface of this transparent substrate layer 1 is coated with the first anti-blue light adhesive layer 2, second optical cement adhesion coating 7 respectively, be coated with the first optical cement adhesion coating 6 between described first anti-blue light adhesive layer 2 and the first separated type material layer 4, between described second optical cement adhesion coating 7 and the second separated type material layer 4, be coated with the second anti-blue light adhesive layer 3;
Described first anti-blue light adhesive layer 2, second anti-blue light adhesive layer 3 is all composed of the following components:
The each ingredients weight parts content of described first anti-blue light adhesive layer 2, second anti-blue light adhesive layer 3 is in table 1:
Table 1
Described isocyanate curing agent model is Bayer L-75;
The weight average molecular weight range 200 ~ 8,000,000 of described acrylic acid series sizing agent, second-order transition temperature is-60 ~-30 DEG C;
Described transparent substrate layer 1 thickness is 50 ~ 100 μm, transmittance > 98%, mist degree < 1.0%.
The thickness of above-mentioned anti-blue light coating is 0.5 μm or 2 μm or 1.5 μm or 3 μm.
Above-mentioned transparent substrate layer 1 embodiment 1 of stating is for film layer, and embodiment 2 is layer of polypropylene foil, and embodiment 3 is laminated polyester film, and embodiment 4 is film layer.
Adopt above-mentioned when having the composite optical adhesive tape absorbing blue light function, it had both had the effect of anti-blue light, royal purple high energy shortwave was had to the function of sorption enhanced, and 360nm-500nm blue wave band filterability reaches more than 90%, better protects eye health; Also to unorganic glass and organic plastics sheet, there is better adhesive property; Secondly, specific formula combination, solves liquid optical cement due to ceria nanopowder: Er fluorescent material adds and causes thickness wayward, and cure shrinkage easily produces the problem of bubble, thus effectively prevent the generation of bubble, touch display screen is better applied.
Above-described embodiment, only for technical conceive of the present invention and feature are described, its object is to person skilled in the art can be understood content of the present invention and implement according to this, can not limit the scope of the invention with this.All equivalences done according to spirit of the present invention change or modify, and all should be encompassed within protection scope of the present invention.

Claims (3)

1. one kind has the composite optical adhesive tape absorbing blue light function, it is characterized in that: comprise a transparent substrate layer (1), the upper and lower surface of this transparent substrate layer (1) is coated with the first anti-blue light adhesive layer (2), the second optical cement adhesion coating (7) respectively, be coated with the first optical cement adhesion coating (6) between described first anti-blue light adhesive layer (2) and the first separated type material layer (4), between described second optical cement adhesion coating (7) and the second separated type material layer (4), be coated with the second anti-blue light adhesive layer (3);
Described first anti-blue light adhesive layer (2), the second anti-blue light adhesive layer (3) are all composed of the following components:
Acrylic ester sizing agent 100 parts,
Isocyanate curing agent 0.075 ~ 0.1 part,
Butanone 10 ~ 20 parts,
Ceria nanopowder: 2 ~ 5 parts, Er fluorescent material,
HMPA 0.2 ~ 0.5 part,
Benzoyl peroxide 1 ~ 2 part,
Silicone oil 0.2 ~ 0.5 part;
Described isocyanate curing agent model is Bayer L-75;
The weight average molecular weight range 200 ~ 8,000,000 of described acrylic acid series sizing agent, second-order transition temperature is-60 ~-30 DEG C;
Described transparent substrate layer (1) thickness is 50 ~ 100 μm, transmittance > 98%, mist degree < 1.0%.
2. anti-blue light OCA optical adhesive tape according to claim 1, is characterized in that: described anti-indigo plant
The thickness of light coating is 0.5 ~ 3 μm.
3. anti-blue light OCA optical adhesive tape according to claim 1, is characterized in that: described transparent substrate layer (1) is film layer or layer of polypropylene foil or laminated polyester film.
CN201410850437.4A 2014-12-31 2014-12-31 Composite optical adhesive tape capable of absorbing blue light Active CN104497903B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105445837A (en) * 2015-12-18 2016-03-30 宁波高新区夏远科技有限公司 Blue-light-proof film
CN108288615A (en) * 2018-03-11 2018-07-17 哈尔滨医大眼科医疗科技开发有限公司 A kind of special eye-protecting lamp of student

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109181677A (en) * 2018-10-08 2019-01-11 崔学金 A kind of irradiative metal

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070004065A1 (en) * 2005-06-30 2007-01-04 3M Innovative Properties Company Phosphor tape article
CN103614089A (en) * 2013-11-22 2014-03-05 东莞市纳利光学材料有限公司 Golden blue ray-resistant protection film and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070004065A1 (en) * 2005-06-30 2007-01-04 3M Innovative Properties Company Phosphor tape article
CN103614089A (en) * 2013-11-22 2014-03-05 东莞市纳利光学材料有限公司 Golden blue ray-resistant protection film and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105445837A (en) * 2015-12-18 2016-03-30 宁波高新区夏远科技有限公司 Blue-light-proof film
CN108288615A (en) * 2018-03-11 2018-07-17 哈尔滨医大眼科医疗科技开发有限公司 A kind of special eye-protecting lamp of student

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Address after: 223900 Sihong Province Economic Development Zone, Suqian, West Ocean West Road, No. 6

Patentee after: Jiangsu Stick new materials Polytron Technologies Inc

Address before: 215400 Taicang, Suzhou, Taicang Economic Development Zone, Qingdao West Road, No. 11, No.

Patentee before: Suzhou Sidike New Material Science & Technology Co., Ltd.

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20170705

Address after: 215400 Taicang, Suzhou, Taicang Economic Development Zone, Qingdao West Road, No. 11, No.

Patentee after: Taicang Stick new Mstar Technology Ltd

Address before: 223900 Sihong Province Economic Development Zone, Suqian, West Ocean West Road, No. 6

Patentee before: Jiangsu Stick new materials Polytron Technologies Inc