CN104479454A - Ink composition for PETG and ink and gloss oil applied to composition - Google Patents
Ink composition for PETG and ink and gloss oil applied to composition Download PDFInfo
- Publication number
- CN104479454A CN104479454A CN201510021911.7A CN201510021911A CN104479454A CN 104479454 A CN104479454 A CN 104479454A CN 201510021911 A CN201510021911 A CN 201510021911A CN 104479454 A CN104479454 A CN 104479454A
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- China
- Prior art keywords
- ink
- composition
- petg
- gloss oil
- organic solvent
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to an ink composition for PETG and ink and gloss oil applied to the composition. The ink composition contains acrylic resin, chloride-vinyl acetate resin, polyethylene wax and a dispersing agent. The ink contains the composition, pigment and an organic solvent. The gloss oil contains the composition and an organic solvent. The formula of the ink composition is simple, contractility resistance of the ink is improved through the chloride-vinyl acetate resin, the ply adhesion is strong and the surface glossiness is high when the ink and the gloss oil are jointly used, and the ink and the gloss oil applied to the composition are suitable for printing usage on PETG material packages.
Description
[technical field]
The present invention relates to pigment art, particularly a kind of PETG ink composite and the application ink of said composition and gloss oil.
[background technology]
PETG full name is polyethylene terephthalate-1,4-cyclohexanedimethanoester ester, by terephthalic acid (PTA) and ethylene glycol (EG), 1,4-cyclohexanedimethanol (CHDM) three kinds of monomers carry out the product of polycondensation, are a kind of outstanding heat-shrinkable film materials.Because it has outstanding thermoforming performance and impact resistance, can production department moulding is complicated and stretch ratio is larger goods; Because it has the same transparency of glass and good glossiness, be applicable to a lot of high-end product.In using, be generally to be wrapped in by the mode of thermal contraction with film-type PETG material to pack on bottle.Because pattern can print on PETG film before packing, therefore the ink that printed patterns is used also needs to adapt to its characteristic, namely ink should have good sticking power with PETG material and also will have outstanding resistance to convergent force, also to have corresponding glossiness, otherwise when the thermal contraction of PETG material, ink coating can deform, fold even peels off, affect surface luster, extreme influence attractive packages.
A lot of research and development have been done on the heat-shrinkable film ink such as PVC, PET, OPS by China, as CN102702857A " the PET heat-shrinkable film plastic printing ink and preparation method thereof without the resistance to alcohol of benzene ", CN103265843A " colored ink and preparation method thereof for printing heat contraction film label ", CN103804989A " colored ink for printing heat contraction film label " etc., however not good cooperation PETG material ages fruit.Therefore the invention provides a kind of new PETG formulation for coating material to adapt to its application scenario.
[summary of the invention]
Main purpose of the present invention is ink and gloss oil in order to provide a kind of PETG ink composite and application said composition.
The present invention is achieved through the following technical solutions above-mentioned purpose: a kind of PETG ink composite, and the composition of every 100 weight parts comprises acrylic resin 40-50 part, polyethylene wax 2-5 part, dispersion agent 12-25 part, and clout is vinyl chloride-vinyl acetate resin.
Compared with prior art, the beneficial effect of PETG ink composite of the present invention is: said composition component is simple, improved the impact resistance power of ink and gloss oil by acrylic resin, improve sticking power between ink and PETG surface and resistance to convergent force by vinyl chloride-vinyl acetate resin and polyethylene wax.
Apply an ink for said composition, comprise composition 31-52 part in the ink of every 100 weight parts, pigment 8-15 part, clout is organic solvent.
Compared with prior art, the beneficial effect of the ink of the present invention's application said composition is: be scattered in organic solvent by pigment and composition, and pigment can be shunk with the contraction of PETG material, prevents ink coating be out of shape or peel off because of cracking.
Apply a gloss oil for said composition, comprise composition 31-52 part in the gloss oil of every 100 weight parts, clout is organic solvent.
Compared with prior art, the beneficial effect of the gloss oil of the present invention's application said composition is: the formula be similar to by ink ensures the sticking power between ink and gloss oil, and makes coating appearance smooth glossy, meets outward appearance needs.
[embodiment]
Following examples for illustration of the present invention, but are not used for limiting the scope of the invention.
In the present invention, A-11 type resin is provided by Rhom and Hass of the U.S., and 76500 type dispersion agents are provided by road extraordinary chemical industry (Shanghai) Co., Ltd. of rich profit.
Embodiment 1
By blended in 2000g ethyl acetate to A-11 type acrylic resin 400g, ternary chlorine vinegar resin 460g, polyethylene wax 20g and 76500 type dispersion agent 120g, extrude as color chips after concentrated retrogradation, color chips is equally divided into two parts after pulverizing, portion directly adds the dispersion of 1000g ethyl acetate as gloss oil, another part adds 250g pigment and disperses as ink by 750g ethyl acetate, by ink smears to PETG film surface, after dry, smear gloss oil, then test after doing.
Embodiment 2
By blended in 2000g ethyl acetate to A-11 type acrylic resin 500g, ternary chlorine vinegar resin 200g, polyethylene wax 50g and 76500 type dispersion agent 250g, send as color chips after concentrated retrogradation, color chips is equally divided into two parts after pulverizing, portion directly adds the dispersion of 500g ethyl acetate as gloss oil, another part adds 150g pigment and disperses as ink by 350g ethyl acetate, by ink smears to PETG film surface, after dry, smear gloss oil, then test after doing.
Embodiment 3
By blended in 2000g ethyl acetate to A-11 type acrylic resin 450g, ternary chlorine vinegar resin 320g, polyethylene wax 30g and 76500 type dispersion agent 200g, send as color chips after concentrated retrogradation, color chips is equally divided into two parts after pulverizing, portion directly adds the dispersion of 700g ethyl acetate as gloss oil, another part adds 120g pigment and disperses as ink by 580g ethyl acetate, by ink smears to PETG film surface, after dry, smear gloss oil, then test after doing.
Ink performance is tested:
Embodiment 1-3 ink gloss oil coating is carried out correlated performance test, and routine in contrast with ink described in CN103265843A, and concrete outcome is in table 1.
Table 1 ink performance is tested:
As shown in Table 1, the ink gloss oil coating of embodiment 1-3 is compared with reference examples ink, impact resistance, resistance to flexible, and strong adhesion, there is very high glossiness.As can be seen here, the result of use of the present invention on PETG material is better than prior art, and the printing be applicable in PETG material packaging uses.
Above-described is only some embodiments of the present invention.For the person of ordinary skill of the art, without departing from the concept of the premise of the invention, can also make some distortion and improvement, these all belong to protection scope of the present invention.
Claims (8)
1. a PETG ink composite, is characterized in that: the composition of every 100 weight parts comprises acrylic resin 40-50 part, polyethylene wax 2-5 part, dispersion agent 12-25 part, and clout is vinyl chloride-vinyl acetate resin.
2. PETG ink composite according to claim 1, is characterized in that: described acrylic resin is A-11 type resin.
3. PETG ink composite according to claim 1, is characterized in that: described vinyl chloride-vinyl acetate resin is the terpolymer of vinylchlorid, vinyl acetate and maleic anhydride.
4. PETG ink composite according to claim 1, is characterized in that: described dispersion agent is 76500 type dispersion agents.
5. application rights requires an ink for composition described in any one in 1-4, and it is characterized in that: comprise composition 31-52 part in the ink of every 100 weight parts, pigment 8-15 part, clout is organic solvent.
6. ink according to claim 5, is characterized in that: described organic solvent is ethyl acetate.
7. application rights requires a gloss oil for composition described in any one in 1-4, and it is characterized in that: comprise composition 31-52 part in the gloss oil of every 100 weight parts, clout is organic solvent.
8. gloss oil according to claim 7, is characterized in that: described organic solvent is ethyl acetate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510021911.7A CN104479454A (en) | 2015-01-15 | 2015-01-15 | Ink composition for PETG and ink and gloss oil applied to composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510021911.7A CN104479454A (en) | 2015-01-15 | 2015-01-15 | Ink composition for PETG and ink and gloss oil applied to composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104479454A true CN104479454A (en) | 2015-04-01 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510021911.7A Pending CN104479454A (en) | 2015-01-15 | 2015-01-15 | Ink composition for PETG and ink and gloss oil applied to composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104479454A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104817887A (en) * | 2015-04-29 | 2015-08-05 | 惠州市舜丰印材科技有限公司 | Water-based printing ink for printing PET (polyethylene terephthalate) films and method for manufacturing water-based printing ink |
| CN105416837A (en) * | 2015-11-30 | 2016-03-23 | 杭州德雅包装有限公司 | Shrink film for preventing scabbing and sticking and production technology and application of shrink film |
| CN106380942A (en) * | 2016-08-25 | 2017-02-08 | 惠州兴鑫涂料化工有限公司 | Transparent gloss oil for food packaging films |
| CN108373658A (en) * | 2018-04-14 | 2018-08-07 | 大丰鑫源达化工有限公司 | LED-UV piezoelectric type ink-jet inks of high adhesion force and preparation method thereof |
| CN110358356A (en) * | 2019-07-29 | 2019-10-22 | 佛山市高明绿色德化工有限公司 | Brilliant ink of coloured silk for 3D acrylic panel and preparation method thereof, application method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS64181A (en) * | 1987-06-22 | 1989-01-05 | Osaka Sealing Insatsu Kk | Thermal transfer ink and sheet made by using it |
| CN102250513A (en) * | 2011-01-19 | 2011-11-23 | 一可油墨涂料（深圳）有限公司 | Polycyclic aromatic hydrocarbon-free screen printing ink for polyvinyl chloride (PVC) and polycarbonate (PC) materials |
| CN102391734A (en) * | 2011-09-21 | 2012-03-28 | 扬州吉瑞尔包装材料有限公司 | Precoating type base paint of aluminium foil for medicament packaging |
| CN103555056A (en) * | 2013-11-18 | 2014-02-05 | 青岛鑫箭印刷机械有限公司 | Heat-shrinkable film label ink |
-
2015
- 2015-01-15 CN CN201510021911.7A patent/CN104479454A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS64181A (en) * | 1987-06-22 | 1989-01-05 | Osaka Sealing Insatsu Kk | Thermal transfer ink and sheet made by using it |
| CN102250513A (en) * | 2011-01-19 | 2011-11-23 | 一可油墨涂料（深圳）有限公司 | Polycyclic aromatic hydrocarbon-free screen printing ink for polyvinyl chloride (PVC) and polycarbonate (PC) materials |
| CN102391734A (en) * | 2011-09-21 | 2012-03-28 | 扬州吉瑞尔包装材料有限公司 | Precoating type base paint of aluminium foil for medicament packaging |
| CN103555056A (en) * | 2013-11-18 | 2014-02-05 | 青岛鑫箭印刷机械有限公司 | Heat-shrinkable film label ink |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104817887A (en) * | 2015-04-29 | 2015-08-05 | 惠州市舜丰印材科技有限公司 | Water-based printing ink for printing PET (polyethylene terephthalate) films and method for manufacturing water-based printing ink |
| CN105416837A (en) * | 2015-11-30 | 2016-03-23 | 杭州德雅包装有限公司 | Shrink film for preventing scabbing and sticking and production technology and application of shrink film |
| CN106380942A (en) * | 2016-08-25 | 2017-02-08 | 惠州兴鑫涂料化工有限公司 | Transparent gloss oil for food packaging films |
| CN108373658A (en) * | 2018-04-14 | 2018-08-07 | 大丰鑫源达化工有限公司 | LED-UV piezoelectric type ink-jet inks of high adhesion force and preparation method thereof |
| CN110358356A (en) * | 2019-07-29 | 2019-10-22 | 佛山市高明绿色德化工有限公司 | Brilliant ink of coloured silk for 3D acrylic panel and preparation method thereof, application method |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150401 |