CN104448226A - Foaming agent composition containing 1,2-dichloroethylene - Google Patents

Foaming agent composition containing 1,2-dichloroethylene Download PDF

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Publication number
CN104448226A
CN104448226A CN201410757803.1A CN201410757803A CN104448226A CN 104448226 A CN104448226 A CN 104448226A CN 201410757803 A CN201410757803 A CN 201410757803A CN 104448226 A CN104448226 A CN 104448226A
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Prior art keywords
polyol
foaming agent
agent composotion
foam
arbitrary
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CN201410757803.1A
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Inventor
陈建海
荆忠俊
顾小兵
徐祥松
苏小兵
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Jiangsu Bluestar Green Technology Co Ltd
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Jiangsu Bluestar Green Technology Co Ltd
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Priority to CN201410757803.1A priority Critical patent/CN104448226A/en
Publication of CN104448226A publication Critical patent/CN104448226A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/487—Polyethers containing cyclic groups
    • C08G18/4879—Polyethers containing cyclic groups containing aromatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/145—Halogen containing compounds containing carbon, halogen and hydrogen only only chlorine as halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/10—Water or water-releasing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/16—Unsaturated hydrocarbons
    • C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/18—Binary blends of expanding agents
    • C08J2203/184—Binary blends of expanding agents of chemical foaming agent and physical blowing agent, e.g. azodicarbonamide and fluorocarbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention provides a foaming agent composition comprising 1,2-dichloroethylene and at least one selected from polyol or polyhydroxy compounds, wherein the content of 1,2-dichloroethylene is more than 1 mol% and not more than 25 mol%. According to the foaming agent composition, by directly replacing HCFC-141b with 1,2-dichloroethylene serving as a foaming agent, a satisfactory foam product can be obtained.

Description

A kind of foaming agent composotion containing 1,2-dichloroethene
Technical field
The present invention relates to a kind of foaming agent composotion containing 1,2-dichloroethene.
Background technology
The production method of urethane or polyisocyanurate foam is well-known, generally consist of under a kind of existence of volatile foaming agent, the reaction of a kind of organic multiple isocyanate (comprising vulcabond) and a kind of many alcohol or many alcohol mixtures, this whipping agent can volatilize because of the heat discharged between isocyanic ester and many alcohol reaction period, by the use of amine or other catalyzer and tensio-active agent, this reaction can be strengthened, catalyzer can guarantee that these foams fully solidify, the size in tensio-active agent then controllable foam hole, add the combustibility that fire retardant then can reduce foams.
In many applications, be by foam-body material in advance mixture become two kinds of components, isocyanic ester or polyisocyantates composition are included in the first component, usually become " A " component; The substance mixture such as many alcohol or many alcohol mixtures, tensio-active agent, catalyzer, whipping agent, fire retardant are included in second component, usually become " B " component.Just urethane or polyisocyanurate foam can be prepared easily by component A and B component being mixed.
Once by trichlorofluoromethane (CFC-11) widely used as whipping agent, because it can destroy atmospheric ozone layer, now by performance and its fluorine ethylene dichloride (HCFC-141b) relatively substitute.But the ODP of HCFC-141b is non-vanishing, still can damage atmospheric ozone layer, therefore Montreal Protocol is listed in and is eliminated in the works.Some developed countries eliminate HCFC-141b in advance, and China will eliminate HCFC-141b in the near future.The surrogate substituting now HCFC-141b in the world mainly contains 1,1,1,3,3-3-pentafluorobutane (HFC-365mfc), 1,1,1,3,3-pentafluoropropane HFC-245fa, 1,3,3,3-tetrafluoeopropene (HFO-1234ze) etc., the manufacture patent of above-mentioned substance all monopolize by major companies such as Zoomlion A Kema, Honeywell, Baeyer, Tao Shi, Du Ponts, in addition production cost is high, promotes slowly.
A kind of foaming agent of market active demand, it is alternative HCFC-141b not only, and is not again the material of the destruction atmospheric ozone layer that the restriction of the existing world uses, simultaneously moderate, can avoid the whipping agent product of foreign patent monopolization.
Summary of the invention
the problem that invention will solve
The object of the invention is to provide the foaming agent composotion containing 1,2-dichloroethene.
for the scheme of dealing with problems
Be selected from by 1,2-dichloroethene and at least one the foaming agent composotion that polyvalent alcohol or polyol form, wherein, the content of 1,2-dichloroethene is more than 1 % by mole and not higher than 25 % by mole.
Preferably, foaming agent composotion, described polyvalent alcohol is the polyhydric alcohol composition of fragrant adoption ester polyol and aromatic polyether polyvalent alcohol.
Preferably, foaming agent composotion, described polyol is selected from the one in polyoxypropylene polyether polyol, alkaline polyol, aromatic amine polyoxytrimethylene ether polyol.
The present invention also provides a kind of rigid foam, is mixed obtained by polyhydric alcohol composition, phosphoric acid trichlorine isopropyl ester, dimethylcyclohexylamine, silicone polyoxyalkylene hydrocarbon copolymer, water, 1,2-dichloroethene and 4,4-vulcabond ditane.
The present invention also provides a kind of fire-retardant poly-isocyanide urea imide ester foam, by polyoxypropylene polyether polyol, phosphoric acid trichlorine isopropyl ester, Tetramethyl Ethylene Diamine, silicone polyoxyalkylene hydrocarbon copolymer, water, 1,2-Ethylene Dichloride and the mixing of 4,4-vulcabond ditane obtain.
The present invention also provides a kind of flexible polyurethane foam, is mixed obtained by alkaline polyol, BDO, phosphoric acid trichlorine isopropyl ester, Tetramethyl Ethylene Diamine, lauric acid two fourth tin, 1,2-dichloroethene and 4,4-vulcabond ditane.
The present invention also provides a kind of low density heat insulation foam, by aromatic amine polyoxytrimethylene ether polyol, polyoxytrimethylene polyol, five methyl diethylentriamine, N-alkyl morpholine, water, 1,2-Ethylene Dichloride and the mixing of 4,4-vulcabond ditane obtain.
the effect of invention
Whipping agent 1,2-dichloroethene provided by the invention directly replaces HCFC-141b just can obtain gratifying froth product as whipping agent use.It is alternative HCFC-141b not only, and is not the material of the destruction atmospheric ozone layer that the restriction of the existing world uses, simultaneously moderate.
Embodiment
Various exemplary embodiment of the present invention, characteristic sum aspect is described in detail below with reference to embodiment.In order to better the present invention is described, in embodiment hereafter, give numerous details.It will be appreciated by those skilled in the art that do not have these details, the present invention can implement equally.In other example, known method, means, material are not described in detail, so that highlight purport of the present invention.
Example one
Be the aromatic polyester polyol of 450 and the polyhydric alcohol composition of aromatic polyether polyvalent alcohol by 100 grams of OH numbers, with 15 grams of phosphoric acid trichlorine isopropyl esters as fire retardant, 2 grams of dimethylcyclohexylamines as catalyzer and 1.5 grams of silicone polyoxyalkylene hydrocarbon copolymers as stablizer, 2 grams of water, 20 gram 1,2-Ethylene Dichloride mixes, then mix with 131 gram of 4,4-vulcabond ditane.Obtaining density is 35KG/m 3rigid foam.
Example two
Using 689 grams of OH numbers be 475 polyoxypropylene polyether polyol and 24 grams of phosphoric acid trichlorine isopropyl esters as fire retardant, 2 grams of Tetramethyl Ethylene Diamines as catalyzer and 10 grams of silicone polyoxyalkylene hydrocarbon copolymers as stablizer, 2 grams of water, 276 gram 1,2-Ethylene Dichloride mixes, then mix with 1000 gram of 4,4-vulcabond ditane.Obtaining density is 39.2KG/m 3fire-retardant poly-isocyanide urea imide ester foam.
Example three
By 680 grams of OH numbers be 36 alkaline polyol and 136 gram 1,4-butyleneglycol, 68 grams of phosphoric acid trichlorine isopropyl esters as fire retardant, 14 grams of Tetramethyl Ethylene Diamines, 1 gram of lauric acid two fourth tin and 106 gram 1,2-Ethylene Dichloride mixes, then mix with 1000 gram of 4,4-vulcabond ditane.Obtaining density is 35.6KG/m 3flexible polyurethane foam.
Example four
Be the aromatic amine polyoxytrimethylene ether polyol of 535 by 74 grams of OH numbers, 576 grams of hydroxy number be the polyoxytrimethylene polyol of 490,3 grams of five methyl diethylentriamines, 14 grams of N-alkyl morpholines, 7 grams of water, 316 gram 1,2-Ethylene Dichloride mixes, then mix with 1000 gram of 4,4-vulcabond ditane.Obtaining density is 22.4KG/m 3refrigerator low density heat insulation foam.
The all types of foams that above-mentioned 4 embodiments provide, all have good performance.
Whipping agent of the present invention is also highly suitable for the foaming of other system beyond urethane or poly-isocyanurate system or component, such as, and the foaming of polyvinyl chloride, epoxy resin, unsaturated polyester, phenolic resin etc.
Although describe the present invention with reference to above embodiment, it should be understood that and the invention is not restricted to disclosed embodiment.The scope of appended claims should make an explanation in the most wide in range scope, to contain all modification, equivalent structure and function.

Claims (7)

1. a foaming agent composotion, is characterized in that, comprises the composition that 1,2-dichloroethene and at least one are selected from polyvalent alcohol or polyol, and wherein, the content of described 1,2-dichloroethene is more than 1 % by mole and not higher than 25 % by mole.
2. foaming agent composotion according to claim 1, is characterized in that, described polyvalent alcohol is the polyhydric alcohol composition of fragrant adoption ester polyol and aromatic polyether polyvalent alcohol.
3. foaming agent composotion according to claim 1, is characterized in that, described polyol is selected from the one in polyoxypropylene polyether polyol, alkaline polyol, aromatic amine polyoxytrimethylene ether polyol.
4. the rigid foam be made up of the foaming agent composotion as described in as arbitrary in claims 1 to 3, it is characterized in that, by polyhydric alcohol composition, phosphoric acid trichlorine isopropyl ester, dimethylcyclohexylamine, silicone polyoxyalkylene hydrocarbon copolymer, water, 1,2-Ethylene Dichloride and the mixing of 4,4-vulcabond ditane obtain.
5. the fire-retardant poly-isocyanide urea imide ester foam be made up of the foaming agent composotion as described in as arbitrary in claims 1 to 3, it is characterized in that, by polyoxypropylene polyether polyol, phosphoric acid trichlorine isopropyl ester, Tetramethyl Ethylene Diamine, silicone polyoxyalkylene hydrocarbon copolymer, water, 1,2-Ethylene Dichloride and the mixing of 4,4-vulcabond ditane obtain.
6. the flexible polyurethane foam be made up of the foaming agent composotion as described in as arbitrary in claims 1 to 3, it is characterized in that, by alkaline polyol, 1,4-butyleneglycol, phosphoric acid trichlorine isopropyl ester, Tetramethyl Ethylene Diamine, lauric acid two fourth tin, 1,2-Ethylene Dichloride and the mixing of 4,4-vulcabond ditane obtain.
7. the low density heat insulation foam be made up of the foaming agent composotion as described in as arbitrary in claims 1 to 3, it is characterized in that, by aromatic amine polyoxytrimethylene ether polyol, polyoxytrimethylene polyol, five methyl diethylentriamine, N-alkyl morpholine, water, 1,2-Ethylene Dichloride and the mixing of 4,4-vulcabond ditane obtain.
CN201410757803.1A 2014-12-10 2014-12-10 Foaming agent composition containing 1,2-dichloroethylene Pending CN104448226A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107250196A (en) * 2015-02-24 2017-10-13 阿基里斯株式会社 Hard polyurethane foams

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1550514A (en) * 2003-04-22 2004-12-01 ���з��ɻ�ѧ�ɷ����޹�˾ Foam premixes having improved processability
CN101120081A (en) * 2005-02-23 2008-02-06 阿克马法国公司 Trans-1,2 dichloroethylene composition
US7442321B1 (en) * 2008-03-07 2008-10-28 Arkema Inc. Azeotrope-like composition of 1,1,1-trifluoro-3-chloropropene and trans-1,2-dichloroethylene
CN101679661A (en) * 2006-03-31 2010-03-24 阿克马法国公司 Blowing agent composition
CN103627020A (en) * 2013-11-07 2014-03-12 江苏蓝色星球环保科技股份有限公司 Foam composition

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1550514A (en) * 2003-04-22 2004-12-01 ���з��ɻ�ѧ�ɷ����޹�˾ Foam premixes having improved processability
CN101120081A (en) * 2005-02-23 2008-02-06 阿克马法国公司 Trans-1,2 dichloroethylene composition
CN101679661A (en) * 2006-03-31 2010-03-24 阿克马法国公司 Blowing agent composition
US7442321B1 (en) * 2008-03-07 2008-10-28 Arkema Inc. Azeotrope-like composition of 1,1,1-trifluoro-3-chloropropene and trans-1,2-dichloroethylene
CN103627020A (en) * 2013-11-07 2014-03-12 江苏蓝色星球环保科技股份有限公司 Foam composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107250196A (en) * 2015-02-24 2017-10-13 阿基里斯株式会社 Hard polyurethane foams
CN107250196B (en) * 2015-02-24 2020-05-12 阿基里斯株式会社 Rigid polyurethane foams

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