CN104494255A - Mirror surface card and preparation method thereof - Google Patents

Mirror surface card and preparation method thereof Download PDF

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Publication number
CN104494255A
CN104494255A CN201410817237.9A CN201410817237A CN104494255A CN 104494255 A CN104494255 A CN 104494255A CN 201410817237 A CN201410817237 A CN 201410817237A CN 104494255 A CN104494255 A CN 104494255A
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Prior art keywords
layer
minute surface
surface card
oil
preparation
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Application number
CN201410817237.9A
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Chinese (zh)
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CN104494255B (en
Inventor
张泉
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Wuhan Tianyu Information Industry Co Ltd
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Wuhan Tianyu Information Industry Co Ltd
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Priority to CN201410817237.9A priority Critical patent/CN104494255B/en
Publication of CN104494255A publication Critical patent/CN104494255A/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/082—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/02—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04—Homopolymers or copolymers of ethene
    • C09D123/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/26—Polymeric coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/416—Reflective

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a mirror surface card and a preparation method thereof, relating to the technical field of preparation of transaction cards. The mirror surface card comprises a PVC base material layer, and a bottom oil layer, a gold plating layer and a protective layer which are sequentially laminated on the PVC base material layer, wherein the gold plating layer is a solid layer formed by metal aluminum; the bottom oil layer is a coating formed by base coat; and the protective layer is a coating formed by protective oil. The preparation method comprises the following steps: coating the PVC base material layer by the base coat; then electroplating the metal aluminum on the bottom oil layer so as to form a gold plating layer; coating the gold plating layer by the protective oil; and finally, preparing the mirror surface card by virtue of other card preparation processes. The prepared mirror surface card has a good mirror surface reflection effect, and the preparation process is simple.

Description

A kind of minute surface card and preparation method thereof
Technical field
The present invention relates to transactional cards preparing technical field, be specifically related to a kind of minute surface card and preparation method thereof.
Background technology
At present on the market so-called " minute surface card ", be all reach reflecting effect by adhering to radium-shine material, gold stamping paper tinsel is compressed on PVC base layer by the mode as by thermoprint, thus forms the card with reflective mirror effect.But utilize the minute surface card of radium-shine manufacture of materials to be the color reflective effect utilizing gold stamping paper tinsel, the roughly image irradiating object that can only be fuzzy, does not reach the reflecting effect of minute surface at all.
Summary of the invention
For the defect existed in prior art, the object of the present invention is to provide a kind of minute surface card and preparation method thereof, obtained minute surface jig is for good minute surface reflecting effect, and preparation process is simple.
For reaching above object; the technical scheme that the present invention takes is: a kind of minute surface card; comprise PVC base layer; and superimposed end oil reservoir, Gold plated Layer and protective layer on it successively; described Gold plated Layer is the solid layer that metallic aluminium is formed; end oil reservoir is the coating that end oil is formed, and protective layer is the coating that protection oil is formed.
On the basis of technique scheme, the end oil of oil reservoir of the described end by weight percentage, comprises component: thermoplastic acrylic 20 ~ 30%, ethylene-vinyl acetate copolymer 10 ~ 15%, ethyl ester 20 ~ 30%, cyclohexanone 10 ~ 20%, calcium carbonate 2 ~ 5%, plasticizer 1 ~ 2%, defoamer 0.1 ~ 0.2%.
On the basis of technique scheme; the protection oil of described protective layer by weight percentage; comprise component: thermoplastic acrylic 20 ~ 30%, vinyl acetate 10 ~ 15%, butyl ester 20 ~ 30%, cyclohexanone 10 ~ 20%, mute powder 2 ~ 5%, levelling agent 0.1 ~ 0.2%, defoamer 0.1 ~ 0.2%.
A preparation method for minute surface card, comprises step:
S1. on PVC base layer, be coated with end oil, under 100 ~ 150 DEG C of high temperature, 100 ~ 130bar condition of high voltage, use laminating apparatus to coordinate mirror steel plate to carry out lamination treatment, make its roughness reach less than 0.025 μm, form end oil reservoir;
S2. adopt vacuum plater, make metallic aluminium melting under vacuum, surface that evaporation, cooling are attached to end oil reservoir, form Gold plated Layer;
S3. at Gold plated Layer surface coating protection oil, after the drying of infra-red drying equipment, protective layer is formed;
S4. on the protection layer ink printing, mount film, lamination, die-cut, obtain minute surface card.
On the basis of technique scheme, oil of the described end by weight percentage, comprises component: thermoplastic acrylic 20 ~ 30%, ethylene-vinyl acetate copolymer 10 ~ 15%, ethyl ester 20 ~ 30%, cyclohexanone 10 ~ 20%, calcium carbonate 2 ~ 5%, plasticizer 1 ~ 2%, defoamer 0.1 ~ 0.2%.
On the basis of technique scheme; described protection oil by weight percentage; comprise component: thermoplastic acrylic 20 ~ 30%, vinyl acetate 10 ~ 15%, butyl ester 20 ~ 30%, cyclohexanone 10 ~ 20%, mute powder 2 ~ 5%, levelling agent 0.1 ~ 0.2%, defoamer 0.1 ~ 0.2%.
Beneficial effect of the present invention is: invention mirror card is different from the minute surface card adopting radium-shine material as specular layer, adopt vacuum plater, in common this specular material of PVC base layer electroplating surface metal aluminium, make metallic aluminium formed reflecting effect the same with mirror specular layer, clearly can irradiate the image of object.And by being coated with the oily interlayer attachment improved between them in the end between PVC base layer and Gold plated Layer; and by carrying out the mirror effect of protective glass surface layer at Gold plated Layer surface coating protection oil; and can direct printed patterns on the protection layer; adopt end oil and protection oil coating respectively; under the prerequisite not changing PVC base layer performance; make the card obtained have reflective mirror effect, preparation process is simple, and strengthens visual effect and the utility function of card.
Accompanying drawing explanation
Fig. 1 is the structural representation of invention mirror card.
Reference numeral:
1-PVC substrate layer, oil reservoir at the bottom of 2-, 3-Gold plated Layer, 4-protective layer.
Detailed description of the invention
Below in conjunction with drawings and Examples, the present invention is described in further detail.
As shown in Figure 1, a kind of minute surface card, comprises PVC base layer 1; and superimposed end oil reservoir 2, Gold plated Layer 3 and protective layer 4 on it successively; the solid layer that Gold plated Layer 3 is formed for metallic aluminium, end oil reservoir 2 is the coating that end oil XBD-Q is formed, and protective layer 4 is the coating that the oily XBD-Z of protection is formed.
The Gold plated Layer 3 formed due to PVC base layer 1 and plated metal can not directly adhere to each other, and therefore must be coated with one deck coating between PVC base layer 1 and Gold plated Layer 3, to increase the adhesive force between them.The end oil XBD-Q of end oil reservoir 2 by weight percentage, comprises following component: 20 ~ 30% thermoplastic acrylics, for strengthening the adhesive force with PVC base layer 1 and Gold plated Layer 3; 10 ~ 15% ethylene-vinyl acetate copolymers (EVA), for strengthening the bonding force with electrodeposited coating; 20 ~ 30% ethyl esters, for dissolving resin, adjustment viscosity and aridity; 10 ~ 20% cyclohexanone, for dissolving resin, adjustment viscosity and aridity; 2 ~ 5% calcium carbonate, for improving the surface roughness of end oil reservoir 2; 1 ~ 2% plasticizer, for adjusting the pliability of end oil reservoir 2; 0.1 ~ 0.2% defoamer, for solving printing adaptability.Oil XBD-Q can improve the surface features of PVC base layer 1 at the end, after end oil XBD-Q film forming, resinous principle is wherein good to the adhesive force of PVC, and directly can carry out plated metal above, and end oil XBD-Q is mainly used in the interlayer improved between Gold plated Layer 3 and PVC base layer 1 and adheres to.
Because the surface of Gold plated Layer 3 is extremely fragile; and easily scratch; destroy the reflecting effect of specular layer; and in order to make bank card; need to print relevant word, pattern on card face; but common offset printing or silk-screen printing cannot be adopted in Gold plated Layer 3, in Gold plated Layer 3, therefore increase protective layer 4 be very important.Protect oily XBD-Z, by weight percentage, comprise following component: 20 ~ 30% thermoplastic acrylics, for strengthening the adhesive force with Gold plated Layer 3; 10 ~ 15% vinyl acetates, for strengthening adhesive force to humour and recoatability; 20 ~ 30% butyl esters, for dissolving resin, adjustment viscosity and aridity; 10 ~ 20% cyclohexanone, for dissolving resin, adjustment viscosity and aridity; 2 ~ 5% mute powder, for improving the absorbency on Gold plated Layer 3 surface; 0.1 ~ 0.2% levelling agent, for solving printing adaptability; 0.1 ~ 0.2% defoamer, for solving printing adaptability.The protective layer 4 protecting oily XBD-Z to be formed, while the mirror effect of protection Gold plated Layer 3, increases the molecular tension of Gold plated Layer 3, thus improves its surface-active, increase ink adhesion, can in the Gold plated Layer 3 of coating protection oil 4 direct printed patterns.
A preparation method for minute surface card, comprises the following steps:
S1. on PVC base layer 1, be coated with end oil XBD-Q, under 100 ~ 150 DEG C of high temperature, 100 ~ 130bar condition of high voltage, use laminating apparatus to coordinate mirror steel plate to carry out lamination treatment, make its roughness reach less than 0.025 μm, reach the roughness that later stage minute surface attachment requires, form end oil reservoir 2.
S2. adopt vacuum plater, make metallic aluminium melting under vacuum, surface that evaporation, cooling are attached to end oil reservoir 2, form Gold plated Layer 3, Gold plated Layer 3 is the specular layer that reflecting effect is good.
S3. at the oily XBD-Z of Gold plated Layer 3 surface coating protection, after the drying of infra-red drying equipment, protective layer 4 is formed.
S4. band matcoveredn 4 the printing of Gold plated Layer 3 curing ink, mount film, lamination, die-cut, obtain minute surface card, additionally by different technique, can produce with the dissimilar card of the abnormal shape card, chip card, magnetic stripe card etc. of mirror effect.
The present invention is not limited to above-mentioned embodiment, and for those skilled in the art, under the premise without departing from the principles of the invention, can also make some improvements and modifications, these improvements and modifications are also considered as within protection scope of the present invention.The content be not described in detail in this description belongs to the known prior art of professional and technical personnel in the field.

Claims (6)

1. a minute surface card; it is characterized in that: comprise PVC base layer (1); and superimposed end oil reservoir (2), Gold plated Layer (3) and protective layer (4) on it successively; the solid layer that described Gold plated Layer (3) is formed for metallic aluminium; the coating that end oil reservoir (2) is formed for end oil, protective layer (4) is the coating that protection oil is formed.
2. minute surface card as claimed in claim 1, it is characterized in that, the end oil at oil reservoir of the described end (2) by weight percentage, comprises component: thermoplastic acrylic 20 ~ 30%, ethylene-vinyl acetate copolymer 10 ~ 15%, ethyl ester 20 ~ 30%, cyclohexanone 10 ~ 20%, calcium carbonate 2 ~ 5%, plasticizer 1 ~ 2%, defoamer 0.1 ~ 0.2%.
3. minute surface card as claimed in claim 1; it is characterized in that; the protection oil of described protective layer (4) by weight percentage; comprise component: thermoplastic acrylic 20 ~ 30%, vinyl acetate 10 ~ 15%, butyl ester 20 ~ 30%, cyclohexanone 10 ~ 20%, mute powder 2 ~ 5%, levelling agent 0.1 ~ 0.2%, defoamer 0.1 ~ 0.2%.
4., based on a preparation method for minute surface card described in claim 1, it is characterized in that, comprise step:
S1. at PVC base layer (1) upper coating end oil, under 100 ~ 150 DEG C of high temperature, 100 ~ 130bar condition of high voltage, use laminating apparatus to coordinate mirror steel plate to carry out lamination treatment, make its roughness reach less than 0.025 μm, form end oil reservoir (2);
S2. adopt vacuum plater, make metallic aluminium melting under vacuum, surface that evaporation, cooling are attached to end oil reservoir (2), form Gold plated Layer (3);
S3. at Gold plated Layer (3) surface coating protection oil, after the drying of infra-red drying equipment, protective layer (4) is formed;
S4. in protective layer (4) curing ink printing, mount film, lamination, die-cut, obtain minute surface card.
5. the preparation method of minute surface card as claimed in claim 4, it is characterized in that, oil of the described end by weight percentage, comprises component: thermoplastic acrylic 20 ~ 30%, ethylene-vinyl acetate copolymer 10 ~ 15%, ethyl ester 20 ~ 30%, cyclohexanone 10 ~ 20%, calcium carbonate 2 ~ 5%, plasticizer 1 ~ 2%, defoamer 0.1 ~ 0.2%.
6. the preparation method of minute surface card as claimed in claim 4; it is characterized in that; described protection oil by weight percentage; comprise component: thermoplastic acrylic 20 ~ 30%, vinyl acetate 10 ~ 15%, butyl ester 20 ~ 30%, cyclohexanone 10 ~ 20%, mute powder 2 ~ 5%, levelling agent 0.1 ~ 0.2%, defoamer 0.1 ~ 0.2%.
CN201410817237.9A 2014-12-24 2014-12-24 A kind of minute surface card and preparation method thereof Active CN104494255B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104708928A (en) * 2015-04-09 2015-06-17 鸿博股份有限公司 Magnetic card and printing method thereof
CN109094230A (en) * 2018-07-25 2018-12-28 广州美祺智能印刷有限公司 A kind of color printing method not fallen the effect of ink
CN111113193A (en) * 2019-12-25 2020-05-08 东莞市晶博光电有限公司 Glass processing technology without paper folding and sheet separation

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07137459A (en) * 1993-11-16 1995-05-30 Tokin Corp Reversible thermal recording material
CN2524919Y (en) * 2002-02-09 2002-12-11 福州佳通第一塑料有限公司 PVC aluminium coating film
CN1432977A (en) * 2002-01-15 2003-07-30 博铼科技股份有限公司 Card forming method capable of producing anti-fake mark

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07137459A (en) * 1993-11-16 1995-05-30 Tokin Corp Reversible thermal recording material
CN1432977A (en) * 2002-01-15 2003-07-30 博铼科技股份有限公司 Card forming method capable of producing anti-fake mark
CN2524919Y (en) * 2002-02-09 2002-12-11 福州佳通第一塑料有限公司 PVC aluminium coating film

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104708928A (en) * 2015-04-09 2015-06-17 鸿博股份有限公司 Magnetic card and printing method thereof
CN104708928B (en) * 2015-04-09 2017-12-15 鸿博股份有限公司 A kind of magnetic card and its printing process
CN109094230A (en) * 2018-07-25 2018-12-28 广州美祺智能印刷有限公司 A kind of color printing method not fallen the effect of ink
CN111113193A (en) * 2019-12-25 2020-05-08 东莞市晶博光电有限公司 Glass processing technology without paper folding and sheet separation
CN111113193B (en) * 2019-12-25 2021-05-14 东莞市晶博光电股份有限公司 Glass processing technology without paper folding and sheet separation

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