CN104485403A - Curved waveguide quantum dot super-luminescent diode with gradually-varied curvature and manufacturing method thereof - Google Patents

Curved waveguide quantum dot super-luminescent diode with gradually-varied curvature and manufacturing method thereof Download PDF

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Publication number
CN104485403A
CN104485403A CN201410854195.6A CN201410854195A CN104485403A CN 104485403 A CN104485403 A CN 104485403A CN 201410854195 A CN201410854195 A CN 201410854195A CN 104485403 A CN104485403 A CN 104485403A
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quantum dot
sweep
light emitting
radiation light
substrate
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王飞飞
吴艳华
胡发杰
金鹏
王占国
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Institute of Semiconductors of CAS
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/48Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
    • H01L33/58Optical field-shaping elements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/005Processes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2933/00Details relating to devices covered by the group H01L33/00 but not provided for in its subgroups
    • H01L2933/0008Processes

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Power Engineering (AREA)
  • Led Devices (AREA)

Abstract

The invention provides a curved waveguide quantum dot super-luminescent diode with the gradually-varied curvature and a manufacturing method of the curved waveguide quantum dot super-luminescent diode. The super-luminescent diode comprises a substrate, a quantum dot gain medium on the substrate and a waveguide structure. The waveguide structure comprises a straight segment part and a curved part, wherein the curve of the curved part is a part of a polynomial, a part of a hyperbola and a part of an ellipse. The curving loss of the super-luminescent diode is increased along with the decrease of the curvature radius so that the loss can be reduced. Besides, under the condition that the length of the curved part or the final deviation angle is not changed, output power can be increased, and similar spectrum output still can be kept.

Description

Curved waveguide quantum dot super radiation light emitting tube of curvature gradual change and preparation method thereof
Technical field
The invention belongs to semi-conductor electronic device field, quantum dot super radiation light emitting tube particularly relating to a kind of low-loss power and preparation method thereof.
Background technology
Super radiation light emitting tube is fibre optic gyroscope, light source conventional in optical coherent chromatographic imaging (being called for short OCT) system, because super radiation light emitting tube has wider spectrum, therefore optical coherence tomography system is made to have higher longitudinal frame, but in actual applications, we often need larger power output to improve the dynamic range of Optical coherence tomography.One section of circular arc that radius of curvature that what the sweep of traditional curved waveguide super radiation light emitting tube adopted is is constant, thus make bending loss coefficient in optical transmission process constant, cause the loss of can not ignore, if and the form of sweep is changed into radius of curvature change waveguiding structure, the bending loss index variation in different places can be made like this, the place of the connection of straight bars sections and sweep not only can be made to link together, and can bending loss be reduced, increase optical output power.
Summary of the invention
(1) technical problem that will solve
The object of the invention is to quantum dot super radiation light emitting tube proposing low-loss power and preparation method thereof, make it constant in sweep length, the angle of final light direction and light output end normal direction realizes lower loss when constant, thus in Optical Coherence Tomography Imaging Technology, improve test dynamic range.
(2) technical scheme
For solving the problems of the technologies described above, the present invention proposes a kind of curved waveguide quantum dot super radiation light emitting tube, comprising: substrate; Be positioned at the quantum dot gain medium on substrate; Waveguiding structure, comprises straight part and sweep, and the curve of sweep is an oval part.
According to a kind of embodiment of the present invention, the formula of sweep is
According to a kind of embodiment of the present invention, the radius of curvature of described sweep is gradual change.
According to a kind of embodiment of the present invention, the final deflecting angle of described waveguiding structure and the angle of exiting surface normal are 7 °, and the length of sweep is 1mm.
According to a kind of embodiment of the present invention, its epitaxial structure is followed successively by substrate, resilient coating, lower coating layer, active area, upper coating layer, ohmic contact layer.
According to a kind of embodiment of the present invention, described active area is indium arsenide/gallium arsenide quantum node structure.
The present invention also proposes a kind of preparation method of curved waveguide quantum dot super radiation light emitting tube, comprising: step S1: on epitaxial wafer, apply one deck photoresist; Step S2: adopt photoetching method to etch waveguiding structure, comprise straight part and sweep, the formula of the curve of sweep is step S3: adopt the method for corrosion by waveguiding structure Graphic transitions on epitaxial wafer; Step S4: on-chip photoresist is removed; Step S5: grow layer of silicon dioxide insulating barrier on substrate; Step S6: again apply photoresist on substrate; Step S7: output electrical pumping window in curved waveguide structure; Step S8: remove photoresist; Step S9: at the back side of substrate and front growing metal electrode; Step S10: alloying of having annealed.
The present invention proposes a kind of curved waveguide quantum dot super radiation light emitting tube on the other hand, comprising: substrate;
Be positioned at the quantum dot gain medium on substrate; Waveguiding structure, comprises straight part and sweep, and the curve of sweep is a hyp part.
According to a kind of embodiment of the present invention, the formula of sweep is
According to a kind of embodiment of the present invention, the radius of curvature of sweep is gradual change.
According to a kind of embodiment of the present invention, the final deflecting angle of described waveguiding structure and the angle of exiting surface normal are 7 °, and the length of sweep is 1mm.
According to a kind of embodiment of the present invention, its epitaxial structure is followed successively by substrate, resilient coating, lower coating layer, active area, upper coating layer, ohmic contact layer.
According to a kind of embodiment of the present invention, described active area is indium arsenide/gallium arsenide quantum node structure.
The present invention also proposes a kind of manufacture method of curved waveguide quantum dot super radiation light emitting tube, comprising: step S1: on epitaxial wafer, apply one deck photoresist; Step S2: adopt photoetching method to etch curved waveguide structure, comprise straight part and sweep, the formula of the curve of sweep is step S3: adopt the method for corrosion by waveguiding structure Graphic transitions on epitaxial wafer; Step S4: on-chip photoresist is removed; Step S5: grow layer of silicon dioxide insulating barrier on substrate; Step S6: again apply photoresist on substrate; Step S7: output electrical pumping window on waveguiding structure; Step S8: remove photoresist; Step S9: at the back side of substrate and front growing metal electrode; Step S10: alloying of having annealed.
The present invention also proposes a kind of curved waveguide quantum dot super radiation light emitting tube, comprising: substrate; Be positioned at the quantum dot gain medium on substrate; Curved waveguide structure, comprises straight part and sweep, and the curve of sweep is a polynomial part.
According to a kind of embodiment of the present invention, the formula of sweep is y=az 2.2+ bz 2.1.
According to a kind of embodiment of the present invention, the radius of curvature of sweep is gradual change.
According to a kind of embodiment of the present invention, the final deflecting angle of described waveguiding structure and the angle of exiting surface normal are 7 °, and the length of sweep is 1mm.
According to a kind of embodiment of the present invention, its epitaxial structure is followed successively by substrate, resilient coating, lower coating layer, active area, upper coating layer, ohmic contact layer.
According to a kind of embodiment of the present invention, described active area is indium arsenide/gallium arsenide quantum node structure.
The present invention also proposes a kind of manufacture method of curved waveguide quantum dot super radiation light emitting tube, comprising: step S1: on epitaxial wafer, apply one deck photoresist; Step S2: adopt photoetching method to etch curved waveguide structure, comprise straight part and sweep, the formula of the curve of sweep is y=az 2.2+ bz 2.1; Step S3: adopt the method for corrosion by described waveguiding structure Graphic transitions on epitaxial wafer; Step S4: on-chip photoresist is removed; Step S5: grow layer of silicon dioxide insulating barrier on substrate; Step S6: again apply photoresist on substrate; Step S7: output electrical pumping window on described waveguiding structure; Step S8: remove photoresist; Step S9: at the back side of substrate and front growing metal electrode; Step S10: alloying of having annealed.
(3) beneficial effect
The low-loss power quantum dot super radiation light emitting tube that the present invention proposes can in sweep length, final deviation angle realizes large power stage when constant, and the superradiation light-emitting tube power being the circular arc of 8.2mm with traditional employing radius of curvature increases to some extent;
The method of the curved waveguide quantum dot super radiation light emitting tube of preparation radius of curvature provided by the invention gradual change is simple, is easy to realize.
Accompanying drawing explanation
Fig. 1 is the plane graph that sweep adopts the quantum dot super radiation light emitting tube of oval radius of curvature tapered waveguide;
Fig. 2 is the plane graph that sweep adopts the quantum dot super radiation light emitting tube of hyp radius of curvature tapered waveguide;
Fig. 3 is the plane graph that sweep adopts the quantum dot super radiation light emitting tube of polynomial radius of curvature tapered waveguide;
Fig. 4 is the structure diagram of epitaxial wafer;
Fig. 5 is preparation technology's flow chart of superradiation light-emitting tube device;
Fig. 6 is that sweep adopts radius of curvature to be the circular arc of 8.2mm, and sweep length is the P-I simulation curve of the curved waveguide quantum dot super radiation light emitting tube of 1mm;
Fig. 7 is that sweep adopts the P-I simulation curve of the curved waveguide quantum dot super radiation light emitting tube of (e=17.607, f=12,0≤z≤1mm);
Fig. 8 is that sweep adopts the P-I simulation curve of the curved waveguide quantum dot super radiation light emitting tube of (c=2, d=4,0≤z≤1mm);
Fig. 9 is that sweep adopts y=az 2.2+ bz 2.1the P-I simulation curve of the curved waveguide quantum dot super radiation light emitting tube of (a=-0.159, b=0.225,0≤z≤1mm).
Embodiment
The quantum dot super radiation light emitting tube of the curved waveguide of the curvature gradual change that the present invention proposes, comprise: substrate and the quantum dot gain medium be positioned on substrate, and waveguiding structure, waveguiding structure comprises straight part and sweep, the curve of sweep can be an oval part, a hyp part and a polynomial part, formula is respectively y = e - e 1 - z 2 f 2 , y = c 1 + z 2 d 2 - c , Y=az 2.2+ bz 2.1, a, b, c, d, e, f are parameter, and y, z are two coordinates of plane coordinate system.
The preparation method of the curved waveguide quantum dot super radiation light emitting tube that the present invention also proposes, comprising:
Step S1: apply one deck photoresist on epitaxial wafer;
Step S2: adopt photoetching method to etch curved waveguide structure, it comprises straight part and sweep, and the curvature of sweep is gradual change;
Step S3: adopt the method for corrosion by waveguiding structure Graphic transitions on epitaxial wafer;
Step S4: on-chip photoresist is removed;
Step S5: grow layer of silicon dioxide insulating barrier on substrate;
Step S6: again apply photoresist on substrate;
Step S7: output electrical pumping window on bent waveguiding structure;
Step S8: remove photoresist;
Step S9: at the back side of substrate and front growing metal electrode;
Step S10: alloying of having annealed.
For making the object, technical solutions and advantages of the present invention clearly understand, below in conjunction with specific embodiment, and with reference to accompanying drawing, the present invention is described in further detail.
Fig. 1 is the plane graph that sweep adopts the quantum dot super radiation light emitting tube of oval radius of curvature tapered waveguide.As shown in Figure 1, waveguiding structure comprises straight part and sweep, and sweep adopts oval e, f are parameter, and y, z are two coordinates of plane coordinate system, and 0≤z≤1mm.The curvature of the waveguiding structure of sweep is gradual change.Preferably, the final deflecting angle of waveguide and the angle of exiting surface normal are 7 °, and the length of sweep is 1mm.
Fig. 2 is the plane graph that sweep adopts the quantum dot super radiation light emitting tube of hyp radius of curvature tapered waveguide.As shown in Figure 2, sweep adopts hyperbola c, d are parameter, and y, z are two coordinates of plane coordinate system, and 0≤z≤1mm.The radius of curvature of sweep is gradual change.Preferably, the final deflecting angle of waveguide and the angle of exiting surface normal are 7 °, and the length of sweep is 1mm.
Fig. 3 is the plane graph that sweep adopts the quantum dot super radiation light emitting tube of polynomial radius of curvature tapered waveguide.As shown in Figure 3, sweep adopts multinomial y=az 2.2+ bz 2.1, a, b are parameters, and y, z are two coordinates of plane coordinate system, 0≤z≤1mm.The radius of curvature of curved waveguide is gradual change, and the radius of curvature of sweep changes from just infinite.Preferably, the final deflecting angle of waveguide and the angle of exiting surface normal are 7 °, and the length of sweep is 1mm.
Refer to Fig. 4, the epitaxial slice structure of the curved waveguide quantum dot super radiation light emitting tube of radius of curvature gradual change is as follows: use MBE method to deposit GaAs resilient coating 3 successively on the substrate 2, n-AlGaAs lower limit layer 4, InAs/GaAs quantum dot active region 5, p-AlGaAs upper limiting layer 6, p+-GaAs ohmic contact layer 7, silicon dioxide insulating layer 8.
Refer to Fig. 5, the fabrication processing of the curved waveguide quantum dot super radiation light emitting tube of radius of curvature gradual change, comprises the following steps:
First, the epitaxial wafer cleaned up applies photoresist, then adopt common photoetching process to engrave curved waveguide structure at photoresist.
Then, wet etching method is utilized to corrode upper limiting layer 7 and ohmic contact layer 8, by the Graphic transitions on photoresist on epitaxial wafer.
Then, adopt the method for PECVD above the groove etched and the silicon dioxide insulating layer 8 of sidewall deposition thickness 400nm.
Then, adopt photoetching and wet corrosion technique to open electrical pumping window on ohmic contact layer 7, and adopt the method for electron beam evaporation to prepare titanium electrode 9.
Finally, to look unfamiliar after substrate thinning polishing long gold germanium nickel backplate 1 at n.
Wherein the active layer of epitaxial wafer adopts indium arsenide/Gallium indium arsenide/GaAs (InAs/In0.15Ga0.85As/GaAs) quantum-dot structure, wherein InAs Quantum Dots Growth is on GaAs layer, In0.15Ga0.85As stress relieve layer is covered on InAs quantum dot, and active layer covers the InAs quantum-dot structure containing 5 ~ 10 cycles.
Fig. 7 is that sweep adopts the P-I simulation curve of the curved waveguide quantum dot super radiation light emitting tube of (e=17.607, f=12,0≤z≤1mm); Fig. 8 is that sweep adopts the P-I simulation curve of the curved waveguide quantum dot super radiation light emitting tube of (c=2, d=4,0≤z≤1mm); Fig. 9 is that sweep adopts y=az 2.2+ bz 2.1the P-I simulation curve of the curved waveguide quantum dot super radiation light emitting tube of (a=-0.159, b=0.225,0≤z≤1mm).
As can be seen from Fig. 7 ~ 9, in curved waveguide quantum dot super radiation light emitting tube, if adopt the structure of curvature gradual change to curved waveguide, effectively can increase optical output power, adopt oval, hyperbola and polynomial construction in curved waveguide structure, the luminous power exported from curved waveguide end increases 7%, 11% and 20% (being the super radiation light emitting tube of the constant arc structure of curvature relative to curved waveguide end) respectively.
Above-described specific embodiment; object of the present invention, technical scheme and beneficial effect are further described; be understood that; the foregoing is only specific embodiments of the invention; be not limited to the present invention; within the spirit and principles in the present invention all, any amendment made, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.

Claims (21)

1. a curved waveguide quantum dot super radiation light emitting tube, comprising:
Substrate;
Be positioned at the quantum dot gain medium on substrate;
Waveguiding structure, comprises straight part and sweep, and the curve of sweep is an oval part.
2. quantum dot super radiation light emitting tube according to claim 1, is characterized in that, the formula of sweep is y = e - e 1 - z 2 f 2 .
3. quantum dot super radiation light emitting tube according to claim 2, is characterized in that, the radius of curvature of described sweep is gradual change.
4. quantum dot super radiation light emitting tube according to claim 3, is characterized in that, the final deflecting angle of described waveguiding structure and the angle of exiting surface normal are 7 °, and the length of sweep is 1mm.
5. quantum dot super radiation light emitting tube according to claim 1, is characterized in that, its epitaxial structure is followed successively by substrate, resilient coating, lower coating layer, active area, upper coating layer, ohmic contact layer.
6. quantum dot super radiation light emitting tube according to claim 5, is characterized in that, described active area is indium arsenide/gallium arsenide quantum node structure.
7. a preparation method for curved waveguide quantum dot super radiation light emitting tube, comprising:
Step S1: apply one deck photoresist on epitaxial wafer;
Step S2: adopt photoetching method to etch waveguiding structure, comprise straight part and sweep, the formula of the curve of sweep is y = e - e 1 - z 2 f 2 ;
Step S3: adopt the method for corrosion by waveguiding structure Graphic transitions on epitaxial wafer;
Step S4: on-chip photoresist is removed;
Step S5: grow layer of silicon dioxide insulating barrier on substrate;
Step S6: again apply photoresist on substrate;
Step S7: output electrical pumping window in curved waveguide structure;
Step S8: remove photoresist;
Step S9: at the back side of substrate and front growing metal electrode;
Step S10: alloying of having annealed.
8. a curved waveguide quantum dot super radiation light emitting tube, comprising:
Substrate;
Be positioned at the quantum dot gain medium on substrate;
Waveguiding structure, comprises straight part and sweep, and the curve of sweep is a hyp part.
9. quantum dot super radiation light emitting tube according to claim 8, is characterized in that, the formula of sweep is y = c 1 + z 2 d 2 - c .
10. quantum dot super radiation light emitting tube according to claim 9, is characterized in that, the radius of curvature of sweep is gradual change.
11. quantum dot super radiation light emitting tubes according to claim 10, is characterized in that, the final deflecting angle of described waveguiding structure and the angle of exiting surface normal are 7 °, and the length of sweep is 1mm.
12. quantum dot super radiation light emitting tubes according to claim 8, is characterized in that, its epitaxial structure is followed successively by substrate, resilient coating, lower coating layer, active area, upper coating layer, ohmic contact layer.
13. quantum dot super radiation light emitting tubes according to claim 12, is characterized in that, described active area is indium arsenide/gallium arsenide quantum node structure.
The manufacture method of 14. 1 kinds of curved waveguide quantum dot super radiation light emitting tubes, comprising:
Step S1: apply one deck photoresist on epitaxial wafer;
Step S2: adopt photoetching method to etch curved waveguide structure, comprise straight part and sweep, the formula of the curve of sweep is y = c 1 + z 2 d 2 - c ;
Step S3: adopt the method for corrosion by waveguiding structure Graphic transitions on epitaxial wafer;
Step S4: on-chip photoresist is removed;
Step S5: grow layer of silicon dioxide insulating barrier on substrate;
Step S6: again apply photoresist on substrate;
Step S7: output electrical pumping window on waveguiding structure;
Step S8: remove photoresist;
Step S9: at the back side of substrate and front growing metal electrode;
Step S10: alloying of having annealed.
15. 1 kinds of curved waveguide quantum dot super radiation light emitting tubes, comprising:
Substrate;
Be positioned at the quantum dot gain medium on substrate;
Curved waveguide structure, comprises straight part and sweep, and the curve of sweep is a polynomial part.
16. quantum dot super radiation light emitting tubes according to claim 15, is characterized in that, the formula of sweep is y=az 2.2+ bz 2.1.
17. quantum dot super radiation light emitting tubes according to claim 16, is characterized in that, the radius of curvature of sweep is gradual change.
18. quantum dot super radiation light emitting tubes according to claim 17, is characterized in that, the final deflecting angle of described waveguiding structure and the angle of exiting surface normal are 7 °, and the length of sweep is 1mm.
19. quantum dot super radiation light emitting tubes according to claim 15, is characterized in that, its epitaxial structure is followed successively by substrate, resilient coating, lower coating layer, active area, upper coating layer, ohmic contact layer.
20. quantum dot super radiation light emitting tubes according to claim 19, is characterized in that, described active area is indium arsenide/gallium arsenide quantum node structure.
The manufacture method of 21. 1 kinds of curved waveguide quantum dot super radiation light emitting tubes, comprising:
Step S1: apply one deck photoresist on epitaxial wafer;
Step S2: adopt photoetching method to etch curved waveguide structure, comprise straight part and sweep, the formula of the curve of sweep is y=az 2.2+ bz 2.1;
Step S3: adopt the method for corrosion by described waveguiding structure Graphic transitions on epitaxial wafer;
Step S4: on-chip photoresist is removed;
Step S5: grow layer of silicon dioxide insulating barrier on substrate;
Step S6: again apply photoresist on substrate;
Step S7: output electrical pumping window on described waveguiding structure;
Step S8: remove photoresist;
Step S9: at the back side of substrate and front growing metal electrode;
Step S10: alloying of having annealed.
CN201410854195.6A 2014-12-31 2014-12-31 Curved waveguide quantum dot super-luminescent diode with gradually-varied curvature and manufacturing method thereof Pending CN104485403A (en)

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Application publication date: 20150401