CN104478301A - Water-borne ultrathin type fireproof heat insulating material and preparation method thereof - Google Patents
Water-borne ultrathin type fireproof heat insulating material and preparation method thereof Download PDFInfo
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- CN104478301A CN104478301A CN201410675067.5A CN201410675067A CN104478301A CN 104478301 A CN104478301 A CN 104478301A CN 201410675067 A CN201410675067 A CN 201410675067A CN 104478301 A CN104478301 A CN 104478301A
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Abstract
The invention discloses a water-borne ultrathin type fireproof heat insulating material and a preparation method thereof. The water-borne ultrathin type fireproof heat insulating material comprises the following components in percentage by weight: 20-40% of puffed basalt particles, 15-30% of water, 35-60% of composite resin, 1.5-3% of a stabilizer, 0.5-1.8% of a dispersant, 0.2-0.5% of a leveling agent, 0.2-0.5% of a thickening agent, 0.2-0.5% of a defoaming agent and 1.5-3% of a heat insulating material MAS. The water-borne ultrathin type fireproof heat insulating material disclosed by the invention is green and environment-friendly, does not release formaldehyde, benzene and other harmful gases, and is stable in performance and high in fireproof heat insulating quality. The water-borne ultrathin type fireproof heat insulating material is simple in preparation process and wide in application range, the problem of high manufacturing cost of EPS, XPS and cement foamed heat insulating plates is solved, meanwhile the working strength and stress of constructors are relieved, the construction difficulty during measuring of special shaped structural parts, cutting of plates and the like by the constructers is reduced, and the construction cost and constriction difficulty are reduced at the same time.
Description
Technical field
The present invention relates to a kind of fire-retardant heat-insulation material, be specifically related to a kind of water super-thin fire-retardant heat-insulation material and preparation method thereof.
Background technology
Along with development that is economic and society, the function such as insulation, energy-saving and environmental protection, fire prevention of people to material of construction is more and more paid attention to.At present, lagging material mainly contains EPS plate (benzene plate), XPS(polystyrene heat insulating board), cement foaming insulation board.But EPS plate, XPS plate exist fire resistance difference, bonding loosely, the drawback such as easily hangs.The complex manufacturing technology of cement foaming insulation board, need workmen to measure at polymorphic structure position, cut out plate etc., constructional difficulties, cost is high.
Summary of the invention
For solving the problem, primary and foremost purpose of the present invention is to provide a kind of environmental protection, stable performance, water super-thin fire-retardant heat-insulation material that fireproof heat insulating quality is high.
Another object of the present invention is to the preparation method that above-mentioned water super-thin fire-retardant heat-insulation material is provided.
The present invention is achieved through the following technical solutions:
A kind of water super-thin fire-retardant heat-insulation material, by weight percentage, comprises following component:
Expanded basalt particle 20% ~ 40%
Water 15% ~ 30%
Compound resin 35% ~ 60%
Stablizer 1.5% ~ 3%
Dispersion agent 0.5% ~ 1.8%
Flow agent 0.2% ~ 0.5%
Thickening material 0.2% ~ 0.5%
Defoamer 0.2% ~ 0.5%
Lagging material MAS 1.5% ~ 3%.
Described expanded basalt particle is silicon dioxide hollow microballon, and principal feature is that density is less compared with glass microballon, and thermal conductivity is lower, and its thermal conductivity is 0.029W/ (mK), and dry density is 278kg/m
3, sun reflectivity is 0.85, and hemispherical emissivity is 0.86.
Described compound resin is the compound resin of potassium silicate liquid ceramics bonding agent, elastic emulsion and silane coupling agent.Preferably, between three, the ratio of compound is 8:1:1.Preferably, the modulus of described potassium silicate liquid ceramics bonding agent is 5.1 ~ 5.4.This compound resin has the excellent properties such as stronger cohesive force, ageing resistance, high temperature resistant, anti-yellowing change, also have nontoxic, tasteless, pollution-free, the excellent characteristics such as easy production, its aqueous solution has good cohesiveness and film-forming properties, after drying and forming-film, most organic solvent such as ability oils, lubricant and hydro carbons, is good compound resin binding agent.Elastic emulsion is a kind of pure acrylic acid high molecular polymer, mainly increases the low temperature bonding power of slurry, low temperature intensity and coating cracking resistance ability here, and potassium silicate liquid ceramics bonding agent can increase high temperature bond power and the hot strength of heat preservation slurry.Silane coupling agent can increase slurry stability in storage and workability, strengthens the over-all properties of the dry film of coating.
Described stablizer is ethylene glycol or propylene glycol.
Described dispersion agent is aniorfic surfactant, as stearic acid, Sodium dodecylbenzene sulfonate etc.;
Described flow agent is polyether-modified polyacrylic ester.
Described thickening material is that rheological agent (as STZC-920) worked in coordination with by cross-linked type macromolecule thickening material (as ASE-60) containing acidic-group or non-ionic associative type;
Described defoamer is one or more in vinyl polymer, mineral oil or siloxanes.
Described lagging material MAS is a kind of thermal insulation material, its matrix material be mainly made up of silicate, silicon-dioxide, aluminum oxide, and its thermal conductivity is 0.011W/ (mK), and dry density is 198kg/m
3, sun reflectivity is 0.87, and hemispherical emissivity is 0.86.
The preparation method of the water super-thin fire-retardant heat-insulation material that the present invention is above-mentioned, comprises the steps:
1) take water, dispersion agent, compound resin respectively by above-mentioned mass percent, evenly pour in mix container;
2) take stablizer, flow agent, thickening material, defoamer by above-mentioned mass percent again, add in mix container respectively, with intelligent dispersion machine controller adjustment rotating speed to 100r/min ~ 300r/min, stir 3min ~ 8min to evenly, namely obtain component A;
3) expanded basalt particle and lagging material MAS mixing and stirring are obtained B component, B component is slowly added in component A while stirring, stir 3mim ~ 8min to evenly, to obtain final product.
The present invention compared with prior art, has following beneficial effect:
Water super-thin fire-retardant heat-insulation material of the present invention environmental protection, formaldehydeless, benzene and the release of other obnoxious flavour, performance
Stable, fireproof heat insulating quality is high.Its preparation technology is simple, of many uses, solve EPS, XPS, a difficult problem that cement foaming insulation board cost of manufacture is high, alleviate working strength and the pressure of workmen simultaneously, decrease workmen to measure at polymorphic structure position, cut out the constructional difficulties that plate etc. causes, reduce construction cost and difficulty of construction simultaneously.
Embodiment
Further illustrate the present invention below by embodiment, following examples are the present invention's preferably embodiment, but embodiments of the present invention are not by the restriction of following embodiment.
embodiment 1
A kind of water super-thin fire-retardant heat-insulation material, by weight percentage, comprises following component:
Expanded basalt particle 40%
Water 15%
Compound resin 40%
Stablizer 1.5%
Dispersion agent 0.5%
Flow agent 0.5%
Thickening material 0.5%
Defoamer 0.5%
Lagging material MAS 1.5%;
Wherein, described expanded basalt particle is silicon dioxide hollow microballon, and its thermal conductivity is 0.029W/ (mK), and dry density is 278kg/m
3, sun reflectivity is 0.85, and hemispherical emissivity is 0.86; Described compound resin is modulus is the potassium silicate liquid ceramics bonding agent of 5.1 ~ 5.4 and the compound resin of silane coupling agent; Described stablizer is ethylene glycol; Described dispersion agent is stearic acid; Described flow agent is polyether-modified polyacrylic ester; Described thickening material is the cross-linked type macromolecule thickening material ASE-60 containing acidic-group; Described defoamer is mineral oil; Described lagging material MAS is a kind of thermal insulation material, and its thermal conductivity is 0.011W/ (mK), and dry density is 198kg/m
3, sun reflectivity is 0.87, and hemispherical emissivity is 0.86.
Its preparation technology, is made up of following step successively:
1) take water, dispersion agent, compound resin respectively by above-mentioned mass percent, evenly pour in mix container;
2) take stablizer, flow agent, thickening material, defoamer by above-mentioned mass percent again, add in mix container respectively, with intelligent dispersion machine controller adjustment rotating speed to 100r/min ~ 300r/min, stir 3min ~ 8min to evenly, namely obtain component A;
3) expanded basalt particle and lagging material MAS mixing and stirring are obtained B component, B component is slowly added in component A while stirring, stir 3mim ~ 8min to evenly, to obtain final product.
The material of above-mentioned gained is carried out body of wall spraying, sample spraying, detect by the performance index of GB/25261-2010 reflective heat-insulation paint for building, its thermal conductivity is 0.029W/ (mK), and dry density is 278kg/m
3, sun reflectivity is 0.85, and hemispherical emissivity is 0.86.
embodiment 2
A kind of water super-thin fire-retardant heat-insulation material, by weight percentage, comprises following component:
Expanded basalt particle 20%
Water 15%
Compound resin 60%
Stablizer 1.5%
Dispersion agent 0.9%
Flow agent 0.2%
Thickening material 0.2%
Defoamer 0.2%
Lagging material MAS 2%;
Wherein, described expanded basalt particle is silicon dioxide hollow microballon, and its thermal conductivity is 0.029W/ (mK), and dry density is 278kg/m
3, sun reflectivity is 0.85, and hemispherical emissivity is 0.86; Described compound resin is modulus is the potassium silicate liquid ceramics bonding agent of 5.1 ~ 5.4 and the compound resin of silane coupling agent; Described stablizer is propylene glycol; Described dispersion agent is Sodium dodecylbenzene sulfonate; Described flow agent is polyether-modified polyacrylic ester; Described thickening material is that rheological agent STZC-920 worked in coordination with by non-ionic associative type; Described defoamer is siloxanes; Described lagging material MAS is a kind of thermal insulation material, its matrix material be mainly made up of silicate, silicon-dioxide, aluminum oxide, and its thermal conductivity is 0.011W/ (mK), and dry density is 198kg/m
3, sun reflectivity is 0.87, and hemispherical emissivity is 0.86.
Its preparation technology is with embodiment 1.
The material of above-mentioned gained is carried out body of wall spraying, sample spraying, detect by the performance index of GB/25261-2010 reflective heat-insulation paint for building, its thermal conductivity is 0.036W/ (mK), and dry density is 298kg/m
3, sun reflectivity is 0.81, and hemispherical emissivity is 0.82.
embodiment 3
A kind of water super-thin fire-retardant heat-insulation material, by weight percentage, comprises following component:
Expanded basalt particle 30%
Water 26%
Compound resin 35%
Stablizer 3%
Dispersion agent 1.8%
Flow agent 0.2%
Thickening material 0.5%
Defoamer 0.5%
Lagging material MAS 3%
Wherein, described expanded basalt particle is silicon dioxide hollow microballon, and its thermal conductivity is 0.029W/ (mK), and dry density is 278kg/m
3, sun reflectivity is 0.85, and hemispherical emissivity is 0.86; Described compound resin is modulus is the potassium silicate liquid ceramics bonding agent of 5.1 ~ 5.4 and the compound resin of silane coupling agent; Described stablizer is ethylene glycol; Described dispersion agent is Sodium dodecylbenzene sulfonate; Described flow agent is polyether-modified polyacrylic ester; Described thickening material is that rheological agent STZC-920 worked in coordination with by non-ionic associative type; Described defoamer is mineral oil; Described lagging material MAS is a kind of thermal insulation material, and its thermal conductivity is 0.011W/ (mK), and dry density is 198kg/m
3, sun reflectivity is 0.87, and hemispherical emissivity is 0.86.
Its preparation technology is with embodiment 1.
The material of above-mentioned gained is carried out body of wall spraying, sample spraying, detect by the performance index of GB/25261-2010 reflective heat-insulation paint for building, its thermal conductivity is 0.031W/ (mK), and dry density is 288kg/m
3, sun reflectivity is 0.84, and hemispherical emissivity is 0.83.
Claims (10)
1. a water super-thin fire-retardant heat-insulation material, is characterized in that, by weight percentage, comprises following component:
Expanded basalt particle 20% ~ 40%
Water 15% ~ 30%
Compound resin 35% ~ 60%
Stablizer 1.5% ~ 3%
Dispersion agent 0.5% ~ 1.8%
Flow agent 0.2% ~ 0.5%
Thickening material 0.2% ~ 0.5%
Defoamer 0.2% ~ 0.5%
Lagging material MAS 1.5% ~ 3%.
2. water super-thin fire-retardant heat-insulation material according to claim 1, is characterized in that: described expanded basalt particle is silicon dioxide hollow microballon, and its thermal conductivity is 0.029W/ (mK), and dry density is 278kg/m
3, sun reflectivity is 0.85, and hemispherical emissivity is 0.86.
3. water super-thin fire-retardant heat-insulation material according to claim 1, it is characterized in that: described compound resin is the compound resin of potassium silicate liquid ceramics bonding agent, elastic emulsion and silane coupling agent, described elastic emulsion is pure acrylic acid high molecular polymer.
4. water super-thin fire-retardant heat-insulation material according to claim 3, is characterized in that: the ratio of weight and number of described potassium silicate liquid ceramics bonding agent, elastic emulsion and silane coupling agent three compound is 8:1:1.
5. water super-thin fire-retardant heat-insulation material according to claim 3, is characterized in that: the modulus of described potassium silicate liquid ceramics bonding agent is 5.1 ~ 5.4.
6. water super-thin fire-retardant heat-insulation material according to claim 1, is characterized in that: described stablizer is ethylene glycol or propylene glycol.
7. water super-thin fire-retardant heat-insulation material according to claim 1, is characterized in that: described dispersion agent is aniorfic surfactant; Described flow agent is polyether-modified polyacrylic ester.
8. water super-thin fire-retardant heat-insulation material according to claim 1, is characterized in that: described thickening material is that rheological agent worked in coordination with by cross-linked type macromolecule thickening material containing acidic-group or non-ionic associative type; Described defoamer is one or more in vinyl polymer, mineral oil or siloxanes.
9. water super-thin fire-retardant heat-insulation material according to claim 1, it is characterized in that: the matrix material that described lagging material MAS is mainly made up of silicate, silicon-dioxide, aluminum oxide, its thermal conductivity is 0.011W/ (mK), and dry density is 198kg/m
3, sun reflectivity is 0.87, and hemispherical emissivity is 0.86.
10. the preparation method of the water super-thin fire-retardant heat-insulation material described in any one of claim 1-9, is characterized in that, comprise the steps:
1) take water, dispersion agent, compound resin respectively by above-mentioned mass percent, evenly pour in mix container;
2) take stablizer, flow agent, thickening material, defoamer by above-mentioned mass percent, with intelligent dispersion machine controller adjustment rotating speed to 100r/min ~ 300r/min, stir 3min ~ 8min to evenly, namely obtain component A;
3) expanded basalt particle and lagging material MAS blending dispersion are evenly obtained B component, B component is slowly added in component A while stirring, stir 3mim ~ 8min to evenly, to obtain final product.
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| CN201410675067.5A CN104478301B (en) | 2014-11-24 | 2014-11-24 | A kind of water super-thin fire-retardant heat-insulation material and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105924040A (en) * | 2016-04-29 | 2016-09-07 | 江苏经纬技术创新咨询有限公司 | Core material for vacuum heat-insulating board and preparation method thereof |
| CN106747000A (en) * | 2016-12-23 | 2017-05-31 | 卢映锟 | A kind of high performance lightweight concrete and preparation method thereof |
| CN109517362A (en) * | 2018-11-05 | 2019-03-26 | 重庆市晨誉建材有限公司 | A kind of novel centrifugal thermal insulation material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1047877A (en) * | 1989-06-03 | 1990-12-19 | 薛志纯 | Compound resin emulsion adhesive |
| CN103289487A (en) * | 2013-05-25 | 2013-09-11 | 佛山市顺德区数码彩涂料有限公司 | Sound-absorbing, insulated and anti-fogging water paint |
| CN103602107A (en) * | 2013-11-19 | 2014-02-26 | 无锡市虎皇漆业有限公司 | Water-based inorganic resin and preparation method thereof |
| CN103602188A (en) * | 2013-11-28 | 2014-02-26 | 王立明 | Water-based paint applied in aluminum-plastic plates and color steel coiled material |
-
2014
- 2014-11-24 CN CN201410675067.5A patent/CN104478301B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1047877A (en) * | 1989-06-03 | 1990-12-19 | 薛志纯 | Compound resin emulsion adhesive |
| CN103289487A (en) * | 2013-05-25 | 2013-09-11 | 佛山市顺德区数码彩涂料有限公司 | Sound-absorbing, insulated and anti-fogging water paint |
| CN103602107A (en) * | 2013-11-19 | 2014-02-26 | 无锡市虎皇漆业有限公司 | Water-based inorganic resin and preparation method thereof |
| CN103602188A (en) * | 2013-11-28 | 2014-02-26 | 王立明 | Water-based paint applied in aluminum-plastic plates and color steel coiled material |
Non-Patent Citations (2)
| Title |
|---|
| 沙力争: "《纸加工技术》", 1 February 2009, 中国轻工业出版社 * |
| 耿耀宗: "《现代水性涂料工艺、配方、应用》", 1 April 2013, 中国石化出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105924040A (en) * | 2016-04-29 | 2016-09-07 | 江苏经纬技术创新咨询有限公司 | Core material for vacuum heat-insulating board and preparation method thereof |
| CN105924040B (en) * | 2016-04-29 | 2018-07-13 | 江苏经纬技术创新咨询有限公司 | A kind of core material of vacuum heat insulation plate and preparation method thereof |
| CN106747000A (en) * | 2016-12-23 | 2017-05-31 | 卢映锟 | A kind of high performance lightweight concrete and preparation method thereof |
| CN109517362A (en) * | 2018-11-05 | 2019-03-26 | 重庆市晨誉建材有限公司 | A kind of novel centrifugal thermal insulation material and preparation method thereof |
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