CN104479575A - Tempered glass film AB glue having anti-blue light function, and preparation method thereof - Google Patents

Tempered glass film AB glue having anti-blue light function, and preparation method thereof Download PDF

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Publication number
CN104479575A
CN104479575A CN201410612065.1A CN201410612065A CN104479575A CN 104479575 A CN104479575 A CN 104479575A CN 201410612065 A CN201410612065 A CN 201410612065A CN 104479575 A CN104479575 A CN 104479575A
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base material
blue light
glue
pet
coating
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CN104479575B (en
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陈克勇
朱文峰
杨忠芝
吴建海
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Dongguan Nali Optical Material Co Ltd
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Dongguan Nali Optical Material Co Ltd
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Abstract

The invention discloses a tempered glass film AB glue having the anti-blue light function, and a preparation method thereof, wherein PET being subjected to an anti-blue light treatment is adopted as the base, and a high-cohesion adhesive is attached on the glass so as to effectively prevent scratches on the LCD screen. According to the present invention, the tempered glass film AB glue of the invention contains a PET polyester film substrate, an UV acrylic acid resin layer is introduced on the PET polyester film substrate, an adhesive layer is introduced on the UV acrylic acid resin layer, a release film is introduced on the adhesive layer, a silica gel layer is arranged under the PET polyester film substrate, and a PET stripping layer is arranged under the silica gel layer; and the tempered glass film AB glue of the present invention has high light transmittance, high gas discharge performance and good re-stripping property, wherein the total light transmittance achieves more than 92.5% so as to ensure the high definition of the LCD image.

Description

A kind of toughened glass film AB glue and preparation method with anti-blue light function
Technical field
The present invention relates to the sclerosis of a kind of protective membrane and adhesive coating, specifically, be in particular to a kind of toughened glass AB glue with anti-blue light function, belong to adhesive material technical field.
Background technology
Along with society electronic digital product gets more and more; the use of touch-screen is more and more universal; people find the loss of screen very large in routine use; in order to make display screen from the invasion of cut, greasy dirt or prevent the reasons such as reflective, user often selects to stick screen protecting film on a display screen.
The surface hardness of general plastic adhesive film is no more than about 3H, in use easy score protection film, cause changing screen protecting film replacement frequency high, and eyes watch screen attentively for a long time, part " blue light " is comprised in the light sent in screen, can not be absorbed by cornea or lens completely, through retina, retinal function may be caused low, cause visual fatigue, the symptom such as dry and astringent, be exposed to for a long time among this LED blue light light and likely the retina of people caused damage, macular degeneration odds increases to two times of mobile phone screen toughened glass screening glass, and due to it, to have resistance to marring good, the high-qualitys such as transparency is high and reliably performance and be subject to the favor of vast mobile phone manufacturing firm.
Toughened glass also has its shortcoming: seem thicker compared with other films, also affects the susceptibility of touch-screen simultaneously, and because toughened glass is hard also crisp, general performance is frangible.Although toughened glass intensity is stronger than simple glass, toughened glass has the possibility of self-destruction (oneself breaks), and simple glass does not exist the possibility of self-destruction.
Only toughened glass can not be attached together with screen, and does not possess anti-blue light function.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art; a kind of toughened glass film AB glue and the preparation method with anti-blue light function are provided; based on the PET through anti-blue light process; one side is silica gel; one side is that special double faced adhesive tape protected by the toughened glass of the tackiness agent of high cohesion; wherein silica gel (automatic vent) fits in mobile phone, and the tackiness agent of high cohesion fits in glass.Adopt coating process, protecting against shock process, high rigidity process is done on surface, can reach 5H, effectively prevents the scratch of LCD screen.
For achieving the above object, the present invention adopts following scheme:
There is a toughened glass film AB glue for anti-blue light function, include PET polyester film base material, introduce UV acrylate resin layer on PET polyester film base material, introduce adhering agent layer on UV acrylate resin layer, on adhering agent layer, introduce release film; PET polyester film base material have layer of silica gel, layer of silica gel have PET peel ply.
Wherein in some embodiments, described UV acrylate resin layer (anti-blue light UV glue) selects vinylformic acid photocuring system, and UV lamp energy is at 30 ~ 200mj/cm 2scope in.
Wherein in some embodiments, the tackiness agent viscosity 8000 ~ 20000cps of described adhering agent layer.
Wherein in some embodiments, described PET polyester film base material selects thickness to be 20 ~ 100 μ.
A kind of method preparing the toughened glass film AB glue with anti-blue light function, AB glue is that base material is coated with anti-blue light UV glue in front by PET material, obtain the PET base material of anti-blue light process, the tackiness agent of the high cohesion that release film is coated with, fitting with through anti-blue light process and the PET polyester film base material front that has been coated with silica gel in the tackiness agent glue face of high cohesion, makes the tackiness agent of high cohesion on release film transfer to the front of PET polyester film base material; Again by the PET polyester film base material reverse side coating organic silica gel through processing, and cover another layer of PET base material (PET peel ply) above; Thus obtain one there is anti-blue light function toughened glass film AB double faced adhesive tape;
It is characterized in that, comprise the following steps:
(1), PET polyester film base material selects thickness to be between 20 ~ 100 μ, and increase surface adhesion force through corona treatment, this film uses scraper type anilox roll be coated with anti-blue light UV glue, required thickness is 3 ~ 8 μ, obtains basic products;
Or micro gravure coating method is selected in anti-blue light UV glue coating, micro gravure coating method is use gravure roll, and nick roller line is several according to different thickness requirement, 50 ~ 140 THREADY DRILL nick rollers, gravure roller surface is carved with pattern or groove cave, and to provide special glue spread, gravure roll is arranged on bearing, part is immersed in supply disk, the axle rotated takes up coating, after a flexible steel scraper is quantitative, takes away coating fluid by reversing motion base material, realize thin uniform layer coating, obtain basic products;
(2) basic products, by step (1) obtained is through baking oven, and by complete for solution evaporation in UV glue, cross UV lamp, UV lamp energy is at 30 ~ 200mj/cm 2scope in, form UV acrylate resin layer, obtain the PET base material with anti-blue light process;
(3), by the release film of 50 ~ 100 μ, use blade coating, adopt comma scraper, the tackiness agent of coating high cohesion, thickness requirement 35 ~ 50 μ, through curing oven, makes release film be covered with adhering agent layer;
(4) the UV acrylate resin layer (anti-blue light UV solidifies face) of the PET base material through anti-blue light process, by step (2) obtained, is covered with the adhering agent layer of the high cohesion of release film;
(5), will do PET base material (the PET polyester film base material) reverse side of above process, use blade coating to adopt comma scraper coating organic silica gel, thickness requirement 35 ~ 50 μ, through curing oven, obtains layer of silica gel;
(6), in layer of silica gel 15 be covered with PET peel ply (50 μ PET base material) away from the one side of PET base material (PET polyester film base material), obtain that there is anti-blue light function toughened glass film AB double faced adhesive tape.
Wherein in some embodiments, the comma scraper of described step (3) adopts intensity, the edge of a knife made by the good round steel of hardness; During frictioning, this scraper maintains static dynamic; The intensity of this scraper, hardness is high, and cutting edge straightness error is little, and pneumatic and micro-adjusting mechanism can be adopted to carry out regulation and control doctor position, coating weight control and frictioning precision high, it is also very convenient to use; Because its frictioning is very even, so be applicable to the accurate frictioning of smooth roll gluing coating.
Wherein in some embodiments, the adhering agent layer of described step (3) selects the tackiness agent viscosity 8000 ~ 20000cps of high cohesion, use the tackiness agent of high cohesion to be conducive to and peel off absorption very well, and prevent from peeling off fragment sputtering when bursting and hurt people.
Wherein in some embodiments, the layer of silica gel of described step (5) adopts silica column, has low sticky automatic absorbing ability, exhaust performance is high, effectively prevents bubble from producing, and coating thickness requires between 35 ~ 50 μ, can effectively get certain shock absorption, there is certain shock resistance effect.
Further, wherein in some embodiments, its step is as follows:
Thickness is selected to be 50 μ PET base material, micro gravure coating method is selected in coating, 140 THREADY DRILL nick rollers, after a flexible steel scraper is quantitative, coating fluid is taken away by reversing motion base material, through baking oven by solvent evaporates, oven temperature is between 80 ~ 100 DEG C, and being coated with anti-blue light UV glue thickness in base material front is 5 μ;
Select thickness to be 100 μ release films, adopt comma to scrape, the tackiness agent of coating high cohesion, thickness is 40 μ; With overlaying on the tackiness agent glue face of high cohesion through anti-blue light process UV face after oven for drying;
To overlay on the PET base material back side on release film, adopt comma to scrape and be coated with machine silicone resin, thickness is 50 μ, covers another PET base material, and thickness is 50 μ;
Obtain one and there is anti-blue light function toughened glass film AB double faced adhesive tape, the tackiness agent of this AB glue high cohesion and toughened glass are fitted, silica gel face and screen glass are fitted, in 5s, gas is drained on 5 inch screen, transmittance is 92.5%, and anti-blue light rate reaches 45%.
The present invention has high light transmittance, and full light transmittance reaches more than 92.5%, ensure that the high definition of liquid crystal panel; Adopt silica column, have low sticky automatic absorbing ability, exhaust performance is high, effectively prevents bubble from producing; There is good releasable, do not come unstuck, effectively prevent cull to be retained in LCD screen surface.
Accompanying drawing explanation
Fig. 1 is the structural representation of the embodiment of the present invention.
Description of reference numerals:
PET polyester film base material 11, UV acrylate resin layer 12, adhering agent layer 13, release film 14, layer of silica gel 15, PET peel ply 16.
Embodiment
For feature of the present invention, technique means and the specific purposes reached, function can be understood further, resolve the advantages and spirit of the present invention, by the present invention is further elaborated by the following examples.
The raw material that the embodiment of the present invention uses is as follows:
PET polyester film base material (PET base material): purchased from Dongguan City Tian Yi Chemical Co., Ltd.;
Anti-blue light UV glue (UV photo-cured coating): anti-blue light glue, purchased from Changxing (Guangzhou) precise dipping company limited;
Tackiness agent (acrylic): select Fanyu, Guangzhou to moisten hundred million chemical industry company limiteds, trade mark AS ~ 1501B;
Silicone resin (silica gel): purchased from organosilicon international trade (Shanghai) Co., Ltd. of SHIN-ETSU HANTOTAI, trade mark KR5230.
The present invention needs to provide one to have anti-blue light function toughened glass film AB double faced adhesive tape, and AB glue is that base material is coated with anti-blue light UV glue in front by PET material.Obtain the PET base material of anti-blue light process; The tackiness agent of the high cohesion that release film is coated with, fitting with through anti-blue light process and the PET base material front that has been coated with silica gel in the tackiness agent glue face of high cohesion, makes the tackiness agent of high cohesion on release film transfer to the front of PET base material.Again by the PET base material reverse side coating organic silica gel through processing, and cover one deck PET base material above.Thus obtain one there is anti-blue light function toughened glass film AB double faced adhesive tape.
Toughened glass film AB double faced adhesive tape of the present invention, based on PET polyester film base material 11, one side is adhering agent layer 13 (acrylic); another side is layer of silica gel 15; be that special double faced adhesive tape protected by toughened glass, wherein layer of silica gel 15 fits in mobile phone, and adhering agent layer 13 fits in glass.Be widely used in touch-screen, ultra-thin, good exhaust effect; High transmission rate more than 92%; Stable.
PET polyester film base material 11 selects thickness to be between 20 ~ 100 μ, this film use scraper type anilox roll be coated with anti-blue light UV glue, required thickness is 3 ~ 8 μ, through baking oven by complete for solution evaporation in UV glue, cross UV lamp, UV lamp energy, in the scope of 30 ~ 200mj/cm2, forms UV acrylate resin layer 12.Obtain the PET base material with anti-blue light process.
By the release film 14 of 50 ~ 100 μ, use blade coating to adopt comma scraper, the tackiness agent of coating high cohesion, thickness requirement 35 ~ 50 μ, through curing oven, form adhering agent layer 13; The anti-blue light UV of PET base material through anti-blue light process is solidified the adhering agent layer 13 that face (UV acrylate resin layer 12) is covered with high cohesion.
The PET base material reverse side of above process will be done, blade coating is used to adopt comma scraper coating organic silica gel, thickness requirement 35 ~ 50 μ, through curing oven, obtain layer of silica gel 15, layer of silica gel 15 is covered with another 50 μ PET base material (PET peel ply 16), obtains thus obtain one having anti-blue light function toughened glass film AB double faced adhesive tape.
Owing to being touch-screen, be no matter that toughened glass or AB glue all need to accomplish thin, just can have better touch sensible, select PET base material that transmittance should be selected high, thickness is thin between 20 ~ 100 μ, and increases surface adhesion force through corona treatment.
Select at anti-blue light UV glue, the present invention selects vinylformic acid photocuring system, and transparency is high, anti-blue light rate UV glue more than 50%.
Owing to being UV solidification, and general thinner base material easy warpage of film in the too high situation of UV energy, UV is selected to be solidificated in 30 ~ 200mj/cm 2.
Micro gravure coating method is selected in this anti-blue light coating, micro gravure coating method is use gravure roll, and nick roller line is several according to different thickness requirement, 50 ~ 140 THREADY DRILL nick rollers, gravure roller surface is carved with pattern or groove cave, to provide special glue spread, gravure roll is arranged on bearing, and part is immersed in supply disk, the axle rotated takes up coating, after a flexible steel scraper is quantitative, take away coating fluid by reversing motion base material, realize thin uniform layer coating.
This coating tackiness agent of high cohesion and employing comma scraper of silica gel mucigel, comma scraper often adopts the good round steel of intensity, hardness to make the edge of a knife.During frictioning, this scraper maintains static dynamic.The intensity of this scraper, hardness is high, and cutting edge straightness error is little, and pneumatic and micro-adjusting mechanism can be adopted to carry out regulation and control doctor position, coating weight control and frictioning precision high, it is also very convenient to use.Because its frictioning is very even, so be applicable to the accurate frictioning of smooth roll gluing coating.
Due to toughened glass stone breakables, select the tackiness agent viscosity 8000 ~ 20000cps of high cohesion, use the tackiness agent of high cohesion to be conducive to and peel off absorption very well, and prevent from peeling off fragment sputtering when bursting and hurt people.
Silica gel adopts special silica column, and have low sticky automatic absorbing ability, exhaust performance is high, effectively prevents bubble from producing, and coating thickness requires between 35 ~ 50 μ, can effectively get certain shock absorption, have certain shock resistance effect.
Of the present invention have anti-blue light function toughened glass film AB double faced adhesive tape and have excellent glass properties again, can not leave cull on liquid crystal panel; Use silicone resin, natural excluding air, prevents bubble; Optical adhesive is applicable to the material such as adhering glass, PET.
Embodiment one:
The present invention is a kind of when having the toughened glass AB glue concrete operations of anti-blue light function, comprises following operation:
Thickness is selected to be 50 μ PET base material, micro gravure coating method is selected in coating, 140 THREADY DRILL nick rollers, after a flexible steel scraper is quantitative, coating fluid is taken away by reversing motion base material, through baking oven by solvent evaporates, oven temperature is between 80 ~ 100 DEG C, and being coated with anti-blue light UV glue thickness in base material front is 5 μ.
Select thickness to be 100 μ release films, adopt comma to scrape, the tackiness agent of coating high cohesion, thickness is 40 μ.Overlay on the tackiness agent glue face of high cohesion with through anti-blue light process UV face after oven for drying.
To overlay on the PET base material back side on release film, adopt comma to scrape and be coated with machine silicone resin, thickness is 50 μ, covers PET base material, and thickness is 50 μ.
Obtain one and there is anti-blue light function toughened glass film AB double faced adhesive tape, the tackiness agent of this AB glue high cohesion and toughened glass are fitted, silica gel face and screen glass are fitted, in 5s, gas is drained on 5 inch screen, transmittance is 92.5%, and anti-blue light rate reaches 45%.
Embodiment two:
The present invention is a kind of when having the toughened glass AB glue concrete operations of anti-blue light function, comprises following operation:
Thickness is selected to be 23 μ PET base material, micro gravure coating method is selected in coating, 90 THREADY DRILL nick rollers, after a flexible steel scraper is quantitative, coating fluid is taken away by reversing motion base material, through baking oven by solvent evaporates, oven temperature is between 80 ~ 100 DEG C, and being coated with anti-blue light UV glue thickness in base material front is 6 μ.
Select thickness to be 50 μ release films, adopt comma to scrape, the tackiness agent of coating high cohesion, thickness is 50 μ.Overlay on the tackiness agent glue face of high cohesion with through anti-blue light process UV face after oven for drying.
To overlay on the PET base material back side on release film, adopt comma to scrape and be coated with machine silicone resin, thickness is 40 μ, covers PET base material, and thickness is 50 μ.
Obtain one and there is anti-blue light function toughened glass film AB double faced adhesive tape, the tackiness agent of this AB glue high cohesion and toughened glass are fitted, silica gel face and screen glass are fitted, in 4S, gas is drained on 5 inch screen, transmittance is 93%, and anti-blue light rate reaches 50%.
The present invention resists blue light toughened glass film following effect: owing to being touch-screen, so need ultra-thin, just can have better touch sensible; Superpower fast automatic exhaust: good exhaust effect, simplifies installation sequence, allows everyone install by oneself; High transmission rate more than 92.5%; Without cull: displacement toughened glass film can not cull, can not affect original mobile phone screen; Non-foaming: having used of a specified duration can not produce bubble automatically; No watermark: the generation avoiding watermark during installation; Stable: to prove through life-time service, long-term stable transparent effect can be reached.
The above embodiment only have expressed some embodiments of the present invention, and it describes comparatively concrete and detailed, but therefore can not be interpreted as limitation of the scope of the invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with claims.

Claims (9)

1. one kind has the toughened glass film AB glue of anti-blue light function, include: PET polyester film base material (11), it is characterized in that, UV acrylate resin layer (12) is introduced on described PET polyester film base material (11), introduce adhering agent layer (13) on described UV acrylate resin layer (12), on described adhering agent layer (13), introduce release film (14);
Described PET polyester film base material (11) have layer of silica gel (15), described layer of silica gel (15) have PET peel ply (16).
2. a kind of toughened glass film AB glue with anti-blue light function according to claim 1, it is characterized in that, described UV acrylate resin layer (12) selects vinylformic acid photocuring system, and UV lamp energy is at 30 ~ 200mj/cm 2scope in.
3. a kind of toughened glass film AB glue with anti-blue light function according to claim 1, is characterized in that, the tackiness agent viscosity 8000 ~ 20000cps of described adhering agent layer (13).
4. a kind of toughened glass film AB glue with anti-blue light function according to claim 1, it is characterized in that, described PET polyester film base material (11) selects thickness to be 20 ~ 100 μ.
5. prepare the method for the toughened glass film AB glue described in any one of Claims 1 to 4 with anti-blue light function for one kind, AB glue is that base material is coated with anti-blue light UV glue in front by PET material, obtain the PET base material of anti-blue light process, the tackiness agent of the high cohesion that release film is coated with, fitting with through anti-blue light process and the PET base material front that has been coated with silica gel in the tackiness agent glue face of high cohesion, makes the tackiness agent of high cohesion on release film transfer to the front of PET base material; Again by the PET base material reverse side coating organic silica gel through processing, and cover one deck PET base material above, thus obtain one there is anti-blue light function toughened glass film AB double faced adhesive tape;
It is characterized in that, comprise the following steps:
(1), PET polyester film base material (11) selects thickness to be between 20 ~ 100 μ, and increase surface adhesion force through corona treatment, this film uses scraper type anilox roll be coated with anti-blue light UV glue, required thickness is 3 ~ 8 μ, obtains basic products;
Or micro gravure coating method is selected in anti-blue light UV glue coating, micro gravure coating method is use gravure roll, and nick roller line is several according to different thickness requirement, 50 ~ 140 THREADY DRILL nick rollers, gravure roller surface is carved with pattern or groove cave, gravure roll is arranged on bearing, and part is immersed in supply disk, and the axle of rotation takes up coating, after a flexible steel scraper is quantitative, take away coating fluid by reversing motion base material, realize thin uniform layer coating, obtain basic products;
(2) basic products, by step (1) obtained is through baking oven, and by complete for solution evaporation in UV glue, cross UV lamp, UV lamp energy is at 30 ~ 200mj/cm 2scope in, formed UV acrylate resin layer (12), obtain the PET base material with anti-blue light process;
(3), by the release film (14) of 50 ~ 100 μ, use blade coating, adopt comma scraper, the tackiness agent of coating high cohesion, thickness requirement 35 ~ 50 μ, through curing oven, makes release film (14) be covered with adhering agent layer (13);
(4) the UV acrylate resin layer (12) of the PET base material through anti-blue light process, by step (2) obtained, is covered with the adhering agent layer (13) of the high cohesion of release film (14);
(5), by doing the PET base material reverse side of above process, use blade coating, adopt comma scraper coating organic silica gel, thickness requirement 35 ~ 50 μ, through curing oven, obtains layer of silica gel (15);
(6), in layer of silica gel (15) be covered with PET peel ply (16), 50 μ PET base material away from the one side of PET base material, obtain that there is anti-blue light function toughened glass film AB double faced adhesive tape.
6. method according to claim 5, is characterized in that, the comma scraper of described step (3) adopts intensity, the edge of a knife made by the good round steel of hardness; During frictioning, this scraper maintains static dynamic; Pneumatic and micro-adjusting mechanism is adopted to carry out regulation and control doctor position.
7. method according to claim 5, is characterized in that, described step (3) adhering agent layer (13) selects the tackiness agent of high cohesion, viscosity 8000 ~ 20000cps.
8. method according to claim 5, is characterized in that, described step (5) layer of silica gel (15) adopts silica column, there is low sticky automatic absorbing ability, exhaust performance is high, effectively prevents bubble from producing, and coating thickness requires between 35 ~ 50 μ.
9. method according to claim 5, is characterized in that, step is as follows:
Thickness is selected to be 50 μ PET base material, micro gravure coating method is selected in coating, 140 THREADY DRILL nick rollers, after a flexible steel scraper is quantitative, coating fluid is taken away by reversing motion base material, through baking oven by solvent evaporates, oven temperature is between 80 ~ 100 DEG C, and being coated with anti-blue light UV glue thickness in base material front is 5 μ;
Select thickness to be 100 μ release films, adopt comma to scrape, the tackiness agent of coating high cohesion, thickness is 40 μ; With overlaying on the tackiness agent glue face of high cohesion through anti-blue light process UV face after oven for drying;
To overlay on the PET base material back side on release film, adopt comma to scrape and be coated with machine silicone resin, thickness is 50 μ, covers another PET base material, and thickness is 50 μ;
Obtain one and there is anti-blue light function toughened glass film AB double faced adhesive tape, the tackiness agent of this AB glue high cohesion and toughened glass are fitted, silica gel face and screen glass are fitted, in 5s, gas is drained on 5 inch screen, transmittance is 92.5%, and anti-blue light rate reaches 45%.
CN201410612065.1A 2014-11-04 2014-11-04 A kind of safety glass film AB glue with anti-blue light function and preparation method Active CN104479575B (en)

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CN105400484A (en) * 2015-12-31 2016-03-16 宁波大榭开发区综研化学有限公司 Silicone adhesive and optical double-sided tape employing silicone adhesive and used for toughened glass protection film
CN105440967A (en) * 2015-12-17 2016-03-30 东莞市纳利光学材料有限公司 Low-thickness toughened glass AB adhesive film and preparation method thereof
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CN105505248A (en) * 2016-01-25 2016-04-20 衡山县佳诚新材料有限公司 Anti-explosion eye protecting film
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CN113930175A (en) * 2021-10-27 2022-01-14 苏州赛伍应用技术股份有限公司 Optical AB glue and preparation method and application thereof

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