CN104446600A - Modified carbide slag foam brick and preparation method thereof - Google Patents
Modified carbide slag foam brick and preparation method thereof Download PDFInfo
- Publication number
- CN104446600A CN104446600A CN201410592398.2A CN201410592398A CN104446600A CN 104446600 A CN104446600 A CN 104446600A CN 201410592398 A CN201410592398 A CN 201410592398A CN 104446600 A CN104446600 A CN 104446600A
- Authority
- CN
- China
- Prior art keywords
- parts
- carbide slag
- modified carbide
- add
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Landscapes
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention discloses a modified carbide slag foam brick which is prepared from the following raw materials in parts by weight: 50-60 parts of waste glass, 15-20 parts of modified carbide slags, 5-10 parts of mica powder, 3-5 parts of titanium dioxide, 2-4 parts of sodium bicarbonate, 0.2-0.4 part of soya bean lecithin, 1-2 parts of sea buckthorn oil, 0.1-0.2 part of ascorbyl palmitate, 4-6 parts of linseed oil, 0.5-1 part of sodium dodecyl sulfate, 1-2 parts of alums, 0.1-0.2 part of peach gum, 0.2-0.4 part of sodium dodecyl benzene sulfonate, 2-4 parts of organosilicon quaternary ammonium salt and 50-60 parts of water. By taking the waste glass and the modified carbide slags as the main raw materials, the foam brick disclosed by the invention has the advantages of good fire resistance and high temperature resistance, high mechanical property, good anti-microbial anti-mold property, energy saving, waste utilization and strong practicability.
Description
Technical field
The present invention relates to building material field, be specifically related to a kind of modified carbide slag foamed brick and preparation method thereof.
Background technology
Foamed brick belongs to the one of air-entrained concrete building block, by adopting whipping agent by after foaming machine physics system bubble, then is added in slip by bubble and mixes, cast, the finally obtained foamed brick with internal porosity.Foamed brick is mainly used in non-load bearing wall, has the features such as cost is low, lightweight, good effect of heat insulation, and being widely used in industry with covil construction, is a kind of materials for wall with superperformance.
Glass material is that people's daily life is required, indispensable material.A large amount of uses of glass also cause inevitably producing a large amount of cullet rubbish in daily productive life.The stable chemical nature of cullet, brought inconvenience both to the production of people and life, create pollution again, and the arrangement of cullet had occupied a large amount of land resources to environment.Therefore, recycle cullet, make cullet resource utilization become an important topic of environmental protection and energy saving.Utilizing cullet to produce foamed brick is a kind of approach of Appropriate application cullet.
Summary of the invention
The object of this invention is to provide a kind of modified carbide slag foamed brick.
The present invention is achieved by the following technical solutions:
A kind of modified carbide slag foamed brick, it is characterized in that, it is obtained by the raw material of following weight parts:
Cullet 50-60, modified carbide slag 15-20, mica powder 5-10, titanium dioxide 3-5, sodium bicarbonate 2-4, soybean lecithin 0.2-0.4, Oleum Hippophae 1-2, Quicifal 0.1-0.2, siritch 4-6, sodium lauryl sulphate 0.5-1, alum 1-2, peach gum 0.1-0.2, Sodium dodecylbenzene sulfonate 0.2-0.4, organosilicon quaternary ammonium salt 2-4, water 50-60;
Wherein modified carbide slag is made up of the raw material of following weight part:
Carbide slag 20-30, tripoly phosphate sodium STPP 4-6, barium sulfate 1-2, lime borate 1-2, calcium lignin sulphonate 0.5-1, polyoxyethylene glycol 0.2-0.4, trolamine 0.5-1, Trisodium Citrate 1-2;
The preparation method of modified carbide slag is:
2-4h is calcined for 800-1000 DEG C after being mixed with barium sulfate, lime borate, Trisodium Citrate and tripoly phosphate sodium STPP by carbide slag, calcium lignin sulphonate and suitable quantity of water stirring 10-20min is added after cooling, filter, wash and drying, add appropriate dehydrated alcohol, add polyoxyethylene glycol and trolamine supersound process 15-30min again, dry after filtering, be ground to 200-300 order, obtain final product.
A preparation method for modified carbide slag foamed brick, is characterized in that, comprises the following steps:
(1) by 200-300 DEG C of process 1-2h after the mixing of cullet, titanium dioxide, mica powder and sodium bicarbonate, add alum and modified carbide slag mixes, after grinding, cross 100-150 mesh sieve, then add the water of 1/3-1/2 amount, 200-400r/min stirs 0.5-1h, obtains component A;
(2) add in the water of surplus by soybean lecithin and peach gum, 60-80 DEG C is stirred 10-20min, adds high speed whisking machine and obtains foam, obtain B component after cooling after adding sodium lauryl sulphate and Sodium dodecylbenzene sulfonate stirring 5-10min;
(3) stir after component A being mixed with B component, it is shaping to add mold cured, dries 1-2h for first 100-150 DEG C, then in retort furnace 600-800 DEG C of sintering 2-4h, cooling;
(4) after organosilicon quaternary ammonium salt being mixed with Oleum Hippophae, siritch and Quicifal 80-90 DEG C, 800-1000r/min stirs 5-10min, then the fragment of brick surface that even application is obtained in (3), 100-120 DEG C of insulation 2-4h, get product after cooling foamed brick.
Wherein organosilicon quaternary ammonium salt is polysiloxane quaternary ammonium.
Advantage of the present invention is:
1. with cullet and modified carbide slag for main raw material, make foamed brick have fire-resistant, that resistance to elevated temperatures good, physical strength is high advantage, energy-conserving profit waste, practical;
2. by carrying out surface treatment to fragment of brick, make foamed brick have excellent antibacterial and mouldproof characteristic and safe and harmless, there is good static electricity resistance, erosion resistance simultaneously, bacterium, the growing of mould can be prevented, decontamination chamber's environment, turn improves durability degree and the stability of product.
Embodiment
Non-limiting examples of the present invention is as follows:
A kind of modified carbide slag foamed brick, is prepared from by the component raw material of following weight (kg):
Cullet 55, modified carbide slag 18, mica powder 8, titanium dioxide 4, sodium bicarbonate 3, soybean lecithin 0.3, Oleum Hippophae 1.5, Quicifal 0.15, siritch 5, sodium lauryl sulphate 0.8, alum 1.5, peach gum 0.15, Sodium dodecylbenzene sulfonate 0.3, organosilicon quaternary ammonium salt 3, water 55;
Wherein, modified carbide slag is made up of the raw material of following weight (kg):
Carbide slag 25, tripoly phosphate sodium STPP 5, barium sulfate 1.5, lime borate 1.5, calcium lignin sulphonate 0.8, polyoxyethylene glycol 0.3, trolamine 0.8, Trisodium Citrate 1.5;
The preparation method of modified carbide slag:
Carbide slag is mixed latter 9000 DEG C calcine 3h with barium sulfate, lime borate, Trisodium Citrate and tripoly phosphate sodium STPP, calcium lignin sulphonate and suitable quantity of water stirring 20min is added after cooling, filter, wash and drying, add appropriate dehydrated alcohol, add polyoxyethylene glycol and trolamine supersound process 30min again, dry after filtering, be ground to 200 orders, obtain final product.
The preparation method of modified carbide slag foamed brick comprises the following steps:
(1) by rear for the mixing of cullet, titanium dioxide, mica powder and sodium bicarbonate 300 DEG C of process 1h, add alum and modified carbide slag mixes, cross 150 mesh sieves after grinding, then add the water of 1/2 amount, 400r/min stirs 1h, obtains component A;
(2) add in the water of surplus by soybean lecithin and peach gum, 80 DEG C are stirred 10min, add high speed whisking machine and obtain foam, obtain B component after cooling after adding sodium lauryl sulphate and Sodium dodecylbenzene sulfonate stirring 10min;
(3) stir after component A being mixed with B component, it is shaping to add mold cured, first dries 2h for 150 DEG C, then in retort furnace 800 DEG C of sintering 2h, cooling;
(4) organosilicon quaternary ammonium salt is mixed latter 90 DEG C with Oleum Hippophae, siritch and Quicifal, 1000r/min stirs 5min, the fragment of brick surface that then even application is obtained in (3), 120 DEG C of insulation 3h, get product after cooling foamed brick.
Through inspection, the foamed brick thermal conductivity of the present embodiment: 0.059W/(mK), ultimate compression strength: 9.1Mpa.
Claims (2)
1. a modified carbide slag foamed brick, is characterized in that, it is obtained by the raw material of following weight parts:
Cullet 50-60, modified carbide slag 15-20, mica powder 5-10, titanium dioxide 3-5, sodium bicarbonate 2-4, soybean lecithin 0.2-0.4, Oleum Hippophae 1-2, Quicifal 0.1-0.2, siritch 4-6, sodium lauryl sulphate 0.5-1, alum 1-2, peach gum 0.1-0.2, Sodium dodecylbenzene sulfonate 0.2-0.4, organosilicon quaternary ammonium salt 2-4, water 50-60;
Described modified carbide slag is made up of the raw material of following weight part:
Carbide slag 20-30, tripoly phosphate sodium STPP 4-6, barium sulfate 1-2, lime borate 1-2, calcium lignin sulphonate 0.5-1, polyoxyethylene glycol 0.2-0.4, trolamine 0.5-1, Trisodium Citrate 1-2;
The preparation method of described modified carbide slag is:
2-4h is calcined for 800-1000 DEG C after being mixed with barium sulfate, lime borate, Trisodium Citrate and tripoly phosphate sodium STPP by carbide slag, calcium lignin sulphonate and suitable quantity of water stirring 10-20min is added after cooling, filter, wash and drying, add appropriate dehydrated alcohol, add polyoxyethylene glycol and trolamine supersound process 15-30min again, dry after filtering, be ground to 200-300 order, obtain final product.
2. the preparation method of a kind of modified carbide slag foamed brick according to claim 1, is characterized in that, comprise the following steps:
(1) by 200-300 DEG C of process 1-2h after the mixing of cullet, titanium dioxide, mica powder and sodium bicarbonate, add alum and modified carbide slag mixes, after grinding, cross 100-150 mesh sieve, then add the water of 1/3-1/2 amount, 200-400r/min stirs 0.5-1h, obtains component A;
(2) add in the water of surplus by soybean lecithin and peach gum, 60-80 DEG C is stirred 10-20min, adds high speed whisking machine and obtains foam, obtain B component after cooling after adding sodium lauryl sulphate and Sodium dodecylbenzene sulfonate stirring 5-10min;
(3) stir after component A being mixed with B component, it is shaping to add mold cured, dries 1-2h for first 100-150 DEG C, then in retort furnace 600-800 DEG C of sintering 2-4h, cooling;
(4) after organosilicon quaternary ammonium salt being mixed with Oleum Hippophae, siritch and Quicifal 80-90 DEG C, 800-1000r/min stirs 5-10min, then the fragment of brick surface that even application is obtained in (3), 100-120 DEG C of insulation 2-4h, get product after cooling foamed brick.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410592398.2A CN104446600A (en) | 2014-10-30 | 2014-10-30 | Modified carbide slag foam brick and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410592398.2A CN104446600A (en) | 2014-10-30 | 2014-10-30 | Modified carbide slag foam brick and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104446600A true CN104446600A (en) | 2015-03-25 |
Family
ID=52893444
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410592398.2A Withdrawn CN104446600A (en) | 2014-10-30 | 2014-10-30 | Modified carbide slag foam brick and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104446600A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105130318A (en) * | 2015-07-08 | 2015-12-09 | 安徽省溜口新型建筑材料有限公司 | Bamboo charcoal powder-containing low energy consumption aerated brick |
| CN105152622A (en) * | 2015-07-08 | 2015-12-16 | 安徽省溜口新型建筑材料有限公司 | Straw ash steam-pressing brick |
-
2014
- 2014-10-30 CN CN201410592398.2A patent/CN104446600A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105130318A (en) * | 2015-07-08 | 2015-12-09 | 安徽省溜口新型建筑材料有限公司 | Bamboo charcoal powder-containing low energy consumption aerated brick |
| CN105152622A (en) * | 2015-07-08 | 2015-12-16 | 安徽省溜口新型建筑材料有限公司 | Straw ash steam-pressing brick |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103253906B (en) | A kind of flyash/bentonite ceramsite concrete hollow insulation block and preparation method thereof | |
| CN105924122B (en) | The modified expanded perlite insulation board and its production method of a kind of light-weight water-proof | |
| CN105948642B (en) | The modified expanded perlite insulation board and its production method of a kind of hydrophobic | |
| CN105948638B (en) | A kind of hydrophobic type modified expanded perlite insulation board and its production method | |
| CN103253984A (en) | Boron mud/loess ceramsite concrete hollow insulation block and preparation method thereof | |
| CN106186854A (en) | A kind of fire-type modified expanded perlite insulation board and production method thereof | |
| CN104446599A (en) | Cold-resistant and impervious foamed brick and preparation method thereof | |
| CN105948641A (en) | Waterproof modified expanded perlite thermal insulation board and production method thereof | |
| CN106186921A (en) | A kind of mineral fibre enhancement mode modified expanded perlite insulation board and production method thereof | |
| CN104446600A (en) | Modified carbide slag foam brick and preparation method thereof | |
| CN105948636B (en) | A kind of enhanced modified expanded perlite insulation board of polyacrylate and its production method | |
| CN104402514A (en) | Wear-resistant corrosion-resistant foam brick and preparation method thereof | |
| CN105948637B (en) | A kind of fiber reinforcement type modified expanded perlite insulation board and its production method | |
| CN104446532A (en) | Light refractory foam brick and preparation method thereof | |
| CN104355670A (en) | Noise-reducing and heat-insulating foam brick and preparation method thereof | |
| CN104355664A (en) | Light foam brick and preparation method thereof | |
| CN105924123B (en) | A kind of cement base modified expanded perlite insulation board and its production method | |
| CN105347840A (en) | Economic wall foamed block material and preparation method thereof | |
| CN104370574A (en) | Sound-absorption heat-insulation foamed brick and preparation method thereof | |
| CN105948606B (en) | A kind of enhanced modified expanded perlite insulation board of polypropylene fibre and its production method | |
| CN104355669A (en) | Modified rice hull ash foam brick and preparation method thereof | |
| CN104355668A (en) | Environmental-friendly foam brick and preparation method thereof | |
| CN104402496A (en) | Foam brick containing tea saponin and preparation method thereof | |
| CN104370572A (en) | Environment-friendly foamed brick and preparation method thereof | |
| CN104355661A (en) | Foam brick produced from aquatic product waste and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20151123 Address after: Tongcheng Nan Lu, Baohe District of Hefei city in Anhui province 230009 No. 369 unit 8 layer A crystal Town Apartments Applicant after: Hefei Kang Ling health preserving Science and Technology Ltd. Address before: 231600 unity Road, Xincheng Development Zone, Hefei, Anhui, Feidong Applicant before: Hefei Chengxin Glass Co., Ltd. |
|
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20150325 |
|
| WW01 | Invention patent application withdrawn after publication |