CN104479499A - Reactive halogen-free flame retardant epoxy coating - Google Patents
Reactive halogen-free flame retardant epoxy coating Download PDFInfo
- Publication number
- CN104479499A CN104479499A CN201410789772.8A CN201410789772A CN104479499A CN 104479499 A CN104479499 A CN 104479499A CN 201410789772 A CN201410789772 A CN 201410789772A CN 104479499 A CN104479499 A CN 104479499A
- Authority
- CN
- China
- Prior art keywords
- response type
- halogen
- type halogen
- free flameproof
- epoxy coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/69—Particle size larger than 1000 nm
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a reactive halogen-free flame retardant epoxy coating. The reactive halogen-free flame retardant epoxy coating is prepared by compounding halogen-free flame retardant epoxy resin with a small amount of a halogen-free flame retardant, wherein the halogen-free flame retardant epoxy resin accounts for 30-60%, and the halogen-free flame retardant account for 15-30%. The reactive halogen-free flame retardant epoxy coating provided by the invention has high strength and good flexibility, the flame retardant is environment-friendly and free from halogen, the additives are low in addition amount, and the flame retardancy (UL-94 1.6mm) of the reactive halogen-free flame retardant epoxy coating reaches the grade UL-94V-0. In addition, the reactive halogen-free flame retardant epoxy coating has high fluidity, excellent adhesion, high impact strength and good practicability and can form a smooth surface.
Description
Technical field
The present invention relates to a kind of epoxypaint, particularly a kind of response type halogen-free flameproof epoxy coating and preparation method thereof.
Background technology
Response type Halogenless fire retarded epoxy resin refers to epoxy resin and the halogen-free flame retardants graft reaction under certain conditions containing ignition-proof element (example: P, N, S element etc.), obtains response type Halogenless fire retarded epoxy resin.Because ignition-proof element directly enters epoxy resin structural, therefore flame retardant effect is stablized, and the product performance impact of processing performance and resin and coating is less.
Chinese invention patent ZL200610020178.8 provides a kind of fire-retardant, antistatic unsaturated polyester resin, reaches corresponding flame retardant properties by the fire-retardant filler such as decabromodiphenyl oxide, antimonous oxide added containing halogen; But on the one hand because halogen harm is large, this kind of product does not meet national environmental protection policy on the other hand, therefore can not extend to market.US Patent No. 6156825 obtains corresponding flame retardant properties (UL-94V-0 level) by one or more in interpolation ATH (aluminium hydroxide), phosphorus fire retardant or nitrogen combustion inhibitor, but the filler flame retardant effects such as ATH are poor, a large amount of filling is needed to obtain flame retardant properties, this kind of way makes paint film property decline, and can not meet the demands; In addition, the interpolation of red phosphorus, affects paint film form and aspect.
Chinese patent ZL201210285636.6 provides a kind of expansion type flame-retardant, its formula is composed as follows: acrylic resin 65 ~ 75%, halogen-free flame retardants 18 ~ 23%, toughner 3 ~ 5%, compatilizer 3 ~ 5%, nano imvite 0.5 ~ 1%, lubricant 0.1 ~ 0.5%, oxidation inhibitor 0.2 ~ 0.5%; Described halogen-free flame retardants carries out coated process gained after being mixed by the part by weight of 3:1:1 by ammonium polyphosphate, polyvalent alcohol and trimeric cyanamide again.This patent achieves the halogen-free flameproof meeting present national environmental protection policy, but flame-retardant system is expansion type flame-retarding, and stability, temperature tolerance are all poor, and cost is high.
Flame-retardant system coating in the market mainly contain Intumscent Flame Retardant System, Halogen flame-retardant system, containing antimony flame-retardant system etc., above system one side stability, temperature tolerance are poor, price, on the other hand Halogen, large containing antimony toxicity, all can not meet current national environmental protection policy; Meanwhile, under European Union Rohs instruction and the impact of current national environmental protection policy, development novel halogen-free flame-retardant polyester coating (i.e. the response type halogen-free antiflaming polyester coating of safety and stability) is very necessary and urgent, and has wide market outlook.
Summary of the invention
One object of the present invention is to provide one can highly effective flame-retardant, does not produce again the novel reaction type halogen-free flameproof epoxy coating (two component) of pungency hydrogen halide toxic substance, to overcome the deficiency of existing additive flame retardant coating technology simultaneously.
Another object of the present invention is the preparation method providing a kind of halogen-free flameproof epoxy coating.
The present invention's polymerization technique used belongs to the general operation technical ability that those of ordinary skill in the art should possess, also can according to " coating process (third edition) " (coating process editorial committee volume, Chemical Industry Press, 1997) guidance of a book prepares.
A kind of response type halogen-free antiflaming polyester coating provided by the invention, by mass percent, comprises following component:
Halogen-free antiflaming polyester coating of the present invention, flame-retarded resin used is one or more combinations in phosphorous epoxy resin, phosphorous-sulphur epoxy resin, uses the grafting compounds epoxy resin containing P, S element and obtains.
Halogen-free antiflaming polyester coating of the present invention, pigment used as: but be not limited only to titanium dioxide, phthalocyanine blue, lemon yellow, red iron oxide, phthalocyanine green, carbon black and iron oxide black etc.These pigment can be independent or be severally arbitrarily applied to the present invention, its particle size range 0.01 μm ~ 45 μm, prioritizing selection 0.1 μm ~ 20 μm.
Halogen-free antiflaming polyester coating of the present invention, halogen-free flameproof filler used as: but be not limited only to aluminium hydroxide (ATH), magnesium hydroxide (MH), melamine cyanurate (MCA), aluminium triphosphate (ATP), Tritolyl Phosphate (TCP), dimethyl methyl phosphonate (DMMP), ammonium polyphosphate (APP), compound phosphorus flame retardant (FR-P), cenosphere and hollow Tao Zhu etc., these fillers can be independent or be severally arbitrarily applied to the present invention, particle size range is 0.05 μm ~ 40 μm, prioritizing selection 0.1 μm ~ 25 μm.The composite fire retardant of same kind fire-retardant filler or multiple fire-retardant filler composition requires that the particle diameter of various fire-retardant filler is complementary, reaches pigment and fire-retardant filler, mutual object of filling between fire-retardant filler and fire-retardant filler.
Halogen-free antiflaming polyester coating of the present invention, fire retarding synergist used as: but be not limited only to triphenylphosphate (TPP), triaryl phosphate, tricresyl phosphate second fat, tetrafluoroethylene, microcapsule coated red phosphor masterbatch and zinc borate etc.These fire retarding synergists can be independent or be severally arbitrarily applied to the present invention, and addition is 2wt% ~ 10wt%, prioritizing selection 4wt% ~ 8wt%.
Halogen-free antiflaming polyester coating of the present invention, dispersion agent used as: but be not limited only to macromolecule polyurethane (molecular weight 2000-40000), macromolecule polyester (molecular weight 1500-20000) and polycarboxylic acid (molecular weight 400-2000) etc., these dispersion agents can be independent or be severally arbitrarily applied to the present invention, consumption 1wt% ~ 6wt%, prioritizing selection 2wt% ~ 4wt%, should select kind and the consumption of dispersion agent according to the dispersion complexity of pigment, filler.
Halogen-free antiflaming polyester coating of the present invention, defoamer used as: but be not limited only to organic silicon modified by polyether, polyester resin change properties of organic silicon, fluorin modified crylic acid ester and vinylformic acid acid esters etc.The one in these defoamers can be selected according to resin properties or severally arbitrarily be applied to the present invention, consumption 0wt% ~ 2.0wt%, prioritizing selection 0.3wt% ~ 0.8wt%.
Halogen-free antiflaming polyester coating of the present invention, flow agent used as: but be not limited only to organic silicon modified by polyether, polyester resin change properties of organic silicon, fluorin modified crylic acid ester and vinylformic acid acid esters etc., can consumption 0wt% ~ 2.0wt%, prioritizing selection 0.3wt% ~ 1.0wt% according to the levelling complexity of halogen-free antiflaming polyester coating;
Halogen-free antiflaming polyester coating of the present invention, solvent used as: but be not limited only to dimethylbenzene, toluene, n-butyl acetate, 1-Methoxy-2-propyl acetate (PMA), vinyl acetic monomer, methyl iso-butyl ketone (MIBK) (MIBK) and butanols etc.Can select the one in these solvents according to the solubility parameter of flame-retarded resin or severally arbitrarily be applied to the present invention, consumption is 10wt% ~ 40wt%;
Halogen-free antiflaming polyester coating of the present invention, with the use of solidifying agent as: but be not limited only to polymeric amide, phenolic aldehyde amine, cashew nut oil modified polymeric amide and polymeric polyisocyanate class etc., according to the demand to coating property, select one or more suitable solidifying agent models.
The beneficial effect that technical solution of the present invention realizes:
Response type halogen-free flameproof epoxy coating provided by the invention, uses the material Graft Epoxy Resin containing elements such as P, S, obtains the response type Halogenless fire retarded epoxy resin of modification, provides excellent adhesion property while providing flame retardant properties.
Response type halogen-free flameproof epoxy coating provided by the invention, has that intensity is high, snappiness good, fire retardant environment friendly non-halogen, and additive addition is few, and flame retardant rating (UL-941.6mm) reaches UL-94V-0 level; Meanwhile, response type halogen-free flameproof epoxy coating mobility is high, smooth surface, and sticking power is excellent, and impact strength is high, has good practical application.
Embodiment
Below describe technical scheme of the present invention in detail.The embodiment of the present invention is only in order to illustrate technical scheme of the present invention and unrestricted, although with reference to preferred embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that, can modify to the technical scheme of invention or equivalent replacement, and not departing from the spirit and scope of technical solution of the present invention, it all should be encompassed in right of the present invention.
The present invention used containing P modified poly ester flame-retarded resin, containing P-S modified poly ester flame-retarded resin and containing P modified poly ester flame-retarded resin all from Jiangsu Baihe Paint Co., Ltd., if other reagent used does not clearly indicate, then use technical grade.
Embodiment 1
Make response type halogen-free antiflaming polyester coating by such as following table 1, film performance detected result is in table 4.
Table 1
Embodiment 2
Make response type halogen-free antiflaming polyester coating by such as following table 2, film performance detected result is in table 4.
Table 2
Embodiment 3
Make response type halogen-free antiflaming polyester coating by such as following table 3, film performance detected result is in table 4.
Table 3
Table 4
Visible by table 4, response type halogen-free flameproof epoxy coating of the present invention (response type Halogenless fire retarded epoxy resin composite addition type halogen-free flameproof filler systems), the film flame retardant properties of coating reaches UL-94V-0 level; Test result it can also be seen that simultaneously, and response type halogen-free flameproof epoxy coating impact strength of the present invention is high, film adhesive is excellent, good mechanical property.
Claims (15)
1. a response type halogen-free flameproof epoxy coating, is characterized in that, by mass percent, comprises following component:
2. response type halogen-free flameproof epoxy coating according to claim 1, the paint that it is characterized in that described coating is admittedly than being 4 ~ 8: 1.
3. response type halogen-free flameproof epoxy coating according to claim 1, is characterized in that described flame-retarded resin is selected from and uses the grafting compounds epoxy resin containing P, S element and obtain.
4. anti-response type halogen-free flameproof epoxy coating according to claim 1, it is characterized in that described halogen-free flameproof filler is selected from one or more of aluminium hydroxide, magnesium hydroxide, melamine cyanurate, aluminium triphosphate, Tritolyl Phosphate, dimethyl methyl phosphonate, ammonium polyphosphate, compound phosphorus flame retardant, cenosphere and hollow Tao Zhu, particle size range is 0.05 μm ~ 40 μm.
5. response type halogen-free flameproof epoxy coating according to claim 1, is characterized in that the particle size range of described pigment is 0.01 μm ~ 45 μm, prioritizing selection 0.1 μm ~ 20 μm.
6. response type halogen-free flameproof epoxy coating according to claim 1, it is characterized in that described fire retarding synergist is selected from triphenylphosphate, triaryl phosphate, tricresyl phosphate second fat, one or more of tetrafluoroethylene, microcapsule coated red phosphor masterbatch and zinc borate.
7. response type halogen-free flameproof epoxy coating according to claim 1, is characterized in that described fire retarding synergist consumption is 4wt% ~ 8wt%.
8. response type halogen-free flameproof epoxy coating according to claim 1, it is characterized in that described dispersion agent be selected from macromolecule polyurethane, macromolecule polyester and polycarboxylic acid one or more.
9. response type halogen-free antiflaming polyester coating according to claim 1, is characterized in that described dispersant dosage is 2wt% ~ 4wt%.
10. response type halogen-free flameproof epoxy coating according to claim 1, is characterized in that described defoamer is selected from organic silicon modified by polyether, polyester resin change properties of organic silicon, one of fluorin modified crylic acid ester and vinylformic acid acid esters kind or several.
11. response type halogen-free antiflaming polyester coating according to claim 1, is characterized in that described defoamer consumption is 0.3wt% ~ 0.8wt%.
12. response type halogen-free flameproof epoxy coatings according to claim 1, is characterized in that described flow agent is selected from organic silicon modified by polyether, polyester resin change properties of organic silicon, one of fluorin modified crylic acid ester and vinylformic acid acid esters kind or several.
13. response type halogen-free flameproof epoxy coatings according to claim 1, is characterized in that described flow agent consumption is 0.3wt% ~ 1.0wt%.
14. response type halogen-free flameproof epoxy coatings according to claim 1, is characterized in that described solvent is selected from one or more of dimethylbenzene, toluene, n-butyl acetate, 1-Methoxy-2-propyl acetate, vinyl acetic monomer, methyl iso-butyl ketone (MIBK) and butanols.
15. response type halogen-free flameproof epoxy coatings according to claim 1, is characterized in that also with the use of a kind of several solidifying agent of polymeric amide, phenolic aldehyde amine, cashew nut oil modified polymeric amide and polymeric polyisocyanate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410789772.8A CN104479499A (en) | 2014-12-18 | 2014-12-18 | Reactive halogen-free flame retardant epoxy coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410789772.8A CN104479499A (en) | 2014-12-18 | 2014-12-18 | Reactive halogen-free flame retardant epoxy coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104479499A true CN104479499A (en) | 2015-04-01 |
Family
ID=52754112
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410789772.8A Pending CN104479499A (en) | 2014-12-18 | 2014-12-18 | Reactive halogen-free flame retardant epoxy coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104479499A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106243916A (en) * | 2016-07-31 | 2016-12-21 | 马晓洁 | A kind of Flame-proof door fire-retardant bicomponent epoxy resin coating and application thereof |
| CN110343410A (en) * | 2019-06-10 | 2019-10-18 | 安徽蓝德正华电子有限公司 | A kind of power distribution cabinet anti-flaming dope and preparation method thereof |
| CN111331981A (en) * | 2020-04-01 | 2020-06-26 | 东莞市瑞年塑胶科技有限公司 | Electrostatic adsorption flame-retardant film |
| CN113185754A (en) * | 2021-05-07 | 2021-07-30 | 西北师范大学 | Attapulgite/antimony trioxide hybrid material, preparation method thereof and application thereof in producing flame-retardant polymer composite material |
| CN116875151A (en) * | 2023-08-10 | 2023-10-13 | 江苏云湖新材料科技有限公司 | Halogen-free flame-retardant epoxy fireproof coating for battery pack shell and preparation method thereof |
-
2014
- 2014-12-18 CN CN201410789772.8A patent/CN104479499A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106243916A (en) * | 2016-07-31 | 2016-12-21 | 马晓洁 | A kind of Flame-proof door fire-retardant bicomponent epoxy resin coating and application thereof |
| CN110343410A (en) * | 2019-06-10 | 2019-10-18 | 安徽蓝德正华电子有限公司 | A kind of power distribution cabinet anti-flaming dope and preparation method thereof |
| CN111331981A (en) * | 2020-04-01 | 2020-06-26 | 东莞市瑞年塑胶科技有限公司 | Electrostatic adsorption flame-retardant film |
| CN111331981B (en) * | 2020-04-01 | 2021-03-19 | 东莞市瑞年塑胶科技有限公司 | Electrostatic adsorption flame-retardant film |
| CN113185754A (en) * | 2021-05-07 | 2021-07-30 | 西北师范大学 | Attapulgite/antimony trioxide hybrid material, preparation method thereof and application thereof in producing flame-retardant polymer composite material |
| CN116875151A (en) * | 2023-08-10 | 2023-10-13 | 江苏云湖新材料科技有限公司 | Halogen-free flame-retardant epoxy fireproof coating for battery pack shell and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104479499A (en) | Reactive halogen-free flame retardant epoxy coating | |
| CN109233101B (en) | Heat-resistant flame-retardant polypropylene composition and preparation method thereof | |
| CN104449263A (en) | Reactive halogen-free flame retardant polyester paint | |
| US8029704B2 (en) | Flexible protective coating | |
| CN104693782A (en) | Halogen-free flame retardant polyether thermoplastic polyurethane elastomer and preparation method thereof | |
| CN109486348B (en) | Preparation method of fireproof anticorrosive paint | |
| CN102850902A (en) | Corrosion-resistant fireproof coating | |
| CN101824182A (en) | Halogen-free expansion type flame-retardant thermoplastic elastomer composition | |
| CN105733376A (en) | Weather-proof, halogen-free, flame-retardant, anti-corrosion and insulating fluorine-carbon coating | |
| CN105602424A (en) | Weather-proof halogen-free flame retardant insulation polyurea coating | |
| CN103059675A (en) | Thermal insulating and fire retardant coating of indoor ultrathin steel structure and preparation method of coating | |
| KR101697814B1 (en) | Polypropylene flame retardant resin composition and extrusion tubing molded product | |
| CN104761843A (en) | Halogen-free flame-retardant cable material | |
| CN110922748A (en) | Low-smoke halogen-free flame-retardant nylon 12 and preparation method thereof | |
| JP2007203726A (en) | Flame retardant metal-clad fabric and metal-clad sheet | |
| CN103740038A (en) | High-glossiness halogen-free flame-retardant ABS material and preparation method thereof | |
| CN104629285A (en) | Halogen-free flame-retardant high toughness modified polycarbonate composition | |
| CN102234407A (en) | Flame-retardant acrylonitrile-butadiene-styrene resin composition and preparation method thereof | |
| CN106700227A (en) | Polypropylene nanometer montmorillonite intumescent flame-retardant composite and preparation method thereof | |
| CN110982465A (en) | Efficient halogen-free flame-retardant epoxy adhesive and preparation method thereof | |
| JP2003055434A (en) | Flame retardant for synthetic resin, and flame- retardant resin composition containing the flame retardant | |
| WO2021020140A1 (en) | Flame retardant composition, flame-retardant resin composition using same, molded article and method for producing molded article | |
| CN102993905B (en) | A kind of fireproofing flame-resistant protective system | |
| CN1854194A (en) | Non-halogen and fire-retardant Nylon 6 resin composition | |
| JP2020122098A (en) | Water-resistant phosphinate flame retardant |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150401 |
|
| WD01 | Invention patent application deemed withdrawn after publication |