CN104441678A - Preparation method of broadband wave-transmission resin based radome with irregular structure - Google Patents

Preparation method of broadband wave-transmission resin based radome with irregular structure Download PDF

Info

Publication number
CN104441678A
CN104441678A CN201410525147.2A CN201410525147A CN104441678A CN 104441678 A CN104441678 A CN 104441678A CN 201410525147 A CN201410525147 A CN 201410525147A CN 104441678 A CN104441678 A CN 104441678A
Authority
CN
China
Prior art keywords
premix
short fiber
shape
resin
fiber shape
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410525147.2A
Other languages
Chinese (zh)
Inventor
王芬
雷宁
尹正帅
郭培江
吴广力
佘平江
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hubei Sanjiang Space Jiangbei Mechanical Engineering Co Ltd
Original Assignee
Hubei Sanjiang Space Jiangbei Mechanical Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hubei Sanjiang Space Jiangbei Mechanical Engineering Co Ltd filed Critical Hubei Sanjiang Space Jiangbei Mechanical Engineering Co Ltd
Priority to CN201410525147.2A priority Critical patent/CN104441678A/en
Publication of CN104441678A publication Critical patent/CN104441678A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • B29C70/34Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
    • B29C70/345Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation using matched moulds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10Coating or impregnating independently of the moulding or shaping step
    • B29B15/12Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • B29B15/14Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length of filaments or wires
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/54Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
    • B29C70/543Fixing the position or configuration of fibrous reinforcements before or during moulding
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/10Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/08Ingredients agglomerated by treatment with a binding agent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/34Electrical apparatus, e.g. sparking plugs or parts thereof
    • B29L2031/3456Antennas, e.g. radomes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Composite Materials (AREA)
  • Textile Engineering (AREA)
  • Moulding By Coating Moulds (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)

Abstract

The invention discloses a net forming method of bismaleimide based broadband wave-transmission composite radome with an irregular structure and large thickness difference. The method comprises the following steps: carrying out toughening modification on bismaleimide resin for improving the mobility of a premix, preparing the premix, shearing the premix in different lengths, laying the premix in a matrix cavity and a performing body in a manner of paving wholly and filling locally, assembling a mold, curing and forming to obtain the radome. The method can be used for effectively solving the problem that the composite material has difficulty in net compression molding due to poor molding manufacturability of the bismaleimide resin, and is especially suitable for net compression molding of the bismaleimide resin based composite material with large size, complex profile and large wall thickness difference. The molded pressed product has good surface quality and internal quality and high qualified rate, the machining operation is not required, the cost is reduced, and the production efficiency and the product quality are improved.

Description

The preparation method of abnormally-structured wideband wave transparent resin-based antenna house
Technical field
The present invention relates to Penetrating preparing technical field, refer to a kind of preparation method of abnormally-structured wideband wave transparent bimaleimide resin base antenna house particularly.
Background technology
Polymer matrix composites pressing, with its good feature such as anti-heat-proof quality, low cost, low-density, high strength, is used widely in Aeronautics and Astronautics field.But along with the raising of missile flight speed, too high Aerodynamic Heating is had higher requirement to the anti-heat-barrier material performance of guided missile, in particular for protecting the antenna house of Antenna Operation, need the high temperature of ability more than 450 DEG C.The bimaleimide resin base composite material that heatproof oxidation performance is high, dielectric properties are excellent is one of a few resin-based materials that can be suitable for, and is widely used in the wideband wave transparent products such as wave transparent window, antenna lid, head-shield, antenna house.But bismaleimide monomer moulding process difference (fusing point is high, poorly soluble, the prepreg that quartz fibre increases dipping obtained is stiff, inviscid, solidification temperature is high), usually there is the defects such as poly-glue, Density inhomogeneity, crackle in pressing, product percent of pass is low, at present only, structure simple product little for mold pressing size, and adopt that reserved to add the method for surplus compared with multimachine shaping more, operation is long, and waste of raw materials is serious, the high and unstable product quality of cost.Along with various technical requirement is more and more higher, product profile becomes increasingly complex, and Wall-Thickness Difference is increasing, and during mold pressing, Resin Flow is poor, and pressing lacks material, wedge angle groove gathers that glue is serious, machine adds difficulty increasing etc. and causes pressing qualification rate very low.
Summary of the invention
Technical problem to be solved by this invention is just to provide the dead size forming method of the effective large scale of a kind of finished product, the dimaleoyl imino wave-penetrating composite material antenna house that abnormally-structured, difference in thickness is large.
For solving the problems of the technologies described above, the dead size forming method of a kind of abnormally-structured wideband wave transparent resin-based antenna house provided by the invention, comprises the following steps:
1) meter takes by ratio of weight and the number of copies: the quartz fibre yarn that the resin-based of the bimaleimide resin of 100 parts, the white carbon of 1 ~ 2 part and 60 ~ 85 parts infiltrates; Not, this is a kind of special quartz fibre.
2) resin toughening: add white carbon in bimaleimide resin, mix;
3) prepare premix: the quartz fibre yarn that resin-based infiltrates is immersed in toughness reinforcing after bimaleimide resin in, be squeezed to dipping evenly, then dry, loose, namely prepare premix; Wherein, this premix is made up of the premix of long fibre shape and the premix of short fiber shape;
4) premix is sheared: premix is cut into the premix of long fibre shape and the premix of short fiber shape; Wherein, the premix length of described short fiber shape is 5 ~ 15mm, and the premix length of described long fibre shape is 30 ~ 50mm;
5) preheated mold: use alcohol and cotton by mold cleaning totally, then at mold cavity surface brush coating release agent, by mould and die preheating to 120 ~ 200 DEG C, insulation 10 ~ 30min, makes mould-cavity temperature even;
6) the premix bed of material of short fiber shape is laid: after mould being cooled to 80 DEG C ± 3 DEG C, insulation 20 ~ 40min, then the premix of short fiber shape is laid on concave die cavity inwall uniformly, and matched moulds compacting, repeat to lay compacting 1 ~ 3 time, again in the premix of the groove uniform filling short fiber shape of concave die cavity, matched moulds compacting, repeats padding and compacting until the premix bed of material surface smoothing of short fiber shape;
7) lay the premix bed of material of long fibre shape: the premix of laying long fibre shape on the premix bed of material surface of short fiber shape, matched moulds compacting, repeats to lay compacting 1 ~ 3 time; Form the premix bed of material of long fibre shape, wherein, the premix layer thickness of long fibre shape is from progressive additive under upper, and maximum gauge difference 15mm;
8) clear dimension compression molding: the die with premix is carried out matched moulds, then is 170 ~ 230 DEG C in temperature, pressure is 7 ~ 23MPa condition compacted under, 3 ~ 8h, the demoulding, obtains abnormally-structured wideband wave transparent resin-based antenna house.
Further, described step 3) in, premix content in premix of short fiber shape is no less than 35%.
Again further, described step 6) and 7) in, laying temperature is 60 ~ 100 DEG C.
Again further, described step 8) in, curing molding condition is: be forced into 7 ~ 23MPa after mould being warming up to 140 ~ 160 DEG C with 0.5 ~ 1.5 DEG C/min speed, 20 ~ 40min is incubated after being warming up to 180 ~ 200 DEG C again, then 200 ~ 220 DEG C of insulation 1 ~ 2h are warming up to, cooling pressurize 1 ~ 2h, natural release after being down to 60 DEG C, 220 ~ 240 DEG C of Post RDBMS 220 ~ 260min.
Large scale of the present invention, the quartz fibre that abnormally-structured, difference in thickness is large strengthen bimaleimide resin base composite material dead size forming method, the resin-based adopted infiltrates formulation quartz fibre, improve the adhesion of quartz fibre and resin, improve the mobility of fiber in resin in solidification temperature-rise period, in resin, add white carbon simultaneously, to resin toughening modification, improve the mobility of resin, to solve in compression molding process that mold cavity is complicated, Resin Flow poor being difficult to fill up mould, product is difficult to one-shot forming, the problem that qualification rate is low.Combine the lay mode of " overall lay+local emphasis is filled " simultaneously, outermost layer lay short fiber, short fiber good fluidity, solve the problem that profile complex product wedge angle groove gathers glue, product wall thickness place increases reinforced lay mode can solve large, the loose quality problems of product different wall place density variation, and internal layer lay long fibre can effectively improve product mechanical property.The molded composite material product that the present invention is shaping, each part interior is closely knit, and product relative density difference controls within 5%.Surface quality is good, without defect such as loose, poly-glue, cavity etc., can solve at present because bimaleimide resin moulded manufacturability difference causes the not high problem of its composite dead size molded product qualification rate and large scale, profile complexity, molded product that wall thickness variation is large to be difficult to dead size formation problems.
Beneficial effect of the present invention is:
1) the present invention is specially adapted to shaping bimaleimide resin base composite material, adopt extraordinary quartz fibre and resin toughening modification to improve the special lay mode of long and short fiber of resin forming manufacturability and " overall lay+local emphasis is filled ", solve large scale, profile complexity, the large molded product of wall thickness variation be difficult to one-shot forming problem.
2) the present invention prepares one-shot forming complex profile pressing, adds, decreases operation, decrease raw-material consumption, reduce cost, improve stock utilization and product quality without the need to machine.Simultaneously easy and simple to handle, be convenient to follow-up production in enormous quantities;
3) one-shot forming complex profile, the surface quality of the large pressing of wall thickness variation and the internal soundness prepared of the present invention is good, and qualification rate is high.
Accompanying drawing explanation
Fig. 1 is that the quartz fibre adopting the inventive method to prepare strengthens bimaleimide resin base composite material antenna house sectional structure schematic diagram;
Fig. 2 is that the quartz fibre adopting the inventive method to prepare strengthens bimaleimide resin base composite material antenna house schematic three dimensional views;
In figure, abnormally-structured wideband wave transparent resin-based antenna house 1, the premix bed of material 2 of short fiber shape, the premix bed of material 3 of long fibre shape.
Detailed description of the invention
In order to explain the present invention better, illustrate main contents of the present invention further below in conjunction with specific embodiment, but content of the present invention is not only confined to following examples.
Embodiment 1
Table 1 product size
Product height overall 130mm
Product is the thickest 12mm
Product is the thinnest 2.5mm
Product maximum outside diameter 280mm
Associative list 1, the dead size forming method of abnormally-structured wideband wave transparent resin-based antenna house 1, comprises the following steps:
1) meter takes by ratio of weight and the number of copies: the quartz fibre yarn that the resin-based of the bimaleimide resin of 100 parts, the white carbon of 2 parts and 75 parts infiltrates;
2) resin toughening: add white carbon in bimaleimide resin, mix;
3) prepare premix: the quartz fibre yarn that resin-based infiltrates is immersed in toughness reinforcing after bimaleimide resin in, be squeezed to dipping evenly, then dry, loose, namely prepare premix; Wherein, this premix is made up of the premix of long fibre shape and the premix of short fiber shape; Premix content in premix of short fiber shape is no less than 35%.
4) premix is sheared: premix is cut into the premix of long fibre shape and the premix of short fiber shape; Wherein, the premix length of described short fiber shape is 5 ~ 15mm, and the premix length of described long fibre shape is 30 ~ 50mm;
5) preheated mold: use alcohol and cotton by mold cleaning totally, then at mold cavity surface brush coating release agent, by mould and die preheating to 150 DEG C, insulation 20min, makes mould-cavity temperature even
6) the premix bed of material 2 of short fiber shape is laid: after mould being cooled to 80 DEG C ± 3 DEG C, insulation 30min, then under temperature is 80 DEG C of conditions, the premix of short fiber shape is laid on uniformly on concave die cavity inwall, and matched moulds compacting, repeat to lay compacting 1 ~ 3 time, then the premix of groove uniform filling short fiber shape at concave die cavity, matched moulds compacting, repeats padding and compacting until the premix bed of material surface smoothing of short fiber shape;
7) lay the premix bed of material 3 of long fibre shape: under temperature is 80 DEG C of conditions, lay the premix of long fibre shape on the premix bed of material 2 surface of short fiber shape, matched moulds compacting, repeat to lay compacting 1 ~ 3 time; Form the premix bed of material 3 of long fibre shape, wherein, the premix bed of material 3 thickness of long fibre shape is from progressive additive under upper;
8) clear dimension compression molding: the die with premix is carried out matched moulds, 18MPa is forced into after mould being warming up to 150 DEG C with 0.5 DEG C/min speed, 30min is incubated after being warming up to 190 DEG C again, then 210 DEG C of insulation 1h are warming up to, cooling pressurize 1h, natural release after being down to 60 DEG C, 230 DEG C of Post RDBMS 230min, the demoulding, obtains abnormally-structured wideband wave transparent resin-based antenna house 1.
Embodiment 2
Table 2 product size
Product height overall 130mm
Product is the thickest 17.5mm
Product is the thinnest 2.5mm
Product maximum outside diameter 280mm
Associative list 2, the dead size forming method of abnormally-structured wideband wave transparent resin-based antenna house 1, comprises the following steps:
1) meter takes by ratio of weight and the number of copies: the quartz fibre yarn that the resin-based of the bimaleimide resin of 100 parts, the white carbon of 1 part and 65 parts infiltrates;
2) resin toughening: add white carbon in bimaleimide resin, mix;
3) prepare premix: the quartz fibre yarn that resin-based infiltrates is immersed in toughness reinforcing after bimaleimide resin in, be squeezed to dipping evenly, then dry, loose, namely prepare premix; Wherein, this premix is made up of the premix of long fibre shape and the premix of short fiber shape; Premix content in premix of short fiber shape is no less than 35%.
4) premix is sheared: premix is cut into the premix of long fibre shape and the premix of short fiber shape; Wherein, the premix length of described short fiber shape is 5 ~ 15mm, and the premix length of described long fibre shape is 30 ~ 50mm;
5) preheated mold: use alcohol and cotton by mold cleaning totally, then at mold cavity surface brush coating release agent, by mould and die preheating to 200 DEG C, insulation 10min, makes mould-cavity temperature even
6) the premix bed of material 2 of short fiber shape is laid: after mould being cooled to 80 DEG C ± 3 DEG C, insulation 30min, then under temperature is 80 DEG C of conditions, the premix of short fiber shape is laid on uniformly on concave die cavity inwall, and matched moulds compacting, repeat to lay compacting 1 ~ 3 time, then the premix of groove uniform filling short fiber shape at concave die cavity, matched moulds compacting, repeats padding and compacting until the premix bed of material surface smoothing of short fiber shape;
7) lay the premix bed of material 3 of long fibre shape: under temperature is 80 DEG C of conditions, lay the premix of long fibre shape on the premix bed of material 2 surface of short fiber shape, matched moulds compacting, repeat to lay compacting 1 ~ 3 time; Form the premix bed of material 3 of long fibre shape, wherein, the premix bed of material 3 thickness of long fibre shape is from progressive additive under upper;
8) clear dimension compression molding: the die with premix is carried out matched moulds, 7MPa is forced into after mould being warming up to 160 DEG C with 1.5 DEG C/min speed, 20min is incubated after being warming up to 200 DEG C again, then 200 DEG C of insulation 2h are warming up to, cooling pressurize 2h, natural release after being down to 60 DEG C, 230 DEG C of Post RDBMS 220min, the demoulding, obtains abnormally-structured wideband wave transparent resin-based antenna house.
Embodiment 3
Table 3 product size
Product height overall 130mm
Product is the thickest 15mm
Product is the thinnest 2.5mm
Product maximum outside diameter 280mm
Associative list 3, the dead size forming method of abnormally-structured wideband wave transparent resin-based antenna house 1, comprises the following steps:
1) meter takes by ratio of weight and the number of copies: the quartz fibre yarn that the resin-based of the bimaleimide resin of 100 parts, the white carbon of 2 parts and 85 parts infiltrates;
2) resin toughening: add white carbon in bimaleimide resin, mix;
3) prepare premix: the quartz fibre yarn that resin-based infiltrates is immersed in toughness reinforcing after bimaleimide resin in, be squeezed to dipping evenly, then dry, loose, namely prepare premix; Wherein, this premix is made up of the premix of long fibre shape and the premix of short fiber shape; Premix content in premix of short fiber shape is no less than 35%.
4) premix is sheared: premix is cut into the premix of long fibre shape and the premix of short fiber shape; Wherein, the premix length of described short fiber shape is 5 ~ 15mm, and the premix length of described long fibre shape is 30 ~ 50mm;
5) preheated mold: use alcohol and cotton by mold cleaning totally, then at mold cavity surface brush coating release agent, by mould and die preheating to 120 DEG C, insulation 30min, makes mould-cavity temperature even
6) the premix bed of material 2 of short fiber shape is laid: after mould being cooled to 80 DEG C ± 3 DEG C, insulation 30min, then under temperature is 80 DEG C of conditions, the premix of short fiber shape is laid on uniformly on concave die cavity inwall, and matched moulds compacting, repeat to lay compacting 1 ~ 3 time, then the premix of groove uniform filling short fiber shape at concave die cavity, matched moulds compacting, repeats padding and compacting until the premix bed of material surface smoothing of short fiber shape;
7) lay the premix bed of material 3 of long fibre shape: under temperature is 80 DEG C of conditions, lay the premix of long fibre shape on the premix bed of material 2 surface of short fiber shape, matched moulds compacting, repeat to lay compacting 1 ~ 3 time; Form the premix bed of material 3 of long fibre shape, wherein, the premix bed of material 3 thickness of long fibre shape is from progressive additive under upper;
8) clear dimension compression molding: the die with premix is carried out matched moulds, 23MPa is forced into after mould being warming up to 150 DEG C with 1.0 DEG C/min speed, 40min is incubated after being warming up to 180 DEG C again, then 220 DEG C of insulation 1h are warming up to, cooling pressurize 1h, natural release after being down to 60 DEG C, 220 DEG C of Post RDBMS 260min, the demoulding, obtains abnormally-structured wideband wave transparent resin-based antenna house.
The raw material used in above-described embodiment is all purchased from market.
The above-mentioned antenna house for preparing is carried out Performance Detection, and index is in table 4
Other unspecified part is prior art.Although above-described embodiment is to invention has been detailed description; but it is only the present invention's part embodiment; instead of whole embodiment, people can also obtain other embodiments according to the present embodiment under without creative prerequisite, and these embodiments all belong to scope.

Claims (4)

1. a dead size forming method for abnormally-structured wideband wave transparent resin-based antenna house, is characterized in that: comprise the following steps:
1) meter takes by ratio of weight and the number of copies: the quartz fibre yarn that the resin-based of the bimaleimide resin of 100 parts, the white carbon of 1 ~ 2 part and 60 ~ 85 parts infiltrates;
2) resin toughening: add white carbon in bimaleimide resin, mix;
3) prepare premix: the quartz fibre yarn that resin-based infiltrates is immersed in toughness reinforcing after bimaleimide resin in, be squeezed to dipping evenly, then dry, loose, namely prepare premix; Wherein, this premix is made up of the premix of long fibre shape and the premix of short fiber shape;
4) premix is sheared: premix is cut into the premix of long fibre shape and the premix of short fiber shape; Wherein, the premix length of described short fiber shape is 5 ~ 15mm, and the premix length of described long fibre shape is 30 ~ 50mm;
5) preheated mold: use alcohol and cotton by mold cleaning totally, then at mold cavity surface brush coating release agent, by mould and die preheating to 120 ~ 200 DEG C, insulation 10 ~ 30min, makes mould-cavity temperature even
6) the premix bed of material of short fiber shape is laid: after mould being cooled to 80 DEG C ± 3 DEG C, insulation 20 ~ 40min, then the premix of short fiber shape is laid on concave die cavity inwall uniformly, and matched moulds compacting, repeat to lay compacting 1 ~ 3 time, again in the premix of the groove uniform filling short fiber shape of concave die cavity, matched moulds compacting, repeats padding and compacting until the premix bed of material surface smoothing of short fiber shape;
7) lay the premix bed of material of long fibre shape: the premix of laying long fibre shape on the premix bed of material surface of short fiber shape, matched moulds compacting, repeats to lay compacting 1 ~ 3 time; Form the premix bed of material of long fibre shape, wherein, the premix layer thickness of long fibre shape is from progressive additive under upper, and maximum gauge difference 15mm;
8) clear dimension compression molding: the die with premix is carried out matched moulds, then is 170 ~ 230 DEG C in temperature, pressure is 7 ~ 23MPa condition compacted under, 3 ~ 8h, the demoulding, obtains abnormally-structured wideband wave transparent resin-based antenna house.
2. the dead size forming method of abnormally-structured wideband wave transparent resin-based antenna house according to claim 1, is characterized in that: described step 3) in, premix content in premix of short fiber shape is no less than 35%.
3. the dead size forming method of abnormally-structured wideband wave transparent resin-based antenna house according to claim 1 or 2, is characterized in that: described step 6) and 7) in, laying temperature is 60 ~ 100 DEG C.
4. the dead size forming method of abnormally-structured wideband wave transparent resin-based antenna house according to claim 1 or 2, it is characterized in that: described step 8) in, curing molding condition is: be forced into 7 ~ 23MPa after mould being warming up to 140 ~ 160 DEG C with 0.5 ~ 1.5 DEG C/min speed, 20 ~ 40min is incubated after being warming up to 180 ~ 200 DEG C again, then 200 ~ 220 DEG C of insulation 1 ~ 2h are warming up to, cooling pressurize 1 ~ 2h, natural release after being down to 60 DEG C, 220 ~ 240 DEG C of Post RDBMS 220 ~ 260min.
CN201410525147.2A 2014-09-30 2014-09-30 Preparation method of broadband wave-transmission resin based radome with irregular structure Pending CN104441678A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410525147.2A CN104441678A (en) 2014-09-30 2014-09-30 Preparation method of broadband wave-transmission resin based radome with irregular structure

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410525147.2A CN104441678A (en) 2014-09-30 2014-09-30 Preparation method of broadband wave-transmission resin based radome with irregular structure

Publications (1)

Publication Number Publication Date
CN104441678A true CN104441678A (en) 2015-03-25

Family

ID=52888791

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410525147.2A Pending CN104441678A (en) 2014-09-30 2014-09-30 Preparation method of broadband wave-transmission resin based radome with irregular structure

Country Status (1)

Country Link
CN (1) CN104441678A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105130483A (en) * 2015-06-12 2015-12-09 湖北三江航天江北机械工程有限公司 Composite quartz ceramic radome body compression molding method and dedicated compression mold
CN105172165A (en) * 2015-09-14 2015-12-23 江西洪都航空工业集团有限责任公司 Thickness correcting method for millimeter wave antenna housing
CN106393733A (en) * 2016-12-01 2017-02-15 江西洪都航空工业集团有限责任公司 Manufacturing method of solid wall composite material radar cover
CN107244082A (en) * 2016-10-26 2017-10-13 上海无线电设备研究所 A kind of forming method of thin-walled Varying-thickness composite antenna housing
CN107866985A (en) * 2016-09-23 2018-04-03 通用汽车环球科技运作有限责任公司 The part and its manufacture method moulded with moldable carbon fiber
US10612163B2 (en) 2017-08-24 2020-04-07 GM Global Technology Operations LLC Modification of continuous carbon fibers during precursor formation for composites having enhanced moldability
US10941510B2 (en) 2017-12-08 2021-03-09 GM Global Technology Operations LLC Equipment for perforated pre-impregnated reinforcement materials
CN112549580A (en) * 2020-11-16 2021-03-26 航天特种材料及工艺技术研究所 Method for forming fiber reinforced resin matrix composite material antenna housing
CN113696510A (en) * 2021-09-26 2021-11-26 北京海利天梦科技有限公司 Machining process for heat shield
CN113787735A (en) * 2021-11-15 2021-12-14 北京玻钢院复合材料有限公司 Composite material grid product and preparation method thereof
US11498318B2 (en) 2019-12-05 2022-11-15 GM Global Technology Operations LLC Class-A components comprising moldable carbon fiber

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070292674A1 (en) * 2006-06-15 2007-12-20 Innegrity, Llc Composite materials including amorphous thermoplastic fibers
CN103313830A (en) * 2010-11-17 2013-09-18 阿克马法国公司 Method for producing fibrous materials pre-impregnated with a thermohardenable polymer
CN103936390A (en) * 2014-02-21 2014-07-23 湖北三江航天江北机械工程有限公司 Preparation method of phosphate composite material radome body

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070292674A1 (en) * 2006-06-15 2007-12-20 Innegrity, Llc Composite materials including amorphous thermoplastic fibers
CN103313830A (en) * 2010-11-17 2013-09-18 阿克马法国公司 Method for producing fibrous materials pre-impregnated with a thermohardenable polymer
CN103936390A (en) * 2014-02-21 2014-07-23 湖北三江航天江北机械工程有限公司 Preparation method of phosphate composite material radome body

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
张强: "《天线罩理论与设计方法》", 31 January 2014, 国防工业出版社 *
王文广等: "《塑料材料的选用 第二版》", 31 March 2007, 化学工业出版社 *
胡保全等: "《先进复合材料 第2版》", 31 May 2013, 国防工业出版社 *
黄家康等: "《玻璃钢模压成型工艺》", 31 August 1982, 中国建筑工业出版社 *

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105130483B (en) * 2015-06-12 2018-03-09 湖北三江航天江北机械工程有限公司 Compound quartz pottery antenna covering cover body compression-molding method and its special compression mould
CN105130483A (en) * 2015-06-12 2015-12-09 湖北三江航天江北机械工程有限公司 Composite quartz ceramic radome body compression molding method and dedicated compression mold
CN105172165A (en) * 2015-09-14 2015-12-23 江西洪都航空工业集团有限责任公司 Thickness correcting method for millimeter wave antenna housing
CN107866985B (en) * 2016-09-23 2020-10-23 通用汽车环球科技运作有限责任公司 Parts moulded with mouldable carbon fibres and method for manufacturing same
CN107866985A (en) * 2016-09-23 2018-04-03 通用汽车环球科技运作有限责任公司 The part and its manufacture method moulded with moldable carbon fiber
CN107244082A (en) * 2016-10-26 2017-10-13 上海无线电设备研究所 A kind of forming method of thin-walled Varying-thickness composite antenna housing
CN107244082B (en) * 2016-10-26 2019-10-18 上海无线电设备研究所 A kind of forming method of thin-walled Varying-thickness composite antenna housing
CN106393733A (en) * 2016-12-01 2017-02-15 江西洪都航空工业集团有限责任公司 Manufacturing method of solid wall composite material radar cover
US10612163B2 (en) 2017-08-24 2020-04-07 GM Global Technology Operations LLC Modification of continuous carbon fibers during precursor formation for composites having enhanced moldability
US10941510B2 (en) 2017-12-08 2021-03-09 GM Global Technology Operations LLC Equipment for perforated pre-impregnated reinforcement materials
US11498318B2 (en) 2019-12-05 2022-11-15 GM Global Technology Operations LLC Class-A components comprising moldable carbon fiber
CN112549580A (en) * 2020-11-16 2021-03-26 航天特种材料及工艺技术研究所 Method for forming fiber reinforced resin matrix composite material antenna housing
CN112549580B (en) * 2020-11-16 2022-06-10 航天特种材料及工艺技术研究所 Method for forming fiber reinforced resin matrix composite material antenna housing
CN113696510A (en) * 2021-09-26 2021-11-26 北京海利天梦科技有限公司 Machining process for heat shield
CN113696510B (en) * 2021-09-26 2023-01-24 北京海利天梦科技有限公司 Machining process for heat shield
CN113787735A (en) * 2021-11-15 2021-12-14 北京玻钢院复合材料有限公司 Composite material grid product and preparation method thereof

Similar Documents

Publication Publication Date Title
CN104441678A (en) Preparation method of broadband wave-transmission resin based radome with irregular structure
CN102416677B (en) Die for building materials products and preparation method thereof
CN102294830B (en) Method for manufacturing thermoplastic fibre reinforced building template
CN107199713A (en) A kind of high-quality forming method of composite material bracket
CN105619841A (en) Forming method for thermoplastic composite material
CN213056086U (en) Forming die of unmanned aerial vehicle combined material spare part
CN104162996A (en) A manufacturing process of a carbon-fibre composite material U-shaped part
CN110861318A (en) Carbon fiber automobile front floor compression molding method
CN104552677A (en) Manufacturing process of composite material die for autoclave
CN107214975B (en) A kind of simulation coating rapid shaping wet process mould pressing process
CN107214980A (en) A kind of quick molding method of thermoplastic fiber reinforced composite board
CN103589137A (en) Quickly molded polyurethane and hemp fiber composite plate based on HP-RTM (high pressure-resin transfer molding) technology
CN108864995B (en) Multi-axial composite material bent pipe and preparation method thereof
CN104690985A (en) Fan blade manufacturing technology based on die pressing method
CN101920562A (en) Clear dimension compression molding method for phenolic resin based complex profile product
CN102248685A (en) Forming method of glass fiber reinforced plastic (GFRP)
CN104816487A (en) Fan blade manufacturing process based on internal pressure method
CN105948620A (en) Method for preparing glass fiber cement felt
CN106584994A (en) Glass fiber reinforced plastic gel-coated plate and preparation method thereof
CN104801026A (en) Baseball bat production method
CN104690987A (en) Draught fan blade manufacturing process based on RTM
CN104801027A (en) Manufacture method for baseball bat
CN204820374U (en) Glass steel mould pressing flange
CN104175574A (en) SMC material molding process
CN106584890A (en) Efficient preparation method of intercity track composite material vehicle door

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20150325