CN104445646A - Scale removal and prevention agent for boiler and preparation method of scale removal and prevention agent - Google Patents
Scale removal and prevention agent for boiler and preparation method of scale removal and prevention agent Download PDFInfo
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- CN104445646A CN104445646A CN201410683670.8A CN201410683670A CN104445646A CN 104445646 A CN104445646 A CN 104445646A CN 201410683670 A CN201410683670 A CN 201410683670A CN 104445646 A CN104445646 A CN 104445646A
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- parts
- acid
- anticrustator
- sodium
- preparation
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 230000002265 prevention Effects 0.000 title abstract 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 57
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 20
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims abstract description 19
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000008367 deionised water Substances 0.000 claims abstract description 19
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims abstract description 19
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 239000002253 acid Substances 0.000 claims description 18
- 229910021641 deionized water Inorganic materials 0.000 claims description 18
- 239000001488 sodium phosphate Substances 0.000 claims description 18
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 18
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 18
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 239000004925 Acrylic resin Substances 0.000 claims description 16
- 229920000178 Acrylic resin Polymers 0.000 claims description 16
- 239000003999 initiator Substances 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 14
- 239000007787 solid Substances 0.000 claims description 14
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000012459 cleaning agent Substances 0.000 claims description 9
- 238000001556 precipitation Methods 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 abstract description 9
- 238000005265 energy consumption Methods 0.000 abstract description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 abstract 1
- 229940048086 sodium pyrophosphate Drugs 0.000 abstract 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 abstract 1
- -1 sodium-chlor, Sodium Chemical compound 0.000 description 10
- 230000003628 erosive effect Effects 0.000 description 8
- 231100000252 nontoxic Toxicity 0.000 description 8
- 230000003000 nontoxic effect Effects 0.000 description 8
- 230000000857 drug effect Effects 0.000 description 7
- 230000005764 inhibitory process Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 239000002455 scale inhibitor Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 2
- QFLWZFQWSBQYPS-AWRAUJHKSA-N (3S)-3-[[(2S)-2-[[(2S)-2-[5-[(3aS,6aR)-2-oxo-1,3,3a,4,6,6a-hexahydrothieno[3,4-d]imidazol-4-yl]pentanoylamino]-3-methylbutanoyl]amino]-3-(4-hydroxyphenyl)propanoyl]amino]-4-[1-bis(4-chlorophenoxy)phosphorylbutylamino]-4-oxobutanoic acid Chemical group CCCC(NC(=O)[C@H](CC(O)=O)NC(=O)[C@H](Cc1ccc(O)cc1)NC(=O)[C@@H](NC(=O)CCCCC1SC[C@@H]2NC(=O)N[C@H]12)C(C)C)P(=O)(Oc1ccc(Cl)cc1)Oc1ccc(Cl)cc1 QFLWZFQWSBQYPS-AWRAUJHKSA-N 0.000 description 1
- ONBQEOIKXPHGMB-VBSBHUPXSA-N 1-[2-[(2s,3r,4s,5r)-3,4-dihydroxy-5-(hydroxymethyl)oxolan-2-yl]oxy-4,6-dihydroxyphenyl]-3-(4-hydroxyphenyl)propan-1-one Chemical group O[C@@H]1[C@H](O)[C@@H](CO)O[C@H]1OC1=CC(O)=CC(O)=C1C(=O)CCC1=CC=C(O)C=C1 ONBQEOIKXPHGMB-VBSBHUPXSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/12—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen
- C02F5/125—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen combined with inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/22—Eliminating or preventing deposits, scale removal, scale prevention
Abstract
The invention discloses a scale removal and prevention agent for a boiler and a preparation method of the scale removal and prevention agent. The scale removal and prevention agent is prepared from the following raw materials in parts by weight: 25-60 parts of citric acid, 15-35 parts of hydrochloric acid, 12-40 parts of sodium chloride, 12-35 parts of sodium hexametaphosphate, 8-25 parts of sodium pyrophosphate, 13-25 parts of acrylic acid, 8-22 parts of ammonium nitrate, 8-19 parts of sulfamic acid and 35-60 parts of de-ionized water. The scale removal and prevention agent can be used for different boilers, the scale prevention rate reaches more than 95%, and the energy consumption of the boiler is remarkably reduced.
Description
Technical field
The present invention relates to scale remover field, particularly relate to a kind of Anticrustator for descaling boiler and preparation method thereof.
Background technology
In Industrial processes, boiler often produces incrustation scale, by increasing energy consumption after incrustation scale produces, thus increases production cost.Scale inhibitor of the prior art exists following not enough: first, usage quantity is larger; Secondly, antiscaling effect is lower; Moreover, corrosive nature is existed to boiler itself.Therefore, develop good, the nontoxic nothing erosion of a kind of antiscaling effect, safe and reliable, ground easy and simple to handle scale inhibitor is very important.
Summary of the invention
the technical problem solved:
In order to provide, a kind of drug effect deenergized period is long, antiscaling effect good, nontoxic without erosion, scale inhibitor safe and reliable, easy and simple to handle, the invention provides a kind of Anticrustator for descaling boiler and preparation method thereof.
technical scheme:
A kind of Anticrustator for descaling boiler, makes by following raw material weight number proportioning: citric acid 25-60 part, hydrochloric acid 15-35 part, sodium-chlor 12-40 part, Sodium hexametaphosphate 99 12-35 part, trisodium phosphate 8-25 part, vinylformic acid 13-25 part, ammonium nitrate 8-22 part, thionamic acid 8-19 part, initiator 3-14 part, acrylic resin jointing compound 4-16 part, deionized water 35-60 part.
As a preferred embodiment of the present invention, make by following raw material weight number proportioning: citric acid 30-55 part, hydrochloric acid 20-30 part, sodium-chlor 15-35 part, Sodium hexametaphosphate 99 15-30 part, trisodium phosphate 10-22 part, vinylformic acid 15-24 part, ammonium nitrate 9-20 part, thionamic acid 9-17 part, initiator 5-12 part, acrylic resin jointing compound 5-14, deionized water 40-55 part.
A preparation method for Anticrustator for descaling boiler, comprises the following steps:
(1) add citric acid, hydrochloric acid, sodium-chlor and deionized water in a kettle., reactor temperature is 35-56 DEG C, is uniformly mixed 1.2-2.3 hour;
(2) in the solution of step (1), add Sodium hexametaphosphate 99, trisodium phosphate, vinylformic acid, ammonium nitrate and thionamic acid, in reactor, temperature rises to 63-78 DEG C, continues reaction 1.1-2.8 hour;
(3) obtain in solution to step (2) and add initiator and acrylic resin jointing compound, separate out precipitation;
(4) centrifugal treating, acquisition solid, dry and can obtain scale cleaning agent under 102-123 DEG C of condition.
As a preferred technical solution of the present invention, step (1) adds citric acid, hydrochloric acid, sodium-chlor and deionized water in a kettle., and reactor temperature is 48 DEG C, is uniformly mixed 1.8 hours.
As a preferred technical solution of the present invention, in the solution of step (1), add Sodium hexametaphosphate 99, trisodium phosphate, vinylformic acid, ammonium nitrate and thionamic acid in step (2), in reactor, temperature rises to 74 DEG C, continues reaction 2.3 hours.
As a preferred technical solution of the present invention, step (4), through centrifugal treating, acquisition solid, is dried and can be obtained scale cleaning agent under 116 DEG C of conditions.
beneficial effect
A kind of Anticrustator for descaling boiler of the present invention and preparation method thereof adopts above technical scheme to have following technique effect: the first, scale inhibition efficiency is high; The second, drug effect is long for deenergized period; Three, nontoxic without erosion, safe and reliable, easy and simple to handle.
Embodiment
Embodiment 1:
A kind of Anticrustator for descaling boiler, makes by following raw material weight number proportioning: citric acid 25 parts, hydrochloric acid 15 parts, 12 parts, sodium-chlor, Sodium hexametaphosphate 99 12 parts, trisodium phosphate 8 parts, 13 parts, vinylformic acid, 8 parts, ammonium nitrate, thionamic acid 8 parts, initiator 3 parts, acrylic resin jointing compound 4 parts, deionized water 35 parts.
A preparation method for Anticrustator for descaling boiler, comprises the following steps:
(1) add citric acid, hydrochloric acid, sodium-chlor and deionized water in a kettle., reactor temperature is 35 DEG C, is uniformly mixed 1.2 hours;
(2) in the solution of step (1), add Sodium hexametaphosphate 99, trisodium phosphate, vinylformic acid, ammonium nitrate and thionamic acid, in reactor, temperature rises to 63 DEG C, continues reaction 1.1 hours;
(3) obtain in solution to step (2) and add initiator and acrylic resin jointing compound, separate out precipitation;
(4) centrifugal treating, acquisition solid, dry and can obtain scale cleaning agent under 102 DEG C of conditions.
The solid scale preventing and removing agent scale inhibition performance that the program obtains is 97.3%, and drug effect reaches 1a deenergized period; Nontoxic without erosion, safe and reliable, easy and simple to handle.
Embodiment 2:
A kind of Anticrustator for descaling boiler, makes by following raw material weight number proportioning: citric acid 30 parts, hydrochloric acid 20 parts, 15 parts, sodium-chlor, Sodium hexametaphosphate 99 15 parts, trisodium phosphate 10 parts, 16 parts, vinylformic acid, 11 parts, ammonium nitrate, thionamic acid 11 parts, initiator 5 parts, acrylic resin jointing compound 6 parts, deionized water 40 parts.
A preparation method for Anticrustator for descaling boiler, comprises the following steps:
(1) add citric acid, hydrochloric acid, sodium-chlor and deionized water in a kettle., reactor temperature is 40 DEG C, is uniformly mixed 1.5 hours;
(2) in the solution of step (1), add Sodium hexametaphosphate 99, trisodium phosphate, vinylformic acid, ammonium nitrate and thionamic acid, in reactor, temperature rises to 66 DEG C, continues reaction 1.6 hours;
(3) obtain in solution to step (2) and add initiator and acrylic resin jointing compound, separate out precipitation;
(4) centrifugal treating, acquisition solid, dry and can obtain scale cleaning agent under 106 DEG C of conditions.
The solid scale preventing and removing agent scale inhibition performance that the program obtains is 98.1%, and drug effect reaches 1.2a deenergized period; Nontoxic without erosion, safe and reliable, easy and simple to handle.
Embodiment 3:
A kind of Anticrustator for descaling boiler, makes by following raw material weight number proportioning: citric acid 35 parts, hydrochloric acid 25 parts, 20 parts, sodium-chlor, Sodium hexametaphosphate 99 20 parts, trisodium phosphate 12 parts, 19 parts, vinylformic acid, 14 parts, ammonium nitrate, thionamic acid 13 parts, initiator 7 parts, acrylic resin jointing compound 9 parts, deionized water 45 parts.
A preparation method for Anticrustator for descaling boiler, comprises the following steps:
(1) add citric acid, hydrochloric acid, sodium-chlor and deionized water in a kettle., reactor temperature is 44 DEG C, is uniformly mixed 1.7 hours;
(2) in the solution of step (1), add Sodium hexametaphosphate 99, trisodium phosphate, vinylformic acid, ammonium nitrate and thionamic acid, in reactor, temperature rises to 69 DEG C, continues reaction 1.9 hours;
(3) obtain in solution to step (2) and add initiator and acrylic resin jointing compound, separate out precipitation;
(4) centrifugal treating, acquisition solid, dry and can obtain scale cleaning agent under 109 DEG C of conditions.
The solid scale preventing and removing agent scale inhibition performance that the program obtains is 98.9%, and drug effect reaches 1.3a deenergized period; Nontoxic without erosion, safe and reliable, easy and simple to handle.
Embodiment 4:
A kind of Anticrustator for descaling boiler, makes by following raw material weight number proportioning: citric acid 40 parts, hydrochloric acid 30 parts, 25 parts, sodium-chlor, Sodium hexametaphosphate 99 25 parts, trisodium phosphate 16 parts, 22 parts, vinylformic acid, 18 parts, ammonium nitrate, thionamic acid 16 parts, initiator 9 parts, acrylic resin jointing compound 11 parts, deionized water 50 parts.
A preparation method for Anticrustator for descaling boiler, comprises the following steps:
(1) add citric acid, hydrochloric acid, sodium-chlor and deionized water in a kettle., reactor temperature is 48 DEG C, is uniformly mixed 2.1 hours;
(2) in the solution of step (1), add Sodium hexametaphosphate 99, trisodium phosphate, vinylformic acid, ammonium nitrate and thionamic acid, in reactor, temperature rises to 74 DEG C, continues reaction 2.3 hours;
(3) obtain in solution to step (2) and add initiator and acrylic resin jointing compound, separate out precipitation;
(4) centrifugal treating, acquisition solid, dry and can obtain scale cleaning agent under 116 DEG C of conditions.
The solid scale preventing and removing agent scale inhibition performance that the program obtains is 99.3%, and drug effect reaches 1.5a deenergized period; Nontoxic without erosion, safe and reliable, easy and simple to handle.
Embodiment 5:
A kind of Anticrustator for descaling boiler, makes by following raw material weight number proportioning: citric acid 60 parts, hydrochloric acid 35 parts, 40 parts, sodium-chlor, Sodium hexametaphosphate 99 35 parts, trisodium phosphate 25 parts, 25 parts, vinylformic acid, 22 parts, ammonium nitrate, thionamic acid 19 parts, initiator 14 parts, acrylic resin jointing compound 16 parts, deionized water 60 parts.
A preparation method for Anticrustator for descaling boiler, comprises the following steps:
(1) add citric acid, hydrochloric acid, sodium-chlor and deionized water in a kettle., reactor temperature is 56 DEG C, is uniformly mixed 2.3 hours;
(2) in the solution of step (1), add Sodium hexametaphosphate 99, trisodium phosphate, vinylformic acid, ammonium nitrate and thionamic acid, in reactor, temperature rises to 78 DEG C, continues reaction 2.8 hours;
(3) obtain in solution to step (2) and add initiator and acrylic resin jointing compound, separate out precipitation;
(4) centrifugal treating, acquisition solid, dry and can obtain scale cleaning agent under 123 DEG C of conditions.
The solid scale preventing and removing agent scale inhibition performance that the program obtains is 99.9%, and drug effect reaches 1.6a deenergized period; Nontoxic without erosion, safe and reliable, easy and simple to handle.
Claims (6)
1. an Anticrustator for descaling boiler, it is characterized in that, make by following raw material weight number proportioning: citric acid 25-60 part, hydrochloric acid 15-35 part, sodium-chlor 12-40 part, Sodium hexametaphosphate 99 12-35 part, trisodium phosphate 8-25 part, vinylformic acid 13-25 part, ammonium nitrate 8-22 part, thionamic acid 8-19 part, initiator 3-14 part, acrylic resin jointing compound 4-16 part, deionized water 35-60 part.
2. a kind of Anticrustator for descaling boiler according to claim 1, it is characterized in that, make by following raw material weight number proportioning: citric acid 30-55 part, hydrochloric acid 20-30 part, sodium-chlor 15-35 part, Sodium hexametaphosphate 99 15-30 part, trisodium phosphate 10-22 part, vinylformic acid 15-24 part, ammonium nitrate 9-20 part, thionamic acid 9-17 part, initiator 5-12 part, acrylic resin jointing compound 5-14, deionized water 40-55 part.
3. the preparation method of a kind of Anticrustator for descaling boiler described in claim 1, is characterized in that, comprise the following steps:
(1) add citric acid, hydrochloric acid, sodium-chlor and deionized water in a kettle., reactor temperature is 35-56 DEG C, is uniformly mixed 1.2-2.3 hour;
(2) in the solution of step (1), add Sodium hexametaphosphate 99, trisodium phosphate, vinylformic acid, ammonium nitrate and thionamic acid, in reactor, temperature rises to 63-78 DEG C, continues reaction 1.1-2.8 hour;
(3) obtain in solution to step (2) and add initiator and acrylic resin jointing compound, separate out precipitation;
(4) centrifugal treating, acquisition solid, dry and can obtain scale cleaning agent under 102-123 DEG C of condition.
4. the preparation method of a kind of Anticrustator for descaling boiler according to claim 3, it is characterized in that, step (1) adds citric acid, hydrochloric acid, sodium-chlor and deionized water in a kettle., and reactor temperature is 48 DEG C, is uniformly mixed 1.8 hours.
5. the preparation method of a kind of Anticrustator for descaling boiler according to claim 3, it is characterized in that, in the solution of step (1), add Sodium hexametaphosphate 99, trisodium phosphate, vinylformic acid, ammonium nitrate and thionamic acid in step (2), in reactor, temperature rises to 74 DEG C, continues reaction 2.3 hours.
6. the preparation method of a kind of Anticrustator for descaling boiler according to claim 3, is characterized in that, step (4) through centrifugal treating, obtain solid, dry under 116 DEG C of conditions and can obtain scale cleaning agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410683670.8A CN104445646B (en) | 2014-11-25 | 2014-11-25 | A kind of Anticrustator for descaling boiler and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410683670.8A CN104445646B (en) | 2014-11-25 | 2014-11-25 | A kind of Anticrustator for descaling boiler and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104445646A true CN104445646A (en) | 2015-03-25 |
| CN104445646B CN104445646B (en) | 2016-09-14 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410683670.8A Expired - Fee Related CN104445646B (en) | 2014-11-25 | 2014-11-25 | A kind of Anticrustator for descaling boiler and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN104445646B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113415876A (en) * | 2021-06-29 | 2021-09-21 | 江苏云尚环保装备有限公司 | Scale remover for leachate anaerobic system and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1130599A (en) * | 1995-03-07 | 1996-09-11 | 中国科学院化学研究所 | High-efficient faintly acid scale preventing and removing agent |
| JP2004105824A (en) * | 2002-09-17 | 2004-04-08 | Ebara Corp | Scale preventive agent and prevention method for water system |
| CN101786733A (en) * | 2010-04-08 | 2010-07-28 | 山东省特种设备检验研究院淄博分院 | Propenol itaconic acid sulfonate multipolymer scale inhibiting agent and preparation method thereof |
| CN102146149A (en) * | 2010-02-09 | 2011-08-10 | 天津市特隆生化有限公司 | Novel scale inhibition and dispersion agent |
| CN102198982A (en) * | 2010-03-26 | 2011-09-28 | 中国石油天然气股份有限公司 | Scale and corrosion inhibitor for circulating cooling water |
| CN102851672A (en) * | 2012-09-25 | 2013-01-02 | 海尔科化工程塑料国家工程研究中心股份有限公司 | Special antiscaling agent for water heater |
| CN103232571A (en) * | 2013-04-08 | 2013-08-07 | 青岛科海生物有限公司 | Production method of environment-friendly itaconic acid polymer water treatment agent |
-
2014
- 2014-11-25 CN CN201410683670.8A patent/CN104445646B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1130599A (en) * | 1995-03-07 | 1996-09-11 | 中国科学院化学研究所 | High-efficient faintly acid scale preventing and removing agent |
| JP2004105824A (en) * | 2002-09-17 | 2004-04-08 | Ebara Corp | Scale preventive agent and prevention method for water system |
| CN102146149A (en) * | 2010-02-09 | 2011-08-10 | 天津市特隆生化有限公司 | Novel scale inhibition and dispersion agent |
| CN102198982A (en) * | 2010-03-26 | 2011-09-28 | 中国石油天然气股份有限公司 | Scale and corrosion inhibitor for circulating cooling water |
| CN101786733A (en) * | 2010-04-08 | 2010-07-28 | 山东省特种设备检验研究院淄博分院 | Propenol itaconic acid sulfonate multipolymer scale inhibiting agent and preparation method thereof |
| CN102851672A (en) * | 2012-09-25 | 2013-01-02 | 海尔科化工程塑料国家工程研究中心股份有限公司 | Special antiscaling agent for water heater |
| CN103232571A (en) * | 2013-04-08 | 2013-08-07 | 青岛科海生物有限公司 | Production method of environment-friendly itaconic acid polymer water treatment agent |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113415876A (en) * | 2021-06-29 | 2021-09-21 | 江苏云尚环保装备有限公司 | Scale remover for leachate anaerobic system and preparation method thereof |
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| Publication number | Publication date |
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| CN104445646B (en) | 2016-09-14 |
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