CN104476932A - Environment-friendly type printing colored tape used for cable protecting bush surface - Google Patents

Environment-friendly type printing colored tape used for cable protecting bush surface Download PDF

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Publication number
CN104476932A
CN104476932A CN201410655415.2A CN201410655415A CN104476932A CN 104476932 A CN104476932 A CN 104476932A CN 201410655415 A CN201410655415 A CN 201410655415A CN 104476932 A CN104476932 A CN 104476932A
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CN
China
Prior art keywords
layer
ethyl acetate
environment
friendly type
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201410655415.2A
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Chinese (zh)
Other versions
CN104476932B (en
Inventor
胡妍
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHENGWU POWER SUPPLY COMPANY, STATE GRID SHANDONG ELECTRIC POWER CO., LTD.
Heze Power Supply Co of State Grid Shandong Electric Power Co Ltd
Original Assignee
Chuzhou Huazun Electrical Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chuzhou Huazun Electrical Technology Co Ltd filed Critical Chuzhou Huazun Electrical Technology Co Ltd
Priority to CN201410655415.2A priority Critical patent/CN104476932B/en
Priority claimed from CN201310049826.2A external-priority patent/CN103085510B/en
Publication of CN104476932A publication Critical patent/CN104476932A/en
Application granted granted Critical
Publication of CN104476932B publication Critical patent/CN104476932B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Abstract

The invention relates to an environment-friendly type printing colored tape used for a cable protecting bush surface. The environment-friendly type printing colored tape comprises a basic tape layer and a heat transferring printing layer which is attached to one surface of a basic tape and is continuously distributed, wherein the basic tape layer is made of polyethylene glycol terephthalate. The heat transferring printing layer comprises the following materials: titanium dioxide, acetic ether, acrylic resin or epoxy resin or ethyl acetate resin, dibutyl ester and acrylic acid mercerizing paint. The breaking strength of the printing colored tape is more than or equal to 120MPa and the breaking elongation of the printing colored tape is more than or equal to 25%. Alcohol cotton with the mol concentration of 20% is used for continuously and repeatedly wiping characters formed on the surface of a cable by the printing colored tape for 20 times under 10 Newton of pressure, and the characters printed on the cable protecting bush surface do not fade. The adhesion force between the printing colored tape and a cable protecting bush is greater; the product is simple to produce, the cost is lower and the product is more environment-friendly.

Description

For the environment-friendly type printing copying ribbon on cable jacket surface
The divisional application of the application for a patent for invention of " a kind of environment-friendly type printing copying ribbon for cable jacket surface " that the present invention is application number is 201310049826.2, the applying date, to be February 8, denomination of invention in 2013 be.
Technical field
The invention belongs to cable material technical field, particularly relate to a kind of environment-friendly type printing copying ribbon for cable jacket surface.
Background technology
Conveniently production management, construction management etc., therefore, needs the length identifying cable exactly, and in prior art, conventional is ink lettering and colour band lettering; Ink lettering needs special ink jet printer, and needs detergent for ink, and cost is relatively high, and affects environment.Existing printing copying ribbon is relative with the adhesive force of cable jacket poor, is difficult to meet the permanent requirement identified, therefore, has brought inconvenience.
Summary of the invention
In order to solve the problem, the invention provides a kind of environment-friendly type printing copying ribbon for cable jacket surface, it can solve the unstable problem of colour band lettering in prior art.
The present invention realizes by the following technical solutions: a kind of environment-friendly type printing copying ribbon for cable jacket surface, and it includes a baseband layer and to be attached on base band surface and the heat of continuous distributed transfer lettering layer.The material of described baseband layer is PETG.Following material is included: titanium dioxide, ethyl acetate, acrylic resin or epoxy resin or ethyl acetate resin, dibutyl ester and acrylic acid silk gloss paint in described heat transfer lettering layer; Fracture strength >=the 120MPa of described printing copying ribbon, elongation at break >=25%.The word described printing copying ribbon being imprinted on to cable surface formation adopts molar concentration to be the alcohol swab of 20%, and continuous wiping repeatedly 20 times under 10 newton's pressure, cable jacket surface lettering is colour-fast.
In the material of the heat transfer lettering layer of the above-mentioned environment-friendly type printing copying ribbon for cable jacket surface, by weight percentage, titanium dioxide is 5% ~ 22%, ethyl acetate is 50% ~ 80%, acrylic resin or epoxy resin or ethyl acetate resin are 5% ~ 10%, dibutyl ester is 5% ~ 10%, and acrylic acid silk gloss paint is 3% ~ 8%.
The thickness of the baseband layer of the above-mentioned environment-friendly type printing copying ribbon for cable jacket surface is 0.08 ~ 0.5mm.
The thickness of the heat transfer lettering layer of the above-mentioned environment-friendly type printing copying ribbon for cable jacket surface is 0.05 ~ 0.2mm.
The above-mentioned environment-friendly type printing copying ribbon for cable jacket surface adopts following methods to be made:
The first step: weigh: by weight percentage, taking titanium dioxide is 5% ~ 22%, and ethyl acetate is 50% ~ 80%, acrylic resin or epoxy resin or ethyl acetate resin are 5% ~ 10%, and dibutyl ester is 5% ~ 10%, and acrylic acid silk gloss paint is 3% ~ 8%.
Second step: dissolve: first heat ethyl acetate to 50 ~ 70 DEG C that the first step takes, again the titanium dioxide that the first step takes inserted ethyl acetate and stir and make fully to dissolve to obtain initial soln, then the acrylic resin taken in the first step or epoxy resin or ethyl acetate resin and butyl ester and acrylic acid silk gloss paint are inserted initial soln, make it fully stir in 50 ~ 70 DEG C to make their dissolve to obtain semi-finished product solution.
3rd step: baseband layer is released, on baseband layer, be coated with the semi-finished product solution being covered with 0.05 ~ 0.2mm thickness simultaneously equably, and make its continuous drying at 60 ~ 80 DEG C, drying time is 5 ~ 10 minutes, forms environment-friendly type printing copying ribbon semi-finished product; The thickness of described baseband layer is 0.08 ~ 0.5mm.
4th step: cut: the environment-friendly type printing copying ribbon semi-finished product the 3rd step obtained cut into the width of needs, forms finished product.5th step: winding: gained finished product in the 4th step is wound on dish core and forms the environment-friendly type printing copying ribbon being used for cable jacket surface.
The material non-toxic of the printing copying ribbon in the present invention, free from extraneous odour, therefore very environmental protection.Use the present invention to have printing copying ribbon, the firmness of the lettering on cable surface is higher, and the present invention makes simply, and cost is lower.
The present invention has following main beneficial effect: the adhesive force of printing copying ribbon and cable jacket is larger, and production is simple, and cost is lower, and product is environmental protection more.
Accompanying drawing explanation
Fig. 1 is the perspective view after the present invention dissects.
Detailed description of the invention
Below in conjunction with accompanying drawing, the present invention is described in further detail.
(embodiment 1)
Ask for an interview Fig. 1, a kind of environment-friendly type printing copying ribbon for cable jacket surface, it includes a baseband layer 1, is attached on base band surface and the heat of continuous distributed transfer lettering layer 2.The material of described baseband layer is PETG, includes following material: titanium dioxide, ethyl acetate, acrylic resin or epoxy resin or ethyl acetate resin, dibutyl ester, acrylic acid silk gloss paint in described heat transfer lettering layer.The fracture strength of described printing copying ribbon is 180MPa, elongation at break is 35%.The word described printing copying ribbon being imprinted on to cable surface formation adopts molar concentration to be the alcohol swab of 20%, and continuous wiping repeatedly 20 times under 10 newton's pressure, cable jacket surface lettering is colour-fast.In the material of described heat transfer lettering layer, by weight percentage, titanium dioxide is 5%, and ethyl acetate is 70%, and acrylic resin or epoxy resin or ethyl acetate resin are 10%, and dibutyl ester is 10%, and acrylic acid silk gloss paint is 5%.
(embodiment 2)
Please refer to Fig. 1, a kind of environment-friendly type printing copying ribbon for cable jacket surface, it includes a baseband layer 1, is attached on base band surface and the heat of continuous distributed transfer lettering layer 2.The material of described baseband layer is PETG.Following material is included: titanium dioxide, ethyl acetate, acrylic resin or epoxy resin or ethyl acetate resin, dibutyl ester, acrylic acid silk gloss paint in described heat transfer lettering layer.The fracture strength of described printing copying ribbon is 150MPa, elongation at break is 23%.The word described printing copying ribbon being imprinted on to cable surface formation adopts molar concentration to be the alcohol swab of 20%, and continuous wiping repeatedly 20 times under 10 newton's pressure, cable jacket surface lettering is colour-fast.In the material of described heat transfer lettering layer, by weight percentage, titanium dioxide is 22%, and ethyl acetate is 52%, and acrylic resin or epoxy resin or ethyl acetate resin are 8%, and dibutyl ester is 10%, and acrylic acid silk gloss paint is 8%.
(embodiment 3)
Please refer to Fig. 1, a kind of environment-friendly type printing copying ribbon for cable jacket surface, it includes a baseband layer 1, is attached on base band surface and the heat of continuous distributed transfer lettering layer 2.The material of described baseband layer is PETG.Following material is included: titanium dioxide, ethyl acetate, acrylic resin or epoxy resin or ethyl acetate resin, dibutyl ester, acrylic acid silk gloss paint in described heat transfer lettering layer.The fracture strength of described printing copying ribbon is 140MPa, elongation at break is 28%.The word described printing copying ribbon being imprinted on to cable surface formation adopts molar concentration to be the alcohol swab of 20%, and continuous wiping repeatedly 20 times under 10 newton's pressure, cable jacket surface lettering is colour-fast.In the material of described heat transfer lettering layer, by weight percentage, titanium dioxide is 15%, and ethyl acetate is 69%, and acrylic resin or epoxy resin or ethyl acetate resin are 5%, and dibutyl ester is 5%, and acrylic acid silk gloss paint is 6%.
Through applicant's repetition test, as long as have the printing copying ribbon of following characteristics, object of the present invention can be reached.
For the environment-friendly type printing copying ribbon on cable jacket surface, it includes a baseband layer 1, is attached on base band surface and the heat of continuous distributed transfer lettering layer 2.The material of described baseband layer 1 is PETG.Following material is included: titanium dioxide, ethyl acetate, acrylic resin or epoxy resin or ethyl acetate resin, dibutyl ester, acrylic acid silk gloss paint in described heat transfer lettering layer 2.Fracture strength >=the 120MPa of described printing copying ribbon, elongation at break >=25%.The word described printing copying ribbon being imprinted on to cable surface formation adopts molar concentration to be the alcohol swab of 20%, and continuous wiping repeatedly 20 times under 10 newton's pressure, cable jacket surface lettering is colour-fast.
In the material of the heat transfer lettering layer 2 of the above-mentioned environment-friendly type printing copying ribbon for cable jacket surface, by weight percentage, titanium dioxide is 5% ~ 22%, ethyl acetate is 50% ~ 80%, acrylic resin or epoxy resin or ethyl acetate resin are 5% ~ 10%, dibutyl ester is 5% ~ 10%, and acrylic acid silk gloss paint is 3% ~ 8%.
The thickness of the baseband layer 1 of the above-mentioned environment-friendly type printing copying ribbon for cable jacket surface is 0.08 ~ 0.5mm.
The thickness of the heat transfer lettering layer 2 of the above-mentioned environment-friendly type printing copying ribbon for cable jacket surface is 0.05 ~ 0.2mm.
The above-mentioned environment-friendly type printing copying ribbon for cable jacket surface adopts following methods to be made:
The first step: weigh: by weight percentage, taking titanium dioxide is 5% ~ 22%, and ethyl acetate is 50% ~ 80%, acrylic resin or epoxy resin or ethyl acetate resin are 5% ~ 10%, and dibutyl ester is 5% ~ 10%, and acrylic acid silk gloss paint is 3% ~ 8%.
Second step: dissolve: first heat ethyl acetate to 50 ~ 70 DEG C that the first step takes, again the titanium dioxide that the first step takes inserted ethyl acetate and stir and make fully to dissolve to obtain initial soln, then the acrylic resin taken in the first step or epoxy resin or ethyl acetate resin and butyl ester and acrylic acid silk gloss paint are inserted initial soln, make it fully stir in 50 ~ 70 DEG C to make their dissolve to obtain semi-finished product solution.
3rd step: released by baseband layer, on baseband layer, be coated with the semi-finished product solution being covered with 0.05 ~ 0.2mm thickness simultaneously equably, and make its continuous drying at 60 ~ 80 DEG C, drying time is 5 ~ 10 minutes, forms environment-friendly type printing copying ribbon semi-finished product.The thickness of described baseband layer is 0.08 ~ 0.5mm.
4th step: cut: the environment-friendly type printing copying ribbon semi-finished product the 3rd step obtained cut into the width of needs, forms finished product.
5th step: winding: gained finished product in the 4th step is wound on dish core and forms the environment-friendly type printing copying ribbon being used for cable jacket surface.
The material non-toxic of the printing copying ribbon in the present invention, free from extraneous odour, therefore very environmental protection.Use the present invention to have printing copying ribbon, the firmness of the lettering on cable surface is higher, and the present invention makes simply, and cost is lower.
The present invention has following main beneficial effect: the adhesive force of printing copying ribbon and cable jacket is larger, and production is simple, and cost is lower, and product is environmental protection more.
The present invention is not limited to above-mentioned preferred forms, and should be appreciated that design of the present invention can be implemented to use by other various forms, they drop in protection scope of the present invention equally.

Claims (1)

1., for the environment-friendly type printing copying ribbon on cable jacket surface, it includes a baseband layer (1) and to be attached on base band surface and the heat of continuous distributed transfer lettering layer (2); It is characterized in that: the material of described baseband layer (1) is PETG; Following material is included: titanium dioxide, ethyl acetate, acrylic resin or epoxy resin or ethyl acetate resin, dibutyl ester, acrylic acid silk gloss paint in described heat transfer lettering layer (2); Fracture strength >=the 120MPa of described printing copying ribbon, elongation at break >=25%; The word described printing copying ribbon being imprinted on to cable surface formation adopts molar concentration to be the alcohol swab of 20%, continuous wiping repeatedly 20 times under 10 newton's pressure, and cable jacket surface lettering is colour-fast; In the material of described heat transfer lettering layer (2), by weight percentage, titanium dioxide is 5%, and ethyl acetate is 70%, and acrylic resin or epoxy resin or ethyl acetate resin are 10%, and dibutyl ester is 10%, and acrylic acid silk gloss paint is 5%; The thickness of described baseband layer (1) is 0.08 ~ 0.5mm; The thickness of described heat transfer lettering layer (2) is 0.05 ~ 0.2mm.
CN201410655415.2A 2013-02-08 2013-02-08 Environment-friendly type printing copying ribbon for cable jacket surface Expired - Fee Related CN104476932B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410655415.2A CN104476932B (en) 2013-02-08 2013-02-08 Environment-friendly type printing copying ribbon for cable jacket surface

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201410655415.2A CN104476932B (en) 2013-02-08 2013-02-08 Environment-friendly type printing copying ribbon for cable jacket surface
CN201310049826.2A CN103085510B (en) 2013-02-08 2013-02-08 Environment-friendly printing ribbon for surface of cable sheath

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN201310049826.2A Division CN103085510B (en) 2013-02-08 2013-02-08 Environment-friendly printing ribbon for surface of cable sheath

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CN104476932A true CN104476932A (en) 2015-04-01
CN104476932B CN104476932B (en) 2016-11-30

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110128876A (en) * 2019-05-23 2019-08-16 新乡市新贝尔信息材料有限公司 A kind of synthetic method for the ink ribbon and its modified polyacrylate resin printing resistance to boiling suitable for infusion bag

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4666320A (en) * 1983-10-15 1987-05-19 Sony Corporation Ink ribbon for sublimation transfer type hard copy
CN1052450A (en) * 1990-11-29 1991-06-26 天津光电通信公司 At thermosensitive ribbon for transfer print surface of non-absorbent matter
CN1647941A (en) * 2005-03-04 2005-08-03 中国乐凯胶片集团公司 Heat transfer printing color ribbon and its preparing method
CN101249763A (en) * 2008-02-03 2008-08-27 深圳市墨库数码耗材有限公司 Thermal sublimation digital image ribbon and method for making same
US20100291326A1 (en) * 2009-05-15 2010-11-18 Sony Corporation Thermal transfer sheet and ink ribbon
CN102381063A (en) * 2011-07-26 2012-03-21 河北工程大学 Heat-transfer-printing color tape capable of being printed with high-temperature-resistant marks and manufacturing method thereof
CN102658735A (en) * 2012-05-31 2012-09-12 焦作市卓立烫印材料有限公司 Flat-pressing resin-based bar code printing thermal transfer ribbon and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4666320A (en) * 1983-10-15 1987-05-19 Sony Corporation Ink ribbon for sublimation transfer type hard copy
CN1052450A (en) * 1990-11-29 1991-06-26 天津光电通信公司 At thermosensitive ribbon for transfer print surface of non-absorbent matter
CN1647941A (en) * 2005-03-04 2005-08-03 中国乐凯胶片集团公司 Heat transfer printing color ribbon and its preparing method
CN101249763A (en) * 2008-02-03 2008-08-27 深圳市墨库数码耗材有限公司 Thermal sublimation digital image ribbon and method for making same
US20100291326A1 (en) * 2009-05-15 2010-11-18 Sony Corporation Thermal transfer sheet and ink ribbon
CN102381063A (en) * 2011-07-26 2012-03-21 河北工程大学 Heat-transfer-printing color tape capable of being printed with high-temperature-resistant marks and manufacturing method thereof
CN102658735A (en) * 2012-05-31 2012-09-12 焦作市卓立烫印材料有限公司 Flat-pressing resin-based bar code printing thermal transfer ribbon and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110128876A (en) * 2019-05-23 2019-08-16 新乡市新贝尔信息材料有限公司 A kind of synthetic method for the ink ribbon and its modified polyacrylate resin printing resistance to boiling suitable for infusion bag

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C41 Transfer of patent application or patent right or utility model
CB03 Change of inventor or designer information

Inventor after: Dang Xiuzhan

Inventor after: Zhang Meng

Inventor after: Wang Wei

Inventor after: Liu Huashe

Inventor after: Liu Hao

Inventor after: Chen Lin

Inventor after: Wang Ran

Inventor before: Hu Yan

COR Change of bibliographic data
TA01 Transfer of patent application right

Effective date of registration: 20160928

Address after: 274032 north of Zhonghua East Road, Heze City, Shandong province (opposite bank of China)

Applicant after: Heze Power Supply Company, State Grid Shandong Electric Power Co., Ltd.

Applicant after: CHENGWU POWER SUPPLY COMPANY, STATE GRID SHANDONG ELECTRIC POWER CO., LTD.

Address before: 239001 room No. 1, science and technology innovation center, No. 82 West Garden Road, Anhui, Chuzhou, China

Applicant before: CHUZHOU HUAZUN ELECTRICAL SCIENCE & TECHNOLOGY CO., LTD.

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20161130

Termination date: 20180208

CF01 Termination of patent right due to non-payment of annual fee