CN104451721A - Ultrasonic cleaning solution for galvanized sensor - Google Patents
Ultrasonic cleaning solution for galvanized sensor Download PDFInfo
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- CN104451721A CN104451721A CN201410647235.XA CN201410647235A CN104451721A CN 104451721 A CN104451721 A CN 104451721A CN 201410647235 A CN201410647235 A CN 201410647235A CN 104451721 A CN104451721 A CN 104451721A
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- ultrasonic cleaning
- emulsifying agent
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
- C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/10—Other heavy metals
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
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Abstract
The invention discloses an ultrasonic cleaning solution for a galvanized sensor. The ultrasonic cleaning solution comprises the components of an O10 emulsifying agent, an O15 emulsifying agent, sodium hydroxide, a fatty alcohol alcoxyl compound, sodium carbonate, sodium alginate, hydrochloric acid, an additive, a defoaming agent and deionized water, wherein the additive comprises an imidazoline corrosion inhibitor and a DX penetrating agent. The ultrasonic cleaning solution disclosed by the invention is capable of powerfully removing the grease, stains and the like which are positioned on a metal surface by adopting the components. In addition, sodium carbonate can accelerate the cleaning speed of the grease, the stains and the like and has no corrosion on a galvanized metal surface; sodium alginate can remove a free ferrous iron ion and the like; on the one hand, the imidazoline corrosion inhibitor and the DX penetrating agent as additives can form a hydrophobic layer on the metal surface to play a shielding role, so that the formation of acid mist is inhibited, and the over-corrosion of the metal surface is prevented; on the other hand, the additive has preferable functions of wetting, permeation and the like, so that iron rust, an oxidation film and the like are fast dissolved and stripped, and the cleaning time is greatly shortened.
Description
Technical field
The present invention relates to a kind of clean-out system, belong to steel product and material surface treatment industry technical field, particularly a kind of zinc-plated sensor ultrasonic cleaning liquid.
Background technology
The pot galvanize of metal products be the most substantially, one of the most effective anticorrosion process.The metal products that can carry out pot galvanize comprises steel wire, sheet material, coil of strip, steel pipe, structural part and fastening piece etc., and wherein steel wire is an important class.
Steel wire must carry out surface treatment before zinc-plated, to remove the pollutent such as oil, rust, dust that Steel Wire Surface produces depositing, in the process such as thermal treatment, or drawing compound, phosphatize phosphate coat etc. that Steel Wire Surface is originally remaining.Current galvanized steel wire is produced and is mostly used ultrasonic wave to process Steel Wire Surface acting in conjunction in conjunction with lotion, substantially increases cleaning speed, achieves the on-line continuous Rapid Cleaning of steel wire.
Application number disclosed in 22 days January in 2014 is the Chinese invention patent of 201310480611.6, the name of its innovation and creation is called " a kind of plating front surface processing technology of hot-dip galvanizing steel wire ", its technological process of production is: the electrolytic cleaning ~ washing of unwrapping wire one hot water wash ~ ultrasonic cleaning one hot water wash one anacidity, wherein: ultrasonic cleaning is: steel wire hot water wash laggard enter ultrasonic cleaner, carry out ultrasonic cleaning, ultrasonic cleaning solution is weakly alkaline grease-removing agent, and ultrasonic cleaning process parameter is: ultrasonic frequency 25 ~ 40kHz: rinse liquid temperature 40 ~ 60 DEG C.
Above-mentioned ultrasonic cleaning solution is owing to being weakly alkaline grease-removing agent, therefore the oxide compound of the metallic surfaces such as steel wire, facts have proved, be then difficult to remove, be especially dispersed in oxide compound in the microscopic pits of surface of metal product and silicomanganese for that be mingled with alloyed oxide a little with uneven state.
Application number disclosed in 14 days September in 2011 is the Chinese invention patent of 201110065473.6, and the name of its innovation and creation is called " galvanized steel wire ultrasonic cleaning solution and preparation method thereof ".The raw materials used proportioning that calculates by weight of this ultrasonic cleaning solution is: 700 parts, water, sodium hydroxide 90^-120 part, emulsifying agent 2-5 part, the hydrochloric acid of 31-36% concentration 250 ~ 350 parts, acid fog inhibitor 3-7 part that the honest Chemical Co., Ltd. in Shanghai produces: described emulsifying agent is 0-8,0-9,0-10, one in 0-15,0-20,0-30 emulsifying agent.
This patent application, but still exist following not enough:
1. needed for, scavenging period is long, and " acid mist " that cause hydrochloric acid to be formed increases the etching time of metal products matrix, therefore corrosion rate increases.
2. although add acid fog inhibitor, the volatilization of acid mist can be suppressed to a certain extent, press down mist rate low, in acid cleaning process, still there will be " excessive erosion " and " acid mist " phenomenon.Metal products matrix will be caused thus to be corroded, large losses material, and consume excessive hydrochloric acid, and not only shorten hydrochloric acid work-ing life, treatment capacity is reduced, and overflow because of acid mist and cause workshop air quality to be affected, serious harm workman is healthy.
Summary of the invention
The technical problem to be solved in the present invention is for above-mentioned the deficiencies in the prior art, and provides a kind of zinc-plated sensor ultrasonic cleaning liquid, and this zinc-plated sensor ultrasonic cleaning liquid can shorten scavenging period, reduces corrosion.
In addition, the application also provides a kind of zinc-plated sensor ultrasonic cleaning liquid, and this zinc-plated sensor ultrasonic cleaning liquid can suppress the formation of excessive erosion and acid mist, saves material and hydrochloric acid consumption, improves hydrochloric acid work-ing life and environmental protection.
For solving the problems of the technologies described above, the technical solution used in the present invention is:
A kind of zinc-plated sensor ultrasonic cleaning liquid, the component of described zinc-plated sensor ultrasonic cleaning liquid is O10 emulsifying agent, O15 emulsifying agent, sodium hydroxide, fatty alcohol alkyl oxide, sodium carbonate, hydrochloric acid, additive, defoamer and deionized water; The mass parts ratio of its each component is as follows:
O10 emulsifying agent 1-4 part
O15 emulsifying agent 1-4 part
Sodium hydroxide 95-115 part
Fatty alcohol alkyl oxide 1-4 part
Sodium carbonate 1-3 part
Sodium alginate 1-3 part
Hydrochloric acid 200-340 part
Additive 3.5-8.5 part
Defoamer 5-10 part
Deionized water 600-690 part
The component of described additive comprises imidazoline inhibitor and DX permeate agent.
Described defoamer is the one in poly-propadiene, soya-bean oil or peanut oil.
Described defoamer is poly-propadiene.
The mass parts ratio of each component of described zinc-plated sensor ultrasonic cleaning liquid is O10 emulsifying agent 2 parts, O15 emulsifying agent 2 parts, 100 parts, sodium hydroxide, fatty alcohol alkyl oxide 2 parts, 2 parts, sodium carbonate, sodium alginate 2 parts, hydrochloric acid 300 parts, additive 6 parts, defoamer 8 parts and deionized water 600 parts.
The preparation method of described zinc-plated sensor ultrasonic cleaning liquid is:
The first step, is first heated to 85-95 DEG C by part deionized water of 300 wherein, then dissolves in water after the heating by described sodium hydrate solid, O10 emulsifying agent, O15 emulsifying agent and fatty alcohol alkyl oxide;
Second step, in another container, dilutes hydrochloric acid with remaining deionized water;
3rd step, places after room temperature until the sodium hydroxide solution in the first step, adds in the sodium hydroxide solution of the first step, mix the hydrochloric acid soln in second step;
4th step, adds sodium carbonate, sodium alginate, additive, defoamer successively in the mixing solutions of the 3rd step, stirs, leave standstill and obtain this product.
After the present invention adopts said components, there is following beneficial effect:
1. the mixture of O10 emulsifying agent, O15 emulsifying agent and fatty alcohol alkyl oxide can the powerful grease, spot etc. removing metallic surface.Meanwhile, sodium carbonate can accelerate the cleaning speed of grease, spot etc., and corrosion-free to galvanized metal surfaces.
2. sodium alginate can will remove free ferrous ion etc.
3. imidazoline inhibitor and DX permeate agent are as additive, can form one deck hydrophobic layer on the one hand, play the effect of shielding, can suppress the formation of acid mist, prevent metallic surface excessive erosion in metallic surface; On the other hand, the additive of the application has the functions such as wetting and infiltration preferably, makes the rapid solution such as iron rust, oxide film and peels off.Accelerate the speed of cleaning, scavenging period is shortened greatly.
Embodiment
With regard to concrete better embodiment, the present invention is further detailed explanation below.
Embodiment 1
A kind of component of zinc-plated sensor ultrasonic cleaning liquid is O10 emulsifying agent, O15 emulsifying agent, sodium hydroxide, fatty alcohol alkyl oxide, sodium carbonate, hydrochloric acid, additive, defoamer and deionized water; The mass parts ratio of its each component is as follows:
O10 emulsifying agent 1 part
O15 emulsifying agent 1 part
95 parts, sodium hydroxide
Fatty alcohol alkyl oxide 1 part
1 part, sodium carbonate
Sodium alginate 1 part
Hydrochloric acid 200 parts
Additive 3.5 parts
Defoamer 5 parts
Deionized water 600 parts
The component of described additive comprises imidazoline inhibitor and DX permeate agent.
The preparation method of zinc-plated sensor ultrasonic cleaning liquid is:
The first step, is first heated to 85 DEG C by part deionized water of 300 wherein, then dissolves in water after the heating by described sodium hydrate solid, O10 emulsifying agent, O15 emulsifying agent and fatty alcohol alkyl oxide;
Second step, in another container, dilutes hydrochloric acid with remaining deionized water;
3rd step, places after room temperature until the sodium hydroxide solution in the first step, adds in the sodium hydroxide solution of the first step, mix the hydrochloric acid soln in second step;
4th step, adds sodium carbonate, sodium alginate, additive, defoamer successively in the mixing solutions of the 3rd step, stirs, leave standstill and obtain this product.
Embodiment 2
A kind of component of zinc-plated sensor ultrasonic cleaning liquid is O10 emulsifying agent, O15 emulsifying agent, sodium hydroxide, fatty alcohol alkyl oxide, sodium carbonate, hydrochloric acid, additive, defoamer and deionized water; The mass parts ratio of its each component is as follows:
O10 emulsifying agent 2 parts
O15 emulsifying agent 2 parts
100 parts, sodium hydroxide
Fatty alcohol alkyl oxide 2 parts
2 parts, sodium carbonate
Sodium alginate 2 parts
Hydrochloric acid 300 parts
Additive 6 parts
Defoamer 8 parts
Deionized water 600 parts
The component of described additive comprises imidazoline inhibitor and DX permeate agent.
The preparation method of zinc-plated sensor ultrasonic cleaning liquid is:
The first step, is first heated to 90 DEG C by part deionized water of 300 wherein, then dissolves in water after the heating by described sodium hydrate solid, O10 emulsifying agent, O15 emulsifying agent and fatty alcohol alkyl oxide;
Second step, in another container, dilutes hydrochloric acid with remaining deionized water;
3rd step, places after room temperature until the sodium hydroxide solution in the first step, adds in the sodium hydroxide solution of the first step, mix the hydrochloric acid soln in second step;
4th step, adds sodium carbonate, sodium alginate, additive, defoamer successively in the mixing solutions of the 3rd step, stirs, leave standstill and obtain this product.
Embodiment 3
A kind of component of zinc-plated sensor ultrasonic cleaning liquid is O10 emulsifying agent, O15 emulsifying agent, sodium hydroxide, fatty alcohol alkyl oxide, sodium carbonate, hydrochloric acid, additive, defoamer and deionized water; The mass parts ratio of its each component is as follows:
O10 emulsifying agent 3 parts
O15 emulsifying agent 3 parts
110 parts, sodium hydroxide
Fatty alcohol alkyl oxide 3 parts
2.5 parts, sodium carbonate
Sodium alginate 2.5 parts
Hydrochloric acid 320 parts
Additive 7 parts
Defoamer 9 parts
Deionized water 650 parts
The component of described additive comprises imidazoline inhibitor and DX permeate agent.
The preparation method of zinc-plated sensor ultrasonic cleaning liquid is:
The first step, is first heated to 90 DEG C by part deionized water of 300 wherein, then dissolves in water after the heating by described sodium hydrate solid, O10 emulsifying agent, O15 emulsifying agent and fatty alcohol alkyl oxide;
Second step, in another container, dilutes hydrochloric acid with remaining deionized water;
3rd step, places after room temperature until the sodium hydroxide solution in the first step, adds in the sodium hydroxide solution of the first step, mix the hydrochloric acid soln in second step;
4th step, adds sodium carbonate, sodium alginate, additive, defoamer successively in the mixing solutions of the 3rd step, stirs, leave standstill and obtain this product.
Embodiment 4
A kind of component of zinc-plated sensor ultrasonic cleaning liquid is O10 emulsifying agent, O15 emulsifying agent, sodium hydroxide, fatty alcohol alkyl oxide, sodium carbonate, hydrochloric acid, additive, defoamer and deionized water; The mass parts ratio of its each component is as follows:
O10 emulsifying agent 4 parts
O15 emulsifying agent 4 parts
115 parts, sodium hydroxide
Fatty alcohol alkyl oxide 4 parts
3 parts, sodium carbonate
Sodium alginate 3 parts
Hydrochloric acid 340 parts
Additive 8.5 parts
Defoamer 10 parts
Deionized water 690 parts
The component of described additive comprises imidazoline inhibitor and DX permeate agent.
The preparation method of zinc-plated sensor ultrasonic cleaning liquid is:
The first step, is first heated to 95 DEG C by part deionized water of 300 wherein, then dissolves in water after the heating by described sodium hydrate solid, O10 emulsifying agent, O15 emulsifying agent and fatty alcohol alkyl oxide;
Second step, in another container, dilutes hydrochloric acid with remaining deionized water;
3rd step, places after room temperature until the sodium hydroxide solution in the first step, adds in the sodium hydroxide solution of the first step, mix the hydrochloric acid soln in second step;
4th step, adds sodium carbonate, sodium alginate, additive, defoamer successively in the mixing solutions of the 3rd step, stirs, leave standstill and obtain this product.
Clean-out system of the present invention is carried out weight loss test according to the standard of " Uniform Corrosion Method of Laboratory Immersion Test method " GB10124-88, tests corrosion condition, test piece metallic substance used is galvanized sheet iron, and soak time is 1 hour.
Meanwhile, adopt application number in prior art to be the clean-out system of 201110065473.6, its predominant amount is hydrochloric acid 300 parts, and acid fog inhibitor 4 parts, with this as reference examples of the present invention.
Test acquired results is:
| Rust cleaning situation | Press down mist rate (%) | Improve cleaning speed (%) | Inhibition situation (%) | |
| Embodiment 1 | Clean light | 90% | 28% | 80% |
| Embodiment 2 | Clean light | 92% | 40% | 87% |
| Embodiment 3 | Clean light | 91.5% | 35% | 85% |
| Embodiment 4 | Clean light | 91% | 30% | 82% |
| Reference examples | Cleaning, but obfuscation | 70% | Nothing | Nothing |
By above test, visible of the present invention with the obvious advantage, be convenient to be widely used in industrial production.
Claims (5)
1. a zinc-plated sensor ultrasonic cleaning liquid, is characterized in that: the component of described zinc-plated sensor ultrasonic cleaning liquid is O10 emulsifying agent, O15 emulsifying agent, sodium hydroxide, fatty alcohol alkyl oxide, sodium carbonate, sodium alginate, hydrochloric acid, additive, defoamer and deionized water; The mass parts ratio of its each component is as follows:
O10 emulsifying agent 1-4 part
O15 emulsifying agent 1-4 part
Sodium hydroxide 95-115 part
Fatty alcohol alkyl oxide 1-4 part
Sodium carbonate 1-3 part
Sodium alginate 1-3 part
Hydrochloric acid 200-340 part
Additive 3.5-8.5 part
Defoamer 5-10 part
Deionized water 600-690 part
The component of described additive comprises imidazoline inhibitor and DX permeate agent.
2. zinc-plated sensor ultrasonic cleaning liquid according to claim 1, is characterized in that: described defoamer is the one in poly-propadiene, soya-bean oil or peanut oil.
3. zinc-plated sensor ultrasonic cleaning liquid according to claim 2, is characterized in that: described defoamer is poly-propadiene.
4. zinc-plated sensor ultrasonic cleaning liquid according to claim 1, is characterized in that: the mass parts ratio of each component of described zinc-plated sensor ultrasonic cleaning liquid is O10 emulsifying agent 2 parts, O15 emulsifying agent 2 parts, 100 parts, sodium hydroxide, fatty alcohol alkyl oxide 2 parts, 2 parts, sodium carbonate, sodium alginate 2 parts, hydrochloric acid 300 parts, additive 6 parts, defoamer 8 parts and deionized water 600 parts.
5. zinc-plated sensor ultrasonic cleaning liquid according to claim 1, is characterized in that: the preparation method of described zinc-plated sensor ultrasonic cleaning liquid is:
The first step, is first heated to 85-95 DEG C by part deionized water of 300 wherein, then dissolves in water after the heating by described sodium hydrate solid, O10 emulsifying agent, O15 emulsifying agent and fatty alcohol alkyl oxide;
Second step, in another container, dilutes hydrochloric acid with remaining deionized water;
3rd step, places after room temperature until the sodium hydroxide solution in the first step, adds in the sodium hydroxide solution of the first step, mix the hydrochloric acid soln in second step;
4th step, adds sodium carbonate, sodium alginate, additive, defoamer successively in the mixing solutions of the 3rd step, stirs, leave standstill and obtain this product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410647235.XA CN104451721A (en) | 2014-11-14 | 2014-11-14 | Ultrasonic cleaning solution for galvanized sensor |
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| CN201410647235.XA CN104451721A (en) | 2014-11-14 | 2014-11-14 | Ultrasonic cleaning solution for galvanized sensor |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107354469A (en) * | 2017-07-25 | 2017-11-17 | 马鞍山联邦机电工程有限公司 | A kind of magnetic sodium alginate micro ball fixes the compound powder cleaning agent of degradation bacteria and cleaning |
| CN115198261A (en) * | 2022-07-20 | 2022-10-18 | 朝阳市加华电子有限公司 | Underwater outboard cable penetrating metal surface treatment liquid |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107354469A (en) * | 2017-07-25 | 2017-11-17 | 马鞍山联邦机电工程有限公司 | A kind of magnetic sodium alginate micro ball fixes the compound powder cleaning agent of degradation bacteria and cleaning |
| CN115198261A (en) * | 2022-07-20 | 2022-10-18 | 朝阳市加华电子有限公司 | Underwater outboard cable penetrating metal surface treatment liquid |
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