CN104496777A - Process for preparing benzaldehyde from phenylethylene through catalytic oxidation by adopting BuN-PMo12 - Google Patents
Process for preparing benzaldehyde from phenylethylene through catalytic oxidation by adopting BuN-PMo12 Download PDFInfo
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- CN104496777A CN104496777A CN201410779823.9A CN201410779823A CN104496777A CN 104496777 A CN104496777 A CN 104496777A CN 201410779823 A CN201410779823 A CN 201410779823A CN 104496777 A CN104496777 A CN 104496777A
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- bun
- pmo
- pmo12
- phenylethylene
- catalytic oxidation
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
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- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
The invention discloses a process for preparing benzaldehyde from phenylethylene through catalytic oxidation by adopting BuN-PMo12 and belongs to the technical field of benzaldehyde preparation. According to the process, benzaldehyde is prepared from phenylethylene through catalytic oxidation in an organic solvent system in a manner of taking hydrogen peroxide as an oxidant and taking BuN-PMo12 as a catalyst, wherein the mole ratio of phenylethylene to hydrogen peroxide to BuN-PMo12 catalyst is 1: (4-6): (0.05-0.08), the temperature of catalytic reaction is 60-75 DEG C, and the reaction pressure is normal pressure. The process for preparing benzaldehyde from phenylethylene through catalytic oxidation by adopting BuN-PMo12, disclosed by the invention, has the advantages that a method for preparing benzaldehyde through catalytic oxidation is provided, the BuN-PMo12 catalyst shows good catalysis performance, the conversion ratio and selectivity are relatively high, and the reaction conditions are mild.
Description
Technical field
The present invention relates to a kind of polyoxometallate Catalytic processes, especially a kind of cinnamic BuN-PMo12 catalyzed oxidation producing benzaldehyde technique, belongs to phenyl aldehyde preparing technical field.
Background technology
Phenyl aldehyde is the important source material of medicine, dyestuff, spices and Resin Industry, also can be used as solvent, softening agent and low-temperature grease etc.Technical benzene formaldehyde synthetic method Reactive Synthesis pressure is high, and environmental pollution is serious, the transformation efficiency of toluene and the shortcoming such as the selectivity ratios of aldehyde is lower.The research of selectivity of styrene catalyzed oxidation producing benzaldehyde has obtained certain progress, but also all there is the shortcomings such as reaction conditions requirement is high, and phenyl aldehyde yield is low.
Along with the development of basic subject and the propelling of process of industrialization, make higher requirement by the performance of catalyzer.The bifunctional " green catalyst " that heteropolyacid has both as a kind of acid-basicity and oxidation-reduction quality and receiving much concern.In the heteropoly compound of multiple configuration, Keggin-type research the most abundant, its thermostability is high, and catalytic activity makes well to show excellent catalytic performance in multiple reaction.
Summary of the invention
Goal of the invention of the present invention is: for above-mentioned Problems existing, provides a kind of and adopts BuN-PMo
12catalyzed oxidation vinylbenzene producing benzaldehyde technique, for the preparation of phenyl aldehyde.
The technical solution used in the present invention is as follows:
A kind of cinnamic BuN-PMo
12catalyzed oxidation producing benzaldehyde technique, in organic solvent system, take hydrogen peroxide as oxygenant, BuN-PMo
12for catalyzer, catalyzed oxidation vinylbenzene producing benzaldehyde, wherein said vinylbenzene, hydrogen peroxide, BuN-PMo
12the mol ratio of catalyzer is 1:4-6:0.05-0.08, and catalyzed reaction temperature is 60-75 DEG C.
Described organic solvent is acetonitrile.
The volume ratio 1:12-15 of described vinylbenzene and acetonitrile.
Described vinylbenzene, hydrogen peroxide, BuN-PMo
12the mol ratio of catalyzer is 1:5:0.07.
Described catalyzed reaction temperature is 70 DEG C.
The reaction pressure of reaction system is normal pressure.
In sum, owing to have employed technique scheme, the invention has the beneficial effects as follows:
Employing BuN-PMo of the present invention
12catalyzed oxidation vinylbenzene producing benzaldehyde technique, provides a kind of method that catalyzed oxidation prepares phenyl aldehyde, catalyst B uN-PMo
12in reaction system, cinnamic transformation efficiency can reach 99.7%, and the selectivity of phenyl aldehyde is 70.74%, catalyst B uN-PMo
12there is good catalytic performance, there is the advantage of reaction conditions gentleness.
Embodiment
All features disclosed in this specification sheets, or the step in disclosed all methods or process, except mutually exclusive feature and/or step, all can combine by any way.
Arbitrary feature disclosed in this specification sheets (comprising any accessory claim, summary), unless specifically stated otherwise, all can be replaced by other equivalences or the alternative features with similar object.That is, unless specifically stated otherwise, each feature is an example in a series of equivalence or similar characteristics.
In the present invention, BuN-PMo
12catalyzer (H
3pMo
12o
40nH
2o) synthesis: in the round-bottomed flask that 250ml is furnished with magneton stirring and reflux exchanger, by the 3.58g Na weighed
2hPO
412H
2o is dissolved in the distilled water of 20ml, with the H of 1:1
2sO
4being acidified to PH is about 2.0, then by the Na of 29.03g
2moO
42H
2o adds in flask after being dissolved in the distilled water of 5.0ml, regulate PH to 2.0, reaction solution is heated to 80 DEG C, and stirring and refluxing cooled after 3 hours, add ether again acidifying extract, after blowing away ether, solid recrystallization obtains product B uN-PMo twice
12catalyzer.
Catalyzed reaction is in the oil bath pan of band magnetic agitation, using 50ml there-necked flask (being convenient to adding and sampling in testing of oxygenant) as reaction vessel, and carry out under being equipped with reflux, add solvent, vinylbenzene, catalyzer and hydrogen peroxide in flask and react.
What adopt in the present invention is common commercially available AR raw material.
embodiment 1
Get vinylbenzene 10mmol(1.15ml), 30% hydrogen peroxide 40mmol(4ml), BuN-PMo
12catalyzer 0.05mol(0.13g), solvent acetonitrile 13.8ml, by vinylbenzene, acetonitrile, BuN-PMo
12catalyzer and hydrogen peroxide add in flask, and system is warming up to 60 DEG C, 1 hour reaction times, reaction pressure normal pressure.
embodiment 2
Get vinylbenzene 10mmol(1.15ml), 30% hydrogen peroxide 50mmol(5ml), BuN-PMo
12catalyzer 0.07mol(0.18g), solvent acetonitrile 15ml, by vinylbenzene, acetonitrile, BuN-PMo
12catalyzer and hydrogen peroxide add in flask, and system is warming up to 70 DEG C, 12 hours reaction times, reaction pressure normal pressure.
embodiment 3
Get vinylbenzene 10mmol(1.15ml), 30% hydrogen peroxide 60mmol(6ml), BuN-PMo
12catalyzer 0.08mol(0.21g), solvent acetonitrile 17.2ml, by vinylbenzene, acetonitrile, BuN-PMo
12catalyzer and hydrogen peroxide add in flask, and system is warming up to 75 DEG C, 6 hours reaction times, reaction pressure normal pressure.
The product of embodiment 1 to embodiment 3 gained is analyzed, and calculates cinnamic transformation efficiency and phenyl aldehyde selectivity.
As following table:
With each component of embodiment 2 when processing parameter for benchmark, do blank test, detected result: cinnamic transformation efficiency 35.69%, phenyl aldehyde selectivity is 32.93%.
Employing BuN-PMo of the present invention
12catalyzed oxidation vinylbenzene producing benzaldehyde technique, provides a kind of method that catalyzed oxidation prepares phenyl aldehyde, catalyst B uN-PMo
12in reaction system, cinnamic transformation efficiency can reach 99.7%, and phenyl aldehyde selectivity is 70.74%, catalyst B uN-PMo
12there is good catalytic performance, there is the advantage of reaction conditions gentleness.
The present invention is not limited to aforesaid embodiment.The present invention expands to any new feature of disclosing in this manual or any combination newly, and the step of the arbitrary new method disclosed or process or any combination newly.
Claims (5)
1. a cinnamic BuN-PMo
12catalyzed oxidation producing benzaldehyde technique, is characterized in that: in organic solvent system, take hydrogen peroxide as oxygenant, BuN-PMo
12for catalyzer, catalyzed oxidation vinylbenzene producing benzaldehyde, wherein said vinylbenzene, hydrogen peroxide, BuN-PMo
12the mol ratio of catalyzer is 1:4-6:0.05-0.08, and catalyzed reaction temperature is 60-75 DEG C, and reaction pressure is normal pressure.
2. cinnamic BuN-PMo as claimed in claim 1
12catalyzed oxidation producing benzaldehyde technique, is characterized in that: described organic solvent is acetonitrile.
3. cinnamic BuN-PMo as claimed in claim 2
12catalyzed oxidation producing benzaldehyde technique, is characterized in that: the volume ratio 1:12-15 of described vinylbenzene and acetonitrile.
4. the cinnamic BuN-PMo as described in claim 1 or 2 or 3
12catalyzed oxidation producing benzaldehyde technique, is characterized in that: described vinylbenzene, hydrogen peroxide, BuN-PMo
12the mol ratio of catalyzer is 1:5:0.07.
5. cinnamic BuN-PMo as claimed in claim 4
12catalyzed oxidation producing benzaldehyde technique, is characterized in that: described catalyzed reaction temperature is 70 DEG C.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111170838A (en) * | 2020-01-14 | 2020-05-19 | 中北大学 | Method and reaction device for preparing benzaldehyde by supergravity ozone oxidation of styrene |
Citations (3)
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---|---|---|---|---|
US5861286A (en) * | 1995-01-19 | 1999-01-19 | V. Mane Fils | Biochemical process for preparing aromatic substances |
CN101306986A (en) * | 2008-07-11 | 2008-11-19 | 湖南大学 | Process for preparing benzaldehyde by catalytic oxidation of phenylethene |
CN101711994A (en) * | 2009-11-19 | 2010-05-26 | 浙江大学 | Heteropolyacid material, preparation method and application thereof |
-
2014
- 2014-12-17 CN CN201410779823.9A patent/CN104496777A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5861286A (en) * | 1995-01-19 | 1999-01-19 | V. Mane Fils | Biochemical process for preparing aromatic substances |
CN101306986A (en) * | 2008-07-11 | 2008-11-19 | 湖南大学 | Process for preparing benzaldehyde by catalytic oxidation of phenylethene |
CN101711994A (en) * | 2009-11-19 | 2010-05-26 | 浙江大学 | Heteropolyacid material, preparation method and application thereof |
Non-Patent Citations (1)
Title |
---|
GERASIMOS S. ARMATAS ET AL: "Highly ordered mesoporous zirconia-polyoxometalate nanocomposite materials for catalytic oxidation of alkenes", 《JOURNAL OF MATERIALS CHEMISTRY》, vol. 21, 7 January 2011 (2011-01-07) * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111170838A (en) * | 2020-01-14 | 2020-05-19 | 中北大学 | Method and reaction device for preparing benzaldehyde by supergravity ozone oxidation of styrene |
CN111170838B (en) * | 2020-01-14 | 2023-04-14 | 中北大学 | Method and reaction device for preparing benzaldehyde by supergravity ozone oxidation of styrene |
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Application publication date: 20150408 |