CN104497243B - A kind of phenolic resin glue manufacture method for the bamboo integrated section bar of wood - Google Patents
A kind of phenolic resin glue manufacture method for the bamboo integrated section bar of wood Download PDFInfo
- Publication number
- CN104497243B CN104497243B CN201410767946.0A CN201410767946A CN104497243B CN 104497243 B CN104497243 B CN 104497243B CN 201410767946 A CN201410767946 A CN 201410767946A CN 104497243 B CN104497243 B CN 104497243B
- Authority
- CN
- China
- Prior art keywords
- wood
- section bar
- phenolic resin
- bamboo
- resin glue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 235000017166 Bambusa arundinacea Nutrition 0.000 title claims abstract description 87
- 235000017491 Bambusa tulda Nutrition 0.000 title claims abstract description 87
- 241001330002 Bambuseae Species 0.000 title claims abstract description 87
- 235000015334 Phyllostachys viridis Nutrition 0.000 title claims abstract description 87
- 239000011425 bamboo Substances 0.000 title claims abstract description 87
- 239000002023 wood Substances 0.000 title claims abstract description 55
- 239000003292 glue Substances 0.000 title claims abstract description 38
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 239000005011 phenolic resin Substances 0.000 title claims abstract description 26
- 229920001568 phenolic resin Polymers 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims abstract description 54
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 49
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000000203 mixture Substances 0.000 claims abstract description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 8
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000010792 warming Methods 0.000 claims abstract description 6
- 230000001105 regulatory effect Effects 0.000 claims abstract description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 24
- 239000000047 product Substances 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 238000012360 testing method Methods 0.000 claims description 8
- 229920001732 Lignosulfonate Polymers 0.000 claims description 3
- 238000005070 sampling Methods 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 8
- 229910052573 porcelain Inorganic materials 0.000 abstract description 4
- 230000006378 damage Effects 0.000 abstract description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 9
- 239000000835 fiber Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 238000009413 insulation Methods 0.000 description 6
- 239000012530 fluid Substances 0.000 description 5
- 239000003513 alkali Substances 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 238000005034 decoration Methods 0.000 description 4
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 238000003763 carbonization Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 102000002322 Egg Proteins Human genes 0.000 description 2
- 108010000912 Egg Proteins Proteins 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 244000179684 Passiflora quadrangularis Species 0.000 description 2
- 235000011266 Passiflora quadrangularis Nutrition 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 239000004035 construction material Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000013007 heat curing Methods 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 210000004681 ovum Anatomy 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 201000004384 Alopecia Diseases 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 241000270295 Serpentes Species 0.000 description 1
- 244000186561 Swietenia macrophylla Species 0.000 description 1
- 229920002522 Wood fibre Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 231100000360 alopecia Toxicity 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000003544 deproteinization Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 238000010413 gardening Methods 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000003032 molecular docking Methods 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- -1 phenolic aldehyde Chemical class 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000013102 re-test Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000010421 standard material Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000002025 wood fiber Substances 0.000 description 1
Landscapes
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The invention discloses a kind of phenolic resin glue manufacture method for the bamboo integrated section bar of wood, comprise the steps: 1) it is stirred being mixed to form mixture by formaldehyde, phenol, sodium hydroxide, diethylene glycol and ferrous oxide, the pH value regulating described mixture by increasing sodium hydroxide is 7～8, then heats to 65～85 DEG C and reacts；2) toward step 1) in product in add formaldehyde, phenol, ferrous oxide and aluminium sesquioxide, be warming up to 85～97 DEG C after being stirred and react.Use the section bar that phenolic resin glue prepares as exterior material, do not soak, do not expand, do not ftracture, indeformable, do not go rotten and do not damage by worms, and the density superelevation of section bar, durable in use, the bamboo integrated section bar of wood can reach the effect of half porcelain.
Description
[technical field]
The present invention relates to the integrated section bar glue field of bamboo wood, be specifically related to a kind of phenolic resin for the bamboo integrated section bar of wood
Glue manufacture method.
[background technology]
Along with the development and progress of society, improving constantly of people's living standard, people live finishing increasingly to indoor
Being particular about, typically other is many can use natural green environment-friendly materials to decorate, rich other not only interior decoration material say
Study carefully, inhabitation outdoor gardening view is built more and more exquisite.But current global famous and precious choice wood prohibit cut down, in great shortage,
And China or even the whole world are increasing to the demand of outdoor building natural timber, wood for outdoor decoration can only use through not
Play the artificial anticorrosive wood of four seasons weather corrosion and be unable to undergo the low-grade timber replacement used for several years, result in outdoor dress
Newly 2 years old, the situation just collapsed for 5 years for 3 years in 1 year for decorations building.
The outdoor building material used now, in addition to stone material, as needed ecological bamboo timber to build view, because energy is weather-proof
First-class famous and precious timber is in great shortage, can only use cannot the low-grade timber of weatherability, as Masson Pine, Lignum seu Ramulus Cunninghamiae Lanceolatae etc., as built bamboo skill
Art view, is to build with the former bamboo of log mostly, if being in outdoor, the former bamboo of log is just ftractureed mouldy general one or two years
Rot.Currently also there is the exterior decoration of the timber after utilizing preservative treatment, although will not ftracture at once, but the most just
It is just to go mouldy rotten in 3 or five years.Outdoor flooring a multitude of names now, example: plastic-wood floor, heavy bamboo floor and anticorrosive wood ground
Plate etc., but be unable to undergo climate change more and expose to the sun and rain, within 3 or five years, the most substantially scrap at most one or two years at least.
[summary of the invention]
Finding through further investigation, the existing bamboo former material of wood does not take off through strict secondary in the integrated front course of processing
Seborrheic alopecia sugar process, as outdoor open-air materials'use it is difficult to ensure that do not go mouldy and damage by worms；The glued liquid effect that impregnation is used
Fruit is the most bad, is unable to undergo heat and shines the test drenched with rain with cold snap change, and the intensity of the bamboo integrated section bar of wood cannot be lasting,
Easily craze and transfiguration, dilatancy, rot to fall apart；Because of present bamboo integrated the used hydraulic press pressure of wood, exist more
800～1000kg/10mm2Left and right, the section bar density that compacting is formed is 800kg/m3One 1050kg/m3Between, far away without
Method keeps out being impregnated with of rainwater, rainwater being impregnated with year in year out, certainly will cause the hygral expansion of section bar and the dry change shunk,
Section bar is scrapped the most completely through can't stand several years；The existing bamboo integrated section bar of wood is typically by hot-press thermosetting and warm of colding pressing
Solidifying two kinds, solidification maximum temperature is arranged on 130 DEG C more, the highest is not more than more than 150 DEG C.
In order to overcome the deficiencies in the prior art, the invention provides a kind of phenolic resin glue system for the bamboo integrated section bar of wood
Make method, with provide a kind of can make bamboo wooden integrated section bar be not easily susceptible to cracking, mouldy and rotten.
A kind of phenolic resin glue manufacture method for the bamboo integrated section bar of wood, comprises the steps:
1) by the formaldehyde that mass fraction is 40～60 parts, the phenol of 30～50 parts, the sodium hydroxide of 5～8 parts, 1～
The ferrous oxide of the diethylene glycol of 5 parts and 0.5～5 part is stirred being mixed to form mixture, by increasing sodium hydroxide
The pH value regulating described mixture is 7～8, then heats to 65～85 DEG C and reacts；Wherein, described hydroxide
Sodium needs to convert the water that mass ratio is 1:1.5～3, and described ferrous oxide needs to convert the water that mass ratio is 1:20～50；
2) toward step 1) in product in add mass fraction be the formaldehyde of 20～40 parts, the benzene of 20～30 parts
Phenol, the ferrous oxide of 0.5～5 part and the aluminium sesquioxide of 0.3～3 part, be warming up to 85～97 DEG C and enter after being stirred
Row reaction；Wherein step 2) in ferrous oxide need to convert the water that mass ratio is 1:20～50, step 2) in three
Al 2 O needs to convert the water that mass ratio is 1:20～50.
In one embodiment, in step 2) after also comprise the steps:
3) to described step 2) in product in add sodium hydroxide solution regulation product viscosity.
In one embodiment, in step 3) after also comprise the steps:
4) by described step 3) in product control at 80～95 DEG C, adding mass fraction is the wood of 1～7 part
Mahogany sulfonate is stirred.
In one embodiment, in described step 1) in, after temperature is warming up to 65～85 DEG C, it is incubated 50～90min
React.
In one embodiment, in step 1) and step 2) between, by step 1) reaction temperature drop to 45～
60℃。
In one embodiment, in step 2) in, it is incubated 45～100min after being warming up to 85～97 DEG C and reacts.
In one embodiment, in step 2) afterwards and in step 3) before, reaction temperature is down to 45～60 DEG C.
In one embodiment, also comprise the steps:
To described step 2) in product in add sodium hydroxide solution regulation product pH value be 7～9.
In one embodiment, after reaction temperature is down to 45～60 DEG C, further product temperature is down to 20～
35 DEG C of viscosity carrying out sampling test reaction product.
In one embodiment, in described step 3) in, reaction temperature is controlled at 55～95 DEG C.
The invention has the beneficial effects as follows: after have employed above-mentioned phenolic resin glue, this bamboo integrated section bar of wood prepared is as family
Outer material, almost can reach following performance under any weather conditions: do not soaks, do not expand, ftracture, constant
Shape, not going rotten and do not damage by worms, and the density superelevation of section bar, durable in use, the bamboo integrated section bar of wood can reach half porcelain
The effect changed.So-called half porcelain of the present invention, refers to that the bamboo integrated section bar of wood has some performances of similar pottery, if not
Immersion, without putrefaction etc..
[detailed description of the invention]
Preferred embodiment to invention is described in further detail below.
The phenolic resin glue manufacture method for the bamboo integrated section bar of wood of a kind of embodiment, comprises the steps:
(1) take formaldehyde 40～60 parts (mass fraction, lower with), phenol 30～50 parts, sodium hydroxide (liquid caustic soda or
Sheet alkali) 5～8 parts (being watered 1:1.5～3), diethylene glycol 1～5 parts and ferrous oxide 0.5～5 parts (be watered 1:20～
50, i.e. ferrous oxide: water is 1:20～50 (mass fraction ratio)), stir in then said mixture is added reactor
After Jun Yun again by add liquid caustic soda or sheet alkali regulation mixture pH value be 7～8, then heat to 65～85 DEG C, so
Rear insulation reaction 50～90min, during insulation, temperature also controls in the range of 65～85 DEG C.
(2), after insulation 50～90min, after temperature drops to 45～60 DEG C, whether test fluid adhesiveness reaches required standard
Requirement.Formaldehyde 20～40 parts, phenol 20～30 parts, ferrous oxide is added again in the product in step (1)
0.5～5 part, aluminium sesquioxide 0.3～3 parts (ferrous oxide and aluminium sesquioxide are respectively watered 1:20～50), stirring
Being warming up to 85～97 DEG C after Jun Yun, insulation reaction 45～100min, during insulation, temperature controls at 85～97 DEG C.
If the formaldehyde additionally added in step (1) in step (2) and ferrous oxide, due in step (1)
Reaction temperature is less than step (2), and the product that step (1) can be caused to be formed is aging, caking.Accordingly, it would be desirable to
After formaldehyde in step (1) and ferrous oxide fully react, then in step (2), add corresponding composition and proportioning.
(3), after insulation 45～100min has been reacted, it is cooled to 45～60 DEG C.Negate the liquid sample that should obtain to be cooled to
After 20～35 DEG C, carry out whether test fluid adhesiveness reaches required standard-required, by adding liquid caustic soda in product
Or the pH value of sheet alkali regulation product is 7～9.If taking liquid sample test fluid adhesiveness not reach required standard-required,
Need the sheet alkali liquor body after adding liquid caustic soda in product or being watered, after stirring, temperature is risen to 55～95 DEG C, then
Sampling cools to 25～35 DEG C of re-test sol viscosity, until viscosity reaches required standard-required.
(4), after test fluid adhesiveness reaches required standard-required, temperature in reactor, is kept also to control at 80～95 DEG C
Time, the lignosulfonates placing into 1～7 part stir.
(5) test fluid adhesiveness reaches required standard-required, cools to less than 45 DEG C and i.e. obtains for bamboo wood integrated-type
The phenolic resin glue of material, can be referred to as " number phenolic resin glue of porcelainization ", and " number phenolic resin glue of porcelainization " is in thoroughly
Bright pink, tasteless, not without pungent the most dazzling.
The manufacture method of the bamboo integrated section bar of wood of a kind of embodiment, comprises the steps:
(1) according to bamboo thick bamboo tube diameter, with save most the principle of material bamboo segmentation be sawn into 1m, 2m and 3m this three
Kind different length specifications, according to thick bamboo tube diameter, carries out thick bamboo tube split or four opens the six bamboo cane sheets opened.
(2) bamboo green grass or young crops, the ring of inwall and the Concretio silicea Bambusae seu schizostachyi of the bamboo chip outer layer being split into bar are removed.
(3) through step 2) after bamboo chip crush and be broken into grenadine shape, broken and constantly keep bamboo fibre net to be still connected.
(4) grenadine shape bamboo chip is put in the boiling water of capped container and boil, add (quality or mole) concentration in boiling water
It is " hydrogen peroxide " of 0.5%.Owing to, in this step, bamboo chip boils in capped container, boil the process of bamboo chip and common electricity
The process of cooking of rice cooker is identical, thus, (time is past to carry out boiling bamboo chip in the outdoor container do not added a cover with existing utilization
Toward the longest such as 10 hours) method compare, this method not only saves the energy but also time-consuming, in certain embodiments, this
Method can save the burning energy of more than 50%, shortens again the digestion time of 50%.And the existing outdoor appearance do not added a cover
Device boils bamboo chip, and the effect of its desaccharide sterilization is the most very limited.And this method remove more up hill and dale the sugar in bamboo chip body,
Protein, starch etc. are easily corrupt or cause the Organic substance of snake, and thoroughly kill all of worm's ovum in bamboo chip and
Harmful levels of pathogens, can effectively ensure that the effect that bamboo wood integrated timber half porcelainization uses.
(5) in being directly entered the retort of High Temperature High Pressure with the bamboo chip after boiling water steaming and decocting, carbonization is carried out.Current indoor
The carbonization air pressure of the bamboo integrated section bar of wood arranges pressure 3～3.5/kp, and maximum temperature is arranged on 110 DEG C～130 DEG C.And this
In step, the air pressure in retort is 4.5～5.4/kp, and maximum temperature is arranged on 140 DEG C～160 DEG C.This is big to bamboo wood
The secondary thorough desaccharide deproteinization of material and starch etc. play significant role, and more thorough to the sterilization and disinsection ovum in big material.
The outdoor use of this bamboo integrated section bar of wood to making serves again a key effect.
(6) bamboo chip after carbonization is shone with the sun dry, or dry with large-scale drying plant mechanization streamline, dry
After bamboo chip moisture content all must not be beyond 8～10%.
(7) bamboo chip after drying is carried out applying glue, be i.e. stained with the phenolic resin glue of above-described embodiment.The most all use
With impregnation, it is convenient and swift for soaking glue great advantage, and disadvantage is that cloth glue is uneven, the bamboo above soaked especially
Sheet glue relative concentration is higher, and the bamboo chip above soaked due to a part of glue adsorbs, if supplementing glue not in time,
The glue concentration of the bamboo chip absorption put into below is the lowest, so absolute to the quality manufacturing the bamboo integrated section bar of wood obtained
Being a fatal defect, such as, the intensity of the integrated section bar of different parts is different, therefore cannot use out of doors.
(8) the bamboo integrated profile length of wood of compacting at present all can only be at 1.8～2 meters, and it cannot become mark because of length limitation
Standardization construction material, the deep use to the bamboo integrated section bar of wood defines bottleneck.
Bamboo chip after applying glue is dried.Bamboo chip spreading after first applying glue being dried before compaction is to building standard material
4～6 meters, make to be docked by zero difference between the bamboo chip of spreading, and will not disconnect, connect by high pressure integrated bamboo wood
Section bar even density, that position, without departing from and reaching the seamless effect docked completely, cannot be found with eyes in joint
It is joint, and directly to close the most identical integrated with natural whole piece fiber of pulling force and bending strength.
(10) the bamboo chip after docking, it is pressed in loading hydraulic press module and obtains the bamboo integrated section bar of wood.Pressure
System can use hot pressing direct heat cure molding or two kinds of methods of heat cure molding of colding pressing.
(11) for making the above-mentioned bamboo integrated section bar of wood be more suitable for as construction material, and more preferable half porcelain effect is reached,
Need to increase the density of integrated timber.Much more typically the production board density of current wood glue plate, medium-density plate and high-density plate exist
600kg～800kg/m3, bamboo wood integrated timber density is at 900kg～1050kg/m3.And this bamboo wood integrated section bar compacting after close
Degree reaches 1100kg～1300kg/m3, considerably increases intensity and hardness, thus is more suitable for outdoor architecture.
(12) the bamboo integrated section bar of wood after high pressure is solidified.The highest solidification temperature is maintained at about 130 DEG C more now.
And in this step, phenolic resin glue solidification temperature need to reach 150 DEG C～200 DEG C.
Owing to adding diethylene glycol in the formula of phenolic resin glue, can quickly make described phenolic aldehyde when pyroreaction solidifies
The various compositions of resin glue are more uniformly dispersed, and more efficiently penetrate in each trickle bamboo and woods fiber aspect,
So that adhesion is more efficient uniformly between bamboo and woods fiber.
Owing to adding ferrous oxide, during hot setting molding, ferrous oxide energy in the formula of phenolic resin glue
It is greatly increased the integrated intensity of bamboo and woods fiber and hardness, makes to be difficult to peel off between the fiber in the bamboo integrated section bar of wood of formation,
Enhance the bond degree of the bamboo integrated section bar of wood, and the water resistance that has been multiplied.Meanwhile, because of ferrous oxide and bamboo wood
Fiber effectively combines, and the bamboo integrated section bar of wood more enhances weather resistance.
Owing to the addition of aluminium sesquioxide in the formula of phenolic resin glue, in bamboo and woods fiber, combine aluminium sesquioxide, with
Sample can strengthen wear-resisting, the shock resistance of the bamboo integrated section bar of wood and anti-rotten characteristic, and the bamboo integrated section bar of wood is reached weather-proof
Arrive important function.
With the addition of lignosulfonates in the formula of phenolic resin glue, the product hardness of the bamboo integrated section bar of wood can be strengthened, subtract
Water, viscose properties, prevent the bamboo integrated section bar craze and transfiguration of wood.
(13), after to the demoulding after the bamboo wood integrated section bar cooling after solidification, the bamboo integrated section bar of wood is taken out.
Above content is to combine concrete preferred implementation further description made for the present invention, it is impossible to assert
Being embodied as of the present invention is confined to these explanations.For general technical staff of the technical field of the invention,
Without departing from the inventive concept of the premise, it is also possible to make some simple deduction or replace, should be all considered as belonging to this
The scope of patent protection that invention is determined by the claims submitted to.
Claims (8)
1., for a phenolic resin glue manufacture method for the bamboo integrated section bar of wood, it is characterized in that, comprise the steps:
1) it is stirred being mixed to form mixture by the ferrous oxide of the formaldehyde that mass fraction is 40～60 parts, the phenol of 30～50 parts, the sodium hydroxide of 5～8 parts, the diethylene glycol of 1～5 part and 0.5～5 part, the pH value regulating described mixture by increasing sodium hydroxide is 7～8, is incubated 50～90min and reacts after then heating to 65～85 DEG C；Wherein, described sodium hydroxide needs to convert the water that mass ratio is 1:1.5～3, and described ferrous oxide needs to convert the water that mass ratio is 1:20～50；
2) toward step 1) in product in add mass fraction be the formaldehyde of 20～40 parts, the phenol of 20～30 parts, the ferrous oxide of 0.5～5 part and the aluminium sesquioxide of 0.3～3 part, be incubated after being warming up to 85～97 DEG C after being stirred and 45～100min react；Wherein step 2) in ferrous oxide need to convert the water that mass ratio is 1:20～50, step 2) in aluminium sesquioxide need to convert the water that mass ratio is 1:20～50.
2. the phenolic resin glue manufacture method for the bamboo integrated section bar of wood as claimed in claim 1, is characterized in that, in step 2) after also comprise the steps:
3) to described step 2) in product in add sodium hydroxide solution regulation product viscosity.
3. the phenolic resin glue manufacture method for the bamboo integrated section bar of wood as claimed in claim 2, is characterized in that, in step 3) after also comprise the steps:
4) by described step 3) in product control at 80～95 DEG C, adding mass fraction is that the lignosulfonates of 1～7 part are stirred.
4. the phenolic resin glue manufacture method for the bamboo integrated section bar of wood as claimed in claim 1, is characterized in that, in step 1) and step 2) between, by step 1) reaction temperature drop to 45～60 DEG C.
5. the phenolic resin glue manufacture method for the bamboo integrated section bar of wood as claimed in claim 2, is characterized in that, in step 2) afterwards and in step 3) before, reaction temperature is down to 45～60 DEG C.
6. the phenolic resin glue manufacture method for the bamboo integrated section bar of wood as claimed in claim 2, is characterized in that, also comprise the steps:
To described step 2) in product in add sodium hydroxide solution regulation product pH value be 7～9.
7. the phenolic resin glue manufacture method for the bamboo integrated section bar of wood as claimed in claim 5, is characterized in that, after reaction temperature is down to 45～60 DEG C, product temperature is down to 20～35 DEG C of viscosity carrying out sampling test reaction product further.
8. the phenolic resin glue manufacture method for the bamboo integrated section bar of wood as claimed in claim 2, is characterized in that, in described step 3) in, reaction temperature is controlled at 55～95 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410767946.0A CN104497243B (en) | 2014-12-12 | 2014-12-12 | A kind of phenolic resin glue manufacture method for the bamboo integrated section bar of wood |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410767946.0A CN104497243B (en) | 2014-12-12 | 2014-12-12 | A kind of phenolic resin glue manufacture method for the bamboo integrated section bar of wood |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104497243A CN104497243A (en) | 2015-04-08 |
| CN104497243B true CN104497243B (en) | 2016-08-31 |
Family
ID=52938708
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410767946.0A Expired - Fee Related CN104497243B (en) | 2014-12-12 | 2014-12-12 | A kind of phenolic resin glue manufacture method for the bamboo integrated section bar of wood |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104497243B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109401696B (en) * | 2018-11-01 | 2022-04-26 | 安吉明微智科技有限公司 | Preparation method of outdoor phenolic resin adhesive for bamboo and wood laminated wood |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5379004A (en) * | 1976-12-21 | 1978-07-13 | Nippon Synthetic Chem Ind | Aseptic treatment of wood and bamboo material |
-
2014
- 2014-12-12 CN CN201410767946.0A patent/CN104497243B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN104497243A (en) | 2015-04-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102107447B (en) | Wood sectional material and manufacturing method thereof | |
| CN102275200A (en) | Method for manufacturing bamboo-fiber composite section | |
| CN104400864B (en) | A kind of preparation method of bamboo and wood mixing charing restructuring composite board square stock | |
| CN105196395B (en) | A kind of open air heavy bamboo floor manufacturing process | |
| CN105313203A (en) | Quick drying method for rosewood | |
| CN102528893A (en) | Method for preparing environment-friendly bamboo recombinant material | |
| CN104493941B (en) | A kind of phenolic resin glue manufacture method for the integrated section bar of bamboo wood | |
| CN107186846B (en) | A kind of processing method of wicker plaiting article raw material wicker | |
| CN104497243B (en) | A kind of phenolic resin glue manufacture method for the bamboo integrated section bar of wood | |
| CN108453854B (en) | High-thermal-conductivity-coefficient wood based on water glass filling and preparation method and application thereof | |
| CN106272835A (en) | A kind of outdoor decoration Recombined bamboo manufacturing process | |
| CN110497484A (en) | A kind of high-strength weathering bamboo matter composite material and its manufacturing method | |
| CN105984003A (en) | Preparation method of SiO2 poplar composite material | |
| CN105563580A (en) | Bamboo and wood corrosion and mould prevention process | |
| CN110281321B (en) | Environment-friendly stable wood and surface layer thermal modification method thereof | |
| CN101116983A (en) | Glued laminated bamboo printing ink staining method | |
| CN106472153A (en) | A kind of manufacture method of bamboo matter environmental protection type flowerpot | |
| CN107127856B (en) | A kind of physical depth carbonization technique of fresh bamboo wood | |
| CN102303336B (en) | A kind of fast growing wood flame-retardant reinforced wood veneer and production method thereof | |
| CN108724397A (en) | A kind of production method of bamboo matter pencil slat | |
| CN106808550B (en) | A kind of high-carbon anti-corrosion bamboo wallboard and its production method | |
| CN108789766A (en) | A kind of closed hot pressing for self-bonding bamboo board method | |
| CN109849136A (en) | Natural timber modification liquid and its preparation method and application | |
| CN109929260A (en) | A method of environment-friendly degradable polymerization sheet is manufactured using agriculture and forestry organic waste material | |
| CN105108858A (en) | Process for producing dark polar wood imitating precious wood |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20151109 Address after: 313300, Zhejiang, Huzhou province Anji County Fengzhen filial piety Red Village village 104 Applicant after: Xiang Lin Address before: 313300, 66 poplar natural village, Fengzhen Poplar Village, Anji County, Huzhou, Zhejiang Province, China Applicant before: Yao Yulin |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180103 Address after: 313300 Zhejiang Huzhou city Anji County Changshuo street, Yunhong Road 1 (Yunhong mansion) 2017 room Patentee after: Anji Ming Wei Zhi Technology Co., Ltd. Address before: 313300, Zhejiang, Huzhou province Anji County Fengzhen filial piety Red Village village 104 Patentee before: Xiang Lin |
|
| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160831 Termination date: 20181212 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |