CN104497750B - A kind of wall coating for building - Google Patents
A kind of wall coating for building Download PDFInfo
- Publication number
- CN104497750B CN104497750B CN201510034185.2A CN201510034185A CN104497750B CN 104497750 B CN104497750 B CN 104497750B CN 201510034185 A CN201510034185 A CN 201510034185A CN 104497750 B CN104497750 B CN 104497750B
- Authority
- CN
- China
- Prior art keywords
- parts
- building
- coating
- herba eichhorniae
- wall coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to technical field of coatings, be specifically related to a kind of wall coating for building.Described coating is counted by weight and is included by following components: water-borne acrylic resin 30 50 parts, aqueous acrylic modified epoxy resin 10 20 parts, polydimethylsiloxane 10 20 parts, organic solvent 18 27 parts, Kaolin 35 parts, ferrum oxide 35 parts, nano titanium oxide 25 parts, Herba Eichhorniae additive 5 10 parts, cuprous sulfate 12 parts, butylamino formic acid iodopropynyl ester 13 parts；Modified hydroxylapatite 5 10 parts.The coating of the present invention can be the most antibacterial, and prevents metope mouldy owing to making moist, thus keeps the bright and clean of metope.
Description
Technical field
The present invention relates to technical field of coatings, be specifically related to a kind of wall coating for building.
Background technology
Wall covering refers to play decoration and protection for building wall, makes building wall beautiful and clean, also is able to play protection building wall simultaneously, extends the effect in its service life.Wall covering includes interior wall coating and exterior coating two large divisions by building wall classification.Interior wall coating focuses on decoration and environmental protection；Exterior coating focuses on protection with durable.Wall covering is in addition to decoration own and protective effect, also to rich and varied, fashion, health environment-friendly trend development.It is desirable to the brilliant magnificent mansion of decorative effect, elegant, romance, warmth；Also it is more desirable to that material itself is pollution-free, health environment-friendly, individual character and be rich in third dimension.
Exterior coating is to be applied over outside vertical surface of building or build the coating of thing.Its film forming Hou of constructing; film is chronically exposed in external environment; must stand to expose to the sun and rain, the wet change of alternate freezing and thawing, the universe, harmful substance corrode and air pollution etc.; keep long protection and decorative effect; that is having the service life that a comparison is permanent, exterior coating must possess certain performance.
The main function of interior wall coating is decoration and protection indoor wall (including ceiling) so that it is beautiful and clean, allows people be in joyful living environment.Interior wall coating uses environmental condition better than exterior coating, therefore requires low compared with exterior coating at aspects such as weatherability, resistance to water, stain resistant and film temperature-change resistances, and for performance, exterior coating can use what interior wall, and interior wall coating can not use what exterior wall.But interior wall coating requires often high than exterior coating in terms of the feature of environmental protection.
Although current wall covering is of a great variety, performance is different, but though exterior wall interior wall coating, equal Shortcomings in terms of water proofing property, although some coating has certain water proofing property, but metope is the most mouldy after making moist, and be not easily cleaned after mouldy, cause metope spatter property poor.
Summary of the invention
The invention aims to solve the problems referred to above, it is provided that a kind of wall coating for building.
In order to reach foregoing invention purpose, the present invention is by the following technical solutions: a kind of wall coating for building, and described coating is counted by weight and included: water-borne acrylic resin 30-50 part, aqueous acrylic modified epoxy resin 10-20 part, polydimethylsiloxane 10-20 part, organic solvent 18-27 part, Kaolin 3-5 part, ferrum oxide 3-5 part, nano titanium oxide 2-5 part, Herba Eichhorniae additive 5-10 part, cuprous sulfate 1-2 part, butylamino formic acid iodopropynyl ester 1-3 part；Modified hydroxylapatite 5-10 part.
Herba Eichhorniae is currently a kind of plant that environment causes serious harm, and it has badly influenced the life of people to the harm of environment, and employing Herba Eichhorniae additive can be the most antibacterial herein.
As preferably, described coating is counted by weight and is included following components: water-borne acrylic resin 40-45 part, aqueous acrylic modified epoxy resin 10-12 part, polydimethylsiloxane 10-15 part, organic solvent 18-20 part, Kaolin 3-4 part, ferrum oxide 4-5 part, nano titanium oxide 2-3 part, Herba Eichhorniae additive 8-10 part, cuprous sulfate 1-2 part, butylamino formic acid iodopropynyl ester 1 part；Modified hydroxylapatite 5-6 part.
As preferably, the preparation method of described Herba Eichhorniae additive is:
(1) taking fresh Herba Eichhorniae, room temperature is shunk to the 40-50% of original weight amount, then soaks 3-5h in copper/saturated copper sulphate solution, after taking-up, dries and be crushed to 200 mesh at 50-80 DEG C；
(2) hydroxyethyl cellulose is dissolved in sodium hydroxide saturated aqueous solution according to the ratio that sodium hydroxide ratio is 1:2, stirring 30min, then product step (1) obtained is according to being that 1:1 joins in mixed liquor with hydroxyethyl cellulose mass ratio, it is warming up to 50-60 DEG C, stirring reaction 30-60min；
(3) by reactant liquor pH regulator to neutral, Herba Eichhorniae additive then it is filtrated to get.
As preferably, the Herba Eichhorniae shunk through room temperature in described step (1), the acetum first using mass concentration to be 5-10% before using copper/saturated copper sulphate solution soaking soaks 10-20min.
As preferably, the preparation method of described modified hydroxylapatite is: takes fresh Herba Eichhorniae and dries at 50-80 DEG C, then 100-200 mesh it is crushed to, by water reflux, extract, 1-2h at 100 DEG C, Herba Eichhorniae is 1:3 with the mass ratio of water, and then sucking filtration obtains filtrate, by hydroxyapatite that particle diameter is 200-500nm according to being that 1:3 joins in filtrate and mixes with filtrate ratio, stirring 30-60min, then dries at 30-50 DEG C, obtains modified hydroxylapatite thing.
As preferably, described in obtain modified hydroxylapatite and join in paraffin oil, ultrasonic disperse 10-30min, then filter and be dried.Hydroxyapatite is to have a lot of hole, and being joined by modified hydroxylapatite in paraffin oil is to the effective ingredient of Herba Eichhorniae attached thereto be carried out sealing, preventing it quickly to run off, extend the expiration date.
As preferably, described organic solvent is dimethylbenzene or butyl acetate.On the one hand both solvents are good to each component solute effect, and another aspect is free from side effects, and will not have a negative impact coating.
As preferably, described coating also includes the N-Methyl pyrrolidone of 5-8 part.N-Methyl pyrrolidone is that a kind of selectivity is strong and the polar solvent of good stability, have that toxicity is low, boiling point is high, dissolving power is strong, nonflammable, biodegradable, recoverable, in the present invention, its effect is to improve Herba Eichhorniae additive and the dispersive property of modified hydroxylapatite, avoid both effective ingredient to reunite to cause losing efficacy, improve the holding time of coating.Simultaneously as it can volatilize with steam, there is hygroscopicity.Therefore after coating coats, it would however also be possible to employ paint film is processed by steam, it is simple to the removal of coating and recovery.
As preferably, the sodium alginate also including 0.1-0.3 part counted by weight by described coating.Sodium alginate can improve the film forming of coating, and enables to the glossiness after coating drying and forming-film, reduces the adhesive force of coating film forming rear surface, it is to avoid the paint film surface contamination globule and dust, thus reduces the generation of paint film surface moldy metamorphism further.
As preferably, the modified chitin also including 0.5-2 part counted by weight by described coating.Chitin is conducive to improving the cohesiveness of dried coating, thus improves the intensity of coating.
The present invention compared with prior art, provides the benefit that: it is mouldy owing to making moist that the coating of the present invention can be effectively prevented metope, thus keeps the bright and clean of metope, and the coating of the present invention can be the most antibacterial, and binding strength is good, and persistently difficult drop-off；The coating holding time before use is long.
Detailed description of the invention
Below by specific embodiment, technical scheme is further described explanation.
If without specified otherwise, the raw material employed in embodiments of the invention is raw material commonly used in the art, and the method employed in embodiment is the conventional method of this area.
Embodiment 1:
The preparation of Herba Eichhorniae additive, method particularly includes:
(1) taking fresh Herba Eichhorniae, room temperature is shunk to the 50% of original weight amount, then soaks 3-5h in copper/saturated copper sulphate solution, after taking-up, dries and be crushed to 200 mesh at 50-80 DEG C；
(2) hydroxyethyl cellulose is dissolved in sodium hydroxide saturated aqueous solution according to the ratio that sodium hydroxide ratio is 1:2, stirring 30min, then product step (1) obtained is according to being that 1:1 joins in mixed liquor with hydroxyethyl cellulose mass ratio, it is warming up to 50-60 DEG C, stirring reaction 30-60min；
(3) by reactant liquor pH regulator to neutral, Herba Eichhorniae additive then it is filtrated to get.
The preparation of modified hydroxylapatite, method particularly as follows:
Take fresh Herba Eichhorniae to dry at 50-80 DEG C, then 100-200 mesh it is crushed to, by water reflux, extract, 1-2h at 100 DEG C, Herba Eichhorniae is 1:3 with the mass ratio of water, then sucking filtration obtains filtrate, by hydroxyapatite that particle diameter is 200-500nm according to being that 1:3 joins in filtrate and mixes with filtrate ratio, stirs 30-60min, then dry at 30-50 DEG C, obtain modified hydroxylapatite thing.
A kind of wall coating for building, its raw materials by weight portion meter (every part of 100g) is prepared: water-borne acrylic resin 30 parts, aqueous acrylic modified epoxy resin 20 parts, polydimethylsiloxane 10 parts, organic solvent (dimethylbenzene or butyl acetate) 27 parts, Kaolin 3 parts, ferrum oxide 5 parts, nano titanium oxide 2 parts, Herba Eichhorniae additive 10 parts, cuprous sulfate 1 part, butylamino formic acid iodopropynyl ester 3 parts；Modified hydroxylapatite 5 parts, the N-Methyl pyrrolidone of 8 parts.
After raw material is ready to, the solid constituent of each component is joined in liquid component, at 40 DEG C, stir 60min, be finished product.
Embodiment 2:
Herba Eichhorniae additive is identical with embodiment 1 with the preparation of modified hydroxylapatite.
A kind of wall coating for building, its raw materials by weight portion meter (every part of 100g) is prepared: water-borne acrylic resin 50 parts, aqueous acrylic modified epoxy resin 10 parts, polydimethylsiloxane 20 parts, organic solvent (dimethylbenzene or butyl acetate) 18 parts, Kaolin 5 parts, ferrum oxide 3 parts, nano titanium oxide 5 parts, Herba Eichhorniae additive 5 parts, cuprous sulfate 2 parts, butylamino formic acid iodopropynyl ester 1 part；Modified hydroxylapatite 10 parts, the N-Methyl pyrrolidone of 5 parts.
After raw material is ready to, the solid constituent of each component is joined in liquid component, at 50 DEG C, stir 30min, be finished product.
Embodiment 3:
The preparation of Herba Eichhorniae additive, method particularly includes:
(1) taking fresh Herba Eichhorniae, room temperature is shunk to the 40% of original weight amount, and the acetum first using mass concentration to be 10% soaks 10-20min, then soaks 3-5h in copper/saturated copper sulphate solution, after taking-up, dries and be crushed to 200 mesh at 50-80 DEG C；
(2) hydroxyethyl cellulose is dissolved in sodium hydroxide saturated aqueous solution according to the ratio that sodium hydroxide ratio is 1:2, stirring 30min, then product step (1) obtained is according to being that 1:1 joins in mixed liquor with hydroxyethyl cellulose mass ratio, it is warming up to 50-60 DEG C, stirring reaction 30-60min；
(3) by reactant liquor pH regulator to neutral, Herba Eichhorniae additive then it is filtrated to get.
The preparation of modified hydroxylapatite, method particularly as follows:
Take fresh Herba Eichhorniae to dry at 50-80 DEG C, then 100-200 mesh it is crushed to, by water reflux, extract, 1-2h at 100 DEG C, Herba Eichhorniae is 1:3 with the mass ratio of water, then sucking filtration obtains filtrate, by hydroxyapatite that particle diameter is 200-500nm according to being that 1:3 joins in filtrate and mixes with filtrate ratio, stirring 30-60min, then dry at 30-50 DEG C, obtain modified hydroxylapatite, in order to improve the dispersibility of hydroxyapatite and improve its in coating right, then add it in paraffin oil, ultrasonic disperse 10min, then filters and is dried.
A kind of wall coating for building, its raw materials by weight portion meter (every part of 100g) is prepared: water-borne acrylic resin 40 parts, aqueous acrylic modified epoxy resin 12 parts, polydimethylsiloxane 10 parts, organic solvent (dimethylbenzene or butyl acetate) 20 parts, Kaolin 4 parts, ferrum oxide 4 parts, nano titanium oxide 3 parts, Herba Eichhorniae additive 8 parts, cuprous sulfate 1 part, butylamino formic acid iodopropynyl ester 3 parts；Modified hydroxylapatite 6 parts, the N-Methyl pyrrolidone of 8 parts, the sodium alginate of 0.3 part, the modified chitin of 0.5 part.
After raw material is ready to, the solid constituent of each component is joined in liquid component, at 40 DEG C, stir 60min, be finished product.
Embodiment 4:
The preparation of Herba Eichhorniae additive, method particularly includes:
(1) taking fresh Herba Eichhorniae, room temperature is shunk to the 40% of original weight amount, and the acetum first using mass concentration to be 5% soaks 10-20min, then soaks 3-5h in copper/saturated copper sulphate solution, after taking-up, dries and be crushed to 200 mesh at 50-80 DEG C；
(2) hydroxyethyl cellulose is dissolved in sodium hydroxide saturated aqueous solution according to the ratio that sodium hydroxide ratio is 1:2, stirring 30min, then product step (1) obtained is according to being that 1:1 joins in mixed liquor with hydroxyethyl cellulose mass ratio, it is warming up to 50-60 DEG C, stirring reaction 30-60min；
(3) by reactant liquor pH regulator to neutral, Herba Eichhorniae additive then it is filtrated to get.
The preparation of modified hydroxylapatite, method particularly as follows:
Take fresh Herba Eichhorniae to dry at 50-80 DEG C, then 100-200 mesh it is crushed to, by water reflux, extract, 1-2h at 100 DEG C, Herba Eichhorniae is 1:3 with the mass ratio of water, then sucking filtration obtains filtrate, by hydroxyapatite that particle diameter is 200-500nm according to being that 1:3 joins in filtrate and mixes with filtrate ratio, stirring 30-60min, then dry at 30-50 DEG C, obtain modified hydroxylapatite, in order to improve the dispersibility of hydroxyapatite and improve its in coating right, then add it in paraffin oil, ultrasonic disperse 30min, then filters and is dried.
A kind of wall coating for building, its raw materials by weight portion meter (every part of 100g) is prepared: water-borne acrylic resin 45 parts, aqueous acrylic modified epoxy resin 15 parts, polydimethylsiloxane 15 parts, organic solvent (dimethylbenzene or butyl acetate) 20 parts, Kaolin 3 parts, ferrum oxide 5 parts, nano titanium oxide 2 parts, Herba Eichhorniae additive 10 parts, cuprous sulfate 1 part, butylamino formic acid iodopropynyl ester 3 parts；Modified hydroxylapatite 5 parts, the N-Methyl pyrrolidone of 8 parts, the sodium alginate of 0.1 part, the modified chitin of 2 parts.
After raw material is ready to, the solid constituent of each component is joined in liquid component, at 40 DEG C, stir 60min, be finished product.
Claims (10)
1. a wall coating for building, it is characterized in that, described coating is counted by weight and is included: water-borne acrylic resin 30-50 part, aqueous acrylic modified epoxy resin 10-20 part, polydimethylsiloxane 10-20 part, organic solvent 18-27 part, Kaolin 3-5 part, ferrum oxide 3-5 part, nano titanium oxide 2-5 part, Herba Eichhorniae additive 5-10 part, cuprous sulfate 1-2 part, butylamino formic acid iodopropynyl ester 1-3 part；Modified hydroxylapatite 5-10 part.
A kind of wall coating for building the most according to claim 1, it is characterized in that, described coating is counted by weight and is included following components: water-borne acrylic resin 40-45 part, aqueous acrylic modified epoxy resin 10-12 part, polydimethylsiloxane 10-15 part, organic solvent 18-20 part, Kaolin 3-4 part, ferrum oxide 4-5 part, nano titanium oxide 2-3 part, Herba Eichhorniae additive 8-10 part, cuprous sulfate 1-2 part, butylamino formic acid iodopropynyl ester 1 part；Modified hydroxylapatite 5-6 part.
A kind of wall coating for building the most according to claim 1, it is characterised in that the preparation method of described Herba Eichhorniae additive is:
(1) taking fresh Herba Eichhorniae, room temperature is shunk to the 40-50% of original weight amount, then soaks 3-5h in copper/saturated copper sulphate solution, after taking-up, dries and be crushed to 200 mesh at 50-80 DEG C；
(2) hydroxyethyl cellulose is dissolved in sodium hydroxide saturated aqueous solution according to the ratio that sodium hydroxide ratio is 1:2, stirring 30min, then product step (1) obtained is according to being that 1:1 joins in mixed liquor with hydroxyethyl cellulose mass ratio, it is warming up to 50-60 DEG C, stirring reaction 30-60min；
(3) by reactant liquor pH regulator to neutral, Herba Eichhorniae additive then it is filtrated to get.
A kind of wall coating for building the most according to claim 3, it is characterised in that the Herba Eichhorniae shunk through room temperature in described step (1), the acetum first using mass concentration to be 5-10% before using copper/saturated copper sulphate solution soaking soaks 10-20min.
A kind of wall coating for building the most according to claim 1, it is characterized in that, the preparation method of described modified hydroxylapatite is: takes fresh Herba Eichhorniae and dries at 50-80 DEG C, then 100-200 mesh it is crushed to, by water reflux, extract, 1-2h at 100 DEG C, Herba Eichhorniae is 1:3 with the mass ratio of water, then sucking filtration obtains filtrate, by hydroxyapatite that particle diameter is 200-500nm according to being that 1:3 joins in filtrate and mixes with filtrate ratio, stirring 30-60min, then dry at 30-50 DEG C, obtain modified hydroxylapatite thing.
A kind of wall coating for building the most according to claim 5, it is characterised in that described in obtain modified hydroxylapatite and join in paraffin oil, ultrasonic disperse 10-30min, then filter and be dried.
A kind of wall coating for building the most according to claim 1, it is characterised in that described organic solvent is dimethylbenzene or butyl acetate.
A kind of wall coating for building the most according to claim 1, it is characterised in that described coating also includes the N-Methyl pyrrolidone of 5-8 part.
A kind of wall coating for building the most according to claim 1, it is characterised in that the sodium alginate also including 0.1-0.3 part counted by weight by described coating.
A kind of wall coating for building the most according to claim 1, it is characterised in that the modified chitin also including 0.5-2 part counted by weight by described coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510034185.2A CN104497750B (en) | 2015-01-23 | 2015-01-23 | A kind of wall coating for building |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510034185.2A CN104497750B (en) | 2015-01-23 | 2015-01-23 | A kind of wall coating for building |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104497750A CN104497750A (en) | 2015-04-08 |
| CN104497750B true CN104497750B (en) | 2016-12-07 |
Family
ID=52939211
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510034185.2A Expired - Fee Related CN104497750B (en) | 2015-01-23 | 2015-01-23 | A kind of wall coating for building |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104497750B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108795190A (en) * | 2018-05-07 | 2018-11-13 | 合肥仁德电子科技有限公司 | A kind of wall covering that can improve Projection Display effect |
| CN109233450A (en) * | 2018-08-07 | 2019-01-18 | 东莞理工学院 | A kind of water hyacinth plant organic coating and preparation method thereof |
| CN115595034B (en) * | 2022-10-25 | 2023-08-08 | 广东润和新材料科技有限公司 | Antiviral and antibacterial nano paint for engine room as well as preparation method and application thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3470336B2 (en) * | 1995-02-20 | 2003-11-25 | ダイキン工業株式会社 | Antifouling agent and composition for non-aqueous paint containing the same |
| NO319405B1 (en) * | 2000-07-05 | 2005-08-08 | Sintef | Organic based lacquer or gel coat, method of preparation and use of same |
| CN102432831B (en) * | 2011-08-30 | 2013-07-24 | 华南理工大学 | Single-component aqueous epoxy resin emulsion capable of being self-cured at normal temperature, and preparation method thereof |
| CN103980776A (en) * | 2013-08-18 | 2014-08-13 | 全椒县泰峰新材料销售有限公司 | Scrubbing-resistant exterior coating |
-
2015
- 2015-01-23 CN CN201510034185.2A patent/CN104497750B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN104497750A (en) | 2015-04-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103193444B (en) | Silicic acid mud interior wall decorating material and preparation method thereof | |
| CN104497750B (en) | A kind of wall coating for building | |
| CN105542595A (en) | Graphene-diatomaceous-earth anti-formaldehyde coating and preparing method thereof | |
| WO2017016091A1 (en) | Interior wall water paint for children's bedroom and preparation method therefor | |
| CN102167936B (en) | Marine organism shell powder paint | |
| CN103509395A (en) | Method for preparing slow-release composite antibacterial coating | |
| CN108410285B (en) | Mildew-proof and bactericidal environment-friendly coating | |
| CN110402959A (en) | A kind of permanent seal cooling leather antibacterial agent and preparation method thereof | |
| CN106830829B (en) | Environment-friendly type inner wall dry powder emulsion paint and preparation method thereof | |
| CN102990748A (en) | Sooting and staining method for environment-friendly wood | |
| CN104725934A (en) | Preparation method of water-based ink, containing Ag-carrying sepiolite antibacterial material, for tipping paper | |
| CN112358757A (en) | Strippable protective film coating and preparation method and application thereof | |
| CN102531461B (en) | Negative ion inorganic dry powder coating and preparation method and construction process thereof | |
| CN106317973A (en) | Environment-friendly fiber coating | |
| CN115260891A (en) | Environment-friendly shell powder coating and preparation process thereof | |
| CN106590194B (en) | A kind of low smell can decompose the high-performance anti-stain latex paint compositions and its preparation method and application of formaldehyde | |
| CN105482707A (en) | Formaldehyde-removing waterborne sealing primer used for artificial board | |
| CN110423503B (en) | Wall waterproof coating and coating method thereof | |
| KR20200063791A (en) | Process for preparing eco-friendly paint composition comprising Polygoum tinctoria and trass | |
| CN114045075A (en) | Anti-formaldehyde coating and preparation method and application thereof | |
| CN101130718A (en) | Compositions for cleaning ''scaly tetter'' and processes for producing same | |
| CN104030612B (en) | The diatom ooze building and ornament materials of high bond strength and biocidal property | |
| CN106902790A (en) | A kind of high-efficiency adsorbent based on ginkgo leaf and preparation method thereof | |
| CN112898841A (en) | Super-matte aldehyde-removing spraying type texture paint and preparation method thereof | |
| CN106675243A (en) | Environment-friendly and healthy white bamboo charcoal functional coating for interior walls |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20161207 Termination date: 20180123 |