CN104476861A - Self-adhesive type ceramic composite belt and preparation method thereof - Google Patents
Self-adhesive type ceramic composite belt and preparation method thereof Download PDFInfo
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- CN104476861A CN104476861A CN201410759213.2A CN201410759213A CN104476861A CN 104476861 A CN104476861 A CN 104476861A CN 201410759213 A CN201410759213 A CN 201410759213A CN 104476861 A CN104476861 A CN 104476861A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B25/08—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/20—Layered products comprising a layer of natural or synthetic rubber comprising silicone rubber
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/55—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/28—Protection against damage caused by moisture, corrosion, chemical attack or weather
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
- B32B2307/7265—Non-permeable
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a self-adhesive type ceramic composite belt. The self-adhesive type ceramic composite belt comprises a self-adhesive ceramic glue layer, a reinforcing layer and an isolating layer, wherein the reinforcing layer and the isolating layer are respectively positioned at the two sides of the self-adhesive ceramic glue layer; the self-adhesive ceramic glue layer and the reinforcing layer are fixed together; the self-adhesive ceramic glue layer is prepared from the following components in parts by weight: 60-100 parts of silicon rubber, 20-100 parts of white carbon black, 20-120 parts of ceramic powder, 1-20 parts of one or more of boric acid, boric anhydride, borate, polyborosiloxane or a boron-containing polymer, 1-20 parts of silicone oil, 0.00001-10 parts of platinum complex and/or platinum compounds, and 0.1-10 parts of a coupling agent. The self-adhesive type ceramic composite belt disclosed by the invention has self-adhesion, is mutually lapped and adhered during winding to achieve good sealing effects, has good moisture-proof and waterproof performances; during production, an isolating film is only needed to be added when the composite belt product is rolled, so that the process is simple and the production is easy.
Description
Technical field
The present invention relates to a kind of composite band, particularly relating to a kind of self-adhering-type can porcelain composite band and preparation method thereof.
Background technology
Current fire protection flame retarding cable mostly adopts magnesium oxide mineral insulation or mica tape to be wound around and realizes fire-resistant function.
But magnesia mineral hot-face insulation cable exists following shortcoming in Manufacture and application: the first, and equipment cost is high, magnesia mineral hot-face insulation cable needs special manufacturing and processing equipment, and expensive, equipment cost is higher; The second, production cost is high, and because the outer jacket of magnesia mineral hot-face insulation cable is full copper, the price of copper is high, makes production cost higher, in practical application, by restriction to a certain extent; 3rd, laying installation and the use of production and processing, transport, circuit are inconvenient, because copper sheath magnesia mineral fire-proof insulation cable has particular/special requirement in the laying installation and use procedure of production and processing, transport, circuit, production and processing as magnesia mineral fire-proof insulation cable can not easy making process image height molecular material, laying installation very complicated, cost of raw material cost is high, be difficult to extensive popularization and application, particularly civil buildings etc., could not obtain extensive, general application up to now.
And the fire-resisting cable that mica tape is wound around, in process of production, need multi-lay winding, due to the restriction of process conditions, overlap joint defect does not possess water resistance often to cause overlapping the slot place to occur, adds the easy embrittlement of mica tape after burning, comes off, reduce fire-resistant effect to a great extent, cause line short, thus be difficult to ensure electric power, communication in the case of fire safe and smooth.Mica tape sealing is also bad, and often fluorine-containing in material, does not meet the requirement of some halogen-free cables.
Currently marketed ceramic composite band product many employings one side ceramic glue and glass-fiber-fabric are composited, although have certain tack between ceramic glue, but the tack that ceramic glue face and glass cloth cover overlap mutually when wrapped is very faint, substantially not there is good sealing, do not have the effect of water-fast protection against the tide.
Summary of the invention
The object of the present invention is to provide a kind of be easy to processing, production cost self-adhering-type that is low, that have fire-resistant function can porcelain composite band, preparation method and its usage.
For achieving the above object, the invention provides a kind of self-adhering-type can porcelain composite band, comprise tack pottery glue-line, strengthening course and separation layer, described strengthening course and separation layer divide occupy described tack pottery glue-line both sides, described tack pottery glue-line and strengthening course are fixed together, and the component of described tack pottery glue-line comprises by mass:
Silicon rubber 60-100 part;
White carbon 20-100 part;
Vitrified powder 20-120 part;
One or more 1-20 parts in boric acid, boric anhydride, borate, poly-polyborosiloxane or boron polymer;
Silicone oil 1-20 part;
Platinum complex and/or platinum compounds calculate 0.00001 ~ 10 part with platinum;
Coupling agent 0.1-10 part;
Vulcanizing agent 0.1 ~ 10 part;
0 ~ 10 part, antioxidant.
Preferably, when described platinum complex or platinum compounds are solution morphology, the solution of described platinum complex to be platinum containing amount the be platinum complex of 100ppm to 10000ppm, described platinum compounds is the platinum compounds of 100 to 10000ppm.
Preferably, described platinum complex is the one or several in the aqueous isopropanol of chloroplatinic acid, diethyl phthalate co-ordination complex, platinum-tetrahydrofuran complex, methyl vinyl silicone co-ordination complex, ethylene methacrylic polymerization of olefin using catalyst platinum catalyst, platinum vinyl complex compound, vinylsiloxane complex compound, chloroplatinic acid-octanol complex catalyst or chloroplatinic acid-divinyl tetramethyl disiloxane.
Preferably, described platinum compounds is the one or several in platinum dioxide, chloroplatinic acid or platinum catalyst.
Preferably, described separation layer is that polyolefine material is made.
Preferably, described polyolefin is selected from the one or several in following material: ethylene-vinyl acetate copolymer (EVA), ethylene-methyl acrylate copolymer (EMA), ethylene-ethyl acrylate copolymer (EEA), ethylene-butyl acrylate copolymer (EBA), low density polyethylene (LDPE) (LDPE), LLDPE (LLDPE), high density polyethylene (HDPE) (HDPE).
Preferably, described silicon rubber is the one or several in dimethyl silicone rubber, methyl vinyl silicone rubber or methyl phenyl vinyl silicone rubber.
Preferably, described coupling agent be in silane coupler, titanate coupling agent or aluminium titanium composite coupler any one or several.
Preferably, described Vitrified powder is the one or several in oxygen compound, oxysalt or glass dust, and/or with a kind of or several mineral matter for main component in oxygen compound, oxysalt or glass dust.
The present invention also provides a kind of self-adhering-type can the preparation method of porcelain composite band, it is characterized in that, comprises the following steps:
1. described silicon rubber 60-100 part, white carbon 20-100 part, Vitrified powder 20-120 part, silicone oil 1-20 part, coupling agent 0.1-10 part, 0 ~ 10 part, antioxidant is mixing in kneader;
2. vacuumize kneader, vacuum remains on-0.1--0.04Mpa, and temperature keeps 100-200 DEG C;
3. in kneader, add platinum complex and/or platinum compounds calculate 0.00001 ~ 10 part with platinum and tackifier 1-20 part carries out kneadings formation bulk tack ceramic rubber;
4. described bulk tack ceramic rubber is shifted out kneader, cooling, after refining opened by the vulcanizing agent adding 0.1 ~ 10 part in mill, namely form tack Ceramic silicon rubber;
5. by step 4. in formed tack Ceramic silicon rubber on multi-rolling mill through calendering, sulfuration, the rolling of interpolation separation layer, namely cutting obtains tack can porcelain composite band.
Self-adhering-type of the present invention porcelain composite band can have tack, and connect at winding phase lap and stick together, good sealing effect, possesses good moistureproof and waterproof performance, and only need add barrier film when composite band product rolling when producing, and technique is simple, is easy to produce.
Detailed description of the invention
By describing technology contents of the present invention, formula rate in detail, being realized object and effect, be explained in detail below in conjunction with embodiment.
Self-adhering-type of the present invention porcelain composite band can comprise tack pottery glue-line and separation layer, comprise tack pottery glue-line, strengthening course and separation layer, described strengthening course and separation layer divide occupy described tack pottery glue-line both sides, described tack pottery glue-line and strengthening course are fixed together, and the component of described tack pottery glue-line comprises by mass:
Silicon rubber 60-100 part;
White carbon 20-100 part;
Vitrified powder 20-120 part;
One or more 1-20 parts in boric acid, boric anhydride, borate, poly-polyborosiloxane or boron polymer;
Silicone oil 1-20 part;
Platinum complex and/or platinum compounds calculate 0.00001 ~ 10 part with platinum;
Coupling agent 0.1-10 part;
Vulcanizing agent 0.1 ~ 10 part;
0 ~ 10 part, antioxidant.
Preferably, when described platinum complex or platinum compounds are solution morphology, the solution of described platinum complex to be platinum containing amount the be platinum complex of 100ppm to 10000ppm, described platinum compounds is the platinum compounds of 100 to 10000ppm.
Preferably, described platinum complex is the one or several in the aqueous isopropanol of chloroplatinic acid, diethyl phthalate co-ordination complex, platinum-tetrahydrofuran complex, methyl vinyl silicone co-ordination complex, ethylene methacrylic polymerization of olefin using catalyst platinum catalyst, platinum vinyl complex compound, vinylsiloxane complex compound, chloroplatinic acid-octanol complex catalyst or chloroplatinic acid-divinyl tetramethyl disiloxane.
Preferably, described platinum compounds is the one or several in platinum dioxide, chloroplatinic acid or platinum catalyst.
Preferably, described separation layer is that polyolefine material is made.
Preferably, described polyolefin is selected from the one or several in following material: ethylene-vinyl acetate copolymer (EVA), ethylene-methyl acrylate copolymer (EMA), ethylene-ethyl acrylate copolymer (EEA), ethylene-butyl acrylate copolymer (EBA), ethylene-propylene diene copolymer (EPDM), low density polyethylene (LDPE) (LDPE), LLDPE (LLDPE), high density polyethylene (HDPE) (HDPE).
Preferably, described silicon rubber is the one or several in dimethyl silicone rubber, methyl vinyl silicone rubber or methyl phenyl vinyl silicone rubber.
Preferably, described coupling agent be in silane coupler, titanate coupling agent or aluminium titanium composite coupler any one or several.
Preferably, described Vitrified powder is the one or several in oxygen compound, oxysalt or glass dust, and/or with a kind of or several mineral matter for main component in oxygen compound, oxysalt or glass dust.
The present invention also provides a kind of self-adhering-type can the preparation method of porcelain composite band, it is characterized in that, comprises the following steps:
1. described silicon rubber 60-100 part, white carbon 20-100 part, Vitrified powder 20-120 part, silicone oil 1-20 part, coupling agent 0.1-10 part, 0 ~ 10 part, antioxidant is mixing in kneader;
2. vacuumize kneader, vacuum remains on-0.1--0.04Mpa, and temperature keeps 100-200 DEG C;
3. in kneader, add platinum complex and/or platinum compounds calculate 0.00001 ~ 10 part with platinum and tackifier 1-20 part carries out kneadings formation bulk tack ceramic rubber;
4. described bulk tack ceramic rubber is shifted out kneader, cooling, after refining opened by the vulcanizing agent adding 0.1 ~ 10 part in mill, namely form tack Ceramic silicon rubber;
5. by step 4. in formed tack Ceramic silicon rubber on multi-rolling mill through calendering, sulfuration, the rolling of interpolation separation layer, namely cutting obtains tack can porcelain composite band.
The self-adhering-type below describing present embodiment can several specific embodiments of porcelain composite band, unless otherwise indicated, all numbers all by weight:
Embodiment 1
By weight, get 100 parts of silicon rubber, 20 parts of white carbons, 20 parts of Vitrified powders, 10 parts of boric anhydrides, 10 parts of silicone oil, the aqueous isopropanol of chloroplatinic acid of 100 parts of 1000ppm, 3 parts of KH560 coupling agents, 1 part of vulcanizing agent, 2 parts of sulfuration dipropionic acid two lauryls, according to above-mentioned self-adhering-type can the preparation method of porcelain composite band obtain self-adhering-type can porcelain composite band.
Embodiment 2
By weight, get aqueous isopropanol, 3KH560 coupling agent, 4 vulcanizing agents of chloroplatinic acid of 100 parts of silicon rubber, 100 parts of white carbons, 110 parts of Vitrified powders, 18 parts of boric acid, 18 parts of silicone oil, 100 parts of 1000ppm, according to above-mentioned self-adhering-type can the preparation method of porcelain composite band obtain self-adhering-type can porcelain composite band.
Embodiment 3
By weight, get 100 parts of silicon rubber, 50 parts of white carbons, 60 parts of Vitrified powders, 2 parts of boric acid, 1 part of silicone oil, the aqueous isopropanol of chloroplatinic acid of 10 parts of 1000ppm, 1 part of KH560 coupling agent, 2 parts of vulcanizing agents, according to above-mentioned self-adhering-type can the preparation method of porcelain composite band obtain self-adhering-type can porcelain composite band.
Comparative example 1
The difference of comparative example and embodiment 1 is: do not add boric anhydride, and other component, content and preparation method are identical with embodiment 1.
Comparative example 2
The difference of comparative example and embodiment 2 is: do not add boric acid, and other component, content and preparation method are identical with embodiment 2.
Comparative example 3
The difference of comparative example and embodiment 3 is: do not add boric acid, and other component, content and preparation method are identical with embodiment 3.
By known for the test of embodiment 1 to embodiment 3 and its corresponding comparative example, composite band prepared by embodiment 1 to embodiment 3 has good tack, and connect at winding phase lap and stick together, good sealing effect, possesses good moistureproof and waterproof performance; And the composite band that comparative example 1 to comparative example 3 makes is without tack, be wound around when phase lap connects not tight, waterproof and dampproof poor-performing.In addition, self-adhering-type of the present invention porcelain composite band can transform formation housing when meeting and burning erosion, and this housing can stop burning away of flame, plays the effect of isolated extraneous flame, thus protection is not damaged by the object burnt.
The present invention is not limited to above-mentioned detailed description of the invention, and those skilled in the art also can make multiple change accordingly, but to be anyly equal to the present invention or similar change all should be encompassed in the scope of the claims in the present invention.
Claims (10)
1. a self-adhering-type can porcelain composite band, comprise tack pottery glue-line, strengthening course and separation layer, described strengthening course and separation layer divide occupy described tack pottery glue-line both sides, described tack pottery glue-line and strengthening course are fixed together, and it is characterized in that: the component of described tack pottery glue-line comprises by mass:
Silicon rubber 60-100 part;
White carbon 20-100 part;
Vitrified powder 20-120 part;
One or more 1-20 parts in boric acid, boric anhydride, borate, poly-polyborosiloxane or boron polymer;
Silicone oil 1-20 part;
Platinum complex and/or platinum compounds calculate 0.00001 ~ 10 part with platinum;
Coupling agent 0.1-10 part;
Vulcanizing agent 0.1 ~ 10 part;
0 ~ 10 part, antioxidant.
2. self-adhering-type as claimed in claim 1 can porcelain composite band, it is characterized in that: when described platinum complex or platinum compounds are solution morphology, the solution of described platinum complex to be platinum containing amount the be platinum complex of 100ppm to 10000ppm, described platinum compounds is the platinum compounds of 100 to 10000ppm.
3. self-adhering-type as claimed in claim 1 can porcelain composite band, it is characterized in that: described platinum complex is the one or several in the aqueous isopropanol of chloroplatinic acid, diethyl phthalate co-ordination complex, platinum-tetrahydrofuran complex, methyl vinyl silicone co-ordination complex, ethylene methacrylic polymerization of olefin using catalyst platinum catalyst, platinum vinyl complex compound, vinylsiloxane complex compound, chloroplatinic acid-octanol complex catalyst or chloroplatinic acid-divinyl tetramethyl disiloxane.
4. self-adhering-type as claimed in claim 1 can porcelain composite band, it is characterized in that: described platinum compounds is the one or several in platinum dioxide, chloroplatinic acid or platinum catalyst.
5. self-adhering-type as claimed in claim 1 can porcelain composite band, it is characterized in that: described separation layer is that polyolefine material is made.
6. self-adhering-type as claimed in claim 5 can porcelain composite band, it is characterized in that: described polyolefin is selected from the one or several in following material: ethylene-vinyl acetate copolymer (EVA), ethylene-methyl acrylate copolymer (EMA), ethylene-ethyl acrylate copolymer (EEA), ethylene-butyl acrylate copolymer (EBA), low density polyethylene (LDPE) (LDPE), LLDPE (LLDPE), high density polyethylene (HDPE) (HDPE).
7. self-adhering-type as claimed in claim 1 can porcelain composite band, it is characterized in that: described silicon rubber is the one or several in dimethyl silicone rubber, methyl vinyl silicone rubber or methyl phenyl vinyl silicone rubber.
8. self-adhering-type as claimed in claim 1 can porcelain composite band, it is characterized in that: described coupling agent be in silane coupler, titanate coupling agent or aluminium titanium composite coupler any one or several.
9. self-adhering-type as claimed in claim 1 can porcelain composite band, it is characterized in that: described Vitrified powder is the one or several in oxygen compound, oxysalt or glass dust, and/or with a kind of or several mineral matter for main component in oxygen compound, oxysalt or glass dust.
10. self-adhering-type as claimed in any one of claims 1-9 wherein can the preparation method of porcelain composite band, it is characterized in that, comprises the following steps:
1. described silicon rubber 60-100 part, white carbon 20-100 part, Vitrified powder 20-120 part, silicone oil 1-20 part, coupling agent 0.1-10 part, 0 ~ 10 part, antioxidant is mixing in kneader;
2. vacuumize kneader, vacuum remains on-0.1--0.04Mpa, and temperature keeps 100-200 DEG C;
3. in kneader, add platinum complex and/or platinum compounds carry out kneadings formation bulk tack ceramic rubber with platinum one or more 1-20 parts calculated in 0.00001 ~ 10 part and boric acid, boric anhydride, borate, poly-polyborosiloxane or boron polymer;
4. described bulk tack ceramic rubber is shifted out kneader, cooling, after refining opened by the vulcanizing agent adding 0.1 ~ 10 part in mill, namely form tack Ceramic silicon rubber;
5. by step 4. in formed tack Ceramic silicon rubber on multi-rolling mill through calendering, sulfuration, the rolling of interpolation separation layer, namely cutting obtains tack can porcelain composite band.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410759213.2A CN104476861A (en) | 2014-12-10 | 2014-12-10 | Self-adhesive type ceramic composite belt and preparation method thereof |
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| CN201410759213.2A CN104476861A (en) | 2014-12-10 | 2014-12-10 | Self-adhesive type ceramic composite belt and preparation method thereof |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105462486A (en) * | 2015-12-09 | 2016-04-06 | 安徽都邦电器有限公司 | Silicone rubber fire-proof high-voltage-resistant insulated wire and preparation method thereof |
| CN106433088A (en) * | 2016-12-16 | 2017-02-22 | 安徽亚兰密封件有限公司 | High-flame-retardance rubber sealing member and preparation method thereof |
| CN108297507A (en) * | 2017-12-29 | 2018-07-20 | 常州市沃科科技有限公司 | A kind of superhigh temperature insulation heat shock resistance plate and its manufacturing method |
| CN109054665A (en) * | 2018-06-25 | 2018-12-21 | 湖北工业大学 | A kind of metal/plastic composite band preparation method of high-adhesive-strength heat resisting water soaking |
| CN111040455A (en) * | 2019-12-31 | 2020-04-21 | 长缆电工科技股份有限公司 | Corrosion-resistant self-adhesive low-smoke halogen-free fireproof wrapping tape material and preparation method thereof |
| CN111183185A (en) * | 2017-10-10 | 2020-05-19 | 纳米及先进材料研发院有限公司 | Impact protection material and method for manufacturing same |
| CN111430066A (en) * | 2020-01-22 | 2020-07-17 | 湖南华菱线缆股份有限公司 | Low-smoke halogen-free 750 ℃ resistant cable |
| CN111978549A (en) * | 2020-09-02 | 2020-11-24 | 中国科学院长春应用化学研究所 | Boron-containing siloxane and boron-based self-adhesive silicone rubber and preparation method thereof |
| CN112750562A (en) * | 2020-12-29 | 2021-05-04 | 贵州新曙光电缆有限公司 | Flexible mineral insulation fireproof cable |
| CN113402993A (en) * | 2021-06-15 | 2021-09-17 | 中核同辐（长春）辐射技术有限公司 | Ceramic silicone rubber composite belt with mica layer and preparation method thereof |
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| CN106433088A (en) * | 2016-12-16 | 2017-02-22 | 安徽亚兰密封件有限公司 | High-flame-retardance rubber sealing member and preparation method thereof |
| CN111183185A (en) * | 2017-10-10 | 2020-05-19 | 纳米及先进材料研发院有限公司 | Impact protection material and method for manufacturing same |
| CN111183185B (en) * | 2017-10-10 | 2021-12-17 | 纳米及先进材料研发院有限公司 | Impact protection material and method for manufacturing same |
| CN108297507A (en) * | 2017-12-29 | 2018-07-20 | 常州市沃科科技有限公司 | A kind of superhigh temperature insulation heat shock resistance plate and its manufacturing method |
| CN108297507B (en) * | 2017-12-29 | 2021-07-09 | 常州市沃科科技有限公司 | Ultra-high temperature insulation thermal shock resistant plate and manufacturing method thereof |
| CN109054665A (en) * | 2018-06-25 | 2018-12-21 | 湖北工业大学 | A kind of metal/plastic composite band preparation method of high-adhesive-strength heat resisting water soaking |
| CN111040455A (en) * | 2019-12-31 | 2020-04-21 | 长缆电工科技股份有限公司 | Corrosion-resistant self-adhesive low-smoke halogen-free fireproof wrapping tape material and preparation method thereof |
| CN111430066A (en) * | 2020-01-22 | 2020-07-17 | 湖南华菱线缆股份有限公司 | Low-smoke halogen-free 750 ℃ resistant cable |
| CN111978549A (en) * | 2020-09-02 | 2020-11-24 | 中国科学院长春应用化学研究所 | Boron-containing siloxane and boron-based self-adhesive silicone rubber and preparation method thereof |
| CN112750562A (en) * | 2020-12-29 | 2021-05-04 | 贵州新曙光电缆有限公司 | Flexible mineral insulation fireproof cable |
| CN113402993A (en) * | 2021-06-15 | 2021-09-17 | 中核同辐（长春）辐射技术有限公司 | Ceramic silicone rubber composite belt with mica layer and preparation method thereof |
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Effective date of registration: 20160418 Address after: 213200 Jiangsu Province, Changzhou city Jintan District South Second Ring Road No. 1699 Applicant after: Changzhou WellCore Technology Co., Ltd. Address before: 518118 Guangdong province Shenzhen Pingshan New District Industrial Park Road, Lan Jing wal Applicant before: Shenzhen Woer Heat-Shrinkable Material Co., Ltd. Applicant before: Shenzhen Woer Special Cable Co., Ltd. Applicant before: Jintan Woer New Material Co., Ltd. Applicant before: Leting wire industry (Huizhou) Co., Ltd. Applicant before: Huizhou LTK Electronic Cable Co., Ltd. |
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